CN109980790A - A kind of nuclear power station energy-storage system based on solid hydrogen technology - Google Patents

A kind of nuclear power station energy-storage system based on solid hydrogen technology Download PDF

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Publication number
CN109980790A
CN109980790A CN201910276867.2A CN201910276867A CN109980790A CN 109980790 A CN109980790 A CN 109980790A CN 201910276867 A CN201910276867 A CN 201910276867A CN 109980790 A CN109980790 A CN 109980790A
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CN
China
Prior art keywords
hydrogen
power station
nuclear power
electrolytic cell
solid
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CN201910276867.2A
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Chinese (zh)
Inventor
潘汉达
何浩冉
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Magnesium Ge Hydrogen Power Technology (suzhou) Co Ltd
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Magnesium Ge Hydrogen Power Technology (suzhou) Co Ltd
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Priority to CN201910276867.2A priority Critical patent/CN109980790A/en
Publication of CN109980790A publication Critical patent/CN109980790A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J15/00Systems for storing electric energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin

Abstract

The invention discloses a kind of nuclear power station energy-storage systems based on solid hydrogen technology, it include: power regulation system, water electrolysis hydrogen producing system and magnesium hydride production system, wherein, nuclear power station is by being connected to control centre, control centre is by being connected to power grid, converter is provided between control centre and electrolytic cell, converter one end is connected by high-tension cable with control centre, and the other end is connected by electric wire with electrolytic cell.According to the present invention, it is based on solid hydrogen technology, electric power when by nuclear power station peak regulation is used for electrolytic hydrogen production, then manufactured hydrogen is used for the generation of solid hydrogen, Optimization of Hydrogen storage and transportation problem.Solid hydrogen is generated using hydrogen and magnesium, solid hydrogen compares hydrogen, is containing hydrogen quality under the same conditions, the volume that solid hydrogen is occupied is minimum, and huge advantage is possessed in terms of storage.And hydrogen in terms of storing transport because hydrogen is inflammable and explosive, risk is high, and solid hydrogen does not generate hydrogen in dry conditions, fool proof.

Description

A kind of nuclear power station energy-storage system based on solid hydrogen technology
Technical field
The present invention relates to Hydrogen Energy technical field of memory, in particular to a kind of nuclear power station energy storage system based on solid hydrogen technology System.
Background technique
Hydrogen has the advantages that calorific capacity height, cleanliness without any pollution, is the fuel and energy for most having development potentiality as the energy Carrier.Hydrogen can be obtained by water electrolysis at present, and the main energy consumption of electrolytic hydrogen production is electric energy, and every cubic metre of hydrogen power consumption is about 4.5~5.5kWh, cost are mainly power consumption.If electrolytic hydrogen production and nuclear power station combined, when using nuclear power station peak regulation Electric power carries out electrolytic hydrogen production, the mass production of hydrogen not only may be implemented, but also can carry out peak regulation to the electric power of nuclear power station and realize have Effect utilizes.
There are five types of modes for hydrogen storage: (1) normal pressure is stored, such as dish gas holder, underground warehouse;(2) high-pressure bottle, such as steel Pressure vessel and steel cylinder;(3) liquid hydrogen is stored;(4) metal hydride: when the container made of hydrogen-storage alloy is cooling and pressure people's hydrogen When, hydrogen is stored;It heats this storage system or reduces its internal pressure, hydrogen will release.Metal hydride at present Alloy system mainly has: l) LaNi5 system alloy;2) MnNi5 system alloy etc.;3) TiMn system alloy;4) TiMn system alloy (ABZ); 5) magnesium system alloy;6) nano-sized carbon etc..(5) in addition to pipeline, high-pressure bottle and liquid hydrogen tank car are also industrially conventional at present answer Hydrogen delivery method.
But present hydrogen storage system has certain problems, first, the storage of hydrogen now is essentially high pressure and deposits Storage, inconvenience extremely, and security requirement are high.Second, container of the case where high pressure storage of existing hydrogen to storage It is required that also high, the cost of storage is also just high.
In view of this, it is really necessary to develop a kind of nuclear power station energy-storage system based on solid hydrogen technology, it is above-mentioned to solve Problem.
Summary of the invention
For the shortcomings of the prior art, the object of the present invention is to provide a kind of cores based on solid hydrogen technology Power station energy-storage system is based on solid hydrogen technology, and electric power when by nuclear power station peak regulation is used for electrolytic hydrogen production, then manufactured hydrogen is used In the generation of solid hydrogen, Optimization of Hydrogen storage and transportation problem.Solid hydrogen is generated using hydrogen and magnesium, solid hydrogen compares hydrogen, Containing hydrogen quality under the same conditions, the volume that solid hydrogen is occupied is minimum, and huge advantage is possessed in terms of storage.And Hydrogen is because hydrogen is inflammable and explosive in terms of storing transport, and risk is high, and solid hydrogen does not generate hydrogen in dry conditions, and ten Divide safety, provide a kind of nuclear power station energy-storage system based on solid hydrogen technology, comprising:
Power regulation system, the power regulation system includes control centre, and control centre is parallel is electrically connected with core Power station, converter and power grid;
Water electrolysis hydrogen producing system, the water electrolysis hydrogen producing system includes electrolytic cell, and electrolytic cell is parallel is communicated with raw material Device for supplying, cooling device and flush of hydrogen gas device, are successively connected with flush of hydrogen gas device by hydrogen flow direction and are connected with hydrogen Gas drying device, hydrogen gas buffer and booster system;
Magnesium hydride production system, the magnesium hydride production system include reaction furnace apparatus and MAG block feed system;
Wherein, nuclear power station is controlled by being connected to control centre, control centre by being connected to power grid Converter is provided between center and electrolytic cell, converter one end is connected by high-tension cable with control centre, and the other end passes through Electric wire is connected with electrolytic cell.
Preferably, electrolytic cell outer surface is provided with a connector, and raw material device for supplying is connected by pipeline with the connector It connects, electrolyte bath device has liquidometer.
Preferably, device has check valve in the pipeline between raw material device for supplying and electrolytic cell, and electrolytic cell is equipped with coolant liquid Inlet and outlet, the coolant liquid inlet and outlet are connected by water pipe with cooling device.
Preferably, electrolytic cell outer surface is equipped with gas outlet, and the gas outlet passes through tracheae and flush of hydrogen gas device import phase Connection.
Preferably, flush of hydrogen gas outside of deivce face offers outlet, and the outlet is filled by the tracheae and hydrogen desiccation The import set is connected, and device has the check valve in the tracheae between flush of hydrogen gas device and hydrogen drying unit.
Preferably, hydrogen drying unit offers outlet, and the outlet is connected by tracheae with hydrogen gas buffer import, The check valve and solenoid valve are equipped in the tracheae between hydrogen drying unit and hydrogen gas buffer.
Preferably, hydrogen gas buffer outer surface offers outlet, and the outlet is connected by the tracheae with booster system It connects, is equipped with the solenoid valve between hydrogen gas buffer and booster system in the tracheae, is equipped with booster pump in booster system.
Preferably, booster system is connected by the tracheae with furnace apparatus hydrogen inlet is reacted, booster system with react Solenoid valve is equipped in the tracheae between furnace apparatus.
Preferably, pressure detecting meter and temperatuer detector are equipped with inside reaction furnace apparatus.
Compared with prior art, the present invention the beneficial effect is that: it is based on solid hydrogen technology, electric power when by nuclear power station peak regulation For electrolytic hydrogen production, then manufactured hydrogen to be used for the generation of solid hydrogen, Optimization of Hydrogen storage and transportation problem.Using hydrogen and Magnesium generates solid hydrogen, and solid hydrogen compares hydrogen, is containing hydrogen quality under the same conditions, the volume pole that solid hydrogen is occupied It is small, huge advantage is possessed in terms of storage.And hydrogen in terms of storing transport because hydrogen is inflammable and explosive, risk is high, and Solid hydrogen does not generate hydrogen in dry conditions, fool proof.
Detailed description of the invention
Fig. 1 is the principle process block diagram of the nuclear power station energy-storage system according to the present invention based on solid hydrogen technology;
Specific embodiment
Present invention will be described in further detail below with reference to the accompanying drawings, foregoing end other objects of the invention, feature, side Face and advantage will be apparent, and so that those skilled in the art can carry out according to the description.In the accompanying drawings, For clarity, shape and size can be amplified, and will be indicated in all figures using identical appended drawing reference identical Or similar component.In the following description, such as center, thickness, height, length, front, back, rear portion, the left side, the right, top The words such as portion, bottom, top, lower part are to be based on the orientation or positional relationship shown in the drawings.Particularly, " height " is equivalent to from top Portion is to the size of bottom, and " width " is equivalent to size from left to right, and " depth " is equivalent to vertical size.These Relative terms are to be not intended to need specifically to be orientated for convenience and usually.It is related to the term of attachment, connection etc. (for example, " connection " and " attachment ") refer to these structures by the relationship that intermediate structure is fixed directly or indirectly to one another or is attached, And movable or rigidly attached or relationship, unless otherwise clearly stating.
Referring to Fig.1, based on the nuclear power station energy-storage system of solid hydrogen technology, comprising:
Power regulation system, the power regulation system include nuclear power station 1, control centre 2, converter 4 and power grid 3;
Water electrolysis hydrogen producing system, the water electrolysis hydrogen producing system include electrolytic cell 7, raw material device for supplying 5, cooling device 6, Flush of hydrogen gas device 8, hydrogen drying unit 9, hydrogen gas buffer 10 and booster system 11;
Magnesium hydride production system, the magnesium hydride production system include reaction furnace apparatus 12 and MAG block feed system 13;
Wherein, for nuclear power station 1 by being connected to control centre 2, control centre 2, which passes through, is connected to power grid 3, Converter 4 is provided between control centre 2 and electrolytic cell 7,4 one end of converter is connected by high-tension cable with control centre 2, separately One end is connected by electric wire with electrolytic cell 7, and the High Level AC Voltage that control centre 2 distributes changes to conjunction by the first transformation of converter 4 The low-voltage AC of suitable size, then rectifying and wave-filtering is carried out, the low-voltage DC for meeting 7 demand of electrolytic cell is exported from converter 4.
Control centre 2 determines 1 electricity volume of nuclear power station by being monitored to electricity service condition on power grid 3, works as electricity When 3 low power consumption of net, control centre 2 adjusts electricity volume, and electric power more than needed is used for electrolytic hydrogen production;When 3 peak of power consumption of power grid When, the upper power grid 3 of total electricity whole conveying that nuclear power station 1 produces is used to alleviate the power grid 3 of peak of power consumption period and pressed by control centre 2 Power.
Further, 7 outer surface of electrolytic cell is provided with a connector, and raw material device for supplying 5 passes through the connector and electrolysis Slot 7 is connected, and 7 interior arrangement of electrolytic cell has liquidometer, and electrolytic cell 7 can be according to distribution electric power and hydrogen manufacturing amount demand, and parallel connection is multiple, Raising efficiency.Electrolytic cell 7 is used for water electrolysis hydrogen producing, can use alkaline aqueous solution electrolytic cell, Polymer Electrolyte Membrane Electrolyzer or solid oxygen Compound electrolytic cell is one of.Under the action of DC electric field, in electrolytic cell 7 electrochemical reaction occurs for hydrone, in cathode Hydrogen is generated, generates oxygen in anode.
Electrolytic cell 7 can constantly consume water in the hydrogen production process, by be arranged in the liquidometer inside electrolytic cell 7 to liquid level into Row monitoring is opened raw material device for supplying 5 and is switched when liquid level drops to setting value, supplements water (as selected alkalinity to electrolytic cell 7 Aqueous solution electrolytic cell then also needs supplement lye).
Further, device has check valve in the pipeline between raw material device for supplying 5 and electrolytic cell 7, prevents liquid reflux.
Electrolytic cell 7 is imported and exported equipped with coolant liquid, and the coolant liquid inlet and outlet are connected by water pipe with cooling device 6, cold But device 6 is connected by water pipe with the coolant liquid of electrolytic cell 7 inlet and outlet, and the electric power that electrolytic cell 7 consumes in the hydrogen production process has A part needs cooling device 6 to guarantee the stabilization inside electrolytic cell 7 because resistance can generate heat.By being arranged in inside electrolytic cell 7 Temperature sensor is monitored temperature, and when temperature is more than setting value, unlatching cooling device 6 cools down.
Further, 7 outer surface of electrolytic cell is equipped with gas outlet, the gas outlet by tracheae and flush of hydrogen gas device 8 into Mouth is connected, and contains impurity from the hydrogen that electrolytic cell 7 generates, and includes water and oxygen.By flush of hydrogen gas device 8, first remove Ionized water is swum, then by being catalyzed so that oxyhydrogen reaction generates water and removes oxygen, then carries out cooling condensation and go to remove water.
Further, 8 outer surface of flush of hydrogen gas device offers outlet, and the outlet passes through the tracheae and hydrogen desiccation The import of device 9 is connected, and flush of hydrogen gas device 8 and 9 device of hydrogen drying unit have described unidirectional, and the hydrogen by washing is logical It crosses hydrogen drying unit to dehumidify, obtains High Purity Hydrogen.
Further, hydrogen drying unit 9 offers outlet, and the outlet passes through tracheae and 10 import phase of hydrogen gas buffer Check valve is equipped in the tracheae of connection, hydrogen drying unit 9 and hydrogen gas buffer 10 prevents gas backstreaming, solenoid valve control On-off, High Purity Hydrogen enter hydrogen gas buffer and are temporarily stored.
Further, 10 outer surface of hydrogen gas buffer offers outlet, and the outlet passes through the tracheae and booster system 11 are connected, and electromagnetic valve switch is equipped between hydrogen gas buffer 10 and booster system 11 and controls on-off, booster system 11 passes through increasing Manufactured High Purity Hydrogen is pressurized to the pressure of reacting furnace demand by press pump.
Further, booster system 11 is connected by the tracheae with 12 hydrogen inlet of furnace apparatus is reacted, booster system 11 with react in tracheae described in furnace apparatus 12 be equipped with electromagnetic valve switch control on-off.
Further, it reacts and is equipped with pressure detecting meter and temperatuer detector inside furnace apparatus 12, it is anti-by pressure detecting meter The pressure value of feedback, to control booster system for pressure needed for hydrogen pressurization to magnesium hydride reaction efficiency highest.It is examined by temperature The temperature value of meter feedback is surveyed, to control temperature needed for reacting furnace 12 is adjusted to magnesium hydride reaction efficiency highest.
MAG block feed system 13, by the way that magnesium ingot is cut die cast again, the MAG block that will meet the requirement of reacting furnace size leads to Conveyer belt transport is crossed, is then added in reacting furnace and reacts, ultimately generate magnesium hydride.
Number of devices and treatment scale described herein are for simplifying explanation of the invention.To application of the invention, Modifications and variations will be readily apparent to persons skilled in the art.
Although the embodiments of the present invention have been disclosed as above, but it is not limited in listed fortune in specification and embodiments With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily real Now other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is not limited to Specific details and legend shown and described herein.

Claims (9)

1. a kind of nuclear power station energy-storage system based on solid hydrogen technology, comprising:
Power regulation system, the power regulation system include control centre (2), and control centre (2) is parallel is electrically connected with Nuclear power station (1), converter (4) and power grid (3);
Water electrolysis hydrogen producing system, the water electrolysis hydrogen producing system include electrolytic cell (7), and electrolytic cell (7) is parallel is communicated with original Expect device for supplying (5), cooling device (6) and flush of hydrogen gas device (8), by hydrogen flow direction successively with flush of hydrogen gas device (8) it is connected and is connected with hydrogen drying unit (9), hydrogen gas buffer (10) and booster system (11);
Magnesium hydride production system, the magnesium hydride production system include reaction furnace apparatus (12) and MAG block feed system (13);
Wherein, nuclear power station (1) is by being connected to control centre (2), and control centre (2) is by being connected to power grid (3), it is provided between control centre (2) and electrolytic cell (7) converter (4), converter (4) one end passes through high-tension cable and control Center (2) is connected, and the other end is connected by electric wire with electrolytic cell (7).
2. as described in claim 1 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that electrolytic cell (7) is outside Surface is provided with a connector, and raw material device for supplying (5) is connected by pipeline with the connector, electrolytic cell (7) interior arrangement There is liquidometer.
3. as claimed in claim 2 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that raw material device for supplying (5) device has check valve in pipeline between electrolytic cell (7), and electrolytic cell (7) is imported and exported equipped with coolant liquid, the coolant liquid disengaging Mouth is connected by water pipe with cooling device (6).
4. as described in claim 1 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that electrolytic cell (7) is outside Surface is equipped with gas outlet, and the gas outlet is connected by tracheae with flush of hydrogen gas device (8) import.
5. as claimed in claim 4 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that flush of hydrogen gas device (8) outer surface offers outlet, and the outlet is connected by tracheae with the import of hydrogen drying unit (9), flush of hydrogen gas dress Set between (8) and hydrogen drying unit (9) that device has the check valve in pipeline.
6. as claimed in claim 5 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that hydrogen drying unit (9) outlet is offered, the outlet is connected by tracheae with hydrogen gas buffer (10) import, hydrogen drying unit (9) and hydrogen The check valve and solenoid valve are equipped between gas surge tank (10) in the tracheae.
7. as described in claim 1 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that hydrogen gas buffer (10) outer surface offers outlet, and the outlet is connected by the tracheae with booster system (11), hydrogen gas buffer (10) It is equipped with the solenoid valve between booster system (11), is equipped with booster pump in booster system (11).
8. as described in claim 1 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that booster system (11) Be connected by the tracheae with the hydrogen inlet for reacting furnace apparatus (12), booster system (11) with react between furnace apparatus (12) The solenoid valve is equipped in the tracheae.
9. as described in claim 1 based on the nuclear power station energy-storage system of solid hydrogen technology, which is characterized in that reaction furnace apparatus (12) internal to be equipped with pressure detecting meter and temperatuer detector.
CN201910276867.2A 2019-04-08 2019-04-08 A kind of nuclear power station energy-storage system based on solid hydrogen technology Pending CN109980790A (en)

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CN201910276867.2A CN109980790A (en) 2019-04-08 2019-04-08 A kind of nuclear power station energy-storage system based on solid hydrogen technology

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CN201910276867.2A CN109980790A (en) 2019-04-08 2019-04-08 A kind of nuclear power station energy-storage system based on solid hydrogen technology

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207603212U (en) * 2017-05-28 2018-07-10 赫普热力发展有限公司 The system that a kind of electrolytic hydrogen production is combined with nuclear power station flexibility peak regulation
CN207664150U (en) * 2017-10-30 2018-07-27 上海镁源动力科技有限公司 Electric generating station system based on magnesium-base hydrogen storage material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207603212U (en) * 2017-05-28 2018-07-10 赫普热力发展有限公司 The system that a kind of electrolytic hydrogen production is combined with nuclear power station flexibility peak regulation
CN207664150U (en) * 2017-10-30 2018-07-27 上海镁源动力科技有限公司 Electric generating station system based on magnesium-base hydrogen storage material

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Application publication date: 20190705

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