CN109971162A - A kind of rush dormancy memory foam preparation method containing lavender - Google Patents

A kind of rush dormancy memory foam preparation method containing lavender Download PDF

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Publication number
CN109971162A
CN109971162A CN201910289628.0A CN201910289628A CN109971162A CN 109971162 A CN109971162 A CN 109971162A CN 201910289628 A CN201910289628 A CN 201910289628A CN 109971162 A CN109971162 A CN 109971162A
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parts
polyether polyol
memory foam
lavender
method containing
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刘志勇
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Foshan Retz Furniture Co Ltd
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Foshan Retz Furniture Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072Mixtures of compounds of group C08G18/63 with other macromolecular compounds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/63Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/08Polyurethanes from polyethers
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent
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    • C08L2201/00Properties
    • C08L2201/06Biodegradable
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    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to sponge product technical fields, and a kind of rush dormancy memory foam preparation method containing lavender is disclosed, raw material includes: 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, 15 parts of polymer polyatomic alcohol, 8 parts of Lavender, 10 parts of MDI, 6 parts of silica white, 20 parts of polyether polyol EP-330N, 1 part of storage stabilizing agent, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 3 parts of chain extender, 4 parts of water, 1 part of foam stabiliser, 1 part of Sulfur according to parts by weight.The rush dormancy memory foam preparation method containing lavender, Lavender has tranquilizing soporific, relaxs one's muscles, it relieves fatigue, antibacterial action and other effects, so that the memory foam has effects that promote to sleep to calm the nerves, while using the MDI raw material of German import, so that content of formaldehyde is zero, conducive to health and environmental protection, make the present invention promote dormancy memory foam comprehensive performance to get a promotion, product competitiveness in the market is substantially better than existing similar product, has stronger promotional value.

Description

A kind of rush dormancy memory foam preparation method containing lavender
Technical field
The present invention relates to sponge product technical field, specially a kind of rush dormancy memory foam preparation method containing lavender.
Background technique
Memory foam refers to the polyetherurethane foam sponge with low resilience mechanical property, belongs to extraordinary sponge, by Europe The exploitation of continent a company, for English namespace uri MEMORY FOAM, memory foam is its literal translation, domestic also referred to as slow-recovery sponge, Space zero pressure, space cotton, TEMPUR Thailand Poole material, low bounce-back material, viscoelastic sponge etc., sponge product is widely used in In furniture item, and it then will use the gel memory foam with low resilience effect as packing material, mesh in medium-to-high grade furniture Preceding main species are exactly polyethers serial foaming and polyurethane moulding form full series, and low resilience, this is one and aims at slow rebound sponge The noun of manufacture, in terms of it is meant that mechanical property:, will not be anti-immediately when slow rebound sponge has received external force pressure deformation Bullet, but delay several seconds time and slowly restore, so if we press slow rebound sponge with hand, it can be seen that the hand of oneself Print, as slow rebound sponge can remember to oppress its thing shape, the title of " slow rebound sponge " also therefore, low resilience Sponge low resilience performance Producing reason, mainly since it has special cellular foam structure, air is forced out abscess, bubble After hole is crushed, although external force has been dispelled, cell wall also has the elastic force of reduction, and since venthole is tiny, air is not Can immediately return in abscess, abscess can not soon restore shape, and the strength of rebound is suppressed, material deformation restore when Between be just extended.
And there is heat-transfer effect difference in current sponge products, this furniture for allowing for filling sponge is not suitable for the summer It is used in its hot weather, this also affects the universal of the furniture of filling sponge material, and current sponge has rebound time mistake Short, physical property is unstable, easy to oxidize and turn to be yellow and discharge noxious material, and oxidation process is accelerated and discharges peculiar smell, unfavorable It in environmental protection, is easily deformed, more important current memory foam, which is difficult to, promotees the effect calmed the nerves of sleeping, too especially for many Busy, the indefinite user of thought, and Lavender complicated component contains tens kinds of compounds, main ingredient have linalool, Bergamio, cineole, β-ocimenum, terpene -4- alcohol, camphor, different, the contained component difference in the type of lavender, the place of production Very big, this just determines that their the different market prices, different application ranges and different odor types, Lavender have town Quiet hypnosis relaxs one's muscles, and relieves fatigue, antibacterial action, reduces the effect of scar, for this purpose, proposing that a kind of rush containing lavender is slept Memory foam preparation method solves the above problems.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the rush dormancy memory foam preparation method containing lavender that the present invention provides a kind of, tool Standby heat-transfer effect is good, indeformable, environmentally friendly and promote the advantages that the calming the nerves that sleep, and solves traditional memory foam there are using effects not Good problem.
(2) technical solution
For the purpose that the above-mentioned heat-transfer effect of realization is good, indeformable, environmentally friendly and rush sleeps tranquilizing the mind, the present invention provides following technology A kind of scheme: rush dormancy memory foam preparation method containing lavender, comprising the following steps:
S1, prepare raw material: raw material include: according to parts by weight 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, 15 parts of polymer polyatomic alcohol, 8 parts of Lavender, 10 parts of MDI, 6 parts of silica white, 20 parts of polyether polyol EP-330N, storage 1 part of stabilizer, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 3 parts of chain extender, 4 parts of water, 1 part of foam stabiliser, 1 part of Sulfur.
S2, according to predetermined weight score by 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, polymer polyatomic alcohol 1 part of 15 parts, 6 parts of silica white, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 4 parts of water and foam stabiliser are injected into mixing simultaneously It is mixed 1-2 hours in machine, the first mixture is made;
S3, it will be stirred under the 20 parts of room temperature of polyether polyol EP-330N measured according to predetermined weight score in step S1 It mixes, after being warming up to 90-100 DEG C, dehydration degassing 2-3 hours, are then cooled to 50- under vacuum degree < 00.9MPa vacuum condition 60 DEG C, 1 part of 3 parts of chain extender, storage stabilizing agent measuring and 1 part of Sulfur is added, is warming up to 80-85 DEG C of reaction 2-3 hours, drops It is spare that the second mixture is made in temperature;
S4, the second mixture obtained in the first mixture obtained in step S2 and step S3 is added separately to mix Mixing is stirred in machine, whipping temp is 30-40 DEG C, and mixing time is 1 hour, and third mixture is made;
S5, third mixture obtained in 8 parts of Lavender, 10 parts of MDI and step S4 is added to third mixing together In object, it is stirred mixing, mixing speed turns for 4000-5000 per minute, and mixing time is 10 minutes, and essential oil mixing is made Object;
S6, mold is preheated to 40-50 DEG C, mould filling coefficient 103%-126%, die pressure 10MPa-15MPa, The blend of essential oils being stirred is poured into mold and is foamed, is opened within 8-10 minutes, stands 1-2 hours, the note containing lavender is made Recall sponge.
The technical program is advanced optimized, the slow-rebound polyether polyol hydroxyl value is 220-320mgKOH/g, described poly- The hydroxyl value for closing object polyalcohol is 25-30mgKOH/g.
The technical program is advanced optimized, the polyether polyol uses polyether polyol for soft PU foam, and soft bubble polyether polyols The hydroxyl value of alcohol is 48-56mgKOH/g.
The technical program is advanced optimized, the organotin catalysts are dibutyl tin dilaurate, and the crosslinking agent is Trimethylolpropane.
The technical program is advanced optimized, the chain extender is diethylene glycol, and the foam stabiliser is AK-7703.
The technical program is advanced optimized, each raw material temperature before injecting mixing machine controls in the step S2 20-25℃。
The technical program is advanced optimized, the MDI raw material are by the modified MDI raw material of German import, and product reaches European environmental protection TVOC burst size of methanal is zero standard, and is authenticated by U.S. certipur-us.
The technical program is advanced optimized, the fineness of the silica white is preferably 60-80 mesh.
Lavender effect has: analgesic, anti-twitch, anti-depression, anti-inflammatory, antirheumatic, antibacterial, anti-spasm, it is antiviral, kill Bacterium, Eradicates ventosity, cholagogue, promotion scab, are excited, promoting cellular activity.Decongesting and deswelling, deodorization, removing toxic substances, diuresis, Promoting menstruation killing fungus, reduces blood pressure, benefit nerve, replys health, is calm, sharp spleen, urge sweat, control wound.Hypertension, bronchitis, larynx Throat pain, cold, throat inflammation, asthma, pulmonary tuberculosis, indigestion, DOMS, bald head, Oily, regeneration smoothing wrinkle, Pimples, anti-inflammatory, promotion scab, eczema, sunburn of burning, tinea, the insane crazy, menstruation of sheep have some setbacks, cramp, help produce, leukorrhea, mitigation Pressure mitigates relaxed and comfortable melancholy uneasy, insomnia, body and mind, antibacterial, deodorization, sterilization and expelling parasite.
(3) beneficial effect
Compared with prior art, the rush dormancy memory foam preparation method containing lavender that the present invention provides a kind of, have with It is lower the utility model has the advantages that
1, the rush dormancy memory foam preparation method for containing lavender, Lavender have tranquilizing soporific, relax one's muscles, delay Solution fatigue, antibacterial action and other effects, so that the memory foam has effects that promote to sleep to calm the nerves, while using the MDI of German import Raw material are conducive to health and environmental protection so that content of formaldehyde is zero, so that the present invention is promoted dormancy memory foam comprehensive performance and get a promotion, Product competitiveness in the market is substantially better than existing similar product, has stronger promotional value.
2, the rush dormancy memory foam preparation method for containing lavender, the addition of silica white, silica white can with it is original slow Rebound gel sponge structure realization combines well, continuous thermally conductive pathways structure is formed, to improve the heat dissipation of memory foam Function has achieved the effect that not heat build-up of radiating, has made it have salubrious effect.
3, the rush dormancy memory foam preparation method for containing lavender, the present invention has low resilience property, and has both resistance to height Mild resistance to ag(e)ing and biodegradable environment friendly, material surface is smooth, specious, and excellent in mechanical performance is constant Shape, the application suitable for human contact.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
A kind of embodiment one: rush dormancy memory foam preparation method containing lavender, comprising the following steps:
S1, prepare raw material: raw material include: according to parts by weight 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, 15 parts of polymer polyatomic alcohol, 8 parts of Lavender, 10 parts of MDI, 6 parts of silica white, 20 parts of polyether polyol EP-330N, storage 1 part of stabilizer, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 3 parts of chain extender, 4 parts of water, 1 part of foam stabiliser, 1 part of Sulfur.
S2, according to predetermined weight score by 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, polymer polyatomic alcohol 1 part of 15 parts, 6 parts of silica white, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 4 parts of water and foam stabiliser are injected into mixing simultaneously It is mixed 1-2 hours in machine, the first mixture is made;
S3, it will be stirred under the 20 parts of room temperature of polyether polyol EP-330N measured according to predetermined weight score in step S1 It mixes, after being warming up to 90 DEG C, dehydration degassing 2 hours, are then cooled to 50 DEG C under vacuum degree < 00.9MPa vacuum condition, are added 3 parts of the chain extender measured, 1 part of storage stabilizing agent and 1 part of Sulfur, are warming up to 80-85 DEG C and react 2 hours, and cooling is made second Mixture is spare;
S4, the second mixture obtained in the first mixture obtained in step S2 and step S3 is added separately to mix Mixing is stirred in machine, whipping temp is 30-40 DEG C, and mixing time is 1 hour, and third mixture is made;
S5, third mixture obtained in 8 parts of Lavender, 10 parts of MDI and step S4 is added to third mixing together In object, it is stirred mixing, mixing speed is 4000 turns per minute, and mixing time is 10 minutes, and blend of essential oils is made;
S6, mold is preheated to 40-50 DEG C, mould filling coefficient 103%-126%, die pressure 10MPa-15MPa, The blend of essential oils being stirred is poured into mold and is foamed, is opened within 8-10 minutes, stands 1-2 hours, the note containing lavender is made Recall sponge.
As the specific prioritization scheme of the present embodiment, slow-rebound polyether polyol hydroxyl value is 220-320mgKOH/g, described The hydroxyl value of polymer polyatomic alcohol is 25-30mgKOH/g.
As the specific prioritization scheme of the present embodiment, polyether polyol uses polyether polyol for soft PU foam, and soft bubble polyethers is more The hydroxyl value of first alcohol is 48-56mgKOH/g.
As the specific prioritization scheme of the present embodiment, organotin catalysts are dibutyl tin dilaurate, the crosslinking agent For trimethylolpropane.
As the specific prioritization scheme of the present embodiment, chain extender is diethylene glycol, and the foam stabiliser is AK-7703.
As the specific prioritization scheme of the present embodiment, MDI raw material are by the modified MDI raw material of German import, and product reaches It is zero standard to European environmental protection TVOC burst size of methanal, and is authenticated by U.S. certipur-us
As the specific prioritization scheme of the present embodiment, the fineness of silica white is preferably 60-80 mesh.
A kind of embodiment two: rush dormancy memory foam preparation method containing lavender, comprising the following steps:
S1, prepare raw material: raw material include: according to parts by weight 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, 15 parts of polymer polyatomic alcohol, 8 parts of Lavender, 10 parts of MDI, 6 parts of silica white, 20 parts of polyether polyol EP-330N, storage 1 part of stabilizer, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 3 parts of chain extender, 4 parts of water, 1 part of foam stabiliser, 1 part of Sulfur.
S2, according to predetermined weight score by 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, polymer polyatomic alcohol 1 part of 15 parts, 6 parts of silica white, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 4 parts of water and foam stabiliser are injected into mixing simultaneously It is mixed 1-2 hours in machine, the first mixture is made;
S3, it will be stirred under the 20 parts of room temperature of polyether polyol EP-330N measured according to predetermined weight score in step S1 It mixes, after being warming up to 95 DEG C, dehydration degassing 2.5 hours, are then cooled to 55 DEG C, add under vacuum degree < 00.9MPa vacuum condition Enter 1 part of 3 parts of chain extender, storage stabilizing agent measuring and 1 part of Sulfur, is warming up to 80-85 DEG C and reacts 2.5 hours, cool down, be made Second mixture is spare;
S4, the second mixture obtained in the first mixture obtained in step S2 and step S3 is added separately to mix Mixing is stirred in machine, whipping temp is 30-40 DEG C, and mixing time is 1 hour, and third mixture is made;
S5, third mixture obtained in 8 parts of Lavender, 10 parts of MDI and step S4 is added to third mixing together In object, it is stirred mixing, mixing speed is 4500 turns per minute, and mixing time is 10 minutes, and blend of essential oils is made;
S6, mold is preheated to 40-50 DEG C, mould filling coefficient 103%-126%, die pressure 10MPa-15MPa, The blend of essential oils being stirred is poured into mold and is foamed, is opened within 8-10 minutes, stands 1-2 hours, the note containing lavender is made Recall sponge.
As the specific prioritization scheme of the present embodiment, slow-rebound polyether polyol hydroxyl value is 220-320mgKOH/g, described The hydroxyl value of polymer polyatomic alcohol is 25-30mgKOH/g.
As the specific prioritization scheme of the present embodiment, polyether polyol uses polyether polyol for soft PU foam, and soft bubble polyethers is more The hydroxyl value of first alcohol is 48-56mgKOH/g.
As the specific prioritization scheme of the present embodiment, organotin catalysts are dibutyl tin dilaurate, the crosslinking agent For trimethylolpropane.
As the specific prioritization scheme of the present embodiment, chain extender is diethylene glycol, and the foam stabiliser is AK-7703.
As the specific prioritization scheme of the present embodiment, MDI raw material are by the modified MDI raw material of German import, and product reaches It is zero standard to European environmental protection TVOC burst size of methanal, and is authenticated by U.S. certipur-us
As the specific prioritization scheme of the present embodiment, the fineness of silica white is preferably 60-80 mesh.
A kind of embodiment three: rush dormancy memory foam preparation method containing lavender, comprising the following steps:
S1, prepare raw material: raw material include: according to parts by weight 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, 15 parts of polymer polyatomic alcohol, 8 parts of Lavender, 10 parts of MDI, 6 parts of silica white, 20 parts of polyether polyol EP-330N, storage 1 part of stabilizer, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 3 parts of chain extender, 4 parts of water, 1 part of foam stabiliser, 1 part of Sulfur.
S2, according to predetermined weight score by 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, polymer polyatomic alcohol 1 part of 15 parts, 6 parts of silica white, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 4 parts of water and foam stabiliser are injected into mixing simultaneously It is mixed 1-2 hours in machine, the first mixture is made;
S3, it will be stirred under the 20 parts of room temperature of polyether polyol EP-330N measured according to predetermined weight score in step S1 It mixes, after being warming up to 100 DEG C, dehydration degassing 3 hours, are then cooled to 60 DEG C, add under vacuum degree < 00.9MPa vacuum condition Enter 1 part of 3 parts of chain extender, storage stabilizing agent measuring and 1 part of Sulfur, be warming up to 80-85 DEG C and react 3 hours, cooling is made the Two mixtures are spare;
S4, the second mixture obtained in the first mixture obtained in step S2 and step S3 is added separately to mix Mixing is stirred in machine, whipping temp is 30-40 DEG C, and mixing time is 1 hour, and third mixture is made;
S5, third mixture obtained in 8 parts of Lavender, 10 parts of MDI and step S4 is added to third mixing together In object, it is stirred mixing, mixing speed is 5000 turns per minute, and mixing time is 10 minutes, and blend of essential oils is made;
S6, mold is preheated to 40-50 DEG C, mould filling coefficient 103%-126%, die pressure 10MPa-15MPa, The blend of essential oils being stirred is poured into mold and is foamed, is opened within 8-10 minutes, stands 1-2 hours, the note containing lavender is made Recall sponge.
As the specific prioritization scheme of the present embodiment, slow-rebound polyether polyol hydroxyl value is 220-320mgKOH/g, described The hydroxyl value of polymer polyatomic alcohol is 25-30mgKOH/g.
As the specific prioritization scheme of the present embodiment, polyether polyol uses polyether polyol for soft PU foam, and soft bubble polyethers is more The hydroxyl value of first alcohol is 48-56mgKOH/g.
As the specific prioritization scheme of the present embodiment, organotin catalysts are dibutyl tin dilaurate, the crosslinking agent For trimethylolpropane.
As the specific prioritization scheme of the present embodiment, chain extender is diethylene glycol, and the foam stabiliser is AK-7703.
As the specific prioritization scheme of the present embodiment, MDI raw material are by the modified MDI raw material of German import, and product reaches It is zero standard to European environmental protection TVOC burst size of methanal, and is authenticated by U.S. certipur-us
As the specific prioritization scheme of the present embodiment, the fineness of silica white is preferably 60-80 mesh.
By three embodiment strength Experimental comparisons, optimal product result is embodiment two, it is therefore preferable that embodiment two is made For the most preferred embodiment of the technical program, it should be appreciated that the application of the present invention is not limited to the above, it is general to this field For logical technical staff, it can be modified or changed according to the above description, and all these modifications and variations all should belong to this hair The protection scope of bright appended claims.
Lavender effect has: analgesic, anti-twitch, anti-depression, anti-inflammatory, antirheumatic, antibacterial, anti-spasm, it is antiviral, kill Bacterium, Eradicates ventosity, cholagogue, promotion scab, are excited, promoting cellular activity.Decongesting and deswelling, deodorization, removing toxic substances, diuresis, Promoting menstruation killing fungus, reduces blood pressure, benefit nerve, replys health, is calm, sharp spleen, urge sweat, control wound.Hypertension, bronchitis, larynx Throat pain, cold, throat inflammation, asthma, pulmonary tuberculosis, indigestion, DOMS, bald head, Oily, regeneration smoothing wrinkle, Pimples, anti-inflammatory, promotion scab, eczema, sunburn of burning, tinea, the insane crazy, menstruation of sheep have some setbacks, cramp, help produce, leukorrhea, mitigation Pressure mitigates relaxed and comfortable melancholy uneasy, insomnia, body and mind, antibacterial, deodorization, sterilization and expelling parasite.
The beneficial effects of the present invention are: this contains the rush dormancy memory foam preparation method of lavender, Lavender has town Quiet hypnosis relaxs one's muscles, and relieves fatigue, antibacterial action and other effects, so that the memory foam has effects that promote to sleep to calm the nerves, simultaneously Using the MDI raw material of German import, so that content of formaldehyde is zero, it is conducive to health and environmental protection, the present invention is made to promote dormancy memory foam Comprehensive performance gets a promotion, and product competitiveness in the market is substantially better than existing similar product, has stronger promotional value, silica white Addition, silica white can with original low resilience gel sponge structure realize be combined well, form continuous thermally conductive pathways Structure has achieved the effect that not heat build-up of radiating, has made it have salubrious effect, this hair to improve the heat sinking function of memory foam It is bright that there is low resilience property, and have both high temperature resistant and resistance to ag(e)ing and biodegradable environment friendly, material surface light Sliding, specious, excellent in mechanical performance is indeformable, suitable for the application of human contact, cooperates with and makees between each component of the present invention There is good toughness with the memory foam of, preparation, it is not tearable in use process, the characteristics of long service life.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. a kind of rush dormancy memory foam preparation method containing lavender, which comprises the following steps:
S1, prepare raw material: raw material includes: 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, polymerization according to parts by weight 15 parts of object polyalcohol, 8 parts of Lavender, MDI10 parts, 6 parts of silica white, EP-330N20 parts of polyether polyol, storage stabilizing agent 1 part, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 3 parts of chain extender, 4 parts of water, 1 part of foam stabiliser, 1 part of Sulfur.
S2, according to predetermined weight score by 50 parts of slow-rebound polyether polyol, 30 parts of polyether polyol, polymer polyatomic alcohol 15 Part, 6 parts of silica white, 2 parts of organotin catalysts, 2 parts of crosslinking agent, 4 parts of water and 1 part of foam stabiliser are injected into mixing machine simultaneously The first mixture is made in middle mixing 1-2 hours;
S3, it will stir, heat up under the EP-330N20 parts of room temperature of polyether polyol measured according to predetermined weight score in step S1 To after 90-100 DEG C, dehydration degassing 2-3 hours, are then cooled to 50-60 DEG C, add under vacuum degree < 00.9MPa vacuum condition Enter 1 part of 3 parts of chain extender, storage stabilizing agent measuring and 1 part of Sulfur, be warming up to 80-85 DEG C of reaction 2-3 hours, cool down, is made Second mixture is spare;
S4, the second mixture obtained in the first mixture obtained in step S2 and step S3 is added separately in mixing machine It is stirred mixing, whipping temp is 30-40 DEG C, and mixing time is 1 hour, and third mixture is made;
S5, third mixture obtained in 8 parts, MDI10 parts of Lavender and step S4 is added together in third mixture, It is stirred mixing, mixing speed turns for 4000-5000 per minute, and mixing time is 10 minutes, and blend of essential oils is made;
S6, mold is preheated to 40-50 DEG C, mould filling coefficient 103%-126%, die pressure 10MPa-15MPa will be stirred The blend of essential oils mixed, which pours into mold, to foam, and is opened within 8-10 minutes, stands 1-2 hours, and the memory sea containing lavender is made It is continuous.
2. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that described slow time Playing polyether polyol hydroxyl value is 220-320mgKOH/g, and the hydroxyl value of the polymer polyatomic alcohol is 25-30mgKOH/g.
3. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that the polyethers Polyalcohol uses polyether polyol for soft PU foam, and the hydroxyl value of polyether polyol for soft PU foam is 48-56mgKOH/g.
4. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that described organic Tin catalyst is dibutyl tin dilaurate, and the crosslinking agent is trimethylolpropane.
5. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that the chain extension Agent is diethylene glycol, and the foam stabiliser is AK-7703.
6. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that the step Each raw material temperature before injecting mixing machine is controlled at 20-25 DEG C in S2.
7. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that the MDI Raw material are by the modified MDI raw material of German import, and it is zero standard that product, which reaches European environmental protection TVOC burst size of methanal, and is passed through U.S. certipur-us certification.
8. a kind of rush dormancy memory foam preparation method containing lavender according to claim 1, which is characterized in that the silica gel The fineness of powder is preferably 60-80 mesh.
CN201910289628.0A 2019-04-11 2019-04-11 A kind of rush dormancy memory foam preparation method containing lavender Pending CN109971162A (en)

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Application publication date: 20190705