CN109987824A - A kind of high light transmission mist degree greenhouse special glass, glasshouse and glass-making processes - Google Patents

A kind of high light transmission mist degree greenhouse special glass, glasshouse and glass-making processes Download PDF

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Publication number
CN109987824A
CN109987824A CN201910349629.XA CN201910349629A CN109987824A CN 109987824 A CN109987824 A CN 109987824A CN 201910349629 A CN201910349629 A CN 201910349629A CN 109987824 A CN109987824 A CN 109987824A
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Prior art keywords
glass
glass substrate
lines
light transmission
mist degree
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Inventor
胡叶亮
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Nanjing Hangzhi Electric Technology Co Ltd
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Nanjing Hangzhi Electric Technology Co Ltd
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Priority to CN201910349629.XA priority Critical patent/CN109987824A/en
Publication of CN109987824A publication Critical patent/CN109987824A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14Greenhouses
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/01Rolling profiled glass articles, e.g. with I, L, T cross-sectional profiles
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K13/00Etching, surface-brightening or pickling compositions
    • C09K13/04Etching, surface-brightening or pickling compositions containing an inorganic acid
    • C09K13/08Etching, surface-brightening or pickling compositions containing an inorganic acid containing a fluorine compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25Greenhouse technology, e.g. cooling systems therefor

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Greenhouses (AREA)

Abstract

The present invention provides a kind of light transmission difference mist degree greenhouse special glass and glasshouses, provide new greenhouse special glass structure, and the upper surface of the glass substrate is equipped with upper surface lines, and the lower surface of glass substrate is equipped with lower surface lines;Etching anti-reflection film also covers upper surface lines and lower surface lines;The difference in height of the peak and valley of the upper surface lines is 1.4-1.9 μm;The peak and valley difference in height of the lower surface lines is 10~160 μm, which raises the light transmittances of glass, and it can be required according to intensity of illumination under different latitude, select the glass suitably scattered, keep sun light transmittance higher, more uniform and glass one anti-reflection film not cracky longer life expectancy is irradiated, achievees the purpose that agriculture in greenhouse increases production.The present invention also provides the manufacturing methods of the special glass.

Description

A kind of high light transmission mist degree greenhouse special glass, glasshouse and glass-making processes
Technical field
The present invention relates to agriculturals, Material Field, and in particular to a kind of high light transmission difference mist degree greenhouse special glass and its system Make method.
Background technique
The green plants that Modern Greenhouse of Agriculture is mainly planted includes vegetables, fruit, flowers etc..Green plants utilizes the sun Luminous energy assimilates carbon dioxide and water manufacture organic substance and the process for discharging oxygen, referred to as photosynthesis.Produced by photosynthesis Organic matter be mainly carbohydrate, and give off energy.It was found that the growth of green plants whole dry weight, 92%~ 96% directly from photosynthesis, and promoting photosynthetic effect is one of the key means for promoting yield.
Photosynthetic effect is evaluated by photosynthetic rate, photosynthetic rate typically refer to the unit time, unit leaf area two The burst size of carbonoxide uptake or oxygen, the external factor for influencing photosynthetic rate mainly have luminous intensity, Xanthophyll cycle and light quality.Light Photosynthetic limiting factor can be become according to deficiency, luminous energy surplus can also have an adverse effect to photosynthesis.Work as Photosynthetic When the light received is more than the amount that can be utilized, the phenomenon that also photosynthetic rate being caused to reduce.Under dark condition, blade without The release of photosynthesis, only respiration.With the increase of luminous intensity, photosynthetic rate can also be correspondinglyd increase;As a certain spy of arrival When determining luminous intensity, the photosynthetic rate of blade is equal to respiratory rate, i.e. carbon dioxide absorption amount is equal to carbon dioxide releasing amount: when super Certain light intensity is crossed, the increase of photosynthetic rate will turn slow.When reaching a certain light intensity, photosynthetic rate is not further added by, i.e., light is full And point.
The illumination condition in earth different latitude region is different.Low latitudes illumination condition is strong, sunshine is strong, if not right Crop carries out illumination protection, and photosynthetic efficiency can reduce, so as to cause the reduction of crop-planting efficiency;Similarly, the light of high latitude area Glass poor according to condition, strong using itself reflectivity at this time, refringence is poor so as to cause light transmittance, can reduce crop reception Luminous intensity, inhibit plant growth.Therefore it needs that different garden glasses is arranged according to different latitudes, illumination condition;Separately Outside, the working environment of garden glass is very easy to lead to the abrasion of glass and breakage in outdoor, can further result in greenhouse and make Object photosynthetic efficiency reduces.It solves the problems, such as that this method is usually to repair or replace glass, does so and waste manpower and material resources wealth Power improves production cost, and reduces service efficiency.
What agricultural greenhouse used in the prior art is all simple glass, and light transmittance is low, without scattering function, reduces crop Yield;Part greenhouse improves light transmittance using the glass for pasting anti-reflection film, but anti-reflection film is easy aging, in routine use and Breakage is easy in cleaning process, translucent effect is poor, and does not have scattering function.
It can be seen that by the analysis to the prior art, it is desirable to provide a kind of light transmittance is high, can be according to different latitude Illumination condition uses different glass type, and the greenhouse special glass for being hardly damaged, improving service life.
Summary of the invention
Goal of the invention: the present invention provides a kind of light transmission difference mist degree greenhouse special glass, and it is dedicated to provide new greenhouse Glass structure, which raises the light transmittances of glass, and can be required according to intensity of illumination under different latitude, select suitable dissipate The glass penetrated keeps sun light transmittance higher, irradiates more uniform and glass one anti-reflection film not cracky longer life expectancy, Achieve the purpose that agriculture in greenhouse increases production.
Invention also provides a kind of technical solutions of glasshouse.
Invention also provides the manufacturing methods of the glass.
Technical solution: following technical scheme can be used in the present invention:
A kind of high light transmission mist degree greenhouse special glass, which is characterized in that including glass substrate and be covered on glass substrate, The etching anti-reflection film of lower surface;The upper surface of the glass substrate is equipped with upper surface lines, and the lower surface of glass substrate is equipped with down Surface pattern;Etching anti-reflection film also covers upper surface lines and lower surface lines;
The difference in height of the peak and valley of the upper surface lines is 1.4-1.9 μm;
The peak and valley difference in height of the lower surface lines is 10~160 μm.
Further, the lower surface lines selection microgroove or middle line or big line;
The microgroove is that the peak and valley difference in height of lines is 10~94 μm.
The middle line is that the peak and valley difference in height of lines is 95~134 μm.
The big line is that the peak and valley difference in height of lines is 135~160 μm.
Further, the microgroove includes several golden words that fall that arrayed in columns in a row is downwardly projected in glass substrate lower surface Tower-shaped convex grain, the end of the convex grain are the peak of microgroove, and convex grain and glass substrate lower surface joint are the paddy of microgroove.
Further, the middle line includes several middle line units in glass substrate lower surface arrayed in columns in a row, each Middle line unit is rectangular, and this it is rectangular in be equipped with downward projection of trapezoidal convex block, the lower surface of the trapezoidal convex block be it is trapezoidal, it is trapezoidal The end of convex block is the peak of middle line, and trapezoidal convex block and glass substrate lower surface joint are the paddy of middle line.
Further, the big line include it is several glass substrate lower surface be arranged successively in column and in a row it is staggered Big line unit, each big line unit includes two L shape convex blocks, and the space between two L shape convex blocks is the lower surface of glass substrate, The L shape convex block end is the peak of big line, and L shape convex block and glass substrate lower surface joint are the paddy of big line.
Further, the material of glass substrate is low iron ultra-clear glasses, and light transmittance is greater than 92.2%;Etch anti-reflection film thickness For 100-180nm.
Present invention simultaneously provides a kind of technical solution of glasshouse, which is used for agricultural greenhouse crop-planting, Using the glass material used in above-mentioned high light transmission mist degree greenhouse special glass glasshouse.
The utility model has the advantages that passing through glass the present invention provides new greenhouse special glass and using the greenhouse of the special glass The different lines of the depth of surface setting changes the mist degree of glass, so as to be required according to intensity of illumination under different latitude, The glass suitably scattered is selected, is provided for the glasshouse farm of different latitude to the high saturating of the mist degree that should apply to the latitude Light greenhouse special glass, keeps sun light transmittance higher, and irradiation is more uniform, in addition etches anti-reflection film and glass surface is one It is whole, so that glass anti-reflection film not cracky longer life expectancy, achievees the purpose that agriculture in greenhouse increases production.It is tested according to the small range of early period Card, 11.5 ten thousand pounds/acre of years of large size tomato, 50,000 pounds/acre of years of small-sized fruit tomato, 150,000 pounds/acre of years of cucumber, 110,000 pounds/acre of romaine lettuce Year, product averagely increases production 20% or more to the chamber crop in different latitude region.
The manufacturing method of manufacture above-mentioned high light transmission mist degree greenhouse special glass provided by the invention, using following technical side Case:
The following steps are included:
Step (1), using upper stack and bottom calender roll to glass raw material carry out calendering formed upper surface lines and under Surface pattern obtains the glass substrate of default haze value;
Step (2) carries out tempering processing to the glass substrate;
Step (3), the glass substrate for obtaining step (2) invade etching solution with 3.4 ° of angles of opposite etching solution liquid level In;Invade the etching solution preset time, glass substrate upper and lower surfaces made to be inwardly formed etching anti-reflection film, etching anti-reflection film with Glass substrate forms an entirety, obtains high light transmission mist degree greenhouse special glass.
Detailed description of the invention
Fig. 1 is the side structure schematic view of high light transmission mist degree of the present invention greenhouse special glass;
Fig. 2 is the partial enlarged view of high light transmission mist degree of the present invention greenhouse special glass;
Fig. 3 is the microgroove schematic diagram of glass substrate lower surface in the present invention;
Fig. 4 is the middle line schematic diagram of glass substrate lower surface in the present invention;
Fig. 5 is the big line schematic diagram of glass substrate lower surface in the present invention;
Fig. 6 is product of the present invention manufacturing process;
Fig. 7 is in product of the present invention etching process, and glass substrate invades the angle schematic diagram of etching solution.
Figure label are as follows: 1, upper surface lines;2, glass substrate.3, lower surface lines;4, microgroove;5, middle line;6, big line; 41, convex grain;51, trapezoidal convex block;61, L shape convex block.
Specific embodiment
The following further describes the present invention in detail with reference to the accompanying drawings and specific embodiments.
Referring to Fig. 1, the present invention discloses a kind of high light transmission mist degree greenhouse special glass, including glass substrate 2 and it is covered in The etching anti-reflection film of glass substrate upper and lower surfaces.To provide biggish light transmittance, the material of the glass substrate in present embodiment Low iron ultra-clear glasses are selected, light transmittance is greater than 92.2%.The upper surface of the glass substrate 2 is equipped with upper surface lines 1, glass base The lower surface of plate is equipped with lower surface lines 3.Etching anti-reflection film also covers upper surface lines and lower surface lines.The etching is anti-reflection Film is by glass substrate horizontal immersion in the etch solution, and after a certain period of time, the upper and lower surfaces of the glass substrate 2 etch Anti-reflection film is formed, anti-reflection film and the glass substrate 2 are an entirety.Anti-reflection film is etched with a thickness of 100-180nm.
The difference in height of the peak and valley of the upper surface lines is 1.4-1.9 μm;The peak and valley height of the lower surface lines Difference is 10~160 μm.As shown in Fig. 2, the peak and valley difference in height of lower surface lines shown in the Fig. 2 is 120 μm.
And for the glasshouse of different latitude, it is also different for the needs of glass mist degree.Corresponding, above-mentioned glass base Plate lower surface lines selects microgroove or middle line or big line;
As shown in figure 3, the microgroove is, the peak and valley difference in height of lines is 10~94 μm.The microgroove include it is several Glass substrate lower surface is downwardly projected the convex grain 41 of reverse pyramid of arrayed in columns in a row, and the end of the convex grain 41 is microgroove Peak, convex grain 41 are the paddy of microgroove with glass substrate lower surface joint.
As shown in figure 4, the middle line is, the peak and valley difference in height of lines is 95~134 μm.The middle line include it is several The middle line unit of glass substrate lower surface arrayed in columns in a row, each middle line unit is rectangular, and rectangular interior be equipped with is dashed forward downwards Trapezoidal convex block 51 out, the lower surface of the trapezoidal convex block 51 are trapezoidal, peak of the end of trapezoidal convex block 51 for middle line, trapezoidal convex block 51 with glass substrate lower surface joint be middle line paddy.
As shown in figure 5, the big line is, the peak and valley difference in height of lines is 135~160 μm.The big line includes several It is arranged successively in column in glass substrate lower surface and in a row staggered big line unit, each big line unit includes two L shapes Convex block 61, the space between two L shape convex blocks 61 are the lower surface of glass substrate, and 61 end of L shape convex block is the peak of big line, L shape convex block 61 and glass substrate lower surface joint are the paddy of big line.
The glasshouse of the special glass of technical solution more than, for the equal energy in high latitude area and low dimensional area Suitable local latitude is enough selected, it is low for the applicable embodiment in a high latitude area and experimental data and one individually below The effect that the applicable embodiment in dimension area and experimental data play the special glass is illustrated.
One, the greenhouse special glass of high latitude area can be suitable for.
The material of the glass substrate is low iron ultra-clear glasses, light transmittance 96%, the height of the peak and valley of upper surface lines Spending difference is 10 μm;The lower surface lines is microgroove, and the different difference in height of the peak and valley of lower surface lines is 30 μm, and high light transmission is not Haze value with mist degree greenhouse special glass is 10%, and the haze value of special glass is lower in the embodiment, and scattering is smaller, is suitble to Greenhouse under the illumination difference environment of high latitude area uses;
In embodiment, the etching anti-reflection film with a thickness of 100nm,
Applicant is in high-order latitude low photoenvironment (Qiqihaer City, Heilongjiang Province), using the greenhouse of ordinary greenhouse glass With in the greenhouse progress planting experiment using the special glass, the comparison table of yield result is as follows.
Simple glass 1 glass of embodiment Volume increase ratio
Large size tomato 9.2 ten thousand pounds/acre of years 11.3 ten thousand pounds/acre of years 23%
Small-sized fruit tomato 4.5 ten thousand pounds/acre of years 5.4 ten thousand pounds/acre of years 21%
Cucumber 12.3 ten thousand pounds/acre of years 15.8 ten thousand pounds/acre of years 28%
Two, suitable for the greenhouse special glass of low latitudes
High light transmission difference mist degree greenhouse special glass characterized by comprising
Glass substrate 1, the material of the glass substrate are low iron ultra-clear glasses, light transmittance 96%, upper surface lines The difference in height of peak and valley is 1.9 μm;Lower surface uses big line, and the different difference in height of the peak and valley of lines is 120 μm.Incorporated by reference to figure 2, illustrate the signal that the different difference in height of peak and valley of the big line is 120 μm.High light transmission difference mist degree greenhouse special glass Haze value is 70%, and the haze value of special glass is higher in the embodiment, and scattering is larger, and direct sunlight can be effectively prevented and lead The local light of cause is saturated and generates light and effect depression effect, is suitble to use under low latitudes sunlight irradiation intense ambient.
In embodiment, it is described etching anti-reflection film with a thickness of 160nm.
Applicant in the low illumination intense ambient of low level latitude (Hainan Province Sanya), using ordinary greenhouse glass greenhouse and Planting experiment is being carried out using the greenhouse of the special glass, the comparison table of yield result is as follows.
Simple glass 2 glass of embodiment Volume increase ratio
Large size tomato 100000 pounds/acre of years 12.1 ten thousand pounds/acre of years 21%
Small-sized fruit tomato 4.72 ten thousand pounds/acre of years 5.9 ten thousand pounds/acre of years 25%
Cucumber 13.5 ten thousand pounds/acre of years 16.9 ten thousand pounds/acre of years 25%
Romaine lettuce 8.7 ten thousand pounds/acre of years 10.6 ten thousand pounds/acre of years 22%
The present invention also provides the manufacturing methods of manufacture above-mentioned high light transmission mist degree greenhouse special glass, comprising the following steps:
Step (1), using upper stack and bottom calender roll to glass raw material carry out calendering formed upper surface lines and under Surface pattern obtains the glass substrate of default haze value;
Step (2) carries out tempering processing to the glass substrate;
Step (3), the glass substrate for obtaining step (2) invade etching solution with 3.4 ° of angles of opposite etching solution liquid level In;Invade the etching solution preset time, glass substrate upper and lower surfaces made to be inwardly formed etching anti-reflection film, etching anti-reflection film with Glass substrate forms an entirety, obtains high light transmission mist degree greenhouse special glass.
Etching in the step (3) uses 50-60 DEG C of 65-70 parts of hot water, 55-65 parts of hydrofluoric acid, ammonium fluoride 15-20 Part, 15-20 parts of glycerol, wherein the quality of hydrofluoric acid accounts for the 36-39% of etching solution gross mass;
When etching, the time of etch preset is 15-180 seconds, and etch temperature is 35-80 degrees Celsius.
Such as the above-mentioned greenhouse special glass suitable for high latitude area, the technological parameter of use are as follows: the etching anti-reflection film Middle etching uses 65 parts of 60 DEG C of hot water, 55 parts of hydrofluoric acid, 15 parts of ammonium fluoride, 15 parts of glycerol, and wherein the quality of hydrofluoric acid accounts for erosion The 36% of etching solution gross mass;When etching, glass substrate immerse etching solution when with 6% angle enter, with reduce up and down into Entering the etched thickness difference of generation, while 6% angle enters to avoid glass substrate generation bubble, etching period is 17 seconds, Etch temperature is 54 degrees Celsius.
And such as the above-mentioned greenhouse special glass suitable for low latitudes, the technological parameter of use are as follows: the etching is anti-reflection Etching uses 65 parts of 60 DEG C of hot water, 55 parts of hydrofluoric acid, 15 parts of ammonium fluoride, 15 parts of glycerol in film, and wherein the quality of hydrofluoric acid accounts for The 36% of etching solution gross mass;When etching, glass substrate is entered when immersing etching solution with 6% angle, to reduce up and down Into the etched thickness difference of generation, while 6% angle enters to avoid glass substrate generation bubble, etching period 17 Second, etch temperature is 54 degrees Celsius.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification and accompanying drawing content is applied directly or indirectly in other relevant skills Art field, is included within the scope of the present invention.

Claims (9)

1. a kind of high light transmission mist degree greenhouse special glass, which is characterized in that including glass substrate and to be covered in glass substrate upper and lower The etching anti-reflection film on surface;The upper surface of the glass substrate is equipped with upper surface lines, and the lower surface of glass substrate is equipped with following table Face lines;Etching anti-reflection film also covers upper surface lines and lower surface lines;
The difference in height of the peak and valley of the upper surface lines is 1.4-1.9 μm;
The peak and valley difference in height of the lower surface lines is 10~160 μm.
2. high light transmission mist degree according to claim 1 greenhouse special glass, it is characterised in that: the lower surface lines selection Microgroove or middle line or big line;
The microgroove is that the peak and valley difference in height of lines is 10~94 μm.
The middle line is that the peak and valley difference in height of lines is 95~134 μm.
The big line is that the peak and valley difference in height of lines is 135~160 μm.
3. high light transmission mist degree according to claim 1 or 2 greenhouse special glass, it is characterised in that: if the microgroove includes The convex grain of the reverse pyramid for being downwardly projected arrayed in columns in a row in glass substrate lower surface is done, the end of the convex grain is microgroove Peak, convex grain and glass substrate lower surface joint are the paddy of microgroove.
4. high light transmission mist degree according to claim 1 or 2 greenhouse special glass, it is characterised in that: if the middle line includes Do the middle line unit in glass substrate lower surface arrayed in columns in a row, it is each in line unit be rectangular, and this it is rectangular in be equipped with to Under trapezoidal convex block outstanding, the lower surface of the trapezoidal convex block be it is trapezoidal, the end of trapezoidal convex block is the peak of middle line, trapezoidal convex block with Glass substrate lower surface joint is the paddy of middle line.
5. high light transmission mist degree according to claim 1 or 2 greenhouse special glass, it is characterised in that: if the big line includes It does and is arranged successively in column in glass substrate lower surface and in a row staggered big line unit, each big line unit include two L Shape convex block, the space between two L shape convex blocks are the lower surface of glass substrate, and the L shape convex block end is the peak of big line, L shape Convex block and glass substrate lower surface joint are the paddy of big line.
6. high light transmission mist degree according to claim 1 greenhouse special glass, it is characterised in that: the material of glass substrate is low Iron ultra-clear glasses, light transmittance are greater than 92.2%;Anti-reflection film is etched with a thickness of 100-180nm.
7. a kind of glasshouse is used for agricultural greenhouse crop-planting, it is characterised in that: using such as any one of claims 1 to 6 The glass material used in described high light transmission mist degree greenhouse special glass glasshouse.
8. a kind of manufacturing method of manufacture high light transmission mist degree greenhouse special glass as described in any one of claims 1 to 6, special Sign is, comprising the following steps:
Step (1) carries out calendering to glass raw material using upper stack and bottom calender roll and forms upper surface lines and lower surface Lines obtains the glass substrate of default haze value;
Step (2) carries out tempering processing to the glass substrate;
Step (3), the glass substrate for obtaining step (2) are in 3.4 ° of angle intrusion etching solutions of opposite etching solution liquid level; The etching solution preset time is invaded, glass substrate upper and lower surfaces is made to be inwardly formed etching anti-reflection film, etches anti-reflection film and glass Substrate forms an entirety, obtains high light transmission mist degree greenhouse special glass.
9. manufacturing method as claimed in claim 8, it is characterised in that: the etching in the step (3) uses 50-60 DEG C of hot water 65-70 parts, 55-65 parts of hydrofluoric acid, 15-20 parts of ammonium fluoride, 15-20 parts of glycerol, wherein it is total to account for etching solution for the quality of hydrofluoric acid The 36-39% of quality;
When etching, the time of etch preset is 15-180 seconds, and etch temperature is 35-80 degrees Celsius.
CN201910349629.XA 2019-04-28 2019-04-28 A kind of high light transmission mist degree greenhouse special glass, glasshouse and glass-making processes Pending CN109987824A (en)

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Application publication date: 20190709