CN109970025A - Water vapour hydrogen production process and device - Google Patents
Water vapour hydrogen production process and device Download PDFInfo
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- CN109970025A CN109970025A CN201910250549.9A CN201910250549A CN109970025A CN 109970025 A CN109970025 A CN 109970025A CN 201910250549 A CN201910250549 A CN 201910250549A CN 109970025 A CN109970025 A CN 109970025A
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- metal powder
- hydrogen
- reactor
- water vapor
- water vapour
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract 93
- 239000001257 hydrogen Substances 0.000 title claims abstract 41
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract 41
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract 40
- 238000004519 manufacturing process Methods 0.000 title claims abstract 16
- 229910052751 metal Inorganic materials 0.000 claims abstract 94
- 239000002184 metal Substances 0.000 claims abstract 94
- 239000000843 powder Substances 0.000 claims abstract 76
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 17
- 239000007788 liquid Substances 0.000 claims abstract 17
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 17
- 239000001301 oxygen Substances 0.000 claims abstract 17
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract 15
- 150000004706 metal oxides Chemical class 0.000 claims abstract 15
- 238000010438 heat treatment Methods 0.000 claims abstract 14
- 230000006698 induction Effects 0.000 claims abstract 3
- 230000035939 shock Effects 0.000 claims abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 12
- 239000000567 combustion gas Substances 0.000 claims 9
- 239000000295 fuel oil Substances 0.000 claims 9
- 239000002817 coal dust Substances 0.000 claims 7
- 238000006243 chemical reaction Methods 0.000 claims 6
- 238000002485 combustion reaction Methods 0.000 claims 5
- 230000004044 response Effects 0.000 claims 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 3
- -1 conveyance conduit Substances 0.000 claims 3
- 238000009434 installation Methods 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000003245 coal Substances 0.000 claims 2
- 238000002309 gasification Methods 0.000 claims 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims 1
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 claims 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 claims 1
- 229910000027 potassium carbonate Inorganic materials 0.000 claims 1
- 239000004323 potassium nitrate Substances 0.000 claims 1
- 235000010333 potassium nitrate Nutrition 0.000 claims 1
- 239000004304 potassium nitrite Substances 0.000 claims 1
- 235000010289 potassium nitrite Nutrition 0.000 claims 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims 1
- 229910052939 potassium sulfate Inorganic materials 0.000 claims 1
- 235000011151 potassium sulphates Nutrition 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 235000017557 sodium bicarbonate Nutrition 0.000 claims 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 239000004317 sodium nitrate Substances 0.000 claims 1
- 235000010344 sodium nitrate Nutrition 0.000 claims 1
- 235000010288 sodium nitrite Nutrition 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 238000009841 combustion method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/10—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Abstract
Vapor hydrogen manufacturing combustion method and device, water is converted into high-pressure steam by steam generator and water vapour booster, high-pressure water vapor and metal powder enter reactor by conveying device, helical blade is installed in reactor cavity, reactor and helical blade are installed into high frequency or hyperfrequency heater coil, high frequency or hyperfrequency heater coil induction heating high-pressure water vapor and metal powder and helical blade, high-pressure water vapor and high-temperature metal powder or fusing metal powder liquid or gasified metal Forward rotational movement and shock helical blade in helical reactors, high-temperature metal powder or fusing high-temperature metal powder liquid or gasified metal are reacted with oxygen in water vapour, generate metal oxide, isolate hydrogen, hydrogen and metal oxide are projected by the reactor other end.
Description
Technical field
The present invention relates to water vapour hydrogen preparation fields.
Background technique
High-pressure water vapor and metal powder mixing are not yet retrieved, into helical reactors；Helical reactors are installed into high frequency
Or in hyperfrequency heater coil, high-pressure water vapor and metal powder Forward rotational movement and shock helical-blade in helical reactors
Piece, machinery dispel metal powder surface oxidation film, improve water vapour and metal powder temperature, excite metal powder reactivity, promote gold
Belong to powder to react with oxygen in water vapour, generates oxide, isolate the hydrogen manufacturing combustion method of hydrogen.
It not yet retrieves high-pressure water vapor to mix with metal powder, high-pressure water vapor and metal powder enter reactor exocoel；Combustion
Intracavitary high-pressure water vapor and metal powder outside the combustion gas of burning or fuel oil or pulverized coal flame heating response device inner cavity and reactor, reactor
Outer intracavitary high-temperature metal powder or fusing high-temperature metal powder liquid or gasified metal are reacted with oxygen in water vapour, generate metal oxide,
Heat is released, hydrogen is isolated；Hydrogen and metal oxide and metal oxidation heat are projected by the reactor exocoel other end；Hydrogen and air
Middle oxygen reaction, burning generate water, release heat；The combustion gas of burning or fuel oil or pulverized coal flame are by another end-fire in reactor inner cavity
Out；The hydrogen manufacturing combustion method that hydrogen burning flame is mixed with combustion gas or fuel oil or pulverized coal flame.
Not yet retrieve high frequency or hyperfrequency heater induction heating high-pressure water vapor and metal powder and helical reactors and
Helical blade is made metal powder surface oxide melt or gasify, ruptured, swashed by high frequency or hyperfrequency heater skin effect
Hair metal powder reactivity, high-pressure water vapor and metal powder Forward rotational movement and shock helical blade in helical reactors,
Make metal powder surface oxide bursts, metal powder is promoted to react with oxygen in water vapour, generate oxide, isolates the hydrogen manufacturing combustion of hydrogen
Firing method.
Summary of the invention
The purpose of the present invention: 1, high-pressure water vapor carrying metal powder is provided enter reactor；Heat high-pressure water vapor and gold
Belong to powder；High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, are generated metal oxide, are put
Heat out isolates the hydrogen production process of hydrogen.2, it provides the hydrogen of high-temperature water vapor and the manufacture of high-temperature metal powder method for oxidation, passes through
The method of hydrogen permeating material purification.3, it provides and high-temperature water vapor is reacted into combustion with oxygen with the hydrogen that high-temperature metal powder method for oxidation manufactures
It burns, generates water, exothermic method.4, it provides and enters the hydrogen of high-temperature water vapor and the manufacture of high-temperature metal powder method for oxidation also
Former reaction unit；Hydrogen and reactive metal oxide, the method for restoring metal.5, it provides high-temperature water vapor and high-temperature metal powder
The hydrogen of method for oxidation manufacture is mixed with water vapour；Hydrogen and oxygen reactive combustion heat vapor；Overheated steam driving steam turbine or
The method of heating boiler, advantage are: reducing heating container, container heating steam intermediate link improves the thermal efficiency.6, providing will
The hydrogen burning and combustion gas or fuel oil or pulverized coal flame Hybrid Heating of high-temperature water vapor and the manufacture of high-temperature metal powder method for oxidation
Method.7, high-pressure water vapor and metal powder Forward rotational movement and shock helical blade, machinery in helical reactors are dispelled
Metal powder surface oxidation film improves water vapour and metal powder temperature, excites metal powder reactivity, promotes metal powder and water vapour
Middle oxygen reaction, generates oxide, the method for isolating hydrogen.8, high frequency or hyperfrequency heater line are installed by helical reactors
In circle, high frequency or hyperfrequency heater induction heating high-pressure water vapor and metal powder and helical reactors and helical blade pass through
High frequency or hyperfrequency heater skin effect make metal powder surface oxide melt or gasify, pass through high-pressure water vapor and metal
Powder hits helical blade, and machinery dispels metal powder surface oxidation film, excites metal powder reactivity, promotes metal powder and water vapour
Middle oxygen reaction, generates oxide, the method for isolating hydrogen.9, hydrogen projects heating sodium hydroxide or hydrogen-oxygen with by the reactor other end
Change potassium, sodium hydroxide or potassium hydroxide are reacted with nitrogen dioxide, sodium nitrate or sodium nitrite or potassium nitrate or potassium nitrite are generated,
Sodium hydroxide or potassium hydroxide are reacted with sulfur dioxide, generate sodium sulphate or sodium bisulfate or potassium sulfate or potassium acid sulfate；Hydrogen-oxygen
Change sodium or potassium hydroxide and carbon dioxide reaction, the method for generating sodium carbonate or sodium bicarbonate or potassium carbonate or saleratus.
The present invention proposes a kind of water vapour hydrogen production process: water is converted into high pressure by steam generator and water vapour booster
Vapor；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heat high-pressure water vapor and
Metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, generate metal oxide,
Heat is released, hydrogen is isolated.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted by steam generator and water vapour booster
High-pressure steam；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating response device and
High-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, raw
At metal oxide, heat is released, hydrogen is isolated；Hydrogen is purified by hydrogen permeating material.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted by steam generator and water vapour booster
High-pressure steam；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating response device and
High-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, raw
At metal oxide, heat is released, hydrogen is isolated；Hydrogen and oxygen reactive combustion generate water, release heat.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted by steam generator and water vapour booster
High-pressure steam；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating response device and
High-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, raw
At metal oxide, heat is released, hydrogen is isolated；Hydrogen enters reduction reaction device, hydrogen and reactive metal oxide, restores gold
Belong to.
Advantage is: 1, metal oxide is reduced into metal by hydrogen, the various metals in suitable minerals, according to hydrogen and metal oxygen
The difference of compound reducing condition, by temperature in control closed container, pressure can extract different gold in different temperatures respectively
Belong to.2, since melting temperature metal is low, metal oxide fusion temperature is high, and when extracting metal with heating, metal oxide is stayed
In metallic ore, metal oxide is reduced into metal with hydrogen, metal earning rate can be improved.3, metal oxide is reduced by hydrogen
Metal, product is water, free from environmental pollution.4, hydrogen economizes on resources discarded oxidation mineral reduction metal.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted by steam generator and water vapour booster
High-pressure steam；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating response device and
High-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, raw
At metal oxide, heat is released, hydrogen is isolated；Hydrogen is mixed with water vapour, hydrogen and oxygen reactive combustion, heats vapor, overheat
Vapor driving steam turbine or heating boiler.
Advantage is: hydrogen flame heating steam；It reduces hydrogen and heats container, container heating steam link improves the thermal efficiency.
Another kind water vapour hydrogen production process proposed by the present invention: reactor includes exocoel and inner cavity, and high-pressure water vapor carries
Metal powder enters reactor exocoel；Combustion gas or fuel oil or coal dust enter reactor inner cavity, heating response device inner cavity and outer intracavitary height
Press water vapour and metal powder；Intracavitary high-temperature metal powder or fusing metal powder liquid or gasified metal and oxygen in water vapour are anti-outside reactor
It answers, generates metal oxide, isolate hydrogen；Hydrogen is projected by the reactor exocoel other end；Combustion gas or fuel oil or coal dust are by reactor
The inner cavity other end projects；Hydrogen burning flame is mixed with combustion gas or fuel oil or pulverized coal flame.
Another kind water vapour hydrogen production process proposed by the present invention, water is converted by steam generator and water vapour booster
High-pressure steam；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor inner cavity；Combustion gas or combustion
Oil or coal dust enter reactor exocoel, heating response device exocoel and inner cavity high-pressure water vapor and metal powder；Reactor inner cavity high temperature
Metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, are generated metal oxide, are isolated hydrogen；Hydrogen
It is projected and is burnt by the reactor inner cavity other end；Combustion gas or fuel oil or coal dust are projected by the reactor exocoel other end to burn.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted into high-pressure water vapor by steam generator；It is high
Pressure water vapour is mixed with metal powder, and high-pressure water vapor and metal powder enter helical reactors；Helical reactors be installed into high frequency or
In hyperfrequency heater heating coil, high frequency or hyperfrequency heater induction heating high-pressure water vapor and metal powder and spiral response
Device and helical blade；High-pressure water vapor and metal powder Forward rotational movement and shock helical blade in helical reactors；High temperature
Metal powder or fusing high-temperature metal powder liquid or gasified metal are reacted with oxygen in water vapour, are generated metal oxide, are isolated hydrogen.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted into high-pressure water vapor by steam generator；It is high
Press water vapour and aluminium powder and magnesium powder mixing；High-pressure water vapor and aluminium powder and magnesium powder enter helical reactors；Helical reactors installation
Into in high frequency or hyperfrequency heater heating coil, high frequency or hyperfrequency heater induction heating high-pressure water vapor and aluminium powder and magnesium
Powder and helical reactors and helical blade；High-pressure water vapor and aluminium powder and magnesium powder Forward rotational movement and are hit in helical reactors
Hit helical blade；Aluminium powder is reacted with oxygen in water vapour, is generated aluminum oxide, is isolated hydrogen；Magnesium powder is reacted with oxygen in water vapour,
Magnesia is generated, hydrogen is isolated.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted into high-pressure water vapor by steam generator；It is high
Pressure water vapour is mixed with aluminium powder and magnesium powder, and high-pressure water vapor and aluminium powder and magnesium powder enter reactor exocoel；Intracavitary peace outside reactor
Fill helical blade；Combustion gas or fuel oil or coal dust enter reactor inner cavity, intracavitary high pressure water outside heating response device inner cavity and reactor
Steam and aluminium powder and magnesium powder, high-pressure water vapor and high temperature aluminium powder or aluminium powder liquid and high temperature magnesium powder or magnesium powder liquid are in helical reactors
Forward rotational movement and shock helical blade；Intracavitary aluminium powder is reacted with oxygen in water vapour outside reactor, generates aluminum oxide, point
Separate out hydrogen；Magnesium powder is reacted with oxygen in water vapour, is generated magnesia, is isolated hydrogen；Hydrogen and aluminum oxide and magnesia are by reacting
The device exocoel other end projects；Hydrogen is reacted with oxygen in air, and burning generates water, releases heat；Combustion gas or fuel oil or coal dust firing fire
Flame is projected by the reactor inner cavity other end.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted into high-pressure water vapor by steam generator；It is high
Press water vapour and aluminium powder and the mixing of lithium powder；Into helical reactors；Helical reactors are installed into high frequency or hyperfrequency heater adds
In heat coil, high frequency or hyperfrequency heater induction heating high-pressure water vapor and aluminium powder and lithium powder and helical reactors and helical-blade
Piece；High-pressure water vapor and high temperature aluminium powder or aluminium powder liquid and lithium powder liquid or gasification lithium Forward rotational movement and are hit in helical reactors
Hit helical blade；Metallic aluminium is reacted with oxygen in water vapour, is generated aluminum oxide, is isolated hydrogen；Oxygen and lithium and aluminium in water vapour
It reacts, generates lithium aluminate, isolate hydrogen；Hydrogen and aluminum oxide and lithium aluminate and heat are by another end-fire of helical reactors
Out.
Another kind water vapour hydrogen production process proposed by the present invention: water is converted into high-pressure water vapor by steam generator；It is high
Press water vapour and aluminium powder and magnesium powder and the mixing of lithium powder；Into helical reactors；Helical reactors are installed into high frequency or hyperfrequency adds
In hot device heating coil, high frequency or hyperfrequency heater induction heating high-pressure water vapor and aluminium powder and magnesium powder and lithium powder and spiral reverse
Answer device and helical blade；High-pressure water vapor and high temperature aluminium powder or aluminium powder liquid and magnesium powder or magnesium powder liquid or gasification magnesium and lithium powder liquid or gas
Change lithium Forward rotational movement and shock helical blade in helical reactors；Metallic aluminium is reacted with oxygen in water vapour, generates three oxygen
Change two aluminium, releases heat, isolate hydrogen；Oxidation reaction occurs for oxygen and magnesium in water vapour, generates magnesia, releases heat, separation
Hydrogen out；Oxygen reacts with lithium and aluminium in water vapour, generates lithium aluminate, releases heat, isolates hydrogen；Hydrogen and aluminum oxide and
Magnesia and lithium aluminate and heat are projected by the helical reactors other end.
Water vapour hydrogen production process is further improved scheme: catalyst is packed into container；Water vapour and catalyst reaction；It urges
Change water vapour carrying metal powder and enters reactor.
Catalyst includes: titanium dioxide, cobalt, copper cobalt, phosphorus cobalt, ferrotungsten cobalt, Iron-doped Nickel Oxide catalyst.
Advantage is: catalyst is by water vapour catalytic separation Cheng Qing and oxygen, oxygen and high-temperature metal powder or fusing high-temperature metal powder
Liquid or gasified metal reaction, generate metal oxide, isolate hydrogen, reduce metal initial ignition temperature, improve hydrogen generation efficiency.
Water vapour hydrogen production process is further improved scheme: hydrogen is projected with by the reactor other end；Hydrogen and oxygen reactive combustion,
Heat sodium hydroxide or potassium hydroxide；The sodium hydroxide or potassium hydroxide of fusing or gasification are reacted with nitrogen dioxide, generate nitric acid
Sodium or sodium nitrite or potassium nitrate or potassium nitrite；The sodium hydroxide or potassium hydroxide of fusing or gasification are reacted with sulfur dioxide,
Generate sodium sulphate or sodium bisulfate or potassium sulfate or potassium acid sulfate；Fusing or gasification and carbon dioxide reaction, generate sodium carbonate
Or sodium bicarbonate or potassium carbonate or saleratus.
Advantage is: dispel pernicious gas in air or combustion gas or fuel oil or coal dust in fire end, purify air, reduce at
This.
A kind of vapor device for producing hydrogen, comprising: steam generator, water vapour booster, water vapour conveying device, control
Valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical blade, heater, water vapour
Water is converted into high-pressure steam, high-pressure water vapor and metal powder and is entered instead by conveying device by generator and water vapour booster
Device is answered, helical blade is installed in reactor cavity, reactor and helical blade are installed into high frequency or hyperfrequency heater coil, high
Frequency or hyperfrequency heater coil induction heating high-pressure water vapor and metal powder and helical blade, high-pressure water vapor and high-temperature metal
Powder or fusing metal powder liquid or gasified metal Forward rotational movement and shock helical blade, high-temperature metal powder in helical reactors
Or fusing high-temperature metal powder liquid or gasified metal are reacted with oxygen in water vapour, are generated metal oxide, are isolated hydrogen, hydrogen and metal
Oxide is projected by the reactor other end.
A kind of vapor device for producing hydrogen, comprising: steam generator, water vapour booster, water vapour conveying device, control
Valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical blade, heater, water vapour
Water is converted into high-pressure steam, high-pressure water vapor and metal powder and is entered instead by conveying device by generator and water vapour booster
Answer device exocoel, intracavitary installation helical blade outside reactor, combustion gas or fuel oil or coal dust enter reactor inner cavity, outside heating response device
Intracavitary high-pressure water vapor and metal powder and helical blade, high-pressure water vapor carry high-temperature metal powder or fusing metal powder liquid or gasification
Metal Forward rotational movement and shock helical blade in helical reactors exocoel, outer intracavitary high-temperature metal powder or fusing metal powder
Liquid or gasified metal are reacted with oxygen in water vapour, generate metal oxide, isolate hydrogen, hydrogen and oxygen reactive combustion, another by exocoel
One end is projected, and combustion gas or fuel oil or pulverized coal flame are projected by the reactor inner cavity other end.
A kind of vapor device for producing hydrogen, comprising: steam generator, water vapour booster, water vapour conveying device, control
Valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical blade, heater, water vapour
Water is converted into high-pressure steam, high-pressure water vapor and metal powder and is entered instead by conveying device by generator and water vapour booster
Device exocoel, intracavitary installation helical blade outside reactor are answered, combustion gas or fuel oil or coal dust enter reactor inner cavity, and reactor is installed into
In high frequency or hyperfrequency heater heating coil, high frequency or hyperfrequency heater induction heating exocoel high-pressure water vapor and metal powder
With reactor and helical blade and inner cavity combustion gas or fuel oil or coal dust；High-pressure water vapor carries high-temperature metal powder or fusing metal powder
Liquid or gasified metal Forward rotational movement and shock helical blade, outer intracavitary high-temperature metal powder or molten in helical reactors exocoel
Change metal powder liquid or gasified metal reacted with oxygen in water vapour, generate metal oxide, isolates hydrogen, hydrogen and oxygen reactive combustion,
It is projected by the exocoel other end, combustion gas or fuel oil or pulverized coal flame are projected by the reactor inner cavity other end.
A kind of vapor device for producing hydrogen, comprising: steam generator, water vapour booster, water vapour conveying device, control
Valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical blade, heater, water vapour
Water is converted into high-pressure steam, high-pressure water vapor and metal powder and is entered instead by conveying device by generator and water vapour booster
Answer device inner cavity, intracavitary installation helical blade in reactor, combustion gas or fuel oil or coal dust enter reactor exocoel, in heating response device
Chamber high-pressure water vapor and metal powder and helical blade, high-pressure water vapor carry high-temperature metal powder or fusing metal powder liquid or gasification gold
Belong in helical reactors inner cavity Forward rotational movement and hits helical blade, inner cavity high-temperature metal powder or fusing metal powder liquid or gas
Change metal to react with oxygen in water vapour, generate metal oxide, hydrogen, hydrogen and oxygen reactive combustion is isolated, by another end-fire in inner cavity
Out, combustion gas or fuel oil or pulverized coal flame are projected by the reactor exocoel other end.
Metal powder described in above-mentioned water vapour hydrogen production process and device include: aluminium powder, magnesium powder, lithium powder and its mixture or
Alloy.
Specific embodiment
The invention will be further described with embodiment with reference to the accompanying drawings of the specification.
Fig. 1 is a kind of aluminium powder and water vapour device for producing hydrogen with the technology of the present invention feature.
Fig. 2 is a kind of magnesium powder and water vapour device for producing hydrogen with the technology of the present invention feature.
Fig. 3 is a kind of magnesium powder and water vapour hydrogen manufacturing reduction apparatus with the technology of the present invention feature.
Fig. 4 is a kind of aluminium powder water vapour hydrogen manufacturing burning and the fuel gas buring combination unit with the technology of the present invention feature.
Fig. 5 is a kind of aluminium powder and the hydrogen manufacturing of magnesium powder water vapour and interior combustion gas and the hyperfrequency heating with the technology of the present invention feature
Device combination unit.
Fig. 6 be have the technology of the present invention feature aluminium powder and lithium powder water vapour hydrogen manufacturing and outer gas heating combination unit
Embodiment 1
A kind of aluminium powder and water vapour device for producing hydrogen are as shown in Figure 1, in which: 1 is steam generator, and 2 be water inlet pipe, and 3 be that water steams
Steam pipe, 4 be water vapour storage tank, and 5 be water vapour, and 6 be water vapour booster, and 7 be steam conveyor tube, and 8 be water vapour gold
Belong to powder mixer, 9 be mixer flange, and 10 be water vapour and metal powder outlet, and 11 be helical axis fixation hole, and 12 be metal powder
Storage tank, 13 be aluminium powder, and 14 be that metal powder quantifies conveyer, and 15 be metal powder delivery pipe, and 16 be metal powder storage cover, and 17 are
Metal powder axial direction conveyer, 18 be axial conveyer flange, and 19 be direct current generator, and 20 be spiral organ axis, and 21 be metal powder conveying
Helical blade, 22 be water vapour and aluminium powder mixed gas, and 23 be reactor, and 24 be reactor flange, and 25 be hyperfrequency heater
Copper coil, 26 be hyperfrequency heater coil cooling circulating water, and 27 be helical axis, and 28 be helical blade, and 29 be water vapour and height
Warm aluminium powder or fusing aluminium powder liquid mixed gas, 30 be aluminum oxide, and 31 be hydrogen, and 32 be outlet end cap, and 33 be end cap jet port,
34 be end cap shaft hole, and 35 be hydrogen burning flame, and 36 be steam turbine or boiler.
In use, mixer flange 9 is bolted together with axial conveyer flange 18 with connection, other end mixer
Flange 9 and reactor flange 24 are bolted together with connection, other end reactor flange 24 and the connection of outlet end cap 32
It being bolted together, metal powder storage tank 12 and metal powder quantify conveyer 12 and are mounted on metal powder axial direction conveyer 17,
Metal powder conveyor screw blade 21 is installed, 20 other end of spiral organ axis is connected with direct current generator 19, helical-blade on spiral organ axis 20
Piece 28 is fixed on helical axis 27, and 27 both ends of helical axis are separately fixed on helical axis fixation hole 11 and end cap shaft hole 34.
Hyperfrequency heater copper coil 25 is wrapped in outside reactor 23, and hyperfrequency heater coil cooling circulating water 26 recycles
Flowing, prevents 25 over hot melting of hyperfrequency heater copper coil.
Water in water inlet pipe 2 is converted into water vapour by steam generator 1, enters water vapour storage tank 4 by steam pipe 3
Water vapour 5 is pressurized by interior storage, water vapour booster 6, tangentially enters water vapour metal powder mixer by steam conveyor tube 7
In 8.
Aluminium powder 13 is quantified conveyer 14 and metal powder delivery pipe 15 by metal powder and quantitatively entered by metal powder storage tank 12
In metal powder axial direction conveyer 17, the rotation of direct current generator 19 drives spiral organ axis 20 and helical blade 21 that aluminium powder 13 is sent into water steaming
In vapour metal powder mixer 8, the tangential high-pressure water vapor into water vapour metal powder mixer 8 is mixed with the rotation of aluminium powder 13,
High-pressure water vapor and aluminium powder mixed gas 22 is made.
High-pressure water vapor and aluminium powder mixed gas 22 are entered in reactor 23 by water vapour and metal powder outlet 10, hyperfrequency
25 induction heating high-pressure water vapor of heater copper coil and aluminium powder mixed gas 22, high temperature aluminium powder 13 or melting aluminum 13 and water vapour
Oxidation reaction occurs for middle oxygen, generates aluminum oxide 30, releases heat, isolates hydrogen 31, hydrogen 31 and high-pressure water vapor are by end cap
Jet port 33 projects, and oxygen reactive combustion in high temperature hydrogen 31 and air, hydrogen burning flame 35 heats high-pressure water vapor, overheats high pressure water
Steam drive steam turbine or boiler 36.
Embodiment 2
A kind of metal magnesium powder and water vapour device for producing hydrogen are as shown in Figure 2, in which: and 37 be steam generator, and 38 be water inlet pipe, 39
It is steam pipe, 40 be water vapour storage tank, and 41 be water vapour, and 42 be water vapour booster, and 43 be high-pressure water vapor delivery pipe,
44 be the unidirectional proportional valve of axial water vapour, and 45 be axial water vapour inlet pipe, and 46 be the unidirectional proportional valve of tangential water vapour, and 47 be tangential
Water vapour inlet pipe, 48 be end seal lid, and 49 be water vapour metal powder mixer, and 50 be blender end flange, and 51 be that mixer goes out
Mouthful, 52 be helical axis fixation hole, and 53 be mixer connecting flange, and 54 be metal powder storage tank, and 55 be magnesium powder, and 56 be metal powder
Quantitative conveyer, 57 be metal powder delivery pipe, and 58 be metal powder storage cover, and 59 be water vapour and magnesium powder mixed gas, and 60 are
Magnetic stirrer, 61 be reactor, and 62 be reactor flange, and 63 be helical blade fixing axle, and 64 be helical blade, and 65 be super
Heating generator copper coil, 66 be hyperfrequency heater coil cooling circulating water, and 67 be water vapour and high temperature magnesium powder or fusing magnesium
Powder liquid or gasification magnesium mixed gas, 68 be magnesia, and 69 be hydrogen, and 70 be reactor outlet end flanges, and 71 be reactor jet port,
72 be outlet end flange helical axis fixation hole, and 73 be metal oxide collector, and 74 be connection bolt, and 75 be hydrogen burning flame,
76 be steam turbine or boiler.
In use, end seal lid 48 and mixer connecting flange 53 are linked together with connection bolt 74, blender end flange
50 and the left flange 62 of reactor linked together with connection bolt 74, the right flange 62 of reactor and reactor outlet end flanges 70 are used
Connection bolt 74 links together, and magnetic stirrer 60 is mounted on water vapour metal powder mixer 49, metal powder storage tank 54
It quantifies conveyer 55 with metal powder to be mounted on water vapour metal powder mixer 49, helical blade 64 is welded on helical blade and fixes
On axis 63,63 both ends of helical blade fixing axle are inserted into helical axis fixation hole 52 respectively and outlet end flange helical axis fixation hole 72
Interior fixation.
Hyperfrequency heater copper coil 65 is wrapped in outside reactor 61, and hyperfrequency heater coil cooling circulating water 66 recycles
Flowing, prevents 65 over hot melting of hyperfrequency heater copper coil.
Water in water inlet pipe 38 is converted into water vapour by steam generator 37, is entered water vapour by steam pipe 39 and is stored
Water vapour 41 is pressurized by storage, water vapour booster 42 in tank 40, and it is unidirectional to enter axial water vapour by steam conveyor tube 43
In proportional valve 44, axial water vapour inlet pipe 45 by high-pressure water vapor axially into water vapour metal powder mixer 49, water vapour
Water vapour 41 is pressurized by booster 42, is entered in the unidirectional proportional valve 46 of tangential water vapour by steam conveyor tube 43, tangential water
Steam inlet tube 47 tangentially enters high-pressure water vapor in water vapour metal powder mixer 49.
Magnesium powder 55 is quantified conveyer 56 and metal powder delivery pipe 57 by metal powder and quantitatively entered by metal powder storage tank 54
In water vapour metal powder mixer 49.
Tangentially enter high-pressure water vapor high speed rotation in water vapour metal powder mixer 49, stirs magnesium powder 55 and high pressure water
Steam mixing, magnetic stirrer 60 stir magnesium powder 55 and mix with high-pressure water vapor, push magnesium powder 55 axially into high-pressure water vapor
Entered in reactor 61 by high-pressure water vapor by mixer outlet 51.
65 induction heating high-pressure water vapor of hyperfrequency heater copper coil and magnesium powder 55 and helical reactors 61 and spiral reverse
Answer device fixing axle 63 and helical blade 64, high temperature magnesium powder 55 or fusing magnesium powder 55 or vaporization magnesium 55 and high-pressure water vapor are in spiral reverse
It answers the adjacent high speed Forward rotational movement along 64 cavity of helical blade in device 61 and hits helical blade 64, hit heat, it will be high
Warm 55 surface film oxide of magnesium powder, which is hit, to be split or removes, and oxygen occurs in high temperature magnesium powder 55 or fusing magnesium powder 55 or gasification magnesium 55 and water vapour
Oxidation reaction generates magnesia 68, releases heat, isolates hydrogen 69, and hydrogen 69 is sprayed with by 61 other end reactor of helical reactors
Loophole 71 projects, and magnesia 68 is sunk in metal oxide collector 73, oxygen reactive combustion in high temperature hydrogen 69 and air, burning
Flame 75 heats steam turbine or boiler 76.
Embodiment 3
A kind of metal magnesium powder and water vapour hydrogen manufacturing vacuum reduction metal device are as shown in Figure 3, in which: and 77 be steam generator,
78 be water inlet pipe, and 79 be steam pipe, and 80 be water vapour storage tank, and 81 be water vapour, and 82 be water vapour booster, and 83 be high pressure
Steam conveyor tube, 84 be the unidirectional proportional valve of axial water vapour, and 85 be axial water vapour inlet pipe, and 86 be that tangential water vapour is unidirectionally fixed
Valve is measured, 87 be tangential water vapour inlet pipe, and 88 be end seal lid, and 89 be water vapour metal powder mixer, and 90 be blender end flange,
91 be mixer outlet, and 92 be helical axis fixation hole, and 93 be mixer connecting flange, and 94 be metal powder storage tank, and 95 be magnesium
Powder, 96 be that metal powder quantifies conveyer, and 97 be metal powder delivery pipe, and 98 be metal powder storage cover, and 99 be water vapour and magnesium powder
Mixed gas, 100 be magnetic stirrer, and 101 be reactor, and 102 be the left flange of reactor, and 103 be the right flange of reactor, 104
It is helical blade fixing axle, 105 be helical blade, and 106 be hyperfrequency heater copper coil, and 107 be hyperfrequency heater coil
Cooling circulating water, 108 be water vapour and high temperature magnesium powder or fusing magnesium liquid drop or gasification magnesium mixed gas, and 109 be magnesia, 110
It is hydrogen, 111 be reactor outlet end flanges, and 112 be end flanges fixation hole, and 113 be end flanges jet port, and 114 be hydrogen memory,
115 be hydrogen efferent duct, and 116 be reduction reaction device, and 117 be metal oxide, and 118 be intake and exhaust valve.
In use, end seal lid 88 and mixer connecting flange 93 are bolted together with connection, blender end flange 90
It is bolted together with the connection of reactor left flange 102, the right flange 103 of reactor and reactor outlet end flanges 111 are used
Connection is bolted together, and magnetic stirrer 100 is mounted on water vapour metal powder mixer 89,94 He of metal powder storage tank
Metal powder quantifies conveyer 95 and is mounted on water vapour metal powder mixer 89, and helical blade 105 is welded on helical blade and fixes
On axis 104,104 both ends of helical blade fixing axle are inserted into helical axis fixation hole 92 respectively and are fixed in end flanges fixation hole 112.
Hyperfrequency heater copper coil 106 is wrapped in outside reactor 101, hyperfrequency heater coil cooling circulating water 107
It circulates, prevents 106 over hot melting of hyperfrequency heater copper coil.
Water in water inlet pipe 78 is converted into water vapour by steam generator 77, is entered water vapour by steam pipe 79 and is stored
Water vapour 81 is pressurized by storage, water vapour booster 82 in tank 80, and it is unidirectional to enter axial water vapour by steam conveyor tube 83
In proportional valve 84, axial water vapour inlet pipe 85 by high-pressure water vapor axially into water vapour metal powder mixer 89, water vapour
Water vapour 81 is pressurized by booster 82, is entered in the unidirectional proportional valve 86 of tangential water vapour by steam conveyor tube 83, tangential water
Steam inlet tube 87 tangentially enters high-pressure water vapor in water vapour metal powder mixer 89.
Magnesium powder 95 is quantified conveyer 96 and metal powder delivery pipe 97 by metal powder and quantitatively entered by metal powder storage tank 94
In water vapour metal powder mixer 89, tangentially enters high-pressure water vapor high speed rotation in water vapour metal powder mixer 89, stir
It mixes magnesium powder 95 to mix with high-pressure water vapor, magnetic stirrer 100 stirs magnesium powder 95 and mixes with high-pressure water vapor, axially into height
Press water vapour that magnesium powder 95 and high-pressure water vapor is pushed to be entered in reactor 101 by mixer outlet 91.
106 induction heating high-pressure water vapor of hyperfrequency heater copper coil and magnesium powder 95 and helical reactors 101 and spiral
Reactor fixing axle 104 and helical blade 105, high temperature magnesium powder 95 or fusing magnesium powder 95 and gasification magnesium 95 and high-pressure water vapor are in spiral shell
It revolves the adjacent high speed Forward rotational movement along 105 cavity of helical blade in reactor 101 and hits helical blade 105, hit life
95 surface film oxide of high temperature magnesium powder is hit and splits or remove by heat, high temperature magnesium powder 95 or fusing magnesium powder 95 and gasify magnesium 95 and water vapour
Oxidation reaction occurs for middle oxygen, generates magnesia 109, releases heat, isolates hydrogen 110, hydrogen 110 is sprayed by helical reactors end flanges
Loophole 113 enters hydrogen memory 114, and high temperature hydrogen 110 is entered in reduction reaction device 116 by hydrogen efferent duct 115, high temperature hydrogen
110 occur reduction reaction with metal oxide 117 in reduction reaction device 116, generate water, metal oxide 117 is reduced into
Metal, intake and exhaust valve 118 controls the entrance of air and the discharge of hydrogen, when temperature is low in reduction reaction device 116, opens
Intake and exhaust valve 118, air enter in reduction reaction device 116, and oxidation reaction burning occurs for oxygen and hydrogen 110 in air, improve
Temperature in reduction reaction device 116, after metal oxide 117 is reduced into metal, by drain tap 118 by reduction reaction device
The discharge of hydrogen 110 storage in 116.
Embodiment 4
A kind of aluminium powder water vapour hydrogen manufacturing burning and fuel gas buring combination unit are as shown in Figure 4, in which: and 119 be steam generator,
120 be water inlet pipe, and 121 be steam pipe, and 122 be water vapour storage tank, and 123 be water vapour, and 124 be water vapour booster, 125
It is delivery pipe on exocoel water vapour, 126 be delivery pipe under exocoel water vapour, and 127 be left end capping, and 128 be that left end capping is fixed
Hole, 129 be water vapour metal powder reactor, and 130 be blender end flange, and 131 be right end capping, and 132 be right end capping injection
Hole, 133 be right end capping fixation hole, and 134 be hollow pipe, and 135 be fuel gas inlet, and 136 be combustion gas, and 137 be gas flame outlet,
138 be exocoel helical blade, and 139 be metal powder storage tank, and 140 be metallic aluminium, and 141 be that metal powder quantifies conveyer, and 142 be gold
Belong to powder delivery pipe, 143 be metal powder storage cover, and 144 be connection bolt, and 146 be water vapour and magnesium powder mixed gas, and 146 are
High temperature aluminium powder or fusing aluminium powder liquid, 147 be aluminum oxide, and 148 be hydrogen, and 149 be hydrogen burning flame, and 150 be fuel gas buring fire
Flame, 151 be steam turbine or boiler.
In use, hollow 134 both ends of inner combustion tube are separately mounted to left end capping fixation hole 128 and right end capping fixation hole
Fixed in 133, left end capping 127 and mixer left end flange 130 are linked together with connection bolt 144, mixer right end method
Orchid 130 and right end capping 131 are linked together with connection bolt 144, and exocoel helical blade 138 is welded on hollow inner combustion tube
134 outsides, magnesium metal storage tank 139 and magnesium metal delivery pipe 142 are welded on water vapour metal powder reactor 129.
Water in water inlet pipe 120 is converted into water vapour by steam generator 119, enters water vapour by steam pipe 121
Water vapour 123 is pressurized by storage, water vapour booster 124 in storage tank 122, by delivery pipe 125 on exocoel water vapour and outside
Delivery pipe 126 enters intracavitary outside water vapour metal powder reactor 129 under chamber water vapour.
Aluminium powder 140 is quantified conveyer 141 by metal powder to metal powder storage tank 139 and metal powder delivery pipe 142 quantifies
It is intracavitary outside into water vapour metal powder reactor 129.
Delivery pipe 126 will enter high-pressure water vapor and mix with aluminium powder 140 under delivery pipe 125 and exocoel water vapour on water vapour
It closes, high-pressure water vapor and aluminium powder 140 enter 129 exocoel of helical reactors.
Combustion gas 136 is entered in hollow pipe 134 by fuel gas inlet 135 burns, and 136 combustion flame of combustion gas heats hollow pipe 134
With outer intracavitary high-pressure water vapor and aluminium powder 140, is projected by gas flame outlet 137, heat steam turbine or boiler 151.
High-pressure water vapor with aluminium powder 140 revolve forward by the high speed in 129 exocoel adjoining spiral blade of helical reactors, 138 cavity
Transhipment is dynamic and hits helical blade 138, and 140 surface film oxide of high temperature aluminium powder is hit and splits or removes, high temperature aluminium powder 140 or melting aluminum
Oxidation reaction occurs for oxygen in powder liquid 140 and water vapour, generates aluminum oxide 147, releases heat, isolates hydrogen 148, hydrogen 148
It is projected by 129 exocoel right end of helical reactors capping spray-hole 132, oxygen reactive combustion in high temperature hydrogen 148 and air releases heat
Amount, hydrogen burning flame 149 and fuel gas buring flame 150 mix, common to heat steam turbine or boiler 151.
Advantage is: 149 temperature of hydrogen burning flame is 2045 DEG C in air, hydrogen burning flame 149 and fuel gas buring flame 150
Mixing improves heating steam turbine or 151 temperature of boiler.
Embodiment 5
A kind of aluminium powder and the hydrogen manufacturing of magnesium powder water vapour and combustion gas and hyperfrequency heater combination unit are as shown in Figure 5, in which: 152 are
Steam generator, 153 be water inlet pipe, and 154 be steam pipe, and 155 be water vapour storage tank, and 156 be water vapour, and 157 be water
Steam output pipe, 158 be water vapour booster, and 159 be delivery pipe on exocoel water vapour, and 160 be delivery pipe under exocoel water vapour,
161 be left end capping, and 162 be left end capping fixation hole, and 163 be water vapour metal powder reactor, and 164 be mixer left end method
Orchid, 165 be mixer right end flange, and 166 be hyperfrequency heater copper coil, and 167 be hyperfrequency heater coil cooling cycle
Water, 168 be right end capping, and 169 be right end capping spray-hole, and 170 be right end capping fixation hole, and 171 be hollow pipe, and 172 be combustion
Oil-in, 173 be fuel oil, and 174 be fuel oil jet port, and 175 be helical blade, and 176 be metal powder storage tank, and 177 be aluminium powder,
178 be magnesium powder, and 179 be that metal powder quantifies conveyer, and 180 be metal powder delivery pipe, and 181 be metal powder storage cover, and 182 be to connect
Connecting bolt, 183 be water vapour and aluminium powder and magnesium powder mixed gas, and 184 be high temperature aluminium powder or fusing aluminium powder liquid, and 185 be high temperature magnesium
Powder or magnesium powder liquid or vaporization magnesium, 186 be aluminum oxide, and 187 be magnesia, and 188 be hydrogen, and 189 be hydrogen burning flame, and 190 are
Fuel gas buring flame, 191 be steam turbine or boiler.
In use, hollow 171 both ends of inner combustion tube are separately mounted to left end capping fixation hole 162 and right end capping fixation hole
Fixed in 170, left end capping 161 and mixer left end flange 164 are linked together with connection bolt 182, mixer right end method
Orchid 165 and right end capping 168 are linked together with connection bolt 182, and exocoel helical blade 175 is welded on 171 outside of hollow pipe,
Metal powder storage tank 176 and metal powder delivery pipe 180 are welded on water vapour metal powder reactor 163.
Water in water inlet pipe 153 is converted into water vapour by steam generator 152, enters water vapour by steam pipe 154
Water vapour 156 is pressurized by storage, water vapour booster 158 in storage tank 155, by delivery pipe 159 on exocoel water vapour and outside
Delivery pipe 160 enters intracavitary outside water vapour metal powder reactor 163 under chamber water vapour.
Metal powder storage tank 176 is by aluminium powder 177 and magnesium powder 178 quantifies conveyer 179 by metal powder and metal powder conveys
Pipe 180 quantitatively enters intracavitary outside water vapour metal powder reactor 163.
Delivery pipe 160 will enter high-pressure water vapor and aluminium powder 177 and magnesium under delivery pipe 159 and exocoel water vapour on water vapour
Powder 178 mixes, and high-pressure water vapor carries aluminium powder 177 and magnesium powder 178 enters 163 exocoel of helical reactors.
166 induction heating high-pressure water vapor of hyperfrequency heater copper coil and aluminium powder 177 and magnesium powder 178 and helical reactors
163 and hollow pipe 171 and helical blade 175 and fuel oil 173, the fuel oil 173 that fuel filler 172 enters sprayed after heating by fuel oil
Mouth 174 projects, and fuel oil 173 burns in conjunction with oxygen in air, heats steam turbine or boiler 191.
High-pressure water vapor and aluminium powder 177 and magnesium powder 178 are in 163 exocoel adjoining spiral blade of helical reactors, 175 cavity
High speed Forward rotational movement and shock helical blade 175, high temperature aluminium powder 177 and 178 surface film oxide of magnesium powder are hit and split or remove,
Oxidation reaction occurs for oxygen in high temperature aluminium powder 177 or fusing aluminium powder liquid 177 and water vapour, generates aluminum oxide 186, releases heat
Amount isolates oxygen in hydrogen 188, high temperature magnesium powder 178 or fusing magnesium powder liquid 178 or gasification magnesium 178 and water vapour and oxidation reaction occurs,
Magnesia 187 is generated, heat is released, isolates hydrogen 188, hydrogen 188 is projected by right end capping spray-hole 169, high temperature hydrogen 188 and sky
Oxygen reacts in gas, and burning, hydrogen burning flame 189 is mixed with fuel burning flame 190, heats steam turbine or boiler 191.
Embodiment 6
A kind of aluminium powder and lithium powder water vapour hydrogen manufacturing and outer gas heating combination unit are as shown in Figure 6, in which: 192 be water vapour hair
Raw device, 193 be water inlet pipe, and 194 be steam pipe, and 195 be water vapour storage tank, and 196 be water vapour, and 197 be water vapour pressurization
Device, 198 be water vapour efferent duct, and 199 be water vapour metal powder mixer, and 200 be blender end flange, 201 be mixer with
Reactor connecting flange, 202 be flange gas outlet, and 203 be flange fixation hole, and 204 be electromagnetic heater, and 205 be metal powder axis
To conveyer, 206 be axial conveyer flange, and 207 be axis hole, and 208 be direct current generator, and 209 be spiral organ axis, and 210 be spiral
Blade, 211 be metal powder storage tank, and 212 be aluminium powder, and 213 be lithium powder, and 214 be that metal powder quantifies conveyer, and 215 be metal powder
Delivery pipe, 216 be metal powder storage cover, and 217 be vapor and metal powder mixed gas, and 218 be reactor, and 219 be anti-
Device flange is answered, 220 be combustion gas or fuel oil jet port, and 221 be hydrogen injection mouth, and 222 be helical axis fixation hole, and 223 be reactor
Inner wall, 224 be helical axis, and 225 be helical blade, and 226 be combustion gas or fuel filler, and 227 be combustion gas or fuel flow control system (FFCS),
228 be bolt, and 229 be combustion gas or fuel oil flame, and 230 be water vapour and aluminium powder and lithium powder mixed gas, and 231 be three oxidations two
Aluminium, 232 be lithium aluminate, and 233 be hydrogen, and 234 be hydrogen injection mouth combustion flame, and 235 be combustion gas or fuel burning flame, and 236 are
Steam turbine or boiler.
In use, axial conveyer flange 206 and blender end flange 200 are linked together with connection bolt 228, mix
Device links together with reactor connecting flange 201 and the connection bolt 228 of reactor flange 219, and helical blade 225 is welded on
224 outside of helical axis, 224 both ends of helical axis are separately mounted in flange fixation hole 203 and helical axis fixation hole 222 fixed, gold
Belong to powder storage tank 211 and metal powder delivery pipe 215 is welded on metal powder axial direction conveyer 205.
Water in water inlet pipe 193 is converted into water vapour by steam generator 192, enters water vapour by steam pipe 194
Water vapour 196 is pressurized by storage, water vapour booster 197 in storage tank 195, enters water vapour by water vapour efferent duct 198
In metal powder mixer 199.
Metal powder storage tank 211 is by aluminium powder 212 and lithium powder 213 quantifies conveyer 214 by metal powder and metal powder conveys
Pipe 215 quantitatively enters in metal powder axial direction conveyer 205, and direct current generator 208 drives spiral organ axis 209 and helical blade 210 will
Aluminium powder 212 and lithium powder 213 are sent into water vapour metal powder mixer 199.
The high-pressure water vapor that water vapour efferent duct 198 tangentially enters is mixed with aluminium powder 212 and lithium powder 213, high-pressure water vapor
It carries aluminium powder 212 and lithium powder 213 and 218 inner cavity of reactor is entered by flange gas outlet 202.
Combustion gas or fuel oil pass through combustion gas or fuel filler 226 and combustion gas or fuel flow control system (FFCS) 227 enters reactor 218
Exocoel, combustion gas or 229 heating response device inner wall 223 of fuel oil flame and 218 inner cavity high-pressure water vapor of reactor and aluminium powder 212 and lithium
Powder 213, high-pressure water vapor and aluminium powder 212 and lithium powder 213 in 218 inner cavity adjoining spiral blade of reactor, 225 cavity high speed to
Preceding rotary motion and shock helical blade 225,212 surface film oxide of high temperature aluminium powder is hit and splits or removes, and lithium powder 213 burns, and adds
Oxygen occurs in 218 inner cavity high-pressure water vapor of thermal reactor and aluminium powder 212, high temperature aluminium powder 212 or fusing aluminium powder liquid 212 and water vapour
Oxidation reaction generates aluminum oxide 231, releases heat, isolates hydrogen 233, melts lithium powder liquid 213 or gasification lithium 213 and water
Oxidation reaction occurs for oxygen and aluminium powder 212 in steam, generates lithium aluminate 232, releases heat, isolates hydrogen 233, hydrogen 233 is by hydrogen
Jet port 221 projects, and high temperature hydrogen 233 is reacted with oxygen in air, burns, and hydrogen burning flame 234 heats steam turbine or boiler 236,
Combustion gas or fuel burning flame 235 are projected by combustion gas or fuel oil jet port 220, heat steam turbine or boiler 236.
Claims (14)
1. water vapour hydrogen production process: water is converted into high-pressure steam by steam generator and water vapour booster；High pressure water steams
Vapour is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heat high-pressure water vapor and metal powder；High-temperature metal
Powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, are generated metal oxide, are released heat, isolate
Hydrogen.
2. water vapour hydrogen production process as described in claim 1, it is characterized in that: steam generator and water vapour booster turn water
Change high-pressure steam into；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating reaction
Device and high-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal and oxygen in high-temperature water vapor are anti-
It answers, generates metal oxide, release heat, isolate hydrogen；Hydrogen is purified by hydrogen permeating material.
3. water vapour hydrogen production process as described in claim 1, it is characterized in that: steam generator and water vapour booster turn water
Change high-pressure steam into；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating reaction
Device and high-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal and oxygen in high-temperature water vapor are anti-
It answers, generates metal oxide, release heat, isolate hydrogen；Hydrogen and oxygen reactive combustion generate water, release heat.
4. water vapour hydrogen production process as described in claim 1, it is characterized in that: steam generator and water vapour booster turn water
Change high-pressure steam into；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating reaction
Device and high-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal and oxygen in high-temperature water vapor are anti-
It answers, generates metal oxide, release heat, isolate hydrogen；Hydrogen enters reduction reaction device, hydrogen and reactive metal oxide, also
Original goes out metal.
5. water vapour hydrogen production process as described in claim 1, it is characterized in that: steam generator and water vapour booster turn water
Change high-pressure steam into；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor；Heating reaction
Device and high-pressure water vapor and metal powder；High-temperature metal powder or fusing metal powder liquid or gasified metal and oxygen in high-temperature water vapor are anti-
It answers, generates metal oxide, release heat, isolate hydrogen；Hydrogen is mixed with water vapour, and hydrogen and oxygen reactive combustion heat vapor,
Overheated steam driving steam turbine or heating boiler.
6. water vapour hydrogen production process as described in claim 1, it is characterized in that: steam generator and water vapour booster turn water
Change high-pressure steam into；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor exocoel；Combustion gas
Or fuel oil or coal dust enter reactor inner cavity, heating response device inner cavity and outer intracavitary high-pressure water vapor and metal powder；Outside reactor
Intracavitary high-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, generate metal oxide, point
Separate out hydrogen；Hydrogen is projected by the reactor exocoel other end to burn；Combustion gas or fuel oil or coal dust are projected by the reactor inner cavity other end to be fired
It burns.
7. water vapour hydrogen production process as described in claim 1, it is characterized in that: steam generator and water vapour booster turn water
Change high-pressure steam into；High-pressure water vapor is mixed with metal powder, and high-pressure water vapor carries metal powder and enters reactor inner cavity；Combustion gas
Or fuel oil or coal dust enter reactor exocoel, heating response device exocoel and inner cavity high-pressure water vapor and metal powder；Reactor inner cavity
High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, are generated metal oxide, are isolated
Hydrogen；Hydrogen is projected by the reactor inner cavity other end to burn；Combustion gas or fuel oil or coal dust are projected by the reactor exocoel other end to burn.
8. the water vapour hydrogen production process as described in claims 1 or 2 or 3 or 4 or 5 or 6 or 7, it is characterized in that: steam generator and
Water is converted into high-pressure steam by water vapour booster；High-pressure water vapor and metal powder are mixed into reactor, reactor installation
Into in high frequency or hyperfrequency heater heating coil；High frequency or hyperfrequency heater induction heating high-pressure water vapor and metal powder；
High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in high-temperature water vapor, are generated metal oxide, are isolated
Hydrogen.
9. the water vapour hydrogen production process as described in claims 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8: it is characterized in that: in reactor cavity
Helical blade, electricity or combustion gas or fuel oil or coal dust heating steam and metal powder and helical blade, high-temperature high-pressure steam are installed
With high-temperature metal powder or fusing metal powder liquid or gasified metal in helical reactors Forward rotational movement and hit helical blade.
10. the water vapour hydrogen production process as described in claims 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8 or 9: it is characterized in that: catalyst
It is packed into container；Water vapour and catalyst reaction；Catalysis water vapour carries metal powder and enters reactor.
11. the water vapour hydrogen production process as described in claims 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8 or 9 or 10: it is characterized in that: high
Wen Qing and oxygen reactive combustion in air, heat sodium hydroxide or potassium hydroxide；The sodium hydroxide or potassium hydroxide of fusing or gasification
It is reacted with nitrogen dioxide, generates sodium nitrate or sodium nitrite or potassium nitrate or potassium nitrite；Or the sodium hydroxide of fusing or gasification
Or potassium hydroxide is reacted with sulfur dioxide, generates sodium sulphate or sodium bisulfate or potassium sulfate or potassium acid sulfate；Or it melts or gasifies
Sodium hydroxide or potassium hydroxide and carbon dioxide reaction, generate sodium carbonate or sodium bicarbonate or potassium carbonate or saleratus.
12. vapor hydrogen manufacturing burner as described in claim 1, comprising: steam generator, water vapour booster, water steam
Vapour conveying device, control valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical-blade
Piece, heater, it is characterized in that: water is converted into high-pressure steam, high-pressure water vapor by steam generator and water vapour booster
Reactor is entered by conveying device with metal powder, helical blade is installed in reactor cavity, reactor and helical blade are installed into
In high frequency or hyperfrequency heater coil, high frequency or hyperfrequency heater coil induction heating high-pressure water vapor and metal powder and spiral shell
Rotation is transported forward in helical reactors for vane piece, high-pressure water vapor and high-temperature metal powder or fusing metal powder liquid or gasified metal
Dynamic and shock helical blade, high-temperature metal powder or fusing high-temperature metal powder liquid or gasified metal are reacted with oxygen in water vapour, are generated
Metal oxide is isolated hydrogen, hydrogen and metal oxide and is projected by the reactor other end.
13. vapor hydrogen manufacturing burner as claimed in claim 6, comprising: steam generator, water vapour booster, water steam
Vapour conveying device, control valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical-blade
Piece, heater, it is characterized in that: water is converted into high-pressure steam, high-pressure water vapor by steam generator and water vapour booster
Reactor exocoel, intracavitary installation helical blade, combustion gas or fuel oil or coal dust outside reactor are entered by conveying device with metal powder
Into reactor inner cavity, intracavitary high-pressure water vapor and metal powder and helical blade outside heating response device, high-pressure water vapor carry high
Warm metal powder or fusing metal powder liquid or gasified metal Forward rotational movement and shock helical blade in helical reactors exocoel,
Outer intracavitary high-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in water vapour, generate metal oxide, separation
Hydrogen out, hydrogen and oxygen reactive combustion, are projected, combustion gas or fuel oil or pulverized coal flame are by another end-fire in reactor inner cavity by the exocoel other end
Out.
14. vapor hydrogen manufacturing burner as claimed in claim 7, comprising: steam generator, water vapour booster, water steam
Vapour conveying device, control valve, metal powder, conveyance conduit, metal powder memory, metal powder conveying device, reactor, helical-blade
Piece, heater, it is characterized in that: water is converted into high-pressure steam, high-pressure water vapor by steam generator and water vapour booster
Reactor inner cavity, intracavitary installation helical blade, combustion gas or fuel oil or coal dust in reactor are entered by conveying device with metal powder
Into reactor exocoel, heating response device inner cavity high-pressure water vapor and metal powder and helical blade, high-pressure water vapor carry high temperature
Metal powder or fusing metal powder liquid or gasified metal in helical reactors inner cavity Forward rotational movement and hit helical blade, inner cavity
High-temperature metal powder or fusing metal powder liquid or gasified metal are reacted with oxygen in water vapour, are generated metal oxide, are isolated hydrogen, hydrogen
It with oxygen reactive combustion, is projected by the inner cavity other end, combustion gas or fuel oil or pulverized coal flame are projected by the reactor exocoel other end.
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| CN201910250549.9A CN109970025A (en) | 2019-03-29 | 2019-03-29 | Water vapour hydrogen production process and device |
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| CN201910250549.9A CN109970025A (en) | 2019-03-29 | 2019-03-29 | Water vapour hydrogen production process and device |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113278984A (en) * | 2021-05-28 | 2021-08-20 | 王广武 | Device for producing hydrogen by steam oxidation and oxygen by oxide electrolysis reduction and preparation method |
| WO2022218969A1 (en) * | 2021-04-13 | 2022-10-20 | Uestuen Orhan | Method and device for generating hydrogen |
| WO2023005750A1 (en) * | 2021-07-25 | 2023-02-02 | 王广武 | High-temperature water vapor and high-temperature metal particles oxidation hydrogen production device and method |
| CN117623220A (en) * | 2024-01-26 | 2024-03-01 | 内蒙古东景生物环保科技有限公司 | High-efficiency steam hydrogen production device |
-
2019
- 2019-03-29 CN CN201910250549.9A patent/CN109970025A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022218969A1 (en) * | 2021-04-13 | 2022-10-20 | Uestuen Orhan | Method and device for generating hydrogen |
| CN113278984A (en) * | 2021-05-28 | 2021-08-20 | 王广武 | Device for producing hydrogen by steam oxidation and oxygen by oxide electrolysis reduction and preparation method |
| WO2023005750A1 (en) * | 2021-07-25 | 2023-02-02 | 王广武 | High-temperature water vapor and high-temperature metal particles oxidation hydrogen production device and method |
| CN117623220A (en) * | 2024-01-26 | 2024-03-01 | 内蒙古东景生物环保科技有限公司 | High-efficiency steam hydrogen production device |
| CN117623220B (en) * | 2024-01-26 | 2024-05-31 | 内蒙古东景生物环保科技有限公司 | High-efficiency steam hydrogen production device |
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Application publication date: 20190705 |