CN109971160A - A kind of shiny-leaved yellowhorn memory foam and preparation method thereof - Google Patents

A kind of shiny-leaved yellowhorn memory foam and preparation method thereof Download PDF

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Publication number
CN109971160A
CN109971160A CN201910232324.0A CN201910232324A CN109971160A CN 109971160 A CN109971160 A CN 109971160A CN 201910232324 A CN201910232324 A CN 201910232324A CN 109971160 A CN109971160 A CN 109971160A
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parts
shiny
polyether polyol
leaved yellowhorn
yellowhorn
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Inventor
林永泉
阮志忠
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Shanghai Xin Yuan Novel Material Science And Technology Ltd
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Shanghai Xin Yuan Novel Material Science And Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/4808Mixtures of two or more polyetherdiols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/02CO2-releasing, e.g. NaHCO3 and citric acid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • C08J2375/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/10Block- or graft-copolymers containing polysiloxane sequences
    • C08J2483/12Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2499/00Characterised by the use of natural macromolecular compounds or of derivatives thereof not provided for in groups C08J2401/00 - C08J2407/00 or C08J2489/00 - C08J2497/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

The invention discloses a kind of shiny-leaved yellowhorn memory foams, in parts by weight, it is formulated are as follows: A:30-80 parts of polyether polyol, B:20-50 parts of polyether polyol, C:10-20 parts of polyether polyol, 0.1-0.8 parts of catalyst, 1-2 parts of silicone oil, shinyleaf yellowhorn shell active carbon powder: 5-20 parts, 3-10 parts of shiny-leaved yellowhorn benevolence powder, water: 1-10 parts, 40-80 parts of isocyanates.Wherein, shinyleaf yellowhorn shell active carbon powder is solid active carbon powder, and shiny-leaved yellowhorn benevolence powder is the solid powdery substance after natural shiny-leaved yellowhorn benevolence crushes by extracting after baking.The present invention reduces the sponge influence to environment and field worker physical and mental health in process of production, reaches environmentally protective requirement compared with tradition;On the other hand, by the way that in formula system, addition shinyleaf yellowhorn shell active carbon powder can effectively adsorb the smell of sponge and reduce the VOC content of sponge;Shiny-leaved yellowhorn benevolence powder is added, can effectively play the role of antibacterial bacteriostatic, and natural pollution-free, to make memory foam more health environment-friendly.

Description

A kind of shiny-leaved yellowhorn memory foam and preparation method thereof
Technical field
The present invention relates to a kind of sponge materials, and in particular to a kind of shiny-leaved yellowhorn memory foam and preparation method thereof.
Background technique
Soft polyurethane foam memory foam is fairly common applied to family property aspect, is especially used in pillow, mattress aspect. General memory foam all selects TDI as the raw material of synthesis, and in process of production, to environment, the physical and mental health of worker is all It has a certain impact.Meanwhile soft polyurethane foam memory foam is produced also only as just a kind of processing material of pillow mattress Material, without other additional functions.
To solve the above-mentioned problems, we are made that a series of improvement.
Summary of the invention
The object of the present invention is to provide a kind of novel shiny-leaved yellowhorn memory foam family property materials, to overcome the prior art Existing disadvantages mentioned above and deficiency.
A kind of shiny-leaved yellowhorn memory foam, which is characterized in that in parts by weight, formula are as follows: polyether polyol A:30- 80 parts, B:20-50 parts of polyether polyol, C:10-50 parts of polyether polyol, 0.1-0.8 parts of catalyst, 1-2 parts of silicone oil, shiny-leaved yellowhorn Shell active carbon powder: 5-20 parts, 3-10 parts of shiny-leaved yellowhorn benevolence powder, water: 1-10 parts, 40-80 parts of isocyanates;
Wherein, the shinyleaf yellowhorn shell active carbon powder is solid active carbon powder, and the shiny-leaved yellowhorn benevolence powder is natural text Hat kernel passes through the solid powdery substance extracted after baking, the shinyleaf yellowhorn shell active carbon powder and shiny-leaved yellowhorn benevolence powder after crushing The adding proportion at end is 2:1, and the water content of the shinyleaf yellowhorn shell active carbon powder controls the shiny-leaved yellowhorn benevolence within 0.05% The acid value of powder controls within 0.1mg/g.
Further, in parts by weight, it is formulated are as follows: A:60 parts of polyether polyol, B:30 parts of polyether polyol, polyethers C:10 parts of polyalcohol, catalyst: 0.56 part, silicone oil: 1.4 parts, shinyleaf yellowhorn shell active carbon powder: 10 parts, shiny-leaved yellowhorn benevolence powder: 5 Part, water: 3.2 parts, isocyanates: 45 parts.
Further, the polyether polyol A is the polyalcohol of hydroxyl value 35mgK0H/g.
Further, the polyether polyol B is the polyalcohol of hydroxyl value 120mgK0H/g.
Further, the polyether polyol C is the polyalcohol of hydroxyl value 28mgK0H/g.
Further, the catalyst is amine and tin catalyst.
Further, the classes of silicone oils is polyether modified silicon oil.
Further, isocyanates MDI.
A kind of preparation method of shiny-leaved yellowhorn memory foam, which comprises the following steps:
(1) preparation of raw material: according to being formulated that the raw material preparation is good;
(2) it mixes: the ready polyether polyol A of step (1), polyether polyol B, polyether polyol C is mixed, with The speed of 6000rpm stirs 6~8s;
(3) it adds: by the mixed solution of step (2) after the reaction was completed, while adding shinyleaf yellowhorn shell active carbon powder and urging Agent after placing 30 minutes, continues while adding shiny-leaved yellowhorn benevolence powder and silicone oil, adds isocyanates after placing 30 minutes;
(4) milky white: mixture being quickly poured into mold, observes it by the translucent viscous fluid for fading to full muddiness, whitening Body;
(5) gel: the foams for observing rising stop increasing, and stablize simultaneously gel, have a large amount of bubbles to spit out from the epidermis.
Beneficial effects of the present invention:
The present invention reduces the sponge influence to environment and field worker physical and mental health in process of production compared with tradition, Reach environmentally protective requirement;On the other hand, by the way that in formula system, addition shinyleaf yellowhorn shell active carbon powder can effectively be inhaled The smell of attached sponge and the VOC content for reducing sponge;Shiny-leaved yellowhorn benevolence powder is added, antibacterial bacteriostatic can be effectively played the role of, And it is natural pollution-free.To make memory foam more health environment-friendly.
Specific embodiment
Below in conjunction with specific embodiment, progress explanation is made to the present invention.It should be understood that following embodiment is merely to illustrate this hair It is bright not for limiting the scope of the invention.
Embodiment 1
A kind of shiny-leaved yellowhorn memory foam, which is characterized in that in parts by weight, formula are as follows: polyether polyol A:30- 80 parts, B:20-50 parts of polyether polyol, C:10-50 parts of polyether polyol, 0.1-0.8 parts of catalyst, 1-2 parts of silicone oil, shiny-leaved yellowhorn Shell active carbon powder: 5-20 parts, 3-10 parts of shiny-leaved yellowhorn benevolence powder, water: 1-10 parts, 40-80 parts of isocyanates;
Wherein, shinyleaf yellowhorn shell active carbon powder is solid active carbon powder, and shiny-leaved yellowhorn benevolence powder is natural shiny-leaved yellowhorn benevolence powder Pass through the solid powdery substance extracted after baking, the adding proportion of shinyleaf yellowhorn shell active carbon powder and shiny-leaved yellowhorn benevolence powder after broken Water content for 2:1, shinyleaf yellowhorn shell active carbon powder controls within 0.05%, and the acid value control of shiny-leaved yellowhorn benevolence powder exists Within 0.1mg/g.
In the present embodiment, in parts by weight, it is formulated are as follows: A:50 parts of polyether polyol, polyether polyol B:35 Part, C:15 parts of polyether polyol, catalyst: 0.5 part, silicone oil: 1.6 parts, shinyleaf yellowhorn shell active carbon powder: 10 parts, shiny-leaved yellowhorn benevolence Powder: 5 parts, water: 3.8 parts, isocyanates: 54.6 parts.
Polyether polyol A is the polyalcohol of hydroxyl value 35mgK0H/g.
Polyether polyol B is the polyalcohol of hydroxyl value 120mgK0H/g.
Polyether polyol C is the polyalcohol of hydroxyl value 28mgK0H/g.
Catalyst is amine and tin catalyst.
Classes of silicone oils is polyether modified silicon oil.
Isocyanates is MDI.
A kind of preparation method of shiny-leaved yellowhorn memory foam the following steps are included:
(1) preparation of raw material: according to being formulated that raw material preparation is good;
(2) it mixes: the ready polyether polyol A of step (1), polyether polyol B, polyether polyol C is mixed, with The speed of 6000rpm stirs 6~8s;
(3) it adds: by the mixed solution of step (2) after the reaction was completed, while adding shinyleaf yellowhorn shell active carbon powder and urging Agent after placing 30 minutes, continues while adding shiny-leaved yellowhorn benevolence powder and silicone oil, adds isocyanates after placing 30 minutes;
(4) milky white: mixture being quickly poured into mold, observes it by the translucent viscous fluid for fading to full muddiness, whitening Body;
(5) gel: the foams for observing rising stop increasing, and stablize simultaneously gel, have a large amount of bubbles to spit out from the epidermis.
Technical characteristic of the invention, first: present invention mainly solves the problem of on the one hand, pass through select MDI as synthesis The raw material of soft polyurethane foam memory foam reduce sponge in process of production to the shadow of environment and field worker physical and mental health It rings, reaches environmentally protective requirement.On the other hand, by the way that in formula system, addition shinyleaf yellowhorn shell active carbon powder can be effective Absorption sponge smell and reduce sponge VOC content;Add shiny-leaved yellowhorn benevolence powder, (in shiny-leaved yellowhorn benevolence containing sterol at Point), it can effectively play the role of antibacterial bacteriostatic, and natural pollution-free.To make memory foam more health environment-friendly.Generally Family property memory foam all uses TDI as the raw material of synthesis, and problem is obvious in terms of smell and VOC, while family property is remembered Recalling cotton and applying needs certain antibacterial bacteriostatic effect in terms of pillow mattress.
It followed by realizes process, a certain amount of shiny-leaved yellowhorn benevolence powder and shinyleaf yellowhorn shell activity is added in conventional formulation system Carbon powder is that problematic, of the invention shinyleaf yellowhorn shell active carbon powder is solid active carbon powder, and shiny-leaved yellowhorn benevolence powder is Natural shiny-leaved yellowhorn benevolence passes through the solid powdery substance extracted after baking after crushing.Both solid additives are easier to react simultaneously Play corresponding effect.But need to consider the compatibility and these substances of these ingredients and polyethers in adding procedure Acid-base property, the influence to foaming system such as water imbibition.It therefore, is the change for being directed to polyethers first, we use three kinds of polyethers The hybrid plan of polyalcohol, comprising: polyether polyol A is the polyalcohol of hydroxyl value 35mgK0H/g, polyether polyol B is hydroxyl value The solid additive that the polyalcohol and polyether polyol C of 120mgK0H/g is the polyalcohol of hydroxyl value 28mgK0H/g to cooperate addition. Secondly, the water content of shinyleaf yellowhorn shell active carbon powder is controlled within 0.05%.Finally by the acid value control of shiny-leaved yellowhorn benevolence powder System is within 0.1mg/g
Finally we are in the ratio on the additive amount of these substances, control shinyleaf yellowhorn shell active carbon powder and shiny-leaved yellowhorn benevolence The adding proportion of powder is 2:1, to guarantee that the design of parameter is not in deviation.It is also exactly the mode added, and catalysis The selection of agent, the selection of classes of silicone oils.As Attention Points above are still adhered in specific solution, catalyst uses amine Class and tin catalyst.Classes of silicone oils uses polyether modified silicon oil.During the preparation process, complete using the scheme successively mixed respectively At reaction.
A specific embodiment of the invention is illustrated above, but the present invention is not limited thereto, without departing from Spirit of the invention, the present invention can also have various change.

Claims (9)

1. a kind of shiny-leaved yellowhorn memory foam, which is characterized in that in parts by weight, formula are as follows: polyether polyol A:30-80 Part, B:20-50 parts of polyether polyol, C:10-20 parts of polyether polyol, 0.1-0.8 parts of catalyst, 1-2 parts of silicone oil, shinyleaf yellowhorn shell Active carbon powder: 5-20 parts, 3-10 parts of shiny-leaved yellowhorn benevolence powder, water: 1-10 parts, 40-80 parts of isocyanates;
Wherein, the shinyleaf yellowhorn shell active carbon powder is solid active carbon powder, and the shiny-leaved yellowhorn benevolence powder is natural shiny-leaved yellowhorn Benevolence passes through the solid powdery substance extracted after baking, the shinyleaf yellowhorn shell active carbon powder and shiny-leaved yellowhorn benevolence powder after crushing Adding proportion is 2:1, and the water content of the shinyleaf yellowhorn shell active carbon powder controls the shiny-leaved yellowhorn benevolence powder within 0.05% Acid value control within 0.1mg/g.
2. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that in parts by weight, formula Are as follows: A:60 parts of polyether polyol, B:30 parts of polyether polyol, C:10 parts of polyether polyol, catalyst: 0.56 part, silicone oil: 1.4 Part, shinyleaf yellowhorn shell active carbon powder: 10 parts, shiny-leaved yellowhorn benevolence powder: 5 parts, water: 3.2 parts, isocyanates: 45 parts.
3. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that the polyether polyol A is hydroxyl value The polyalcohol of 35mgK0H/g.
4. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that the polyether polyol B is hydroxyl value The polyalcohol of 120mgK0H/g.
5. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that the polyether polyol C is hydroxyl value The polyalcohol of 28mgK0H/g.
6. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that the catalyst is amine and tin class Catalyst.
7. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that the classes of silicone oils is polyether-modified Silicone oil.
8. a kind of shiny-leaved yellowhorn memory foam according to claim 1, which is characterized in that isocyanates MDI.
9. a kind of preparation method of shiny-leaved yellowhorn memory foam, which comprises the following steps:
(1) preparation of raw material: according to being formulated that the raw material preparation is good;
(2) it mixes: the ready polyether polyol A of step (1), polyether polyol B, polyether polyol C is mixed, with The speed of 6000rpm stirs 6~8s;
(3) it adds: by the mixed solution of step (2) after the reaction was completed, while adding shinyleaf yellowhorn shell active carbon powder and catalyst, After placing 30 minutes, continue while adding shiny-leaved yellowhorn benevolence powder and silicone oil, adds isocyanates after placing 30 minutes;
(4) milky white: mixture being quickly poured into mold, observes it by the translucent thick liquid for fading to full muddiness, whitening;
(5) gel: the foams for observing rising stop increasing, and stablize simultaneously gel, have a large amount of bubbles to spit out from the epidermis.
CN201910232324.0A 2019-03-26 2019-03-26 A kind of shiny-leaved yellowhorn memory foam and preparation method thereof Pending CN109971160A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5079239A (en) * 1990-02-16 1992-01-07 Harbor Branch Oceanographic Institution, Inc. Sterol disulfates and methods of use
CN102153080A (en) * 2011-03-29 2011-08-17 内蒙古农业大学 Yellowhorn shell activated carbon and preparation method thereof
CN102153722A (en) * 2011-02-25 2011-08-17 北京万博汇佳科贸有限公司 Slow-resilience polyether polyol and method for manufacturing slow-resilience soft foam therewith
CN105669935A (en) * 2016-03-03 2016-06-15 上海大学 Hemp stalk core powder modified antibacterial type soft polyurethane composite foaming material
CN107828231A (en) * 2017-11-30 2018-03-23 重庆色度科技有限公司 A kind of high-tension sponge applied to child safety seat and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5079239A (en) * 1990-02-16 1992-01-07 Harbor Branch Oceanographic Institution, Inc. Sterol disulfates and methods of use
CN102153722A (en) * 2011-02-25 2011-08-17 北京万博汇佳科贸有限公司 Slow-resilience polyether polyol and method for manufacturing slow-resilience soft foam therewith
CN102153080A (en) * 2011-03-29 2011-08-17 内蒙古农业大学 Yellowhorn shell activated carbon and preparation method thereof
CN105669935A (en) * 2016-03-03 2016-06-15 上海大学 Hemp stalk core powder modified antibacterial type soft polyurethane composite foaming material
CN107828231A (en) * 2017-11-30 2018-03-23 重庆色度科技有限公司 A kind of high-tension sponge applied to child safety seat and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
何东平: "《木本油料加工技术》", 31 October 2016, 中国轻工业出版社 *

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