CN109970202A - A kind of black-odor riverway administering method strengthened based on electricity - Google Patents

A kind of black-odor riverway administering method strengthened based on electricity Download PDF

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Publication number
CN109970202A
CN109970202A CN201811573194.9A CN201811573194A CN109970202A CN 109970202 A CN109970202 A CN 109970202A CN 201811573194 A CN201811573194 A CN 201811573194A CN 109970202 A CN109970202 A CN 109970202A
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China
Prior art keywords
water
black
river
strengthened
cathode
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CN201811573194.9A
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Chinese (zh)
Inventor
孙黎
马瑶
马力
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ANHUI HUIZETONG ENVIRONMENTAL TECHNOLOGY Co Ltd
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ANHUI HUIZETONG ENVIRONMENTAL TECHNOLOGY Co Ltd
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Priority to CN201811573194.9A priority Critical patent/CN109970202A/en
Publication of CN109970202A publication Critical patent/CN109970202A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/005Combined electrochemical biological processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/163Nitrates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/009Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a kind of black-odor riverway administering methods strengthened based on electricity, are related to water-treatment technology field.Including establishing electric strengthened artificial wet land system, wind-photovoltaic complementary power supply system and water body transportation system;Rainwater and river water are delivered to after electric strengthened artificial wet land system carries out purified treatment by water body transportation system and are discharged into river again;Wherein electric strengthened artificial wet land system includes vertical current constructed wetland and the electrode pair that is arranged on vertical current constructed wetland;Electrode is to including cathode and anode.The present invention passes through the anodic oxidation of iron and the cathode denitrification of graphite felt, using electronics caused by scene as electron donor, the removing of nitrogen phosphorus, high-efficiency cleaning are carried out, the unit area treating capacity of artificial swamp is greatly increased, the construction cost of land area and artificial swamp has been saved.

Description

A kind of black-odor riverway administering method strengthened based on electricity
Technical field
The invention belongs to water-treatment technology fields, more particularly to a kind of black-odor riverway administering method strengthened based on electricity.
Background technique
Urban rives are the important components of the water-based important component in basin and urban ecological system, are municipal waters One of the index that environmental quality is judged.Lifeblood of the urban river as city not only has water circulation, water and soil conservation, water storage tune The functions such as flood, water quality self-restraint, but also be adjustable temperature and humidity, improve urban microclimate, healthy Urban Water Environment is that city can The important leverage of sustainable development.However as the quickening of economic fast development and urbanization, many urban river water quality in China Pollution and Ecological degenerative problem are very prominent, or even seasonality and perennially black and odorous water phenomenon occur.Therefore, city is solved The pollution in river, the ecology for restoring river and social function problem are passes urgently to be resolved during many urban sustainable developments One of key task." water prevention and cure of pollution action plan " requirement that State Council prints and distributes, arrives the year two thousand twenty, the Changjiang river, the Yellow River, the Zhujiang River, preserved egg Excellent (reaching or better than the III class) ratio of the big major river valley water quality in river, Huaihe River, Haihe River, Liaohe River etc. seven totally reaches 70% or more, Ground level and the above completed region of the city black and odorous water control within 10%.To the year two thousand thirty, national seven big major river valley water quality are excellent Good ratio totally reaches 75% or more, and completed region of the city black and odorous water is totally eliminated, city centralization drinking water source water Matter reaches or is generally 95% or so better than III class ratio.
The usual water body normally transparent degree of black-odor riverway is poor, and TN, TP and ammonia nitrogen are exceeded serious, some are detained in rivers COD also It severely exceeds, oxidation-reduction potential is low, and habitat is severe, and water body loses self-purification capacity.Cause the black smelly reason in river mainly again External source enters two aspect of river pollution and endogenous pollution.The pollutants such as a large amount of nitrogen phosphorus and organic matter, nothing are usually contained in initial rainwater Control the pollution situation that river can be aggravated into river.Meanwhile contaminated river is also required to fast purification, to be conducive to aquatic The recovery of state.
For current these problems, novel fast purification facility is needed to be collected purification to first rain and to black Smelly river water carries out strengthened purification.Electric energy is provided using wind light mutual complementing based on the artificial swamp that electricity is strengthened, utilizes iron as anode, Graphite felt is cathode, can quickly be removed to the nitrogen phosphorus in water body, and can degrade to organic matter.Electric strengthened artificial is wet Wetland variation efficiency can be improved in ground, reduces occupied area, is particluarly suitable for using in the treating city black foul river of soil anxiety.
Summary of the invention
The purpose of the present invention is to provide a kind of black-odor riverway administering methods strengthened based on electricity, pass through the anodic oxidation of iron The removing of nitrogen phosphorus, high-efficient cleaning are carried out using electronics caused by scene as electron donor with the cathode denitrification of graphite felt It is clean, the unit area treating capacity of artificial swamp is greatly increased, the construction cost of land area and artificial swamp has been saved.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
The present invention is a kind of black-odor riverway administering method strengthened based on electricity, comprising:
A, electric strengthened artificial wet land system, wind-photovoltaic complementary power supply system and water body transportation system are established;
B, after rainwater and river water being delivered to electric strengthened artificial wet land system progress purified treatment by water body transportation system It is discharged into river again.
Further, the electric strengthened artificial wet land system includes vertical current constructed wetland and is arranged in perpendicular flow artificial Electrode pair on wetland;
Wherein, the vertical current constructed wetland includes a pond body, is filled with filler in the pond body;The top of the pond body Drainpipe and water inlet pipe are respectively equipped with bottom;
Wherein, the electrode is to including cathode and anode, and the anode is iron staff, and the cathode is graphite felt;The sun Pole and cathode are all made of wind-photovoltaic complementary power supply system and are powered.
Further, the anode and cathode is laid in pond body top;The laying height of the anode and cathode is pond The 1/4-3/4 of body total height;The arrangement of anode and cathode is to lay a pair of of anode and cathode, sun every 50-100cm distance The spacing of pole and cathode is 40-60cm.
Further, the filler includes haydite, biomass carbon, stone and gravel.
Further, a gravel layer is equipped at the top and bottom of the pond body.
Further, the water body transportation system includes interconnected rainwater-collecting ditch and rainwater collection pool;Further include The river water in rainwater collection pool and river is pumped to the primer pump and water pipeline of electric strengthened artificial wet land system respectively.
Further, when operation, which is intake water inlet tube by bottom, and the water after final purification is by pond body The drainpipe discharge wetland pond body on top enters river.
Further, when carrying out rainwater treatment, rainwater is introduced by the primer pump being laid in rainwater collection pool and is hung down Direct current artificial swamp is handled;For the just high problem of ammonia-nitrogen content in the rain, the vertical current constructed wetland is by top drainpipe It intakes, the reoxygenation effect at top is made full use of first to be nitrified, and the denitrification and dephosphorization function progress nitrogen phosphorus of electricity reinforcing are de- It removes, enters back into bottom.
It further, can be by the primer pump that is laid in river by rainwater in no rainwater or black smelly river burst Vertical current constructed wetland is introduced to be handled;It, should for nitrate nitrogen in river under even in everyday situations and the higher problem of total nitrogen content Vertical current constructed wetland is intake water inlet tube by bottom, via the denitrification dephosphorization function that denitrification and electricity are strengthened, after final purification Water enters river by the drainpipe discharge wetland pond body on top;Carry out denitrification, the water after final purification by lower part drainpipe Discharge wetland pond body enters river.
Further, also kind is implanted with plant on the gravel layer at the top of the pond body of vertical current constructed wetland;The plant Including canna, reed, the stem or leaf of cattail, wild rice stem, vetiver etc..
The invention has the following advantages:
1, the present invention is made by the anodic oxidation of iron and the cathode denitrification of graphite felt using electronics caused by scene For electron donor, the removing of nitrogen phosphorus is carried out, high-efficiency cleaning greatly increases the unit area treating capacity of artificial swamp, saves The construction cost of land area and artificial swamp.
2, the present invention considers the Nitrogen form feature of rainwater and river respectively, by the laying of primer pump and aqueduct, The operational mode for flexibly changing vertical-flow wetland, realizes optimal riverway water quality purification effect, can effectively administer external source and endogenous dirt Dye prevents river from black smelly phenomenon occurs.
3, the present invention carries out the supply of the electric energy of wetland by wind light mutual complementing, realizes energy conservation and safeguards simple function, And the adaptability of weather is greatly increased, and has saved operating cost.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, will be described below to embodiment required Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for ability For the those of ordinary skill of domain, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is that present invention electricity strengthens vertical streaming artificial wet land system structural schematic diagram;
Fig. 2 is that electrolysis electricity strengthens vertical streaming artificial wet land system when carrying out enterprising underwater water outlet to the removal effect of ammonia nitrogen Fruit;
Fig. 3 is that electrolysis electricity strengthens removal of the vertical streaming artificial wet land system when carrying out lower water inlet upper water-out to nitrate nitrogen Effect.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts all other Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
A kind of black-odor riverway administering method strengthened based on electricity, comprising:
A, electric strengthened artificial wet land system, wind-photovoltaic complementary power supply system 1 and water body transportation system are established;
B, after rainwater and river water being delivered to electric strengthened artificial wet land system progress purified treatment by water body transportation system It is discharged into river again.
Preferably, electric strengthened artificial wet land system includes vertical current constructed wetland 3 and is arranged in vertical current constructed wetland On electrode to 2;
Wherein, the vertical current constructed wetland 3 includes a pond body, is filled with filler in the pond body;The top of the pond body Portion and bottom are respectively equipped with drainpipe 4 and water inlet pipe 5;
Wherein, the electrode includes cathode and anode to 2, and the anode is iron staff, and the cathode is graphite felt;The sun Pole and cathode are all made of wind-photovoltaic complementary power supply system and are powered.
The anode and cathode is laid in pond body top;The laying height of the anode and cathode is pond body total height 1/4-3/4;The arrangement of anode and cathode is to lay a pair of of anode and cathode every 50-100cm distance, anode and cathode Spacing is 40-60cm.
The filler includes haydite, biomass carbon, stone and gravel.
A gravel layer is equipped at the top and bottom of the pond body.
The water body transportation system includes interconnected rainwater-collecting ditch and rainwater collection pool;It further include respectively by rainwater River water in collecting pit and river is pumped to the primer pump and water pipeline of electric strengthened artificial wet land system.
Also kind is implanted with plant 6 on the gravel layer at the top of the pond body of vertical current constructed wetland 3;The plant 6 includes beauty People any of several broadleaf plants, reed, the stem or leaf of cattail, wild rice stem, vetiver etc..
Embodiment 2
When carrying out the purification of initial rainwater and malodorous black water, due to contain in initial rainwater and malodorous black water ammonia nitrogen concentration compared with Height, at this time electricity strengthen vertical-flow wetland using it is upper water inlet and the form of lower water outlet, in favor of the oxidation of ammonia nitrogen.
Water flow flowing mode are as follows: flowed by porous water pipe from drainpipe 4, then led from the gravel layer of the other end by water inlet pipe 5 Out.
When the voltage of power supply system maintains 20V, in the flow process of water, released by electrolytic iron sacrificed anticathode Phosphorus in iron ion and water generates insoluble ferric phosphate, carries out the removal of phosphorus.And during intaking gradually downlink, due to Dissolved oxygen gradually decreases, and denitrification is gradually dominant, under the assistance of exogenous electron, can carry out the denitrification of electric reinforcing Effect, while realizing the removal of nitrogen, promote the water quality that river enters flowing water.
Test result as shown in Fig. 2, hydraulic detention time be 20 hours when, can the ammonia nitrogen to 50mg/L thoroughly taken off It removes.
Embodiment 3
When the purification of daily carry out river water and the maintenance of wetland, since nitrate nitrogen content is higher in river water, at this time to nitre The removal of state nitrogen and denitrification and total nitrogen is crucial;At this time electricity strengthen vertical-flow wetland using it is lower water inlet and the form of upper water-out, In favor of denitrification.
Water flow flowing mode are as follows: flowed by porous water pipe from water inlet pipe 5, then led from the gravel layer of the other end by drainpipe 4 Out.
When the voltage of power supply system maintains 20V, test result as shown in figure 3, hydraulic detention time be 10 hours when, i.e., Can the nitrate nitrogen to 50mg/L thoroughly removed.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example. Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (6)

1. a kind of black-odor riverway administering method strengthened based on electricity characterized by comprising
A, electric strengthened artificial wet land system, wind-photovoltaic complementary power supply system (1) and water body transportation system are established;
B, rainwater and river water are delivered to after electric strengthened artificial wet land system carries out purified treatment by water body transportation system and are arranged again Enter river.
2. a kind of black-odor riverway administering method strengthened based on electricity according to claim 1, which is characterized in that the electricity is strong Changing artificial wet land system includes vertical current constructed wetland (3) and the electrode being arranged on vertical current constructed wetland to (2);
Wherein, the vertical current constructed wetland includes a pond body, is filled with filler in the pond body;The top and bottom of the pond body Portion is respectively equipped with drainpipe (4) and water inlet pipe (5);
Wherein, the electrode is to including cathode and anode, and the anode is iron staff, and the cathode is graphite felt;The anode and Cathode is all made of wind-photovoltaic complementary power supply system and is powered.
3. a kind of black-odor riverway administering method strengthened based on electricity according to claim 2, which is characterized in that the anode Pond body top is laid in cathode.
4. a kind of black-odor riverway administering method strengthened based on electricity according to claim 2, which is characterized in that the filler Including haydite, biomass carbon, stone and gravel.
5. a kind of black-odor riverway administering method strengthened based on electricity according to claim 2 or 3, which is characterized in that described A gravel layer is equipped at the top and bottom of pond body.
6. a kind of black-odor riverway administering method strengthened based on electricity according to claim 1, which is characterized in that the water body Transportation system includes interconnected rainwater-collecting ditch and rainwater collection pool;Further including respectively will be in rainwater collection pool and river River water is pumped to the primer pump and water pipeline of electric strengthened artificial wet land system.
CN201811573194.9A 2018-12-21 2018-12-21 A kind of black-odor riverway administering method strengthened based on electricity Pending CN109970202A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112875978A (en) * 2020-12-02 2021-06-01 灵珑生态科技(江苏)有限公司 Utilize river course pollution bypass clean system that electrolysis is reinforceed

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003080260A (en) * 2001-09-13 2003-03-18 Mitsui Eng & Shipbuild Co Ltd Water or soil quality improving method and system
WO2014071069A1 (en) * 2012-10-31 2014-05-08 Battelle Memorial Institute Process water treatment using liquid-liquid extraction technology
CN105152351A (en) * 2015-10-13 2015-12-16 南京大学 Photoelectric artificial wetland and application thereof
CN207468298U (en) * 2017-10-16 2018-06-08 苏州德华生态环境科技股份有限公司 A kind of scientific and technological wetland bank filter system administered for black-odor riverway
CN207619112U (en) * 2017-12-05 2018-07-17 上海清宁环境规划设计有限公司 A kind of collaboration power supply nitration denitrification strengthened denitrification device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003080260A (en) * 2001-09-13 2003-03-18 Mitsui Eng & Shipbuild Co Ltd Water or soil quality improving method and system
WO2014071069A1 (en) * 2012-10-31 2014-05-08 Battelle Memorial Institute Process water treatment using liquid-liquid extraction technology
CN105152351A (en) * 2015-10-13 2015-12-16 南京大学 Photoelectric artificial wetland and application thereof
CN207468298U (en) * 2017-10-16 2018-06-08 苏州德华生态环境科技股份有限公司 A kind of scientific and technological wetland bank filter system administered for black-odor riverway
CN207619112U (en) * 2017-12-05 2018-07-17 上海清宁环境规划设计有限公司 A kind of collaboration power supply nitration denitrification strengthened denitrification device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112875978A (en) * 2020-12-02 2021-06-01 灵珑生态科技(江苏)有限公司 Utilize river course pollution bypass clean system that electrolysis is reinforceed

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Application publication date: 20190705