CN109944071A - Moisture absorption heating agent and preparation method thereof - Google Patents
Moisture absorption heating agent and preparation method thereof Download PDFInfo
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- CN109944071A CN109944071A CN201810235905.5A CN201810235905A CN109944071A CN 109944071 A CN109944071 A CN 109944071A CN 201810235905 A CN201810235905 A CN 201810235905A CN 109944071 A CN109944071 A CN 109944071A
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 60
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 57
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 57
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 239000007788 liquid Substances 0.000 claims abstract description 27
- 239000006185 dispersion Substances 0.000 claims abstract description 26
- 229920002678 cellulose Polymers 0.000 claims abstract description 25
- 239000001913 cellulose Substances 0.000 claims abstract description 25
- KXCLCNHUUKTANI-RBIYJLQWSA-N keratan Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@H](COS(O)(=O)=O)O[C@H]1O[C@@H]1[C@@H](O)[C@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H]([C@@H](COS(O)(=O)=O)O[C@@H](O)[C@@H]3O)O)[C@H](NC(C)=O)[C@H]2O)COS(O)(=O)=O)O[C@H](COS(O)(=O)=O)[C@@H]1O KXCLCNHUUKTANI-RBIYJLQWSA-N 0.000 claims description 26
- 239000002608 ionic liquid Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 11
- 210000002268 wool Anatomy 0.000 claims description 10
- 210000003746 feather Anatomy 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 239000002070 nanowire Substances 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 8
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 241000272814 Anser sp. Species 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 210000004209 hair Anatomy 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- -1 alkyl imidazole Chemical compound 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- FHDQNOXQSTVAIC-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCN1C=C[N+](C)=C1 FHDQNOXQSTVAIC-UHFFFAOYSA-M 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZXLOSLWIGFGPIU-UHFFFAOYSA-N 1-ethyl-3-methyl-1,2-dihydroimidazol-1-ium;acetate Chemical compound CC(O)=O.CCN1CN(C)C=C1 ZXLOSLWIGFGPIU-UHFFFAOYSA-N 0.000 description 1
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 229920000832 Cutin Polymers 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of moisture absorption heating agent and preparation method thereof.Moisture absorption heating agent includes 10 parts by weight to the protein of 90 parts by weight, high molecular dispersion liquid and surplus and protein and the immiscible carrier of high molecular dispersion liquid.High molecular dispersion liquid includes nano-cellulose of 90 parts by weight to 10 parts by weight.
Description
Technical field
The present invention relates to a kind of moisture absorption heating agent and preparation method thereof, more particularly to one kind to have protein and nanofiber
The moisture absorption heating agent and preparation method thereof of element.
Background technique
It is influenced by global climate transition, often occurs extremely cold extreme climate in winter.In order in response to extremely cold ring
Border, textile industry continually develop various function materials, wherein the material with moisture absorption heating characteristic is considered as most potential and opens
Send out target.
Due to the factor of construction, aqueous vapor is not easy to react with the protein contacts generation in woollen general woollen, therefore inhales
Wet heat generation is bad.In addition, the common material of hygroscopic heating fibers is mostly acryl fiber on the market at present, it is using solidifying
The principle fever of gas is born water, but the moisture absorption heating of acryl fiber is still insufficient.Therefore, it develops with excellent moisture absorption hair
Hot material is still the target that industry is made great efforts.
Summary of the invention
The present invention provides a kind of moisture absorption heating agent and preparation method thereof, with good moisture absorption heating, and can pass through
Coating or impregnation etc. processing procedure means attachment on the textile so that textile has effects that moisture absorption heating.
Moisture absorption heating agent of the invention includes the protein, high molecular dispersion liquid and surplus of 10 parts by weight to 90 parts by weight
With protein and the immiscible carrier of high molecular dispersion liquid.High molecular dispersion liquid includes nanometer of 90 parts by weight to 10 parts by weight
Cellulose.
The preparation method of moisture absorption heating agent of the invention includes the following steps.Woollen containing protein is mixed with ionic liquid
Merge heating, obtains the mixed solution of protein and ionic liquid to extract protein.By mixed solution and protein
Non-solvent is mixed and is filtered, to obtain regenerated protein.Regenerated protein is mixed with high molecular dispersion liquid.
In one embodiment of this invention, above-mentioned protein is, for example, keratan.
In one embodiment of this invention, above-mentioned carrier is, for example, water or alcohols.
In one embodiment of this invention, the above-mentioned woollen containing protein is, for example, wool or feather.
In one embodiment of this invention, above-mentioned ionic liquid is, for example, the structure as shown in formula (1):
Wherein R1 and R2 is-CH independently of one another3、-CH2CH3、-CH2CH2CH3Or-CH2CH2CH2CH3, R3 F-、Cl-、
Br-、HSO4 -、HCOO-、CH3COO-Or H2PO4 -。
In one embodiment of this invention, above-mentioned high molecular dispersion liquid is, for example, nano-cellulose, and regenerated protein
Solid content with high molecular dispersion liquid is than being, for example, between 1:9 between 9:1.
In one embodiment of this invention, the preparation method of above-mentioned moisture absorption heating agent further includes by carrier and regenerated protein
Matter and high molecular dispersion liquid mixing, wherein carrier and protein and high molecular dispersion liquid are immiscible.
Based on above-mentioned, due to that can be bonded again when nano-cellulose and protein contacts and heat release, suction of the invention
Wet exothermic mixture can have more preferably moisture absorption heating, and moisture absorption heating agent can more effectively improve temperature after absorbing aqueous vapor.
To make the foregoing features and advantages of the present invention clearer and more comprehensible, special embodiment below, and it is detailed to cooperate attached drawing to make
Carefully it is described as follows.
Detailed description of the invention
Fig. 1 is the flow chart of the preparation method of the moisture absorption heating agent of the embodiment of the present invention.
Description of symbols
S100, S200, S300: step.
Specific embodiment
The extremely cold environment as caused by climatic variation, in the market for the demand of the material with good moisture absorption heating
Increasingly increase, however, the moisture absorption heating of product on the market is still not good enough at present, therefore in order in response to the pole city cold air Hou Ji
Demand, the present invention by embodiment propose it is a kind of with good moisture absorption heating and can be compatible with fabric moisture absorption heating agent.
However, following embodiment is not intended to limit the invention.
Fig. 1 is the flow chart of the preparation method of the moisture absorption heating agent of the embodiment of the present invention.Fig. 1 is please referred to, it is of the invention
The preparation method of the moisture absorption heating agent of embodiment is as follows.Firstly, step S100 is carried out, by woollen and ionic liquid containing protein
It is mixed and heated, obtains the mixed solution of protein and ionic liquid to extract protein.In one embodiment, contain albumen
The woollen of matter is, for example, to mix via homogenization with ionic liquid.
In one embodiment, the above-mentioned woollen containing protein can be animal hair or hair, e.g. wool or feather, and above-mentioned
Protein be, for example, keratan.Since protein has moisture absorption heating functional group (e.g.-NH abundant2、-COOH、-OH
Or combinations thereof), so heat can be released when protein is in conjunction with aqueous vapor, so that temperature improves.
In one embodiment, ionic liquid is, for example, the structure as shown in formula (1):
Wherein R1 and R2 is-CH independently of one another3、-CH2CH3、-CH2CH2CH3Or-CH2CH2CH2CH3, R3 F-、Cl-、
Br-、HSO4 -、HCOO-、CH3COO-Or H2PO4 -.Above-mentioned ionic liquid can be alkyl imidazole type ionic liquid.Specifically,
Alkyl imidazole type ionic liquid is made of cation and anion, and cation is alkyl imidazole type cation.Implement herein
In mode, the molecular weight of ionic liquid can be between 100 to 2000 dalton (Dalton).
Then, step S200 is carried out, mixed solution obtained in step S100 is mixed and mistake with the non-solvent of protein
Filter, to obtain regenerated protein.In the present embodiment, due to protein insoluble in non-solvent remaining substance in mixed solution
Non-solvent will be dissolved in, so the substance other than protein can be removed by filtration treatment, with obtain it is solid again
Raw egg white matter.Above-mentioned non-solvent is, for example, water, alcohols or acetone, and preferably water or alcohols.
Being formed by regenerated protein via step S200 is the protein extracted from woollen, with higher pure
Degree.In the case where above-mentioned protein is keratan, compared to natural horny element, regenerated protein of the invention (regeneration cutin
Element) about 4 DEG C to 5 DEG C or more can be more effectively improved after absorbing aqueous vapor, such as improve from 28 DEG C to 33 DEG C or more, thus
It is more suitable for the functional fabric of moisture absorption heating.
Later, step S300 is carried out, regenerated protein obtained in step S200 is mixed with high molecular dispersion liquid, with
To moisture absorption heating agent of the invention.In one embodiment, high molecular dispersion liquid is, for example, the dispersion liquid containing nano-cellulose.This
Outside, in moisture absorption heating agent of the invention, the content ratio of regenerated protein and nano-cellulose in this way between 1:9 to 9:1 it
Between.That is, moisture absorption heating agent of the invention includes the regenerated protein and 90 parts by weight to 10 weight of 10 parts by weight to 90 parts by weight
The nano-cellulose of part.In the range of this content ratio, moisture absorption heating agent of the invention can be more effective after absorbing aqueous vapor
Temperature is improved on ground.
It can be bonded again when being contacted due to nano-cellulose and regenerated protein and heat release, compared to only having nanometer
The moisture absorption heating agent of cellulose or protein, moisture absorption heating agent of the invention pass through between nano-cellulose and regenerated protein
It is bonded again and can be further improved temperature.In the present embodiment, temperature can be improved about 4 DEG C to 5 DEG C or more by moisture absorption heating agent.
In some embodiments, nano-cellulose is, for example, carboxymethyl cellulose (CMC), sodium alginate, oxidized form nanometer
Cellulose (TOCN), mechanical defibering type nano-cellulose (MCN), sour hydrolysis-type nano-cellulose (ACN) or ammonium persulfate modification
Type nano-cellulose (APSCN), wherein oxidized form nano-cellulose (TOCN) is, for example, 2,2,6,6- tetramethyl piperidine -1- oxidation
Object oxidized form nano-cellulose.
In addition, when carrying out step S300, it optionally will be with protein and the immiscible load of high molecular dispersion liquid
Agent is mixed with regenerated protein and high molecular dispersion liquid, so that regenerated protein can spread more evenly across and be applied to subsequent
Coating or infiltration processing procedure.Above-mentioned carrier is, for example, water or alcohols.
Since regenerated protein can be spreaded more evenly across and be applied with the nano-cellulose in high molecular dispersion liquid by carrier
In subsequent coating or impregnation processing procedure, therefore, the moisture absorption heating agent processed and applied with higher containing carrier.
Preparation method through the embodiment of the present invention, which is formed by moisture absorption heating agent, has good moisture absorption heating, can
More effectively temperature is improved after absorbing aqueous vapor, therefore can be as coating fluid, and passes through the means of coating or impregnation etc.
Coating layer or film are formed on the textile, so that processed fabric has the functional of moisture absorption heating.For example, originally
The moisture absorption heating agent of case can be coated on nonwoven fabric via the mode of sprinkling water mist, to be fabricated to the facial mask with warming effect.
In addition, moisture absorption heating agent of the invention can also be added in spinning solution, it is further fabricated to hygroscopic heating fibers.Therefore, this hair
Bright moisture absorption heating agent has a variety of applications, and is not only restricted to above content.
Hereinafter, by experimental example come the effect of confirming above-described embodiment, but the invention is not limited to the following contents.
<experimental example 1>
By wool and 1- butyl -3- methyl-imidazolium chloride ([BMIM] Cl) (ionic liquid shown in formula (1), wherein R1
For-CH2CH2CH2CH3, R2 is-CH3, and R3 is Cl-) be mixed and heated, keratan and ion are obtained to extract keratan
The mixed solution of liquid.Mixed solution is mixed and filtered with water (non-solvent of keratan), to obtain regeneration keratan.
Later, the keratan being obtained by extraction from wool and the macromolecule containing oxidation nanometer cellulose (TOCN) are dispersed
Liquid is mixed to form moisture absorption heating agent, and wherein the weight ratio of keratan and oxidation nanometer cellulose (TOCN) are 2:1.
<experimental example 2>
Keratan is extracted from wool by testing 1 identical mode, then keratan and will contain carboxymethyl cellulose
(CMC) high molecular dispersion liquid mixing, forms moisture absorption heating agent, wherein the weight ratio of keratan and carboxymethyl cellulose (CMC)
For 2:1.
<experimental example 3>
Keratan is extracted from wool by testing 1 identical mode, then keratan and will contain the height of sodium alginate
Molecular dispersions mixing, forms moisture absorption heating agent, and wherein the weight ratio of keratan and sodium alginate is 2:1.
<experimental example 4>
By goose feather and 1- ethyl-3-methylimidazole acetate ([EMIM] OAc) (ionic liquid shown in formula (1), wherein R1
For-CH2CH3, R2 is-CH3, and R3 is CH3COO-) be mixed and heated, keratan and ionic liquid are obtained to extract keratan
The mixed solution of body.Mixed solution is mixed and filtered with the non-solvent of protein, to obtain regeneration keratan.
Later, the keratan being obtained by extraction in goose feather is mixed into shape with the high molecular dispersion liquid containing oxidation nanometer cellulose
At moisture absorption heating agent, wherein the weight ratio of keratan and oxidation nanometer cellulose is 2:1.
<comparative example 1>
Comparative example 1 is wool.
<comparative example 2>
Comparative example 2 is goose feather.
<comparative example 3>
The regeneration keratan extracted from wool by testing 1 identical mode.
<comparative example 4>
The regeneration keratan extracted from goose feather by testing 4 identical modes.
Moisture absorption heating test
The sample of 0.5 gram of experimental example 1~4 and comparative example 1~4 is placed on the culture dish that diameter is 30mm respectively.It will
Environment temperature is set as 24 DEG C, and ambient humidity is set as 50%.Sample is set to absorb water mist using humidifier, wherein humidification water is about
For 0.167ml/min, and temperature difference caused by each sample is recorded, as shown in table 1.
Table 1
According to table 1, compared to the wool of comparative example 1~4, goose feather and regeneration keratan, due to experimental example 1~4
Moisture absorption heating agent has keratan and nano-cellulose simultaneously, therefore can cause the biggish temperature difference after absorbing water mist.Namely
It says, moisture absorption heating agent of the invention has preferable moisture absorption heating.
Although the present invention explains that as above however, it is not to limit the invention, any technical field with embodiment
Middle technical staff, without departing from the spirit and scope of the present invention, when can make a little change and retouching, therefore protection of the invention
Range is subject to view as defined in claim.
Claims (10)
1. a kind of moisture absorption heating agent characterized by comprising
The protein of 10 parts by weight to 90 parts by weight；
High molecular dispersion liquid, including 90 parts by weight to the nano-cellulose of 10 parts by weight；And
Surplus with the protein and the immiscible carrier of the high molecular dispersion liquid.
2. moisture absorption heating agent according to claim 1, wherein the protein is keratan.
3. moisture absorption heating agent according to claim 1, wherein the carrier includes water or alcohols.
4. a kind of preparation method of moisture absorption heating agent characterized by comprising
Woollen containing protein is mixed and heated with ionic liquid, obtained with extracting the protein protein with
The mixed solution of the ionic liquid；
The mixed solution is mixed and filtered with the non-solvent of the protein, to obtain regenerated protein；And
The regenerated protein is mixed with high molecular dispersion liquid.
5. the preparation method of moisture absorption heating agent according to claim 4, wherein the protein is keratan.
6. the preparation method of moisture absorption heating agent according to claim 4, wherein the woollen containing protein includes wool
Or feather.
7. the preparation method of moisture absorption heating agent according to claim 4, wherein the ionic liquid includes by shown in formula (1)
Structure:
Wherein R1 and R2 is-CH independently of one another3、-CH2CH3、-CH2CH2CH3Or-CH2CH2CH2CH3, R3 F-、Cl-、Br-、
HSO4 -、HCOO-、CH3COO-Or H2PO4 -。
8. the preparation method of moisture absorption heating agent according to claim 4, wherein the high molecular dispersion liquid includes Nanowire
Dimension element, and the content of the regenerated protein and nano-cellulose ratio between 1:9 between 9:1.
9. the preparation method of moisture absorption heating agent according to claim 4, further include by carrier and the regenerated protein with
And high molecular dispersion liquid mixing, wherein the carrier and the protein and the high molecular dispersion liquid are immiscible.
10. the preparation method of moisture absorption heating agent according to claim 9, wherein the carrier includes water or alcohols.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW106144756A TWI673408B (en) | 2017-12-20 | 2017-12-20 | Hygroscopic exothermic agent and method for manufaturing the same |
| TW106144756 | 2017-12-20 |
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| CN109944071A true CN109944071A (en) | 2019-06-28 |
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| TW (1) | TWI673408B (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05163677A (en) * | 1991-12-10 | 1993-06-29 | Kanebo Ltd | Highly water-absorbing resin-finished cloth |
| CN1660901A (en) * | 2004-12-24 | 2005-08-31 | 中国科学院长春应用化学研究所 | Method for preparing solution of keratin |
| CN1687513A (en) * | 2005-03-29 | 2005-10-26 | 东华大学 | Method for fabricating wool keratin clad acrylon, polypropylene, capron and textiles |
| CN1763301A (en) * | 2004-10-18 | 2006-04-26 | 香港理工大学 | Functional finishing adjuvant for fabric, its preparation and application process |
| CN101463137A (en) * | 2009-01-16 | 2009-06-24 | 四川大学 | Method for preparing natural polymer blended membrane with ion liquid as solvent |
| CN102229665A (en) * | 2011-05-17 | 2011-11-02 | 华东理工大学 | Method for extracting poultry feather keratin by using water insoluble ionic liquid and relative poultry feather keratin solution |
| CN103492177A (en) * | 2012-04-18 | 2014-01-01 | 株式会社应新Mlp | Multilayer sheet, heat-retaining structure provided with same, and method for producing multilayer sheet |
| CN104762680A (en) * | 2015-03-26 | 2015-07-08 | 苏州威尔德工贸有限公司 | Regenerated protein fiber containing ionic liquid |
| CN104774254A (en) * | 2015-03-31 | 2015-07-15 | 上海大学 | Method for extracting keratin in feather by using imidazole chloride ionic liquid |
| CN105640785A (en) * | 2014-09-19 | 2016-06-08 | 李和伟 | Novel film using device |
| CN105951440A (en) * | 2016-05-18 | 2016-09-21 | 江苏阳光股份有限公司 | Production technology for anti-ultraviolet finishing liquid for elastic worsted fabric |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100369900C (en) * | 2006-01-24 | 2008-02-20 | 广东工业大学 | Process for preparing ionic liquid |
| CN107489023A (en) * | 2016-06-13 | 2017-12-19 | 江苏阳光股份有限公司 | One kind being capable of quick-drying wool fabric |
-
2017
- 2017-12-20 TW TW106144756A patent/TWI673408B/en active
-
2018
- 2018-03-21 CN CN201810235905.5A patent/CN109944071A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05163677A (en) * | 1991-12-10 | 1993-06-29 | Kanebo Ltd | Highly water-absorbing resin-finished cloth |
| CN1763301A (en) * | 2004-10-18 | 2006-04-26 | 香港理工大学 | Functional finishing adjuvant for fabric, its preparation and application process |
| CN1660901A (en) * | 2004-12-24 | 2005-08-31 | 中国科学院长春应用化学研究所 | Method for preparing solution of keratin |
| CN1687513A (en) * | 2005-03-29 | 2005-10-26 | 东华大学 | Method for fabricating wool keratin clad acrylon, polypropylene, capron and textiles |
| CN101463137A (en) * | 2009-01-16 | 2009-06-24 | 四川大学 | Method for preparing natural polymer blended membrane with ion liquid as solvent |
| CN102229665A (en) * | 2011-05-17 | 2011-11-02 | 华东理工大学 | Method for extracting poultry feather keratin by using water insoluble ionic liquid and relative poultry feather keratin solution |
| CN103492177A (en) * | 2012-04-18 | 2014-01-01 | 株式会社应新Mlp | Multilayer sheet, heat-retaining structure provided with same, and method for producing multilayer sheet |
| CN105640785A (en) * | 2014-09-19 | 2016-06-08 | 李和伟 | Novel film using device |
| CN104762680A (en) * | 2015-03-26 | 2015-07-08 | 苏州威尔德工贸有限公司 | Regenerated protein fiber containing ionic liquid |
| CN104774254A (en) * | 2015-03-31 | 2015-07-15 | 上海大学 | Method for extracting keratin in feather by using imidazole chloride ionic liquid |
| CN105951440A (en) * | 2016-05-18 | 2016-09-21 | 江苏阳光股份有限公司 | Production technology for anti-ultraviolet finishing liquid for elastic worsted fabric |
Non-Patent Citations (2)
| Title |
|---|
| 李卫东等: "《纳米纤维素接枝PET纤维织物的制备和表征》", 《纤维素科学与技术》 * |
| 王江波等: "《羊毛角蛋白液涂覆处理涤纶的亲水性研究》", 《合成纤维工业》 * |
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| TWI673408B (en) | 2019-10-01 |
| TW201928135A (en) | 2019-07-16 |
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Application publication date: 20190628 |