CN110000329A - Formwork curing agent for model casting - Google Patents

Formwork curing agent for model casting Download PDF

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Publication number
CN110000329A
CN110000329A CN201910402016.8A CN201910402016A CN110000329A CN 110000329 A CN110000329 A CN 110000329A CN 201910402016 A CN201910402016 A CN 201910402016A CN 110000329 A CN110000329 A CN 110000329A
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CN
China
Prior art keywords
water
prodan
curing agent
weight
formwork
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Application number
CN201910402016.8A
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Chinese (zh)
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CN110000329B (en
Inventor
庄合义
庄朝勇
唐文国
董树东
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TIANJIN RONGHENG GROUP CO Ltd
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TIANJIN RONGHENG GROUP CO Ltd
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Priority to CN201910402016.8A priority Critical patent/CN110000329B/en
Publication of CN110000329A publication Critical patent/CN110000329A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/02Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives
    • B22C1/10Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives for influencing the hardening tendency of the mould material

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Mold Materials And Core Materials (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention is the formwork curing agent for model casting, is made of the raw material of following parts by weight: six water crystallization aluminium chloride 10-15;Prodan 10-15;Two water tablets shape calcium chloride 15-20;Isopropanol 0.1-1.5;Anhydrous boric acid 1.2-1.8;Clear water 55-75.Prodan, which has waterglass, significantly promotees hard effect, especially cooperates its effect to become apparent with bleeding agent isopropanol.The use of prodan can reduce the dosage of two water tablets shape calcium chloride, and remaining the Na2O in shell hardening process significantly reduces, therefore hot strength of investment shell and wet strength significantly increase, and can guarantee casting dimension accuracy.

Description

Formwork curing agent for model casting
Technical field
The present invention relates to a kind of formwork curing agents for model casting.
Background technique
Precision-investment casting industry mostly uses waterglass for binder, and a kind of common formwork curing agent is by six water crystallizations Aluminium chloride, two water tablets shape calcium chloride, anhydrous boric acid, bleeding agent and clear water prepare composition in proportion, wherein bleeding agent be JFC or One kind of X405 or wins-8010, the formwork curing agent also contain wetting agent S1003 or SR-2.
Above-mentioned curing agent is using six water crystallization aluminium chloride and two water tablets shape calcium chloride as major ingredient, although overcoming using ammonium chloride Haves the defects that severe exacerbation working condition, but there are larger amount of Na2O is residual in formwork hardening process for two water tablets shape calcium chloride It stays, which reduce formwork elevated temperature strength and wet strength, thereby reduces casting dimension accuracy.
Summary of the invention
The purpose of the present invention is to solve using six water crystallization aluminium chloride and two water tablets shape calcium chloride as the curing agent of major ingredient Existing above-mentioned technical problem and a kind of formwork curing agent for model casting is disclosed.
Formwork curing agent of the invention is made of the raw material of following parts by weight: six water crystallization aluminium chloride 10-15;Prodan 10-15;Two water tablets shape calcium chloride 15-20;Isopropanol 0.1-1.5;Anhydrous boric acid 1.2-1.8;Clear water 55-75.
The present invention is for the curing agent in quartz sand, waterglass formwork solidification process, wherein six water crystallization aluminium chloride Effect is the intensity to enhance formwork, since six water crystallization aluminium reaction speed are slow, formwork in hardening process with Waterglass neutralizes mutually and promotes to hydrolyze, and waterglass pH value is made gradually to decline and Silica hydrogel is precipitated, while six water crystallization aluminium chloride PH value be stepped up, by hydrolytic-polymeric reaction be precipitated AL (OH) 3 alumina gel, formed silica gel coagulated altogether with alumina gel, so mould Shell intensity is high.
The chilled aqueous solution of prodan is in neutrality, and hydrothermal solution has waterglass and significantly promote hard effect, especially in alkalinity Its effect is cooperated to become apparent with bleeding agent isopropanol.
The use of prodan can reduce the dosage of two water tablets shape calcium chloride, make the Na in formwork hardening process2O residual It significantly reduces, therefore formwork elevated temperature strength and wet strength significantly increase, and can guarantee casting dimension accuracy.
The present invention is protected with above-mentioned removed compared with the curing agent of major ingredient using six water crystallization aluminium chloride and two water tablets shape calcium chloride Hold working condition etc. be improved significantly it is outer also have the following characteristics that prodan and isopropanol accelerate formwork setting rate, This curing agent rises intensity of the formwork when hardening 5 minutes obviously, and aforementioned 15 clock of curing agent can be reached when hardening 10 minutes Hardening effect, not only shorten the formwork production cycle, also make dewaxing roast after formwork dimensional accuracy be significantly increased, in turn Casting qualified rate is increased to 94-96% by original 89-92%, increases economic benefit.
Specific embodiment
The present invention is further illustrated below with reference to embodiment.
Feed quality requirements: six water crystallization aluminium chloride, content are greater than 90%;Prodan, content are greater than 97%;Two water tablets Shape calcium chloride, content are greater than 72%;Isopropanol, concentration 99%;Anhydrous boric acid, content are greater than 98%;Clear water.
Embodiment 1
Raw material is in parts by weight: taking six water crystallization aluminium chloride, 15 parts by weight, 10 parts by weight of prodan, two water tablets shape chlorination 20 parts by weight of calcium, 0.1 parts by weight of isopropanol, 1.8 parts by weight of anhydrous boric acid.
75 parts by weight of injected clear water (room temperature) in stirring pool, sequentially add above-mentioned raw materials and continuously stir 30 points under stirring It shuts down after clock, is poured into big tank through corrosion protection pump, melting reaction uses after 2 hours, curing agent pH value 7-7.3.
Embodiment 2
Raw material is in parts by weight: taking six water crystallization aluminium chloride, 12 parts by weight, 13 parts by weight of prodan, two water tablets shape chlorination 17 parts by weight of calcium, 1 parts by weight of isopropanol, 1.5 parts by weight of anhydrous boric acid.
65 parts by weight of injected clear water (room temperature) in stirring pool, sequentially add above-mentioned raw materials and continuously stir 30 points under stirring It shuts down after clock, is poured into big tank through corrosion protection pump, melting reaction uses after 2 hours, curing agent pH value 7.1-7.4.
Embodiment 3
Raw material is in parts by weight: taking six water crystallization aluminium chloride, 10 parts by weight, 15 parts by weight of prodan, two water tablets shape chlorination 15 parts by weight of calcium, 1.5 parts by weight of isopropanol, 1.2 parts by weight of anhydrous boric acid.
55 parts by weight of injected clear water (room temperature) in stirring pool, sequentially add above-mentioned raw materials and continuously stir 30 points under stirring It shuts down after clock, is poured into big tank through corrosion protection pump, melting reaction uses after 2 hours, curing agent pH value 7.3-7.4.

Claims (1)

1. being used for the formwork curing agent of model casting, it is characterised in that be made of the raw material of following parts by weight: six water crystallization chlorinations Aluminium 10-15;Prodan 10-15;Two water tablets shape calcium chloride 15-20;Isopropanol 0.1-1.5;Anhydrous boric acid 1.2-1.8;Clear water 55-75。
CN201910402016.8A 2019-05-15 2019-05-15 Formwork hardener for investment casting Active CN110000329B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910402016.8A CN110000329B (en) 2019-05-15 2019-05-15 Formwork hardener for investment casting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910402016.8A CN110000329B (en) 2019-05-15 2019-05-15 Formwork hardener for investment casting

Publications (2)

Publication Number Publication Date
CN110000329A true CN110000329A (en) 2019-07-12
CN110000329B CN110000329B (en) 2021-07-20

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101362190A (en) * 2008-09-28 2009-02-11 上海应用技术学院 Composite curing method of sodium silicate binder
CN102133614A (en) * 2010-01-25 2011-07-27 襄樊市科民化工科技有限公司 Formwork curing agent and production method thereof
CN103102119A (en) * 2011-11-10 2013-05-15 比亚迪股份有限公司 Hardening agent and preparation method thereof
CN103212666A (en) * 2013-04-03 2013-07-24 沈阳汇亚通铸造材料有限责任公司 Slurry-shaped inorganic enhancing agent for casting sodium silicate self-hardening sand and preparation method thereof
CN103658522A (en) * 2013-12-24 2014-03-26 江苏丰泽生物工程设备制造有限公司 Precision casting technology for small type fermentation tank
CN104226890A (en) * 2014-09-30 2014-12-24 济南圣泉集团股份有限公司 Sodium silicate reinforcing agent for casting and preparation method
CN104525847A (en) * 2014-12-22 2015-04-22 南京优耐特精密机械制造有限公司 Shell hardening agent
CN105312486A (en) * 2015-10-20 2016-02-10 天津荣亨集团股份有限公司 Shuttering hardening agents
CN105347727A (en) * 2015-11-26 2016-02-24 自贡格灵新材料科技有限公司 High-permeability liquid hardening agent
CN107931515A (en) * 2017-12-18 2018-04-20 定远县宝隆机械制造有限公司 A kind of investment casting formwork composite hardening agent prescription
CN108145091A (en) * 2017-12-18 2018-06-12 定远县宝隆机械制造有限公司 A kind of case hardening agent prescription of model casting

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101362190A (en) * 2008-09-28 2009-02-11 上海应用技术学院 Composite curing method of sodium silicate binder
CN102133614A (en) * 2010-01-25 2011-07-27 襄樊市科民化工科技有限公司 Formwork curing agent and production method thereof
CN103102119A (en) * 2011-11-10 2013-05-15 比亚迪股份有限公司 Hardening agent and preparation method thereof
CN103212666A (en) * 2013-04-03 2013-07-24 沈阳汇亚通铸造材料有限责任公司 Slurry-shaped inorganic enhancing agent for casting sodium silicate self-hardening sand and preparation method thereof
CN103658522A (en) * 2013-12-24 2014-03-26 江苏丰泽生物工程设备制造有限公司 Precision casting technology for small type fermentation tank
CN104226890A (en) * 2014-09-30 2014-12-24 济南圣泉集团股份有限公司 Sodium silicate reinforcing agent for casting and preparation method
CN104525847A (en) * 2014-12-22 2015-04-22 南京优耐特精密机械制造有限公司 Shell hardening agent
CN105312486A (en) * 2015-10-20 2016-02-10 天津荣亨集团股份有限公司 Shuttering hardening agents
CN105347727A (en) * 2015-11-26 2016-02-24 自贡格灵新材料科技有限公司 High-permeability liquid hardening agent
CN107931515A (en) * 2017-12-18 2018-04-20 定远县宝隆机械制造有限公司 A kind of investment casting formwork composite hardening agent prescription
CN108145091A (en) * 2017-12-18 2018-06-12 定远县宝隆机械制造有限公司 A kind of case hardening agent prescription of model casting

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
徐庆柏: "《铸造文集》", 31 January 2016, 合肥工业大学出版社 *

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