CN109971329A - A kind of high rigidity water paint and preparation method thereof - Google Patents

A kind of high rigidity water paint and preparation method thereof Download PDF

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Publication number
CN109971329A
CN109971329A CN201910185861.4A CN201910185861A CN109971329A CN 109971329 A CN109971329 A CN 109971329A CN 201910185861 A CN201910185861 A CN 201910185861A CN 109971329 A CN109971329 A CN 109971329A
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parts
nano
agent
aqueous polyurethane
high rigidity
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廖世杰
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SICHUAN HONGKAI CHEMICAL TECHNOLOGY Co Ltd
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SICHUAN HONGKAI CHEMICAL TECHNOLOGY Co Ltd
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Priority to CN201910185861.4A priority Critical patent/CN109971329A/en
Publication of CN109971329A publication Critical patent/CN109971329A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of high rigidity water paints and preparation method thereof, belong to water paint technical field, comprise the following components in parts by weight: 60-80 parts of modified aqueous polyurethane;0.1-0.5 parts of nano aluminium oxide;1-2 parts of nano silica, 1-2 parts of nano-titanium dioxide;0.6-0.8 parts of defoaming agent;15-20 parts of deionized water;1-2 parts of levelling agent;1-2 parts of coalescing agent;1-1.5 parts of dispersing agent.Using above-mentioned formula and it is aided with the water paint that the obtained hardness of simple and convenient preparation method is high, wearability is good and heat resistance is strong, synthesis improves the service performance of its relatively general water paint.

Description

A kind of high rigidity water paint and preparation method thereof
Technical field
The present invention relates to water paint technical fields, more particularly, to a kind of high rigidity water paint and preparation method thereof.
Background technique
Paint is rooted in the hearts of the people in consumer, that many consumers understand paint or seldom including some The boss of sale paint more than ten years not quite understands the harm of paint.Paint can only after brushing the latter moon ability It moves in, consumer thinks this when of paint just without toxicity, this is wrong in fact, and no penetrating odor is formaldehyde It has evaporate into the receptible degree of physiology institute of people, and benzene contained in paint curing agent and diluent, toluene, free TDI is also Volatilizing, these things will volatilize completely completely at least needs time of decades, and these aromatic hydrocarbon materials for baby and The intellectual development of unborn child has a significant impact, and free TDI also has carcinogenic danger, countries in Europe very Already prohibit the use of paint.
And water paint, it is the Novel environment-friendlymaterial material using water as diluent, minimum discharge.Paint is replaced with water paint, it can be with VOC content in atmosphere is effectively reduced, and then improves haze weather.Therefore, the mainstream side that sealing wax is also present coating industry is promoted To.
However water paint is in use, hardness, in terms of performance be weaker than paint so that water paint After spray coating, not scratch-resistant and collision is easy depainting, significantly impacts using effect;The heat insulating effect of water paint simultaneously It is poor, when its on building in use, the effect of insulation can not be played to interior, so that room temperature is with external environment Variation is big, and the energy consumption for cooling of air-conditioning can be greatly improved in summer, waste a large amount of energy.
Summary of the invention
The present invention provides a kind of high rigidity water paints and preparation method thereof, low to solve water paint hardness, wear no resistance The problem of.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is summarized as follows:
A kind of high rigidity water paint, comprises the following components in parts by weight: 60-80 parts of modified aqueous polyurethane;It is nano oxidized 0.1-0.5 parts of aluminium;1-2 parts of nano silica, 1-2 parts of nano-titanium dioxide;0.6-0.8 parts of defoaming agent;Deionized water 15-20 Part;1-2 parts of levelling agent;1-2 parts of coalescing agent;1-1.5 parts of dispersing agent;
Wherein, modified aqueous polyurethane includes following component: aqueous polyurethane emulsion and nano ATO (antimony tin), Mass ratio is 10:0.8-1.2.
Aqueous polyurethane is modified using nano ATO, in the intermiscibility for not destroying aqueous polyurethane and deionized water Under conditions of, assign modified aqueous polyurethane with excellent heat preservation and insulation, reduce paint film generated under strong illumination aging, The problem of damage;And nano aluminium oxide, nano silica, nano-titanium dioxide are dispersed in modified water using dispersing agent Property polyurethane in, using between above-mentioned nano material and nano ATO synergistic effect enhancing coating hardness, promote the resistance to of coating Mill property.The present invention is first modified aqueous polyurethane, and is aided with nano aluminium oxide, nano silica, nano-titanium dioxide It is enhanced, so that the paint film hardness with higher that water paint obtained is formed, wearability is enhanced, while also being had There is preferable thermal and insulating performance, improves the synthesis service performance of water paint.
Further, above-mentioned high rigidity water paint, comprises the following components in parts by weight: 70-80 parts of modified aqueous polyurethane; 0.2-0.3 parts of nano aluminium oxide;1-1.5 parts of nano silica, 1.5-2 parts of nano-titanium dioxide;0.7-0.8 parts of defoaming agent; 15-20 parts of deionized water;1.5-2 parts of levelling agent;1.5-2 parts of coalescing agent;1.3-1.5 parts of dispersing agent;
Wherein, modified aqueous polyurethane includes following component: aqueous polyurethane emulsion and nano ATO, mass ratio 10: 1。
Further, the dispersing agent is polyacrylic hydrosol;So that nano aluminium oxide, nano-titanium dioxide, receiving Rice silica can be preferably dispersed in modified aqueous polyurethane, and generate preferable synergistic effect with it, promote coating Hardness, wearability and heat-insulation and heat-preservation.
Further, the levelling agent is the copolymer of siloxanes and polyethers;Its mobility that can improve coating and levelling Property, reduce the disadvantage that coating may generate in coating process.
Further, the coalescing agent is 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates;After water volatilization, Promote paint solution to form the paint film of even compact, improves the film forming of paint solution.
Further, the defoaming agent is the mixture of polyoxypropylene ethylene oxide glycerin ether and dimethyl silicone polymer, Its mass ratio is 1: 1;The bubble in paint solution is eliminated using the defoaming agent of compounding, performance is mild, will not to nano aluminium oxide, The dispersibility of nano silica, nano-titanium dioxide in modified aqueous polyurethane has an impact.
Further, the preparation method of above-mentioned high rigidity water paint, includes the following steps:
(1) pH of aqueous polyurethane emulsion is adjusted between 9-10 with ammonium hydroxide, and by all addition of nano ATO ultrasound Into aqueous polyurethane emulsion, modified aqueous polyurethane is obtained;
(2) by dispersing agent, nano aluminium oxide, nano silica, nano-titanium dioxide, deionized water is put into agitator tank Fast stirring is carried out, mixing speed is controlled in 1400r/min, mixing time 2-5h, is sent in defoaming device and is taken off after stirring 20-25min is steeped, nano material dispersion liquid is obtained;
(3) nano material dispersion liquid, modified aqueous polyurethane, defoaming agent, levelling agent, delustering agent, coalescing agent are put into It in agitator tank, is stirred with the speed of 300-400r/min, after stirring 1-1.5h, pH adjusting agent is added, adjusts mixture PH value is 9-10, obtains high rigidity water paint.
Further, the pH adjusting agent is DMEA.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
1. being modified using nano ATO to aqueous polyurethane, the mixing of nano ATO and aqueous polyurethane is reached and receives Meter level is other, and dispersion effect is good, improves the heat resistance of coating, and can play fabulous heat insulation, meets spray pair Daylighting and heat-insulated dual needs;
2. modified aqueous polyurethane is mixed with nano aluminium oxide, nano silica, nano-titanium dioxide, add Dispersing agent is dispersed in it in modified aqueous polyurethane, under the synergistic effect of these substances, can be improved the hard of coating Degree, wear-resisting property and heat resistanceheat resistant performance, improve the synthesis service performance of coating, and the hardness of coating is in 2H or more;
3. the pH of aqueous polyurethane emulsion is adjusted to 9-10 with ammonium hydroxide when being prepared, so that itself and nano ATO PH value is close, when compounding to the two, its dispersibility is promoted, so that each component distributing in modified aqueous polyurethane obtained Uniformly, the overall performance of coating obtained is promoted;
4. whole preparation process is simple and convenient, and the consumption energy is less, low in cost, practical value with higher.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not used to limit The fixed present invention, i.e., described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Therefore, the model of claimed invention is not intended to limit to the detailed description of the embodiment of the present invention below It encloses, but is merely representative of selected embodiment of the invention.Based on the embodiment of the present invention, those skilled in the art are not making Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of creative work.
It should be noted that the relational terms of term " first " and " second " or the like be used merely to an entity or Operation is distinguished with another entity or operation, and without necessarily requiring or implying between these entities or operation, there are any This actual relationship or sequence.Moreover, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that including described There is also other identical elements in the process, method, article or equipment of element.
Embodiment 1
A kind of high rigidity water paint, comprises the following components in parts by weight: 60 parts of modified aqueous polyurethane;Nano aluminium oxide 0.1 part;1 part of nano silica, 1 part of nano-titanium dioxide;0.6 part of defoaming agent;15 parts of deionized water;1 part of levelling agent;Film forming 1 part of auxiliary agent;1 part of dispersing agent.
The preparation method of above-mentioned high rigidity water paint includes the following steps:
(1) pH of aqueous polyurethane emulsion is adjusted between 9-10 with ammonium hydroxide, and by all addition of nano ATO ultrasound Into aqueous polyurethane emulsion, modified aqueous polyurethane is obtained, wherein the mass ratio of aqueous polyurethane and nano ATO are as follows: 10: 1.2。
(2) by dispersing agent, nano aluminium oxide, nano silica, nano-titanium dioxide, deionized water is put into agitator tank Fast stirring is carried out, mixing speed is controlled in 1400r/min, mixing time 2-5h, is sent in defoaming device and is taken off after stirring 20-25min is steeped, nano material dispersion liquid is obtained;
(3) nano material dispersion liquid, modified aqueous polyurethane, defoaming agent, levelling agent, delustering agent, coalescing agent are put into It in agitator tank, is stirred with the speed of 300-400r/min, after stirring 1-1.5h, DMEA is added as pH adjusting agent, adjusts The pH value of mixture is 9-10, obtains high rigidity water paint.
And respective performances detection is carried out to the high rigidity water paint that the present embodiment obtains, obtained data are as follows:
Hardness of paint film is measured using pencil hardness test, specific test method is referring to " 86 film of GB6739- Hardness pencil measuring method ", the hardness of paint film measured is 2H;
Water resistance (boiling water boiling 1h): each performance is unchanged;
Artificial weathering ageing resistance (600h): it does not blister, is unstripped, flawless.
Embodiment 2
A kind of high rigidity water paint, comprises the following components in parts by weight: 68 parts of modified aqueous polyurethane;Nano aluminium oxide 0.3 part;1.5 parts of nano silica, 1.4 parts of nano-titanium dioxide;0.7 part of defoaming agent;19 parts of deionized water;Levelling agent 1.7 Part;1.5 parts of coalescing agent;1.2 parts of dispersing agent.
The preparation method of above-mentioned high rigidity water paint includes the following steps:
(1) pH of aqueous polyurethane emulsion is adjusted between 9-10 with ammonium hydroxide, and by all addition of nano ATO ultrasound Into aqueous polyurethane emulsion, modified aqueous polyurethane is obtained, wherein the mass ratio of aqueous polyurethane and nano ATO are as follows: 10: 1.1;
(2) by dispersing agent, nano aluminium oxide, nano silica, nano-titanium dioxide, deionized water is put into agitator tank Fast stirring is carried out, mixing speed is controlled in 1400r/min, mixing time 2-5h, is sent in defoaming device and is taken off after stirring 20-25min is steeped, nano material dispersion liquid is obtained;
(3) nano material dispersion liquid, modified aqueous polyurethane, defoaming agent, levelling agent, delustering agent, coalescing agent are put into It in agitator tank, is stirred with the speed of 300-400r/min, after stirring 1-1.5h, DMEA is added as pH adjusting agent, adjusts The pH value of mixture is 9-10, obtains high rigidity water paint.
And respective performances detection is carried out to the high rigidity water paint that the present embodiment obtains, obtained data are as follows:
Hardness of paint film is measured using pencil hardness test, specific test method is referring to " 86 film of GB6739- Hardness pencil measuring method ", the hardness of paint film measured is 2H;
Water resistance (boiling water boiling 1h): each performance is unchanged;
Artificial weathering ageing resistance (600h): it does not blister, is unstripped, flawless.
Embodiment 3
A kind of high rigidity water paint, comprises the following components in parts by weight: 80 parts of modified aqueous polyurethane;Nano aluminium oxide 0.5 part;2 parts of nano silica, 2 parts of nano-titanium dioxide;0.8 part of defoaming agent;20 parts of deionized water;2 parts of levelling agent;Film forming 2 parts of auxiliary agent;1.5 parts of dispersing agent.
The preparation method of above-mentioned high rigidity water paint includes the following steps:
(1) pH of aqueous polyurethane emulsion is adjusted between 9-10 with ammonium hydroxide, and by all addition of nano ATO ultrasound Into aqueous polyurethane emulsion, modified aqueous polyurethane is obtained, wherein the mass ratio of aqueous polyurethane and nano ATO are as follows: 10: 1.2;
(2) by dispersing agent, nano aluminium oxide, nano silica, nano-titanium dioxide, deionized water is put into agitator tank Fast stirring is carried out, mixing speed is controlled in 1400r/min, mixing time 2-5h, is sent in defoaming device and is taken off after stirring 20-25min is steeped, nano material dispersion liquid is obtained;
(3) nano material dispersion liquid, modified aqueous polyurethane, defoaming agent, levelling agent, delustering agent, coalescing agent are put into It in agitator tank, is stirred with the speed of 300-400r/min, after stirring 1-1.5h, DMEA is added as pH adjusting agent, adjusts The pH value of mixture is 9-10, obtains high rigidity water paint.
And respective performances detection is carried out to the high rigidity water paint that the present embodiment obtains, obtained data are as follows:
Hardness of paint film is measured using pencil hardness test, specific test method is referring to " 86 film of GB6739- Hardness pencil measuring method ", the hardness of paint film measured is 2H;
Water resistance (boiling water boiling 1h): each performance is unchanged;
Artificial weathering ageing resistance (600h): it does not blister, is unstripped, flawless.
Embodiment 4
A kind of high rigidity water paint, comprises the following components in parts by weight: 70 parts of modified aqueous polyurethane;Nano aluminium oxide 0.2 part;1 part of nano silica, 1.5 parts of nano-titanium dioxide;0.7 part of defoaming agent;15 parts of deionized water;1.5 parts of levelling agent; 1.5 parts of coalescing agent;1.3 parts of dispersing agent.
The preparation method of above-mentioned high rigidity water paint includes the following steps:
(1) pH of aqueous polyurethane emulsion is adjusted between 9-10 with ammonium hydroxide, and by all addition of nano ATO ultrasound Into aqueous polyurethane emulsion, modified aqueous polyurethane is obtained, wherein the mass ratio of aqueous polyurethane and nano ATO are as follows: 10: 1;
(2) by dispersing agent, nano aluminium oxide, nano silica, nano-titanium dioxide, deionized water is put into agitator tank Fast stirring is carried out, mixing speed is controlled in 1400r/min, mixing time 2-5h, is sent in defoaming device and is taken off after stirring 20-25min is steeped, nano material dispersion liquid is obtained;
(3) nano material dispersion liquid, modified aqueous polyurethane, defoaming agent, levelling agent, delustering agent, coalescing agent are put into It in agitator tank, is stirred with the speed of 300-400r/min, after stirring 1-1.5h, DMEA is added as pH adjusting agent, adjusts The pH value of mixture is 9-10, obtains high rigidity water paint.
And respective performances detection is carried out to the high rigidity water paint that the present embodiment obtains, obtained data are as follows:
Hardness of paint film is measured using pencil hardness test, specific test method is referring to " 86 film of GB6739- Hardness pencil measuring method ", the hardness of paint film measured is 3H;
Water resistance (boiling water boiling 1h): each performance is unchanged;
Artificial weathering ageing resistance (600h): it does not blister, is unstripped, flawless.
It is as described above the embodiment of the present invention.The present invention is not limited to the above-described embodiments, anyone should learn that The structure change made under the inspiration of the present invention, the technical schemes that are same or similar to the present invention each fall within this Within the protection scope of invention.

Claims (8)

1. a kind of high rigidity water paint, which is characterized in that comprise the following components in parts by weight: 60-80 parts of modified aqueous polyurethane; 0.1-0.5 parts of nano aluminium oxide;1-2 parts of nano silica, 1-2 parts of nano-titanium dioxide;0.6-0.8 parts of defoaming agent;Go from Sub- water 15-20 parts;1-2 parts of levelling agent;1-2 parts of coalescing agent;1-1.5 parts of dispersing agent;
Wherein, modified aqueous polyurethane includes following component: aqueous polyurethane emulsion and nano ATO, mass ratio 10:0.8- 1.2。
2. a kind of high rigidity water paint as described in claim 1, which is characterized in that comprise the following components in parts by weight: modified 70-80 parts of aqueous polyurethane;0.2-0.3 parts of nano aluminium oxide;1-1.5 parts of nano silica, nano-titanium dioxide 1.5-2 Part;0.7-0.8 parts of defoaming agent;15-20 parts of deionized water;1.5-2 parts of levelling agent;1.5-2 parts of coalescing agent;Dispersing agent 1.3- 1.5 part;
Wherein, modified aqueous polyurethane includes following component: aqueous polyurethane emulsion and nano ATO, mass ratio 10:1.
3. a kind of high rigidity water paint as described in claim 1, which is characterized in that the dispersing agent is that polyacrylate is water-soluble Liquid.
4. a kind of high rigidity water paint as described in claim 1, which is characterized in that the levelling agent is siloxanes and polyethers Copolymer.
5. a kind of high rigidity water paint as described in claim 1, which is characterized in that the coalescing agent is 2,2,4- front threes Base -1,3- pentanediol mono isobutyrate.
6. a kind of high rigidity water paint as described in claim 1, which is characterized in that the defoaming agent is that polyoxypropylene aoxidizes second The mixture of alkene glycerin ether and dimethyl silicone polymer, mass ratio 1: 1.
7. a kind of preparation method of high rigidity water paint as described in claim 1, which comprises the steps of:
(1) pH of aqueous polyurethane emulsion is adjusted between 9-10 with ammonium hydroxide, and nano ATO ultrasound all is added to water In property polyaminoester emulsion, modified aqueous polyurethane is obtained;
(2) by dispersing agent, nano aluminium oxide, nano silica, nano-titanium dioxide, deionized water is put into agitator tank and carries out Speed stirring, mixing speed control are sent to deaeration 20- in defoaming device in 1400r/min, mixing time 2-5h after stirring 25min obtains nano material dispersion liquid;
(3) nano material dispersion liquid, modified aqueous polyurethane, defoaming agent, levelling agent, coalescing agent are put into agitator tank, with The speed of 300-400r/min is stirred, and after stirring 1-1.5h, pH adjusting agent is added, and the pH value for adjusting mixture is 9-10, Obtain high rigidity water paint.
8. the preparation method of high rigidity water paint as claimed in claim 7, which is characterized in that the pH adjusting agent is DMEA.
CN201910185861.4A 2019-03-12 2019-03-12 A kind of high rigidity water paint and preparation method thereof Pending CN109971329A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115537061A (en) * 2022-09-23 2022-12-30 四川宏凯化工科技有限公司 Water-based paint odor scavenger and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102911591A (en) * 2011-08-04 2013-02-06 中国人民解放军装甲兵工程学院 Transparent thermal insulation coating with nano porous auxiliary and preparation method thereof
CN103073982A (en) * 2013-01-18 2013-05-01 杭州电子科技大学 Preparation method of scratch-resistant transparent heat-insulating coating for building glass
KR101488867B1 (en) * 2014-08-29 2015-02-02 (주)노루페인트 Energy-saving type translucent glass coating composition and translucent energy-saving type glass

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102911591A (en) * 2011-08-04 2013-02-06 中国人民解放军装甲兵工程学院 Transparent thermal insulation coating with nano porous auxiliary and preparation method thereof
CN103073982A (en) * 2013-01-18 2013-05-01 杭州电子科技大学 Preparation method of scratch-resistant transparent heat-insulating coating for building glass
KR101488867B1 (en) * 2014-08-29 2015-02-02 (주)노루페인트 Energy-saving type translucent glass coating composition and translucent energy-saving type glass

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
吴玉程等: "《工程材料基础》", 30 December 2014, 合肥工业大学出版社 *
杜卫民: "《纳米材料化学的理论与工程应用研究》", 31 May 2018, 电子科技大学出版社 *
许戈文等: "纳米氧化锡锑改性水性聚氨酯的制备与表征", 《应用化学》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115537061A (en) * 2022-09-23 2022-12-30 四川宏凯化工科技有限公司 Water-based paint odor scavenger and preparation method thereof

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Application publication date: 20190705