CN109975481A - Volatile organic component detection method, device, storage medium and terminal - Google Patents
Volatile organic component detection method, device, storage medium and terminal Download PDFInfo
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Abstract
本申请提供挥发性有机成分检测方法、装置、存储介质及终端,其包括:获取待测材料的多批次样品的挥发性成分检测数据,据以形成该待测材料的挥发性成分数据集合;根据所述挥发性成分数据集合获取该待测材料的各批次样品的检测基准数据,并分别计算各批次样品的挥发性成分检测数据与对应的检测基准数据之间的相似度,据以确定该待测材料的相似度上限阈值、中心阈值、以及下限阈值;可视化输出各批次样品的与基准数据的相似度与所述上限阈值、中心阈值、以及下限阈值之间的比较结果信息。本申请采用可视化的相似度质控图,以相似度均值及预设倍数相似度标准偏差或相似度限值计算质控图上下限及中心限,快速有效评估包装用纸的质量稳定性。
The present application provides a volatile organic component detection method, device, storage medium and terminal, which include: acquiring volatile component detection data of multiple batches of samples of a material to be tested, so as to form a volatile component data set of the material to be tested; The detection reference data of each batch of samples of the material to be tested is obtained according to the volatile component data set, and the similarity between the volatile component detection data of each batch of samples and the corresponding detection reference data is calculated respectively. Determine the upper limit threshold, center threshold, and lower threshold of similarity of the material to be tested; visually output the comparison result information between the similarity of each batch of samples and the reference data and the upper threshold, center threshold, and lower threshold. This application adopts the visual similarity quality control chart, and calculates the upper and lower limits and the central limit of the quality control chart with the similarity mean value and the preset multiple similarity standard deviation or similarity limit, so as to quickly and effectively evaluate the quality stability of packaging paper.
Description
技术领域technical field
本申请涉及挥发性有机成分的质量稳定性检测技术领域,特别是涉及挥发性有机成分检测方法、装置、存储介质及终端。The present application relates to the technical field of quality stability detection of volatile organic components, and in particular, to a method, device, storage medium and terminal for detection of volatile organic components.
背景技术Background technique
在工业生产中,包装用纸的制备流程复杂,由于印刷工艺的应用将不可避免地引入包括挥发性有机成分(Volatile organic compounds,VOCs)在内的化学组分。包装用纸中VOCs含量过高会影响使用者的感官感受,对于食品、化妆品、烟草等行业,包装材料中VOCs含量高低及其稳定性一直是产品质控的关键点,但目前对于VOCs的质量稳定性评估尚缺乏全面有效的方法。In industrial production, the preparation process of packaging paper is complicated, and chemical components including volatile organic compounds (VOCs) will inevitably be introduced due to the application of printing process. Excessive VOCs content in packaging paper will affect the user's sensory experience. For food, cosmetics, tobacco and other industries, the level of VOCs content in packaging materials and their stability have always been the key points of product quality control. There is still no comprehensive and effective method for stability assessment.
申请内容Application content
鉴于以上所述现有技术的缺点,本申请的目的在于提供挥发性有机成分检测方法、装置、存储介质及终端,用于解决现有技术中的问题。In view of the above-mentioned shortcomings of the prior art, the purpose of the present application is to provide a volatile organic component detection method, device, storage medium and terminal for solving the problems in the prior art.
为实现上述目的及其他相关目的,本申请的第一方面提供一种挥发性有机成分检测方法,其包括:获取待测材料的多批次样品的挥发性成分检测数据,据以形成该待测材料的挥发性成分数据集合;根据所述挥发性成分数据集合获取该待测材料的各批次样品的检测基准数据,并分别计算各批次样品的挥发性成分检测数据与对应的检测基准数据之间的相似度,据以确定该待测材料的上限阈值、中心阈值、以及下限阈值;可视化输出各批次样品的的相似度与所述上限阈值、中心阈值、以及下限阈值之间的比较结果信息。In order to achieve the above-mentioned purpose and other related purposes, a first aspect of the present application provides a volatile organic component detection method, which includes: acquiring volatile component detection data of multiple batches of samples of a material to be tested, so as to form the The volatile component data set of the material; the detection benchmark data of each batch of samples of the material to be tested is obtained according to the volatile component data set, and the volatile component detection data of each batch of samples and the corresponding detection benchmark data are calculated respectively. The similarity between the samples to determine the upper threshold, the center threshold, and the lower threshold of the material to be tested; the comparison between the similarity of each batch of samples and the upper threshold, the center threshold, and the lower threshold is visualized result information.
于本申请的第一方面的一些实施例中,所述方法中的形成该待测材料的挥发性成分数据集合的方式包括:从所述待测材料的多批次样品的挥发性成分检测数据中剔除离群数据;根据剔除了离群数据后的挥发性成分检测数据,建立该待测材料的的挥发性成分数据库;其中所述挥发性成分数据库包括该待测材料的各批次样品的各个挥发性成分检测指标及检测数据。In some embodiments of the first aspect of the present application, the manner of forming the volatile component data set of the material to be tested in the method includes: detecting data from volatile components of multiple batches of samples of the material to be tested Eliminate outlier data; establish a volatile component database of the material to be tested according to the volatile component detection data after removing the outlier data; wherein the volatile component database includes the data of each batch of samples of the material to be tested Each volatile component detection index and detection data.
于本申请的第一方面的一些实施例中,所述待测材料的各批次样品的检测基准数据包括各批次样品的全部挥发性成分检测数据的均值。In some embodiments of the first aspect of the present application, the detection reference data of each batch of samples of the material to be tested includes an average value of all volatile component detection data of each batch of samples.
于本申请的第一方面的一些实施例中,利用余弦相似度算法计算各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度。In some embodiments of the first aspect of the present application, the cosine similarity algorithm is used to calculate the similarity between the volatile component detection data of each batch of samples and the detection reference data.
于本申请的第一方面的一些实施例中,所述方法包括:根据各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度,计算该些批次样品的相似度均值作为所述中心阈值。In some embodiments of the first aspect of the present application, the method includes: calculating the similarity of the batches of samples according to the similarity between the volatile component detection data of each batch of samples and the detection reference data The mean serves as the central threshold.
于本申请的第一方面的一些实施例中,所述方法包括:以所述中心阈值与第一预设倍数标准偏差之差确定所述下限阈值,但下限阈值不低于0。In some embodiments of the first aspect of the present application, the method includes: determining the lower threshold value by the difference between the central threshold value and a first preset multiple standard deviation, but the lower threshold value is not lower than 0.
于本申请的第一方面的一些实施例中,所述方法包括:以所述中心阈值与第二预设倍数标准偏差之和确定所述上限阈值,但上限阈值不高于1。In some embodiments of the first aspect of the present application, the method includes: determining the upper threshold as the sum of the central threshold and a second predetermined multiple standard deviation, but the upper threshold is not higher than 1.
为实现上述目的及其他相关目的,本申请的第二方面提供一种挥发性有机成分检测装置,其包括:数据获取模块,用于获取待测材料的多批次样品的挥发性成分检测数据,据以形成该待测材料的挥发性成分数据集合;数据处理模块,用于根据所述挥发性成分数据集合获取该待测材料的检测基准数据,并分别计算各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度,据以确定该待测材料的相似度上限阈值、中心阈值、以及下限阈值;可视化输出模块,用于可视化输出各批次样品的的相似度与所述上限阈值、中心阈值、以及下限阈值之间的比较结果信息。In order to achieve the above object and other related purposes, a second aspect of the present application provides a volatile organic component detection device, which includes: a data acquisition module for acquiring volatile component detection data of multiple batches of samples of a material to be tested, According to this, a volatile component data set of the material to be tested is formed; a data processing module is used to obtain the detection reference data of the tested material according to the volatile component data set, and calculate the volatile component detection of each batch of samples respectively. The similarity between the data and the detection benchmark data is used to determine the upper threshold, center threshold, and lower threshold of the similarity of the material to be tested; the visual output module is used to visually output the similarity of each batch of samples and The comparison result information among the upper threshold, the central threshold, and the lower threshold.
为实现上述目的及其他相关目的,本申请的第三方面提供一种计算机可读存储介质,其上存储有计算机程序,所述计算机程序被处理器执行时实现所述挥发性有机成分检测方法。In order to achieve the above object and other related objects, a third aspect of the present application provides a computer-readable storage medium on which a computer program is stored, and the computer program implements the volatile organic component detection method when executed by a processor.
为实现上述目的及其他相关目的,本申请的第四方面提供一种电子终端,包括:处理器及存储器;所述存储器用于存储计算机程序,所述处理器用于执行所述存储器存储的计算机程序,以使所述终端执行所述挥发性有机成分检测方法。In order to achieve the above object and other related purposes, a fourth aspect of the present application provides an electronic terminal, comprising: a processor and a memory; the memory is used to store a computer program, and the processor is used to execute the computer program stored in the memory , so that the terminal executes the volatile organic component detection method.
如上所述,本申请的挥发性有机成分检测方法、装置、存储介质及终端,具有以下有益效果:本申请采用相似度算法和单值质控图实现对包装用纸中VOCs质量稳定性的评估,利用离群值检测方法建立包装用纸中各类VOCs组分基础数据库,并以各VOCs组分检测均值为基准,通过相似度算法计算各批次样品与基准间相似度,以相似度均值及预设倍数相似度标准偏差或相似度限值计算质控图上下限及中心限,绘制相似度质控图,可快速有效评估包装用纸的质量稳定性。As mentioned above, the volatile organic component detection method, device, storage medium and terminal of the present application have the following beneficial effects: the present application adopts the similarity algorithm and the single-value quality control chart to realize the evaluation of the quality stability of VOCs in packaging paper , using the outlier detection method to establish a basic database of various VOCs components in packaging paper, and using the average detection value of each VOCs component as the benchmark, the similarity between each batch of samples and the benchmark is calculated by the similarity algorithm, and the mean value of the similarity is calculated. and the preset multiple similarity standard deviation or similarity limit to calculate the upper and lower limit and center limit of the quality control chart, and draw the similarity quality control chart, which can quickly and effectively evaluate the quality stability of packaging paper.
附图说明Description of drawings
图1显示为本申请一实施例中挥发性有机成分检测方法的流程示意图。FIG. 1 shows a schematic flowchart of a method for detecting volatile organic components in an embodiment of the present application.
图2显示为本申请一实施例中相似度质控图的示意图。FIG. 2 is a schematic diagram of a similarity quality control chart in an embodiment of the present application.
图3显示为本申请一实施例中相似度质控图的示意图。FIG. 3 is a schematic diagram of a similarity quality control chart in an embodiment of the present application.
图4显示为本申请一实施例中相似度质控图的示意图。FIG. 4 is a schematic diagram of a similarity quality control chart in an embodiment of the present application.
图5显示为本申请一实施例中挥发性有机成分检测装置的示意图。FIG. 5 is a schematic diagram of a volatile organic component detection device according to an embodiment of the present application.
图6显示为本申请一实施例中检测终端的结构示意图。FIG. 6 is a schematic structural diagram of a detection terminal in an embodiment of the present application.
具体实施方式Detailed ways
以下通过特定的具体实例说明本申请的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本申请的其他优点与功效。本申请还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本申请的精神下进行各种修饰或改变。需说明的是,在不冲突的情况下,以下实施例及实施例中的特征可以相互组合。The embodiments of the present application are described below through specific specific examples, and those skilled in the art can easily understand other advantages and effects of the present application from the contents disclosed in this specification. The present application can also be implemented or applied through other different specific embodiments, and various details in this specification can also be modified or changed based on different viewpoints and applications without departing from the spirit of the present application. It should be noted that the following embodiments and features in the embodiments may be combined with each other under the condition of no conflict.
需要说明的是,在下述描述中,参考附图,附图描述了本申请的若干实施例。应当理解,还可使用其他实施例,并且可以在不背离本申请的精神和范围的情况下进行机械组成、结构、电气以及操作上的改变。下面的详细描述不应该被认为是限制性的,并且本申请的实施例的范围仅由公布的专利的权利要求书所限定。这里使用的术语仅是为了描述特定实施例,而并非旨在限制本申请。空间相关的术语,例如“上”、“下”、“左”、“右”、“下面”、“下方”、“下部”、“上方”、“上部”等,可在文中使用以便于说明图中所示的一个元件或特征与另一元件或特征的关系。It should be noted that, in the following description, reference is made to the accompanying drawings, which describe several embodiments of the present application. It is to be understood that other embodiments may be utilized and mechanical, structural, electrical, as well as operational changes may be made without departing from the spirit and scope of the present application. The following detailed description should not be considered limiting, and the scope of embodiments of the present application is limited only by the claims of the issued patent. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to limit the application. Spatially related terms, such as "upper," "lower," "left," "right," "below," "below," "lower," "above," "upper," etc., may be used in the text for ease of description The relationship of one element or feature shown in the figures to another element or feature.
在本申请中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”、“固持”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In this application, unless otherwise expressly specified and limited, terms such as "installation", "connection", "connection", "fixing", "fixing" and other terms should be understood in a broad sense, for example, it may be a fixed connection or a It is a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be directly connected, or indirectly connected through an intermediate medium, or it can be the internal communication between two components. For those of ordinary skill in the art, the specific meanings of the above terms in this application can be understood according to specific situations.
再者,如同在本文中所使用的,单数形式“一”、“一个”和“该”旨在也包括复数形式,除非上下文中有相反的指示。应当进一步理解,术语“包含”、“包括”表明存在所述的特征、操作、元件、组件、项目、种类、和/或组,但不排除一个或多个其他特征、操作、元件、组件、项目、种类、和/或组的存在、出现或添加。此处使用的术语“或”和“和/或”被解释为包括性的,或意味着任一个或任何组合。因此,“A、B或C”或者“A、B和/或C”意味着“以下任一个:A;B;C;A和B;A和C;B和C;A、B和C”。仅当元件、功能或操作的组合在某些方式下内在地互相排斥时,才会出现该定义的例外。Also, as used herein, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context dictates otherwise. It should be further understood that the terms "comprising", "comprising" indicate the presence of a stated feature, operation, element, component, item, kind, and/or group, but do not exclude one or more other features, operations, elements, components, The existence, appearance or addition of items, categories, and/or groups. The terms "or" and "and/or" as used herein are to be construed to be inclusive or to mean any one or any combination. Thus, "A, B or C" or "A, B and/or C" means "any of the following: A; B; C; A and B; A and C; B and C; A, B and C" . Exceptions to this definition arise only when combinations of elements, functions, or operations are inherently mutually exclusive in some way.
在工业生产中,包装用纸的制备流程复杂,由于印刷工艺的应用将不可避免地引入包括挥发性有机成分(Volatile organic compounds,VOCs)在内的化学组分。包装用纸中VOCs含量过高会影响使用者的感官感受,对于食品、化妆品、烟草等行业,包装材料中VOCs含量高低及其稳定性一直是产品质控的关键点,但目前对于VOCs的质量稳定性评估尚缺乏全面有效的方法。In industrial production, the preparation process of packaging paper is complicated, and chemical components including volatile organic compounds (VOCs) will inevitably be introduced due to the application of printing process. Excessive VOCs content in packaging paper will affect the user's sensory experience. For food, cosmetics, tobacco and other industries, the level of VOCs content in packaging materials and their stability have always been the key points of product quality control. There is still no comprehensive and effective method for stability assessment.
鉴于现有技术中的种种问题,本申请提供挥发性有机成分检测方法、装置、存储介质及终端,来有效解决该些技术问题。本申请的主要思想,旨在采用相似度算法和单值质控图实现对包装用纸中VOCs质量稳定性的评估,利用离群值检测方法建立包装用纸中各类VOCs组分基础数据库,并以各VOCs组分检测均值为基准,通过相似度算法计算各批次样品与基准间相似度,以相似度均值及预设倍数相似度标准偏差或相似度限值计算质控图上下限及中心限,绘制相似度质控图,可快速有效评估包装用纸的质量稳定性。In view of various problems in the prior art, the present application provides a volatile organic component detection method, device, storage medium and terminal to effectively solve these technical problems. The main idea of this application is to use the similarity algorithm and the single-value quality control chart to realize the evaluation of the quality stability of VOCs in packaging paper, and to use the outlier detection method to establish a basic database of various VOCs components in packaging paper. And based on the average detection of each VOCs component, the similarity between each batch of samples and the benchmark is calculated by the similarity algorithm, and the upper and lower limits of the quality control chart and The central limit and the similarity quality control chart can be drawn, which can quickly and effectively evaluate the quality stability of packaging paper.
需要说明的是,本申请提供的技术方案不仅可用于检测包装用纸的VOC成分,还可用于检测家具装饰材料、汽车配件材料漆、纺织制品、玩具、或者在较高温度下使用时会挥发出有机成分化合物的电子制品等等的VOC成分。下文,将结合具体的实施例对本申请的技术方案做详细的解释说明。It should be noted that the technical solutions provided in this application can not only be used to detect the VOC components of packaging paper, but also can be used to detect furniture decoration materials, auto parts material paints, textile products, toys, or volatilization when used at higher temperatures. VOC components such as electronic products that produce organic compounds. Hereinafter, the technical solutions of the present application will be explained in detail with reference to specific embodiments.
如图1所示,展示本申请一实施例中挥发性有机成分检测方法的流程示意图。As shown in FIG. 1 , a schematic flowchart of a method for detecting volatile organic components in an embodiment of the present application is shown.
在一些实施方式中,所述方法可应用于控制器,例如:ARM控制器、FPGA控制器、SoC控制器、DSP控制器、或者MCU控制器等等。在一些实施方式中,所述方法也可应用于包括存储器、存储控制器、一个或多个处理单元(CPU)、外设接口、RF电路、音频电路、扬声器、麦克风、输入/输出(I/O)子系统、显示屏、其他输出或控制设备,以及外部端口等组件的计算机;所述计算机包括但不限于如台式电脑、笔记本电脑、平板电脑、智能手机、智能电视、个人数字助理(Personal Digital Assistant,简称PDA)等个人电脑。在另一些实施方式中,所述方法还可应用于服务器,所述服务器可以根据功能、负载等多种因素布置在一个或多个实体服务器上,也可以由分布的或集中的服务器集群构成。In some embodiments, the method may be applied to a controller, such as an ARM controller, an FPGA controller, a SoC controller, a DSP controller, or an MCU controller, among others. In some embodiments, the method may also be applied to include a memory, a memory controller, one or more processing units (CPUs), peripheral interfaces, RF circuits, audio circuits, speakers, microphones, input/output (I/ O) Computers with components such as subsystems, display screens, other output or control devices, and external ports; such computers include, but are not limited to, such as desktop computers, notebook computers, tablet computers, smart phones, smart TVs, personal digital assistants (Personal Digital Assistants) Digital Assistant, referred to as PDA) and other personal computers. In other embodiments, the method can also be applied to a server, and the server can be arranged on one or more entity servers according to various factors such as function and load, and can also be composed of a distributed or centralized server cluster.
于本实施例中,所述挥发性有机成分检测方法包括步骤S11、步骤S12、步骤S13。In this embodiment, the volatile organic component detection method includes step S11, step S12, and step S13.
在步骤S11中,获取待测材料的多批次样品的挥发性成分检测数据,据以形成该待测材料的挥发性成分数据集合。In step S11, the volatile component detection data of multiple batches of samples of the material to be tested are acquired, so as to form a volatile component data set of the material to be tested.
VOC是挥发性有机化合物(Volatile organic compounds)的英文缩写,室外主要来自燃料燃烧和交通运输,室内主要来自燃煤和天然气等燃烧产物、吸烟、采暖和烹调等的烟雾,建筑和装饰材料、家具、家用电器、清洁剂和人体本身的排放等等。所述挥发性有机化合物例如:烟草行业的油墨、有机溶剂等,纺织品行业的鞋类制品所用的胶水等,玩具行业的涂改液或香味剂等,家具装饰材料中用到的涂料、油漆、或者胶黏剂等,汽车配件材料中用到的胶水或油漆等,电子电气行业中用到的清洁溶剂等等。VOC is the English abbreviation of Volatile Organic Compounds. Outdoors are mainly from fuel combustion and transportation, indoors are mainly from combustion products such as coal and natural gas, smoking, heating and cooking smoke, building and decoration materials, furniture, etc. , household appliances, cleaning agents and the human body itself emissions and so on. The volatile organic compounds are for example: inks, organic solvents, etc. in the tobacco industry, glues used in footwear products in the textile industry, etc., correction fluids or fragrances in the toy industry, etc., coatings, paints, or Adhesives, etc., glue or paint used in auto parts materials, cleaning solvents used in the electrical and electronic industry, etc.
在一实施例中,形成该待测材料的挥发性成分数据集合的方式包括:从所述待测材料的多批次样品的挥发性成分检测数据中剔除离群数据;根据剔除了离群数据后的挥发性成分检测数据,建立该待测材料的的挥发性成分数据库;其中所述挥发性成分数据库包括该待测材料的各批次样品的各个挥发性成分检测指标及检测数据。本实施例中,剔除离群数据的方式可对所获取的挥发性成分检测数据做数据预处理,防止离群数据对VOC检测产生干扰,有效提升检测的准确精度。In one embodiment, the method of forming the volatile component data set of the material to be tested includes: removing outlier data from the volatile component detection data of multiple batches of samples of the material to be tested; After the volatile component detection data, a volatile component database of the material to be tested is established; wherein the volatile component database includes each volatile component detection index and detection data of each batch of samples of the material to be tested. In this embodiment, the method of eliminating outlier data can perform data preprocessing on the acquired volatile component detection data, preventing outlier data from interfering with VOC detection, and effectively improving the accuracy of detection.
具体的,采用Grubbs检验方法逐一检测各批次样品中的每份挥发性成分检测数据中是否存在离群数据,将检测到的离群数据剔除,不参与平均值的计算,并最终以该批次样品中的挥发性成分的检测均值来替代。其中,显著性水平α可取0.01或者0.05等数据,本实施例对此不作限定。Specifically, the Grubbs test method is used to detect whether there is outlier data in each volatile component detection data in each batch of samples one by one, and the detected outlier data is eliminated without participating in the calculation of the average value. The mean value of the detection of the volatile components in the sub-sample is used instead. The significance level α may take data such as 0.01 or 0.05, which is not limited in this embodiment.
需要说明的是,离群数据的检测方法包括但不限于Grubbs检验方法,在其它的实施例中,还可选用如基于邻近度的离群点检测、基于密度的检测和基于聚类技术等检测方法,本申请对此不作限定。It should be noted that the detection method of outlier data includes, but is not limited to, the Grubbs test method. In other embodiments, detections such as proximity-based outlier detection, density-based detection, and clustering-based technology can also be selected. method, which is not limited in this application.
在步骤S12中,根据所述挥发性成分数据集合获取该待测材料的各批次样品的检测基准数据,并分别计算各批次样品的挥发性成分检测数据与对应的检测基准数据之间的相似度,据以确定该待测材料的上限阈值、中心阈值、以及下限阈值。In step S12, the detection reference data of each batch of samples of the material to be tested is acquired according to the volatile component data set, and the difference between the volatile component detection data of each batch of samples and the corresponding detection reference data is calculated respectively. The similarity is used to determine the upper threshold, center threshold, and lower threshold of the material to be tested.
在一实施例中,所述待测材料的各批次样品的检测基准数据包括各批次样品的全部挥发性成分检测数据的均值。需要说明的是,各批次样品的检测基准数据包括但不限于检测数据的均值,在其他的实施例中,还可选用检测数据的中位值或者均方根值等,本申请对此不作限定。In one embodiment, the detection reference data of each batch of samples of the material to be tested includes an average value of all volatile component detection data of each batch of samples. It should be noted that the detection benchmark data of each batch of samples includes, but is not limited to, the mean value of the detection data. In other embodiments, the median value or the root mean square value of the detection data can also be selected, which is not made in this application. limited.
在一实施例中,利用余弦相似度算法计算各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度。余弦相似度算法是指利用向量空间中两个向量夹角的余弦值作为衡量两个个体间差异的大小的计算方法,余弦值越接近1,表面夹角越接近0度,也即两个向量越相似,两个个体间的差异越小。In one embodiment, the cosine similarity algorithm is used to calculate the similarity between the volatile component detection data of each batch of samples and the detection reference data. The cosine similarity algorithm refers to using the cosine value of the angle between two vectors in the vector space as a calculation method to measure the difference between two individuals. The closer the cosine value is to 1, the closer the surface angle is to 0 degrees, that is, the two vectors The more similar, the smaller the difference between the two individuals.
举例而言,可利用下文的公式1)进行余弦相似度计算:For example, the cosine similarity calculation can be performed using the following formula 1):
其中,S表示相似度,ak为纸张样品a的第k个挥发性有机化合物组分检测值,bk为纸张样品检测基准b的烟气成分k检测值,n为选择的挥发性有机化合物成分总数。Among them, S represents the similarity, a k is the detected value of the k-th volatile organic compound component of the paper sample a, b k is the detected value of the smoke component k of the paper sample detection benchmark b, and n is the selected volatile organic compound Total number of ingredients.
在一实施例中,根据各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度,计算该些批次样品的相似度均值作为所述中心阈值。也即,先分别计算各批次样品的相似度值,再计算该些相似度值的平均值,以该平均值作为中心阈值,具体可利用下文的公式2)进行计算:In one embodiment, according to the similarity between the volatile component detection data of each batch of samples and the detection reference data, the average similarity of the batches of samples is calculated as the central threshold. That is, first calculate the similarity value of each batch of samples, then calculate the average value of these similarity values, and use the average value as the central threshold value, specifically, the following formula 2) can be used to calculate:
其中,CL表示中心阈值,n表示所述待测材料的全部样品的批次总数,Sk表示第k批次样品的相似度。Among them, CL represents the center threshold, n represents the total number of batches of all samples of the material to be tested, and Sk represents the similarity of the kth batch of samples.
在一实施例中,以所述中心阈值与第一预设倍数标准偏差之差确定所述下限阈值。例如,以所述中心阈值与3倍数标准偏差之差确定所述下限阈值,具体可利用下文的公式3)和公式4)进行计算:In one embodiment, the lower threshold is determined by the difference between the central threshold and a first preset multiple standard deviation. For example, the lower threshold is determined by the difference between the central threshold and 3 times the standard deviation, and can be calculated specifically by using the following formula 3) and formula 4):
LCL=CL-3σ; 公式3)LCL=CL-3σ; Equation 3)
其中,LCL表示下限阈值,σ表示标准偏差,n表示所述待测材料的全部样品的批次总数,Sk表示第k批次样品的相似度,表示相似度均值。Among them, LCL represents the lower limit threshold, σ represents the standard deviation, n represents the total number of batches of all samples of the material to be tested, Sk represents the similarity of the kth batch of samples, represents the mean similarity.
在一实施例中,以所述中心阈值与第二预设倍数标准偏差之和确定所述上限阈值。例如:以所述中心阈值与3倍数标准偏差之和确定所述上限阈值,具体可利用下文的公式5)进行计算:In one embodiment, the upper threshold is determined by the sum of the central threshold and a second preset multiple standard deviation. For example: the upper threshold is determined by the sum of the central threshold and 3 times the standard deviation, which can be calculated by using the following formula 5):
UCL=CL+3σ; 公式5)UCL=CL+3σ; Equation 5)
其中,UCL表示上限阈值,CL和σ的计算方式已于上文中予以解释,故不再赘述。Among them, UCL represents the upper limit threshold, and the calculation methods of CL and σ have been explained above, so they will not be repeated.
需要说明的是,所述第一预设倍数和第二预设倍数的取值可以是相同的,例如都取值3倍,也可以是不同的,本申请对此不作限定。It should be noted that the values of the first preset multiple and the second preset multiple may be the same, for example, both may be 3 times the value, or may be different, which is not limited in this application.
在步骤S13中,可视化输出各批次样品的的相似度与所述上限阈值、中心阈值、以及下限阈值之间的比较结果信息。In step S13, the comparison result information between the similarity of each batch of samples and the upper threshold, the center threshold, and the lower threshold is output visually.
在一实施例中,以二维坐标视图的方式输出各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度与所述上限阈值、中心阈值、以及下限阈值之间的比较结果信息。In one embodiment, the similarity between the volatile component detection data of each batch of samples and the detection reference data and the upper threshold, the center threshold, and the lower threshold are output in a two-dimensional coordinate view. Compare the result information.
每批次样品中各VOCs组分的检测结果应与检测基准计算相似度,计算结果应按时间顺序依次描点绘制于既定的相似度质控图中,以评估每批次样品中各VOCs组分的整体波动性和待测材料的样品质量稳定性。The detection results of each VOCs component in each batch of samples should be calculated for similarity with the detection benchmark, and the calculated results should be plotted in the established similarity quality control chart in chronological order to evaluate the VOCs components in each batch of samples. The overall volatility and sample quality stability of the material to be tested.
优选的,后续每批次样品中VOCs组分的检测方法、检测的VOCs组分及生产工艺配方应与建立检测基准时所采用的检测方法、相似度评估参数和纸张生产参数一致。若上述任一条件发生改变,相似度质控图应重新绘制和评估。Preferably, the detection method of VOCs components in each subsequent batch of samples, the detected VOCs components and the production process formula should be consistent with the detection methods, similarity evaluation parameters and paper production parameters used in establishing the detection benchmark. If any of the above conditions are changed, the similarity quality control chart should be redrawn and evaluated.
为便于理解,现结合图2进行进一步的解释说明本实施例中的相似度质控图。图2展示的是某待测材料的6批次样品的VOC检测数据,横轴表示该6批次样品,纵轴表示相似度值,本实施例以相似度0.6到1.0的范围为示例。图中右上至下的3根实线分别表示相似度的上限阈值、中心阈值、以及下限阈值。每批次样品的相似度采用圆点表示,将各批次样品的相似度圆点连接成折线。For ease of understanding, the similarity quality control chart in this embodiment is further explained with reference to FIG. 2 . Figure 2 shows the VOC detection data of 6 batches of samples of a certain material to be tested. The horizontal axis represents the 6 batches of samples, and the vertical axis represents the similarity value. In this embodiment, the range of similarity from 0.6 to 1.0 is used as an example. The three solid lines from the top right to the bottom in the figure represent the upper threshold, center threshold, and lower threshold of similarity, respectively. The similarity of each batch of samples is represented by dots, and the similarity dots of each batch of samples are connected into a polyline.
因此,本实施例提供的可视化视图可将各批次样品的相似度与上限阈值、中心阈值、以及下限阈值之间的比较结果清晰且直接地予以展示,便于分析和归总。例如:从图2可知,批次4样品对应的相似度低于下限阈值LCL,故可直观地知晓批次4样品的质量稳定性差。Therefore, the visual view provided by this embodiment can clearly and directly display the comparison results between the similarity of each batch of samples and the upper threshold, the center threshold, and the lower threshold, which is convenient for analysis and summarization. For example, it can be seen from Figure 2 that the similarity corresponding to the batch 4 samples is lower than the lower threshold LCL, so it can be intuitively known that the quality stability of the batch 4 samples is poor.
本领域普通技术人员可以理解:实现上述各方法实施例的全部或部分步骤可以通过计算机程序相关的硬件来完成。前述的计算机程序可以存储于一计算机可读存储介质中。该程序在执行时,执行包括上述各方法实施例的步骤;而前述的存储介质包括:ROM、RAM、磁碟或者光盘等各种可以存储程序代码的介质。Those of ordinary skill in the art can understand that all or part of the steps of implementing the above method embodiments may be completed by hardware related to computer programs. The aforementioned computer program may be stored in a computer-readable storage medium. When the program is executed, the steps including the above method embodiments are executed; and the foregoing storage medium includes: ROM, RAM, magnetic disk or optical disk and other media that can store program codes.
如图3所示,展示本申请一实施例中相似度质控图的示意图。本实施例提供的相似度质控图用于评估包装用纸A1的30批次样品的质量稳定性,具体通过如下的步骤流程生成图3所示的相似度质控图。As shown in FIG. 3 , a schematic diagram of a similarity quality control graph in an embodiment of the present application is shown. The similarity quality control chart provided in this example is used to evaluate the quality stability of 30 batches of samples of packaging paper A1. Specifically, the similarity quality control chart shown in FIG. 3 is generated through the following step process.
首先,取包装用纸A1的30批次样品中挥发性成分定性定量检测数据。采用Grubbs检验对每一批次样品中VOCs检测结果进行离群值检验,剔除异常值后,建立包装用纸A1的VOCs基础数据库。First, take the qualitative and quantitative detection data of volatile components in 30 batches of samples of packaging paper A1. The Grubbs test was used to test the outliers of the VOCs detection results in each batch of samples. After eliminating the outliers, the basic VOCs database of packaging paper A1 was established.
其次,计算包装用纸A1中所有VOCs组分检测均值为检测基准值,并采用余弦相似度算法依次计算30批次样品VOCs检测值与检测基准值之间的相似度,并统计分析相似度中心阈值和标准偏差,测得包装用纸A1的相似度均值为0.931,标准偏差为0.070,其中A1*为检测基准。于本实施例中,基于约1倍的标准偏差计算得到上限阈值1.0,基于约3倍的标准偏差计算得到下限阈值0.722。因此,包装用纸A1的质控限范围为[0.722,1],中心值为0.931。Secondly, the average detection value of all VOCs components in packaging paper A1 is calculated as the detection reference value, and the cosine similarity algorithm is used to calculate the similarity between the VOCs detection value and the detection reference value of 30 batches of samples in turn, and the similarity center is statistically analyzed. Threshold value and standard deviation, the average similarity of the measured packaging paper A1 is 0.931, and the standard deviation is 0.070, where A1* is the detection benchmark. In this embodiment, the upper limit threshold value 1.0 is calculated based on about 1 times the standard deviation, and the lower limit threshold value 0.722 is calculated based on about 3 times the standard deviation. Therefore, the quality control limit range of packaging paper A1 is [0.722, 1], and the center value is 0.931.
由图3可知,包装用纸A1所有样品相似度值均分布于中心阈值的上下两侧,且均在质控范围内波动,无超限异常点,标明包装用纸A1的样品质量均一性较好,检测数据均在可控范围内波动。It can be seen from Figure 3 that the similarity values of all samples of packaging paper A1 are distributed on the upper and lower sides of the central threshold, and they all fluctuate within the quality control range, and there are no out-of-limit abnormal points, indicating that the sample quality of packaging paper A1 is more uniform. Well, the detection data all fluctuate within a controllable range.
如图4所示,展示本申请另一实施例中相似度质控图的示意图。本实施例提供的相似度质控图用于评估包装用纸B1的20批次样品的质量稳定性,具体通过如下的步骤流程生成图4所示的相似度质控图。As shown in FIG. 4 , a schematic diagram of a similarity quality control graph in another embodiment of the present application is shown. The similarity quality control chart provided in this example is used to evaluate the quality stability of 20 batches of samples of packaging paper B1. Specifically, the similarity quality control chart shown in FIG. 4 is generated through the following step process.
首先,获取包装用纸B1的20批次样品中挥发性成分定性定量检测数据。采用Grubbs检验对每一批次样品中VOCs检测结果进行离群值检验,剔除异常值后,建立商标纸B1的VOCs基础数据库。First, qualitative and quantitative detection data of volatile components in 20 batches of samples of packaging paper B1 were obtained. The Grubbs test was used to test the outliers of the VOCs detection results in each batch of samples. After eliminating the outliers, the basic VOCs database of trademark paper B1 was established.
其次,计算包装用纸B1中所有VOCs组分检测均值为检测基准值,并采用余弦相似度算法依次计算20批次样品VOCs检测值与检测基准值之间的相似度,并统计分析相似度中心阈值和标准偏差,测得包装用纸B1相似度均值为0.891,标准偏差为0.113,其中B1*为检测基准。于本实施例中,基于约1倍的标准偏差计算得到上限阈值1.0,基于约3倍的标准偏差计算得到下限阈值0.552。因此,包装用纸A1的质控限范围为[0.552,1],中心值为0.891。Secondly, the average detection value of all VOCs components in packaging paper B1 is calculated as the detection reference value, and the cosine similarity algorithm is used to calculate the similarity between the detection value of VOCs in 20 batches of samples and the detection reference value in turn, and the similarity center is statistically analyzed. Threshold value and standard deviation, the average value of B1 similarity of packaging paper is measured to be 0.891, and the standard deviation is 0.113, of which B1* is the detection benchmark. In this embodiment, the upper limit threshold value 1.0 is calculated based on about 1 times the standard deviation, and the lower limit threshold value 0.552 is calculated based on about 3 times the standard deviation. Therefore, the quality control limit range of packaging paper A1 is [0.552, 1], and the center value is 0.891.
由图4可知,保证用纸B1的大部分样品相似度值均分布于中心阈值的上下两侧,且均在质控范围内波动。但是,B1*-8样品对相似度为0.462,低于质控下限被判为异常点,溯源8#样品各VOCs检测结果,溯源结果表明该样品中两种挥发性成分丁酮和乙酸乙酯检测值为组内最小值,且显著低于基准值,其中,乙酸乙酯为纸张中主要挥发性成分。由此表明,8#样品中挥发性组分的整体波动性较大,产生波动的原因主要是由于丁酮和乙酸乙酯的检测量偏差较大,这可能由于纸张样品检测过程中出现异常或该样品生产过程中配方产生了变化而引起样品间的质量差异。It can be seen from Figure 4 that most of the sample similarity values of the guaranteed paper B1 are distributed on the upper and lower sides of the central threshold, and all fluctuate within the quality control range. However, the similarity of B1*-8 sample pair is 0.462, which is lower than the lower limit of quality control and judged as an abnormal point. The traceability of the VOCs detection results of the 8# sample shows that two volatile components, butanone and ethyl acetate, are in the sample. The detected value was the minimum value in the group and was significantly lower than the reference value, among which ethyl acetate was the main volatile component in the paper. This shows that the overall volatility of the volatile components in the 8# sample is large, and the reason for the fluctuation is mainly due to the large deviation of the detection amount of butanone and ethyl acetate, which may be due to abnormality or abnormality in the detection process of the paper sample. This sample was produced during formulation changes resulting in quality differences between samples.
如图5所示,展示本申请一实施例中挥发性有机成分检测装置的示意图。所述检测装置包括数据获取模块51、数据处理模块52、以及可视化输出模块52。As shown in FIG. 5 , a schematic diagram of a volatile organic component detection device in an embodiment of the present application is shown. The detection device includes a data acquisition module 51 , a data processing module 52 , and a visual output module 52 .
数据获取模块51用于获取待测材料的多批次样品的挥发性成分检测数据,据以形成该待测材料的挥发性成分数据集合。数据处理模块52用于根据所述挥发性成分数据集合获取该待测材料的检测基准数据,并分别计算各批次样品的挥发性成分检测数据与所述检测基准数据之间的相似度,据以确定该待测材料的上限阈值、中心阈值、以及下限阈值。可视化输出模块52用于可视化输出各批次样品的的相似度与所述上限阈值、中心阈值、以及下限阈值之间的比较结果信息。The data acquisition module 51 is configured to acquire volatile component detection data of multiple batches of samples of the material to be tested, so as to form a volatile component data set of the material to be tested. The data processing module 52 is configured to obtain the detection reference data of the material to be tested according to the volatile component data set, and calculate the similarity between the volatile component detection data of each batch of samples and the detection reference data, according to the data. To determine the upper threshold, center threshold, and lower threshold of the material to be tested. The visual output module 52 is configured to visually output the comparison result information between the similarity of each batch of samples and the upper threshold, the center threshold, and the lower threshold.
需要说明的是,本实施例提供的挥发性有机成分检测装置的实施方式,与上文中提供的挥发性有机成分检测方法的实施方式类似,故不再赘述。另外需要说明的是,应理解以上装置的各个模块的划分仅仅是一种逻辑功能的划分,实际实现时可以全部或部分集成到一个物理实体上,也可以物理上分开。且这些模块可以全部以软件通过处理元件调用的形式实现;也可以全部以硬件的形式实现;还可以部分模块通过处理元件调用软件的形式实现,部分模块通过硬件的形式实现。例如,数据处理模块可以为单独设立的处理元件,也可以集成在上述装置的某一个芯片中实现,此外,也可以以程序代码的形式存储于上述装置的存储器中,由上述装置的某一个处理元件调用并执行以上数据处理模块的功能。其它模块的实现与之类似。此外这些模块全部或部分可以集成在一起,也可以独立实现。这里所述的处理元件可以是一种集成电路,具有信号的处理能力。在实现过程中,上述方法的各步骤或以上各个模块可以通过处理器元件中的硬件的集成逻辑电路或者软件形式的指令完成。It should be noted that, the implementation of the volatile organic component detection device provided in this embodiment is similar to the implementation of the volatile organic component detection method provided above, so it will not be repeated. In addition, it should be noted that it should be understood that the division of each module of the above apparatus is only a division of logical functions, and may be fully or partially integrated into a physical entity in actual implementation, or may be physically separated. And these modules can all be implemented in the form of software calling through processing elements; they can also all be implemented in hardware; some modules can also be implemented in the form of calling software through processing elements, and some modules can be implemented in hardware. For example, the data processing module can be a separately established processing element, or can be integrated into a certain chip of the above-mentioned device to realize, in addition, it can also be stored in the memory of the above-mentioned device in the form of program code, and processed by one of the above-mentioned devices. The element calls and executes the functions of the above data processing modules. The implementation of other modules is similar. In addition, all or part of these modules can be integrated together, and can also be implemented independently. The processing element described here may be an integrated circuit with signal processing capability. In the implementation process, each step of the above-mentioned method or each of the above-mentioned modules can be completed by an integrated logic circuit of hardware in the processor element or an instruction in the form of software.
例如,以上这些模块可以是被配置成实施以上方法的一个或多个集成电路,例如:一个或多个特定集成电路(Application Specific Integrated Circuit,简称ASIC),或,一个或多个微处理器(digital signal processor,简称DSP),或,一个或者多个现场可编程门阵列(Field Programmable Gate Array,简称FPGA)等。再如,当以上某个模块通过处理元件调度程序代码的形式实现时,该处理元件可以是通用处理器,例如中央处理器(Central Processing Unit,简称CPU)或其它可以调用程序代码的处理器。再如,这些模块可以集成在一起,以片上系统(system-on-a-chip,简称SOC)的形式实现。For example, the above modules may be one or more integrated circuits configured to implement the above methods, such as: one or more specific integrated circuits (Application Specific Integrated Circuit, ASIC for short), or one or more microprocessors ( digital signal processor, referred to as DSP), or, one or more Field Programmable Gate Array (Field Programmable Gate Array, referred to as FPGA) and the like. For another example, when one of the above modules is implemented in the form of processing element scheduling program code, the processing element may be a general-purpose processor, such as a central processing unit (Central Processing Unit, CPU for short) or other processors that can call program codes. For another example, these modules can be integrated together and implemented in the form of a system-on-a-chip (SOC for short).
如图6所示,展示本申请一实施例中检测终端的结构示意图。本实例提供的检测终端,包括:处理器61、存储器62、收发器63、通信接口64和系统总线65;存储器62和通信接口64通过系统总线65与处理器61和收发器63连接并完成相互间的通信,存储器62用于存储计算机程序,通信接口64和收发器63用于和其他设备进行通信,处理器61用于运行计算机程序,使电子终端执行如上挥发性有机成分检测方法的各个步骤。As shown in FIG. 6 , a schematic structural diagram of a detection terminal in an embodiment of the present application is shown. The detection terminal provided in this example includes: a processor 61, a memory 62, a transceiver 63, a communication interface 64, and a system bus 65; the memory 62 and the communication interface 64 are connected to the processor 61 and the transceiver 63 through the system bus 65 and complete each other Communication between, the memory 62 is used to store the computer program, the communication interface 64 and the transceiver 63 are used to communicate with other devices, the processor 61 is used to run the computer program, so that the electronic terminal executes the various steps of the above volatile organic component detection method .
上述提到的系统总线可以是外设部件互连标准(Peripheral ComponentInterconnect,简称PCI)总线或扩展工业标准结构(Extended Industry StandardArchitecture,简称EISA)总线等。该系统总线可以分为地址总线、数据总线、控制总线等。为便于表示,图中仅用一条粗线表示,但并不表示仅有一根总线或一种类型的总线。通信接口用于实现数据库访问装置与其他设备(例如客户端、读写库和只读库)之间的通信。存储器可能包含随机存取存储器(Random Access Memory,简称RAM),也可能还包括非易失性存储器(non-volatile memory),例如至少一个磁盘存储器。The system bus mentioned above may be a Peripheral Component Interconnect (PCI for short) bus or an Extended Industry Standard Architecture (Extended Industry Standard Architecture, EISA for short) bus or the like. The system bus can be divided into address bus, data bus, control bus and so on. For ease of presentation, only one thick line is used in the figure, but it does not mean that there is only one bus or one type of bus. The communication interface is used to realize the communication between the database access device and other devices (eg client, read-write library and read-only library). The memory may include random access memory (Random Access Memory, RAM for short), and may also include non-volatile memory (non-volatile memory), such as at least one disk storage.
上述的处理器可以是通用处理器,包括中央处理器(Central Processing Unit,简称CPU)、网络处理器(Network Processor,简称NP)等;还可以是数字信号处理器(Digital Signal Processing,简称DSP)、专用集成电路(Application SpecificIntegrated Circuit,简称ASIC)、现场可编程门阵列(Field-Programmable Gate Array,简称FPGA)或者其他可编程逻辑器件、分立门或者晶体管逻辑器件、分立硬件组件。The above-mentioned processor may be a general-purpose processor, including a central processing unit (Central Processing Unit, referred to as CPU), a network processor (Network Processor, referred to as NP), etc.; may also be a digital signal processor (Digital Signal Processing, referred to as DSP) , Application Specific Integrated Circuit (ASIC for short), Field-Programmable Gate Array (FPGA for short) or other programmable logic devices, discrete gate or transistor logic devices, and discrete hardware components.
综上所述,本申请提供挥发性有机成分检测方法、装置、存储介质及终端,采用相似度算法和单值质控图实现对包装用纸中VOCs质量稳定性的评估,利用离群值检测方法建立包装用纸中各类VOCs组分基础数据库,并以各VOCs组分检测均值为基准,通过相似度算法计算各批次样品与基准间相似度,以相似度均值及预设倍数相似度标准偏差或相似度限值计算质控图上下限及中心限,绘制相似度质控图,可快速有效评估包装用纸的质量稳定性。所以,本申请有效克服了现有技术中的种种缺点而具高度产业利用价值。To sum up, the present application provides a volatile organic component detection method, device, storage medium and terminal. The similarity algorithm and the single-value quality control chart are used to realize the evaluation of the quality stability of VOCs in packaging paper, and the outlier detection is used. Methods The basic database of various VOCs components in packaging paper was established, and the average detection value of each VOCs component was used as the benchmark, and the similarity between each batch of samples and the benchmark was calculated by the similarity algorithm. The standard deviation or similarity limit can be used to calculate the upper and lower limits and the center limit of the quality control chart, and draw the similarity quality control chart, which can quickly and effectively evaluate the quality stability of packaging paper. Therefore, the present application effectively overcomes various shortcomings in the prior art and has high industrial application value.
上述实施例仅例示性说明本申请的原理及其功效,而非用于限制本申请。任何熟悉此技术的人士皆可在不违背本申请的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本申请所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本申请的权利要求所涵盖。The above-mentioned embodiments merely illustrate the principles and effects of the present application, but are not intended to limit the present application. Anyone skilled in the art can make modifications or changes to the above embodiments without departing from the spirit and scope of the present application. Therefore, all equivalent modifications or changes made by those with ordinary knowledge in the technical field without departing from the spirit and technical idea disclosed in this application should still be covered by the claims of this application.
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