CN109943308A - A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent - Google Patents

A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent Download PDF

Info

Publication number
CN109943308A
CN109943308A CN201910186695.XA CN201910186695A CN109943308A CN 109943308 A CN109943308 A CN 109943308A CN 201910186695 A CN201910186695 A CN 201910186695A CN 109943308 A CN109943308 A CN 109943308A
Authority
CN
China
Prior art keywords
oil
heavy component
drives
plugging agent
component deposit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910186695.XA
Other languages
Chinese (zh)
Inventor
周万富
王鑫
刘向斌
李国�
李胜利
王海静
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daqing Oilfield Co Ltd
China Petroleum and Natural Gas Co Ltd
Original Assignee
Daqing Oilfield Co Ltd
China Petroleum and Natural Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daqing Oilfield Co Ltd, China Petroleum and Natural Gas Co Ltd filed Critical Daqing Oilfield Co Ltd
Priority to CN201910186695.XA priority Critical patent/CN109943308A/en
Publication of CN109943308A publication Critical patent/CN109943308A/en
Pending legal-status Critical Current

Links

Landscapes

  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The present invention relates to technical field of tertiary oil recovery, especially belong to a kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent, it solves oil field CO2It drives crude oil heavy component deposit in pit shaft and blocks de-plugging problem.The present invention is made of following ingredients by mass percentage: 70%~90% industrial alcohol ether, 10%~30% diesel oil.The present invention is used for CO2It drives crude oil heavy component deposit in pit shaft and blocks de-plugging, effectively dredging pit shaft, smoothly remove for test equipment, well killing fluid and flushing fluid circulation, anti-corrosion dosing etc. provide channel, solve the problems, such as the production such as test, dosing, bar card, kill-job, well-flushing.

Description

A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent
Technical field
The present invention relates to technical field of tertiary oil recovery, belong to CO2A kind of oil field CO under the conditions of displacement2It drives former with pit shaft Oily heavy component deposit de-plugging agent.
Background technique
During carbon dioxide drive, due to CO2Extraction to crude oil light components and its phase in the wellbore State variation, so that well wellbore heavy component is easily deposited on pit shaft, causes bar card, serious person can cause pit shaft to block, so that well Cylinder can not be successfully dosing, kill-job and clean-out service without circulation canal, normally produce to influence oil field.In injection end because of surface flow Journey failure, working system change, and part gas injection well easily returns oil.When restoring gas injection, the crude oil in pit shaft is due to low temperature and CO2's It washing away repeatedly, the heavy component of crude oil is deposited on tube inner wall, and it easily causes test equipment to go into the well and meets card when being hampered or above mention instrument, Seriously affect successfully tested rate.Through detecting, CO2Repelling crude oil heavy component is with C16Based on upper higher carbon number hydrocarbon, colloid, pitch, wax Content is up to 60%, and the content of colloid in conventional water drive crude oil heavy component, pitch, wax only has 30% or so.Conventional heavy Component de-plugging agent is in CO2Dissolution dispersion rate is poor under drive low temperature environment, is unable to satisfy CO2Field demand is driven, CO is now badly in need of2Drive well Effective block releasing technique of cylinder crude oil heavy component deposition tamper.The present invention provides a kind of oil field CO2It drives and uses wellbore oil heavy Component deposit de-plugging agent.
Summary of the invention
Object of the present invention is to develop effectively to release CO2The de-plugging agent for driving wellbore oil heavy component deposition tamper, has Effect dredging pit shaft, solves the problems, such as a kind of oil field CO of the production such as test, dosing, bar card, kill-job, well-flushing2Drive wellbore oil weight Matter component deposit de-plugging agent.
Particular technique content of the invention is as follows: it is made of following ingredients by mass percentage: 70%~90% industrial alcohols Ether, 10%-30% diesel oil.
Industrial alcohol ether is one of butyl glycol ether or 1,2- propandiol butyl ether.
Diesel oil is label 0 ,-No. 10 ,-No. 20 ,-No. 35, one of-No. 50.
Block releasing technique principle of the invention are as follows: contain ether in the composition of alcohol ether, can dissolve each other with diesel oil for lipophilic group Solution system is formed, according to the principle of similar compatibility, the crude oil heavy component which can effectively dissolve in dispersion pit shaft is heavy Product object has further speeded up the dissolution rate of dispersion of heavy deposit by the wetability and permeability of alcohol ether.Utilize alcohol ether Low temperature resistance, it is ensured that the system is in CO2Drive the validity of pit shaft low temperature environment.
Compared with the prior art the present invention has the advantages that
1) low temperature resistant, under -20 DEG C of environment, effective de-plugging;
2) non-corrosive energy;
3) intersolubility is good, extemporaneous preparation is simple and easy.
Specific embodiment: the present invention will be further explained below with reference to examples: a kind of oil field CO2Drive wellbore oil Heavy component deposit de-plugging agent, is made of following ingredients by mass percentage: 70%~90% industrial alcohol ether, 10%~30% bavin Oil.
Industrial alcohol ether is one of butyl glycol ether or 1,2- propandiol butyl ether.
Diesel oil is label 0 ,-No. 10 ,-No. 20 ,-No. 35, one of-No. 50.
A kind of oil field CO of embodiment 1, present embodiment2Drive use wellbore oil heavy component deposit de-plugging agent, it by Industrial alcohol ether, diesel oil composition, are made of following ingredients: 70%1,2- propandiol butyl ethers, No. 30%0 diesel oil by mass percentage.
The CO of present embodiment2It drives as follows with the preparation method of wellbore oil heavy component deposit de-plugging agent: pressing 1,2- The mass percent of propandiol butyl ether and No. 0 diesel oil is that 70%:30% is mixed, and is stirred at low speed in mixed process, until mixing Uniformly obtain the wellbore oil heavy component deposit de-plugging agent of present embodiment.
It is analyzed by laboratory experiment, at different temperatures heavy component deposit and CO2It drives and uses wellbore oil heavy component When deposit de-plugging agent volumetric usage ratio is 1:3, at room temperature, 3h can effectively dissolve heavy group to the de-plugging agent formula system Dividing deposit, 72h can effectively dissolve heavy component deposit under the conditions of -20 DEG C, it is able to satisfy live de-plugging requirement completely, remaining Temperature experimental result is shown in Table 1.
1 crude oil heavy component deposit de-plugging agent de-plugging measurement result table of table
Embodiment 2, by taking Carbon Dioxide Test area a bite gas injection well wellbore oil heavy component deposit de-plugging test well as an example, it is first Preparation method in example 1 is first pressed in matching liquid pool prepares the well that butyl glycol ether and-No. 50 diesel quality percentages are 80%:20% Cylinder crude oil heavy component deposit de-plugging agent 5m3, de-plugging agent is injected from oil pipe or oil jacket annulus with ground injection pump, to oil pipe In be completely filled with termination of pumping after de-plugging agent, closing well reacts open flow drain after 56h, for 24 hours after metaideophone.As can be seen from Table 2, it is infused before de-plugging It is 8m that enter pressure, which be 15MPa time with fluence,3, design day is unable to complete with fluence, and injection pressure is to match in 13MPa time after de-plugging Fluence is 15m3, fluence, de-plugging success can be matched complete design day.
Construction well day injection allocation situation table before and after 2 de-plugging of table
Embodiment 3, by taking Carbon Dioxide Test area flatly extraction well shaft crude oil heavy component deposit de-plugging test well as an example, it is first Preparation method in example 1 is first pressed in matching liquid pool prepares the well that butyl glycol ether and-No. 50 diesel quality percentages are 90%:10% Cylinder crude oil heavy component deposit de-plugging agent 5m3, de-plugging agent is injected from oil pipe or oil jacket annulus with ground injection pump, to oil pipe In be completely filled with termination of pumping after de-plugging agent, closing well reacts 72h, continuously returns lifting rate about 6m after open flow3More than, drain age velocity is very fast, Thus illustrate that pit shaft is unimpeded, de-plugging success.

Claims (3)

1. a kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent, it is characterised in that: by mass percentage under It arranges into and is grouped as: 70%~90% industrial alcohol ether, 10%~30% diesel oil.
2. a kind of oil field CO according to claim 12It drives and uses wellbore oil heavy component deposit de-plugging agent, feature exists In: industrial alcohol ether is one of butyl glycol ether or 1,2- propandiol butyl ether.
3. a kind of oil field CO according to claim 12It drives and uses wellbore oil heavy component deposit de-plugging agent, feature exists In: diesel oil is label 0 ,-No. 10 ,-No. 20 ,-No. 35, one of-No. 50.
CN201910186695.XA 2019-03-13 2019-03-13 A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent Pending CN109943308A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910186695.XA CN109943308A (en) 2019-03-13 2019-03-13 A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910186695.XA CN109943308A (en) 2019-03-13 2019-03-13 A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent

Publications (1)

Publication Number Publication Date
CN109943308A true CN109943308A (en) 2019-06-28

Family

ID=67008830

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910186695.XA Pending CN109943308A (en) 2019-03-13 2019-03-13 A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent

Country Status (1)

Country Link
CN (1) CN109943308A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838524A (en) * 2010-05-13 2010-09-22 四川西南油大石油工程有限公司 Oil soluble jam releasing agent for drilling fluid
CN102146281A (en) * 2011-01-25 2011-08-10 中国石油天然气股份有限公司 Oil-soluble paraffin-removal viscosity breaker
CN102746838A (en) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 Blocking remover of gas well shaft
CN103421477A (en) * 2012-05-21 2013-12-04 克拉玛依市三达新技术开发有限责任公司 Preparation method of blocking remover for relieving near-wellbore area gas condensate and particle obstruction
CN108359437A (en) * 2018-04-14 2018-08-03 中国石油集团川庆钻探工程有限公司长庆井下技术作业公司 A kind of oil well lotion paraffin remover and its preparation method and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838524A (en) * 2010-05-13 2010-09-22 四川西南油大石油工程有限公司 Oil soluble jam releasing agent for drilling fluid
CN102146281A (en) * 2011-01-25 2011-08-10 中国石油天然气股份有限公司 Oil-soluble paraffin-removal viscosity breaker
CN102746838A (en) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 Blocking remover of gas well shaft
CN103421477A (en) * 2012-05-21 2013-12-04 克拉玛依市三达新技术开发有限责任公司 Preparation method of blocking remover for relieving near-wellbore area gas condensate and particle obstruction
CN108359437A (en) * 2018-04-14 2018-08-03 中国石油集团川庆钻探工程有限公司长庆井下技术作业公司 A kind of oil well lotion paraffin remover and its preparation method and application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王大全,等: "《精细化工辞典》", 30 June 1998 *

Similar Documents

Publication Publication Date Title
US3380531A (en) Method of pumping viscous crude
CN105863560B (en) Oil well steam hot wash and the compound wax removal system of chemical agent and compound dewaxing method
CN102775973B (en) Scale removing agent applicable to alkaline-surfactant-polymer flooding and scale removing and unfreezing process
CN101328798A (en) Method for extracting thick oil
CN102775975A (en) Blocking remover for reservoir of oil well
CN1831295A (en) Technology method for deblock of oil field oil-water well using biological acid
RU2642738C1 (en) Method of multi-stage treatment of injection well bottomhole zone in terrigenous and carbonate formations
CN110219627A (en) A method of enhancing offshore oilfield oil well acidation effect
CN108003857A (en) A kind of efficiently emulsion-type oil well Wax removing agent and preparation method thereof
CN106753299A (en) A kind of thin oil well selective water shutoff agent and preparation method and application
CN102274701A (en) Surfactant and preparation and application thereof
CN110105942B (en) Wax remover and preparation method and application thereof
CN109943308A (en) A kind of oil field CO2It drives and uses wellbore oil heavy component deposit de-plugging agent
CN110484227B (en) Asphaltene dispersant and application thereof, and method for inhibiting asphaltene precipitation in thickened oil and removing asphaltene deposit in thickened oil
CN1861979A (en) Method of heavy oil cold flow production
CN113416576A (en) Compound demulsifier and application thereof
CN206053907U (en) A kind of water injection well chemicals dosing plant
CN1209439C (en) Oil-based mud flushing liquor and preparation method thereof
CN114989797B (en) Composite paraffin removal and descaling agent for oil well and blocking removal process of static pipe column of composite paraffin removal and descaling agent
CN102040992B (en) Rod blockage prevention liquid for carbon dioxide huff-puff enhanced oil recovery and injection method thereof
CN112961662A (en) Wetting reversal agent, wetting reversal liquid and pressure flooding water injection method
CN101852073A (en) Novel integration technique for improving recovery ratio of thick oil with high thickness and low yield
CN101717626A (en) Application of methylnaphthalene in lowering viscosity of thickened oil
CN111500310A (en) Crude oil composite demulsifier and preparation method thereof
RU2366811C2 (en) Nethod of production of highly paraffinic crude

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190628

WD01 Invention patent application deemed withdrawn after publication