CN109999647A - Eliminate chimney white cigarette system in coal-burning power plant - Google Patents

Eliminate chimney white cigarette system in coal-burning power plant Download PDF

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Publication number
CN109999647A
CN109999647A CN201910276371.5A CN201910276371A CN109999647A CN 109999647 A CN109999647 A CN 109999647A CN 201910276371 A CN201910276371 A CN 201910276371A CN 109999647 A CN109999647 A CN 109999647A
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CN
China
Prior art keywords
flue gas
chimney
coal
type heat
condenser
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910276371.5A
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Chinese (zh)
Inventor
吴江
刘志强
肖怡萱
何平
贾焘
周敏
马昕霞
赵晓燕
邹建术
吴嘉曦
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Shanghai University of Electric Power
University of Shanghai for Science and Technology
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Shanghai University of Electric Power
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Priority to CN201910276371.5A priority Critical patent/CN109999647A/en
Publication of CN109999647A publication Critical patent/CN109999647A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/80Semi-solid phase processes, i.e. by using slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Chimneys And Flues (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of coal-burning power plants to eliminate chimney white cigarette system, including electrostatic precipitator, wet desulphurization device, water pump, cooler, tail flue gas condenser, recycling pond, chimney, electrostatic precipitator one end connects smoke inlet pipe, the other end connects chimney by wet desulphurization device, tail flue gas condenser, the tail flue gas condenser connection recycling pond, tail flue gas condenser connects water pump, cooler forms cooling medium circuit.It is mingled with the flue gas of a large amount of vapor when by tail flue gas condenser, since temp-difference condensing acts on the vapor in condensable most of flue gas, the saline pollution object being dissolved in vapor is removed simultaneously, the system can play the purpose for eliminating throat white cigarette, and flue gas saline pollution object content is reduced simultaneously, flue gas emission cleanliness is substantially improved.Wall type heat exchanger media temperature among condenser is reduced using cooler, so that cooling medium and the flue gas heat exchange temperature difference increase, can be good at carrying out flue gas condensing, improve condensation efficiency.

Description

Eliminate chimney white cigarette system in coal-burning power plant
Technical field
The present invention relates to a kind of coal-burning power plant's tail flue gas processing system, especially a kind of coal-burning power plant that is applied to eliminates cigarette Chimney white cigarette system.
Background technique
China is consumption of coal big country, and thermoelectricity consumption coal accounts for 47% or so of coal aggregate consumption, and caused by coal burning Air pollution problems inherent is increasingly serious, and should adopt an effective measure makes coal-burning power plant's emission reach constantly raised environmental protection mark It is quasi-.The Limestone-gypsum Wet Flue Gas Desulfurization Process that major part coal-burning power plant uses at present will lead to humidity of flue gas increase, easily in throat Form white cigarette.This has seriously affected the fear phychology of environmental visual and nearby residents.Therefore, it reduces in coal-burning power plant's discharge flue gas A large amount of white cigarettes that the saline pollution object and chimney breast being mingled with are formed have critically important meaning.
Summary of the invention
Object of the present invention is to solve the above problems, and providing a kind of coal-burning power plant and eliminating chimney white cigarette system, the system The white cigarette of coal-burning power plant's chimney outlet can not only be reduced, moreover it is possible to flue gas salt content is reduced, to mitigate flue gas emission to ring The influence in border.
The purpose of the present invention is achieved through the following technical solutions:
A kind of coal-burning power plant eliminates chimney white cigarette system, including electrostatic precipitator, wet desulphurization device, water pump, cooler, Tail flue gas condenser, recycling pond, chimney, described electrostatic precipitator one end connect smoke inlet pipe, and the other end passes through wet process Desulfurizer, tail flue gas condenser connect chimney, the tail flue gas condenser connection recycling pond, the tail portion cigarette Gas condenser connects water pump, cooler forms cooling medium circuit.
Further, the tail flue gas condenser includes gas inlet pipeline, dividing wall type heat exchanger, condensing hot air furnace dress It sets, exhanst gas outlet pipeline, the dividing wall type heat exchanger and water pump, cooler form circulation loop, the condensate water recovery device Below dividing wall type heat exchanger, and connect recycling pond.
Further, described dividing wall type heat exchanger one end connects coal-fired plant flue gas discharge outlet by gas inlet pipeline, The other end connects chimney by exhanst gas outlet pipeline.
Further, exhanst gas outlet pipeline is set above the dividing wall type heat exchanger, and passes through exhanst gas outlet pipeline and cigarette Chimney connection;State dividing wall type heat exchanger into flue gas mouth connect gas inlet pipeline.
Further, cooling medium carries out condensing heat-exchange by dividing wall type heat exchanger and flue gas, cooling Jie heated up after heat exchange Matter is cooled down using cooler, then by water pump boosting be again fed to dividing wall type heat exchanger carry out condensation change Heat forms cooling circuit, and generated condensed water is recycled to recycling pond by condensate water recovery device, finally again by recycle-water It send to water treatment system and is handled.
The beneficial effects of the present invention are:
1. reducing exhaust gas temperature using condensing heat-exchange in tail flue gas part makes Water vapor condensation Cheng Shui in flue gas simultaneously, Dissolution simultaneously condenses together with the salt in vapor also companion vapor into condensed water, reduces the salt in the flue gas of discharge The white plume phenomenon that flue gas is formed in throat can be effectively reduced in class and water capacity, reduces discharge flue gas to the shadow of environment It rings.
2. wall type heat exchanger media temperature among condenser is reduced using cooler, so that cooling medium and flue gas heat exchange temperature Difference increases, and can be good at carrying out flue gas condensing, improves condensation efficiency.
3. being mingled with a large amount of salts in the condensed water formed after brackish water steam liquefied in flue gas, can be filled subsequently through processing Extraction salt is set, wherein salt can be used for other industrial uses, and purified water can be used for power plant's addition water or other purposes.
4. present system is reasonable in design, initial investment is small, easy to operate, easy to maintain, is conducive to large-scale promotion And implementation.
Detailed description of the invention
Fig. 1 is one structural schematic diagram of embodiment that coal-burning power plant of the invention eliminates chimney white cigarette system;
Fig. 2 is the heat exchanging part structural schematic diagram of the tail flue gas condenser in embodiment one;
Fig. 3 is two structural schematic diagram of embodiment that coal-burning power plant of the invention eliminates chimney white cigarette system;
Fig. 4 is the heat exchanging part structural schematic diagram of the tail flue gas condenser in embodiment two.
In figure: 1- electrostatic precipitator, 2- wet desulphurization device, 3- water pump, 4- cooler, 5- tail flue gas condenser, 6- Recycle pond, 7- chimney, 21- gas inlet pipeline, 22- dividing wall type heat exchanger, 23- exhanst gas outlet pipeline, 24- condensing hot air furnace Device.
Specific embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment one:
As shown in Figure 1, a kind of device for eliminating chimney white cigarette applied to coal-burning power plant, including electrostatic precipitator 1, wet process are de- Sulphur device 2, water pump 3, cooler 4, tail flue gas condenser 5, recycling pond 6 and chimney 7.
Exhanst gas outlet passes sequentially through electrostatic precipitator 1, wet desulphurization device 2, tail flue gas condenser 5 and connects chimney 7.Water Pump 3, cooler 4 and tail flue gas condenser 5 form cooling medium circuit.It recycles pond 6 and is set to 5 bottom of tail flue gas condenser Portion is ultimately connected to water treatment system.
As shown in Fig. 2, the tail flue gas condenser 5 for condensing flue gas includes gas inlet pipeline 21, wall-type heat exchange Device 22, exhanst gas outlet pipeline 23 and condensate water recovery device 24.Wherein dividing wall type heat exchanger 22 is followed with water pump 3, the composition of cooler 4 Loop back path, water pump 3 give circulation power.22 one end of dividing wall type heat exchanger connects coal-fired plant flue gas by gas inlet pipeline 21 Discharge outlet, the other end connect chimney 7 by exhanst gas outlet pipeline 23.Condensate water recovery device 24 is set under dividing wall type heat exchanger 22 It simultaneously collects condensed water and send condensed water to recycling pond 6 in side.
Implement two:
As shown in figure 3, a kind of elimination white cigarette device for being mounted on thermal power plant's chimney, including electrostatic precipitator 1, wet desulphurization Device 2, water pump 3, cooler 4, tail flue gas condenser 5, recycling pond 6 and chimney 7.Electrostatic precipitator 1, wet desulphurization device 2, tail flue gas condenser 5 and chimney 7 are sequentially communicated.Chimney 7 is placed in 5 top of tail flue gas condenser.Flue gas 7 passes sequentially through quiet Electric precipitator 1, wet desulphurization device 2, tail flue gas condenser 5 and chimney 7.Cooling medium circuit is by water pump 3,4 and of cooler Tail flue gas condenser 5 forms.It recycles pond 6 and is set to 5 bottom of tail flue gas condenser, be ultimately connected to water treatment system.
As shown in figure 4, tail flue gas condenser 5 includes gas inlet pipeline 21, dividing wall type heat exchanger 22, smoke outlet tube Road 23 and condensate water recovery device 24.Wherein dividing wall type heat exchanger 22 connect composition circulation loop, water pump with water pump 3, cooler 4 3 give circulation power.Condensate water recovery device 24 is set to 22 lower section of dividing wall type heat exchanger and collects condensed water and send condensed water To recycling pond 6.Exhanst gas outlet pipeline 23 is set above dividing wall type heat exchanger 22, and passes through exhanst gas outlet pipeline 23 and chimney 7 Connection;Dividing wall type heat exchanger 22 connects gas inlet pipeline 21 into flue gas mouth.
Power-plant flue gas treatment process are as follows: flue gas carries out flue gas ash removal by electrostatic precipitator, then passes through wet desulphurization device Flue gas desulfurization is carried out, flue gas desulfurization device is mostly the empty tower structure of countercurrent spray, and flue gas connects with the desulfurization slurry in absorption tower Touching, the technique increase humidity of flue gas while desulfurization, and exhaust gas temperature reduces, and flue gas is slow during chimney is soaring Cooling eventually leads to and forms a large amount of white plumes under dew point in chimney outlet flue-gas temperature.The present apparatus is in wet desulphurization Dividing wall type heat exchanger device is added between device and chimney, so that flue gas carries out condensing heat-exchange in the part, so that flue gas is at this Temperature, which reaches, under device is condensed into water under dew-point temperature, since solubility of the salts substances in vapor is far below in water Solubility, the flue gas containing a large amount of vapor has also taken away the dissolution of a large amount of scripts at this time during being condensed into water in this section Salts substances in flue gas vapor reduce chimney so that the content of vapor and salts substances has decline in flue gas The content of saline pollution object in the flue gas of discharge, simultaneously because in flue gas vapor reduction, be also not easy to be formed in chimney breast A large amount of white plumes, are conducive to the misgivings for giving up the people to flue gas emission, improve coal-fired plant flue gas and discharge cleanliness.
Referring to Fig.2,4, in tail flue gas condenser, cooling medium carries out condensation with flue gas by dividing wall type heat exchanger and changes Heat, the cooling medium to heat up after heat exchange are cooled down using cooler, after by water pump boosting be again fed to partition Formula heat exchanger carries out condensing heat-exchange, forms cooling circuit.The condensed water of generation is recycled to recycle-water by condensate water recovery device Recycle-water is finally sent to water treatment system again and is handled by pond.
The present invention is causing humidity of flue gas to increase compared to existing ubiquitous system, tail flue gas after wet desulphurization device Add, if direct emission atmosphere, vapor condenses to form largely white plumes, to eliminate this phenomenon, adds after wet desulphurization device The heat pipe for condensing flue gas is filled, after carrying out heat exchange with cryogenic media most of wet flue gas is condensed Cheng Shui since the solubility of flue gas salinity in water is greater than the solubility in vapor, therefore is also carried a large amount of in condensed water Flue gas saline pollution object so that achieve the purpose that reduce flue gas in salt content.Simultaneously because water capacity declines in flue gas, discharge The flue gas of chimney is also not easy to form a large amount of white plumes in throat out, gives up the people to the misgivings of flue gas emission, improves Coal-fired plant flue gas discharges cleanliness.
The above purport example of implementing is to describe specific implementation process of the invention, main feature and advantage.It should be pointed out that this hair It is bright not limited by above-described embodiment.Under general principles and spirit, the improvement or retouching done are accordingly to be regarded as the present invention Protection scope.

Claims (5)

1. a kind of coal-burning power plant eliminates chimney white cigarette system, including electrostatic precipitator, wet desulphurization device, water pump, cooler, tail Portion's flue gas condenser, recycling pond, chimney, it is characterised in that: described electrostatic precipitator one end connects smoke inlet pipe, the other end Chimney, the tail flue gas condenser connection recycling pond, institute are connected by wet desulphurization device, tail flue gas condenser State tail flue gas condenser connection water pump, cooler composition cooling medium circuit.
2. coal-burning power plant according to claim 1 eliminates chimney white cigarette system, it is characterised in that: the tail flue gas is cold Condenser includes gas inlet pipeline, dividing wall type heat exchanger, condensate water recovery device, exhanst gas outlet pipeline, the wall-type heat exchange Device and water pump, cooler form circulation loop, and the condensate water recovery device is set to below dividing wall type heat exchanger, and connects recycling Pond.
3. coal-burning power plant according to claim 2 eliminates chimney white cigarette system, it is characterised in that: the wall-type heat exchange Device one end connects coal-fired plant flue gas discharge outlet by gas inlet pipeline, and the other end connects chimney by exhanst gas outlet pipeline.
4. coal-burning power plant according to claim 2 eliminates chimney white cigarette system, it is characterised in that: the wall-type heat exchange Exhanst gas outlet pipeline is set above device, and is connect by exhanst gas outlet pipeline with chimney;The dividing wall type heat exchanger is into flue gas mouth Connect gas inlet pipeline.
5. coal-burning power plant according to claim 3 or 4 eliminates chimney white cigarette system, it is characterised in that: cooling medium passes through Dividing wall type heat exchanger and flue gas carry out condensing heat-exchange, and the cooling medium to heat up after heat exchange is cooled down using cooler, Then dividing wall type heat exchanger is again fed to by water pump boosting and carries out condensing heat-exchange, form cooling circuit, generated condensation Water is recycled to recycling pond by condensate water recovery device, finally again send recycle-water to water treatment system and handles.
CN201910276371.5A 2019-04-08 2019-04-08 Eliminate chimney white cigarette system in coal-burning power plant Pending CN109999647A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110801705A (en) * 2019-11-29 2020-02-18 西安交通大学 White smoke eliminating device based on smoke condensation and chemical adsorption
CN111443155A (en) * 2020-03-18 2020-07-24 上海创蓝检测技术有限公司 Off-line testing method for discharge amount of soluble salt in wet desulphurization flue gas of power plant

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101881387B1 (en) * 2017-09-22 2018-07-24 이호승 Apparatus for eliminating white-smoke
CN109529583A (en) * 2018-12-20 2019-03-29 大唐环境产业集团股份有限公司 UTILIZATION OF VESIDUAL HEAT IN is discarded for coal-burning power plant and eliminates the device and method of chimney white cigarette

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101881387B1 (en) * 2017-09-22 2018-07-24 이호승 Apparatus for eliminating white-smoke
CN109529583A (en) * 2018-12-20 2019-03-29 大唐环境产业集团股份有限公司 UTILIZATION OF VESIDUAL HEAT IN is discarded for coal-burning power plant and eliminates the device and method of chimney white cigarette

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110801705A (en) * 2019-11-29 2020-02-18 西安交通大学 White smoke eliminating device based on smoke condensation and chemical adsorption
CN110801705B (en) * 2019-11-29 2021-03-12 西安交通大学 White smoke eliminating device based on smoke condensation and chemical adsorption
CN111443155A (en) * 2020-03-18 2020-07-24 上海创蓝检测技术有限公司 Off-line testing method for discharge amount of soluble salt in wet desulphurization flue gas of power plant

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Application publication date: 20190712

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