CN109988460A - Colourless the coating of drafting ink and its security purposes - Google Patents
Colourless the coating of drafting ink and its security purposes Download PDFInfo
- Publication number
- CN109988460A CN109988460A CN201910327580.8A CN201910327580A CN109988460A CN 109988460 A CN109988460 A CN 109988460A CN 201910327580 A CN201910327580 A CN 201910327580A CN 109988460 A CN109988460 A CN 109988460A
- Authority
- CN
- China
- Prior art keywords
- colourless
- coating
- drafting
- drafting ink
- starch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 238000000576 coating method Methods 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000006184 cosolvent Substances 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- 239000002250 absorbent Substances 0.000 claims abstract description 9
- 239000008107 starch Substances 0.000 claims abstract description 9
- 235000019698 starch Nutrition 0.000 claims abstract description 9
- 230000002745 absorbent Effects 0.000 claims abstract description 8
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
- 229920002785 Croscarmellose sodium Polymers 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims 1
- MJEMIOXXNCZZFK-UHFFFAOYSA-N ethylone Chemical compound CCNC(C)C(=O)C1=CC=C2OCOC2=C1 MJEMIOXXNCZZFK-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 10
- 238000005213 imbibition Methods 0.000 abstract description 6
- 239000004033 plastic Substances 0.000 abstract description 6
- 229920003023 plastic Polymers 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000009965 odorless effect Effects 0.000 abstract description 5
- 238000003854 Surface Print Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 2
- 238000007639 printing Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of colourless the coating of drafting ink and its security purposes, belong to field of anti-counterfeit technology.The colourless the coating of drafting ink is adequately mixed liquid made of dissolving each other as water soluble acrylic resin, super absorbent resin, starch, pure water and hydrophilic cosolvent.In mass, water soluble acrylic resin 4-5%, super absorbent resin 2-3%, hydrophilic cosolvent 6-7%, starch 17-20%, pure water surplus.Colourless the coating of drafting ink colorless and odorless provided by the invention, good in the material surface printing effect of the water imbibitions such as plastics, art paper, smooth millboard difference, attachment fastness is strong, can sufficiently realize antiforge function；Have the advantages that environmentally protective, low in cost simultaneously, has broad application prospects in field of anti-counterfeit technology.
Description
Technical field
The invention belongs to field of anti-counterfeit technology, are related to a kind of for anti-fake colourless the coating of drafting ink.
Background technique
The various counterfeit and shoddy goods of today's society overflow, and have been evolved into public hazards.And pandemic laser is complete at present
The method for anti-counterfeit such as image, figure code inquiry, alternating temperature, color-changing anti-counterfeit are ceased, forgery can be all copied, cannot fundamentally reach
To anti-fake purpose.
Specific character or pattern are printed in advance with colorless ink in body surface, then under certain condition by the specific character
Or pattern displaying comes out, and is a kind of effective method for anti-counterfeit.Since specific character or pattern can be specified freely and at any time
Change, fake producer are difficult to grasp its content and changing rule, enhance the difficulty of forgery；And it will be printed in advance with colorless ink
Specific character or the condition that displays of pattern it is easy to accomplish so that certified products is easy identification and identification.
Current packaging material is for beauty, commonly using the material of the water imbibitions such as plastics, art paper or smooth millboard difference
Material is met difficulty on these materials using colorless ink printing is anti-fake.People there is an urgent need to one kind can be in aforementioned water-absorbent
The colorless ink applied on the material of difference.
Summary of the invention
The purpose of the present invention is overcoming technical problem of the existing technology, provide one kind be suitble to plastics, art paper or
The colorless ink of the material surface printing of the water imbibitions such as person's smooth millboard difference.The purpose of the present invention is real by the following technical programs
It is existing.
Colourless the coating of drafting ink, which is characterized in that the colourless the coating of drafting ink is water soluble acrylic resin, high-hydroscopicity
Resin, starch, pure water and hydrophilic cosolvent are sufficiently mixed liquid made of dissolving each other.Super absorbent resin is a kind of function high score
Sub- material has hydrophilic radical, largely can absorb moisture and be swollen and be able to maintain the synthetic resin that moisture does not outflow, Ke Yixuan
It is connect from starch grafted acrylate class, graft acrylamide, high substituted degree cross-linked carboxymethyl cellulose, cross-linked carboxymethyl cellulose
Branch one of acrylamide or cross-linking type hydroxyethyl cellulose graft acrylamide polymer or a variety of.Super absorbent resin one
As can be absorbed and be equivalent to 100 times of resin volume or more of moisture, highest water absorption rate is up to 1000 times or more.
The composition colorless and odorless formed by said components, in the material of the water imbibitions such as plastics, art paper, smooth millboard difference
Surface printing effect is good, and attachment fastness is strong, can sufficiently realize antiforge function.The composition is free of volatility toxic solvent, right
Atmosphere non-environmental-pollution will not damage the health of printing people, while cost is again lower.And it is not deliquesced after absorbing water, it is particularly suitable
It is printed on PE, BOPP, PVC, PET, PP plastic film, is also applied for laminated film printing and intaglio plate and flexographic printing.
Further, in mass, water soluble acrylic resin 4-5%, super absorbent resin 2-3%, hydrophilic cosolvent
6-7%, starch 17-20%, pure water surplus.
Further, the hydrophilic cosolvent is methanol, ethyl alcohol, acetone, isopropanol, n-butanol, butyl glycol ether and third
One or more of glycol n-butyl ether.
Another object of the present invention is to provide the security purposes of colourless the coating of drafting ink of the present invention.With the present invention
Printing specific character or pattern are completed for printing rear colorless and odorless, use water the colourless the coating of drafting ink in body surface in advance
The specific character or pattern displaying can be come out in body surface brushing, water volatilize body surface it is dry after the specific character or
Pattern loss, certified products are easy identification and identification.
Colourless the coating of drafting ink colorless and odorless provided by the invention, in the water imbibitions such as plastics, art paper, smooth millboard difference
Material surface printing effect is good, and attachment fastness is strong, can sufficiently realize antiforge function；Have simultaneously environmentally protective, low in cost
The advantages of, it has broad application prospects in field of anti-counterfeit technology.
Specific embodiment
In mass, water soluble acrylic resin 4-5%, super absorbent resin 2-3%, hydrophilic cosolvent 6-7%, starch
17-20%, pure water surplus are adequately mixed and dissolve each other to form colourless the coating of drafting ink.Hydrophilic cosolvent is methanol, ethyl alcohol, third
One or more of ketone, isopropanol, n-butanol, butyl glycol ether and propylene glycol n-butyl ether.
Material surface with colourless the coating of drafting ink in the water imbibitions such as plastics, art paper, smooth millboard difference prints specific text
Word or pattern, printing effect is good, and attachment fastness is strong.It is completed for printing rear colorless and odorless, being brushed with water in body surface can should
Specific character or pattern displaying come out, and the specific character or pattern loss after water volatilization body surface is dry, certified products are easy identification
And identification.
Claims (5)
1. colourless the coating of drafting ink, which is characterized in that the colourless the coating of drafting ink is by water soluble acrylic resin, high-hydroscopicity
Resin, starch, pure water and hydrophilic cosolvent are sufficiently mixed liquid made of dissolving each other.
2. colourless the coating of drafting ink according to claim 1, which is characterized in that in mass, water soluble acrylic resin
4-5%, super absorbent resin 2-3%, hydrophilic cosolvent 6-7%, starch 17-20%, pure water surplus.
3. colourless the coating of drafting ink according to claim 1, which is characterized in that the super absorbent resin connects selected from starch
Branch Acrylates, graft acrylamide, high substituted degree cross-linked carboxymethyl cellulose, cross-linked carboxymethyl cellulose grafted propylene acyl
One of amine or cross-linking type hydroxyethyl cellulose graft acrylamide polymer are a variety of.
4. colourless the coating of drafting ink according to claim 1, which is characterized in that the hydrophilic cosolvent be methanol, ethyl alcohol,
One or more of acetone, isopropanol, n-butanol, butyl glycol ether and propylene glycol n-butyl ether.
5. the security purposes of colourless the coating of drafting ink described in claim 1-4 any claim.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910327580.8A CN109988460A (en) | 2019-04-30 | 2019-04-30 | Colourless the coating of drafting ink and its security purposes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910327580.8A CN109988460A (en) | 2019-04-30 | 2019-04-30 | Colourless the coating of drafting ink and its security purposes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109988460A true CN109988460A (en) | 2019-07-09 |
Family
ID=67135051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910327580.8A Pending CN109988460A (en) | 2019-04-30 | 2019-04-30 | Colourless the coating of drafting ink and its security purposes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109988460A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110503890A (en) * | 2019-09-16 | 2019-11-26 | 北京中防丽颜科技有限公司 | Identification information carrier, anti-counterfeit structure and manufacturing method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101944306A (en) * | 2009-07-03 | 2011-01-12 | 深圳市华德防伪技术开发有限公司 | Humidity sensitive anti-counterfeiting label and method for printing and making same |
| CN105951519A (en) * | 2016-04-28 | 2016-09-21 | 华南理工大学 | Water-induced anti-counterfeit paper and preparation method thereof |
-
2019
- 2019-04-30 CN CN201910327580.8A patent/CN109988460A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101944306A (en) * | 2009-07-03 | 2011-01-12 | 深圳市华德防伪技术开发有限公司 | Humidity sensitive anti-counterfeiting label and method for printing and making same |
| CN105951519A (en) * | 2016-04-28 | 2016-09-21 | 华南理工大学 | Water-induced anti-counterfeit paper and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 王箴主编: "《化工辞典》", 30 April 1993, 化学工业出版社 * |
| 邝生鲁主编: "《现代精细化工高新技术与产品合成工艺》", 31 December 1997, 科学技术文献出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110503890A (en) * | 2019-09-16 | 2019-11-26 | 北京中防丽颜科技有限公司 | Identification information carrier, anti-counterfeit structure and manufacturing method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20211115 Address after: 150090 room 2605, No. 368, Changjiang Road, Nangang concentration area, economic development zone, Harbin, Heilongjiang Province Applicant after: Harbin guanding Technology Development Co., Ltd Address before: 150040 room 3102, unit 3, building D, No. 45, Tongshun street, Daoli District, Harbin, Heilongjiang Province Applicant before: Xiao Ying |
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| TA01 | Transfer of patent application right |