CN109935877A - A kind of chemical energy device for converting electric energy - Google Patents
A kind of chemical energy device for converting electric energy Download PDFInfo
- Publication number
- CN109935877A CN109935877A CN201910244618.5A CN201910244618A CN109935877A CN 109935877 A CN109935877 A CN 109935877A CN 201910244618 A CN201910244618 A CN 201910244618A CN 109935877 A CN109935877 A CN 109935877A
- Authority
- CN
- China
- Prior art keywords
- electrolyte
- electrochemistry region
- region
- electrochemistry
- reducing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000126 substance Substances 0.000 title claims abstract description 33
- 230000005518 electrochemistry Effects 0.000 claims abstract description 119
- 239000003792 electrolyte Substances 0.000 claims abstract description 108
- 230000001590 oxidative effect Effects 0.000 claims abstract description 47
- 239000007800 oxidant agent Substances 0.000 claims abstract description 46
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 43
- 239000004020 conductor Substances 0.000 claims description 64
- 239000002245 particle Substances 0.000 claims description 23
- 230000005611 electricity Effects 0.000 claims description 10
- 108091006146 Channels Proteins 0.000 description 52
- 239000003054 catalyst Substances 0.000 description 27
- 239000000047 product Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- -1 oxygen ion Chemical class 0.000 description 9
- 229910052796 boron Inorganic materials 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- RFVVBBUVWAIIBT-UHFFFAOYSA-N beryllium nitrate Chemical compound [Be+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O RFVVBBUVWAIIBT-UHFFFAOYSA-N 0.000 description 2
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003034 coal gas Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- WOAHJDHKFWSLKE-UHFFFAOYSA-N 1,2-benzoquinone Chemical compound O=C1C=CC=CC1=O WOAHJDHKFWSLKE-UHFFFAOYSA-N 0.000 description 1
- WHQOKFZWSDOTQP-UHFFFAOYSA-N 2,3-dihydroxypropyl 4-aminobenzoate Chemical compound NC1=CC=C(C(=O)OCC(O)CO)C=C1 WHQOKFZWSDOTQP-UHFFFAOYSA-N 0.000 description 1
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 1
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 description 1
- RBWNDBNSJFCLBZ-UHFFFAOYSA-N 7-methyl-5,6,7,8-tetrahydro-3h-[1]benzothiolo[2,3-d]pyrimidine-4-thione Chemical compound N1=CNC(=S)C2=C1SC1=C2CCC(C)C1 RBWNDBNSJFCLBZ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 239000004151 Calcium iodate Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 description 1
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004153 Potassium bromate Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- JPILVNODWOLMNY-UHFFFAOYSA-N [Mg].Cl(=O)(=O)O Chemical compound [Mg].Cl(=O)(=O)O JPILVNODWOLMNY-UHFFFAOYSA-N 0.000 description 1
- GSMXFPGKQNHYPM-UHFFFAOYSA-N [Sr].Cl(=O)(=O)(=O)O Chemical compound [Sr].Cl(=O)(=O)(=O)O GSMXFPGKQNHYPM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- KHPLPBHMTCTCHA-UHFFFAOYSA-N ammonium chlorate Chemical compound N.OCl(=O)=O KHPLPBHMTCTCHA-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- URGYLQKORWLZAQ-UHFFFAOYSA-N azanium;periodate Chemical compound [NH4+].[O-]I(=O)(=O)=O URGYLQKORWLZAQ-UHFFFAOYSA-N 0.000 description 1
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- YALMXYPQBUJUME-UHFFFAOYSA-L calcium chlorate Chemical compound [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O YALMXYPQBUJUME-UHFFFAOYSA-L 0.000 description 1
- UHWJJLGTKIWIJO-UHFFFAOYSA-L calcium iodate Chemical compound [Ca+2].[O-]I(=O)=O.[O-]I(=O)=O UHWJJLGTKIWIJO-UHFFFAOYSA-L 0.000 description 1
- 235000019390 calcium iodate Nutrition 0.000 description 1
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 1
- 235000019402 calcium peroxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- IJCCOEGCVILSMZ-UHFFFAOYSA-L copper;dichlorate Chemical compound [Cu+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O IJCCOEGCVILSMZ-UHFFFAOYSA-L 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- ZICFUFGMZGWZMA-UHFFFAOYSA-L iron(2+) diiodate Chemical compound [Fe+2].[O-]I(=O)=O.[O-]I(=O)=O ZICFUFGMZGWZMA-UHFFFAOYSA-L 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- GTTYPHLDORACJW-UHFFFAOYSA-N nitric acid;sodium Chemical compound [Na].O[N+]([O-])=O GTTYPHLDORACJW-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000019396 potassium bromate Nutrition 0.000 description 1
- 229940094037 potassium bromate Drugs 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229960005076 sodium hypochlorite Drugs 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- GTQFPPIXGLYKCZ-UHFFFAOYSA-L zinc chlorate Chemical compound [Zn+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O GTQFPPIXGLYKCZ-UHFFFAOYSA-L 0.000 description 1
- TUDPEWOTGHYZBQ-UHFFFAOYSA-L zinc;dibromate Chemical compound [Zn+2].[O-]Br(=O)=O.[O-]Br(=O)=O TUDPEWOTGHYZBQ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
The invention discloses a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, electrolyte is set on the electrochemistry region A, the electrochemistry region B is arranged on the electrolyte, the electrolyte is set as double conductivity type electrolyte, the electrochemistry region A is connected to setting with oxidant feed channel, and the electrochemistry region B is connected to setting with reducing agent feed channel, and product is arranged on double conductivity type electrolyte and exports channel.The chemical energy device for converting electric energy structure disclosed in this invention is simple, high-efficient, the service life is long, good reliability.
Description
Technical field
The present invention relates to electricity field, electrochemical field more particularly to a kind of chemical energy device for converting electric energy.
Background technique
In traditional chemical energy device for converting electric energy (such as fuel cell), the generating process of reaction product and the life of ion
To carry out in the same region at process, such as in hydrogen fuel cell, oxygen receive the process for being electronically generated negative oxygen ion and
Negative oxygen ion and proton reaction, which generate the process of water, to be occurred in the same area, in this way, not only influencing ionogenic speed
Rate also influences the usage amount of catalyst, can also cause back reaction, and then influence the life and reliability of device.If can send out
Bright one kind can make the generating process of ion and ionic reaction generates the chemical energy electric energy that the process of product is carried out in different zones
Conversion equipment is then of great significance.Therefore, it is necessary to invent a kind of new chemical energy device for converting electric energy.
Summary of the invention
To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:
Scheme 1: a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, in the electrification
Electrolyte is set on the A of school district domain, and the electrochemistry region B is arranged on the electrolyte, and the electrolyte is set as double conductivity type electricity
Xie Zhi, the electrochemistry region A are connected to setting, the electrochemistry region B and reducing agent feed channel with oxidant feed channel
Connection setting is arranged product on double conductivity type electrolyte and exports channel.
Scheme 2: a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, in the electrification
Electrolyte A is set on the A of school district domain, electrolyte B is set on the electrolyte A, the electrochemistry region B is arranged in the electrolysis
On matter B, the electrochemistry region A is connected to setting, the electrochemistry region B and reducing agent feed channel with oxidant feed channel
Connection setting is arranged product between electrolyte A and the electrolyte B and exports channel.
Scheme 3: a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, in the electrification
Electrolyte A is set on the A of school district domain, electrolyte X is set on the electrolyte A, electrolyte B, institute are set on the electrolyte X
It states electrochemistry region B to be arranged on the electrolyte B, the electrolyte X is set as double conductivity type electrolyte, the electrochemistry region A
Setting is connected to oxidant feed channel, the electrochemistry region B is connected to setting with reducing agent feed channel, in double conductivity type
Product is set on electrolyte and exports channel.
Scheme 4: a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, in the electrification
Electrolyte A is set on the A of school district domain, porous conductor region is set on the electrolyte A, is arranged on the porous conductor region
Electrolyte B, on the electrolyte B, the electrochemistry region A and oxidant feed channel connect for the electrochemistry region B setting
Logical setting, the electrochemistry region B are connected to setting with reducing agent feed channel, product are arranged on the porous conductor region
Channel is exported, the conductor in the porous conductor region is set as being formed by the oxidant in oxidant feed channel non-electronic
It charged particle and can be moved on it by the non-electronic charged particle that the reducing agent in reducing agent feed channel is formed
Conductor.
Scheme 5: a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, in the electrification
Electrolyte A is set on the A of school district domain, porous conductor region is set on the electrolyte A, is arranged on the porous conductor region
The electrochemistry region B, the electrochemistry region A are connected to setting, the electrochemistry region B and reduction with oxidant feed channel
The connection setting of agent feed channel, is arranged product on the porous conductor region and exports channel, the porous conductor region
Conductor is set as the non-electronic charged particle formed by the oxidant in oxidant feed channel and by the reducing agent feed
The conductor that the non-electronic charged particle that reducing agent in channel is formed can move on it.
Scheme 6: a kind of chemical energy device for converting electric energy, including electrochemistry region A and electrochemistry region B, in the electrification
Electrolyte A is set on the A of school district domain, porous conductor region is set on the electrolyte A, is arranged on the porous conductor region
The electrochemistry region B, the electrochemistry region B are connected to setting, the electrochemistry region A and reduction with oxidant feed channel
The connection setting of agent feed channel, is arranged product on the porous conductor region and exports channel, the porous conductor region
Conductor is set as the non-electronic charged particle formed by the oxidant in oxidant feed channel and by the reducing agent feed
The conductor that the non-electronic charged particle that reducing agent in channel is formed can move on it.
In the present invention, so-called " double conductivity type electrolyte " is to refer to conduct the non-electronic band electrochondria generated by oxidant
Son can also conduct the electrolyte of the non-electronic charged particle generated by reducing agent.Such as it can also both be conducted with proton conducting
The electrolyte of negative oxygen ion.
In the present invention, so-called " porous conductor region " refers to including that can conduct the non-electronic electrification generated by oxidant
Particle can also conduct the region of the porous conductor of the non-electronic charged particle generated by reducing agent.Such as it both can be with proton conducting
The region of the porous conductor of negative oxygen ion can also be conducted.
In the present invention, the catalyst A and the catalyst B are selectively chosen and are set as same catalyst.
In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.
In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including
Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature.
It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention
The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification
School district domain includes two or three in these three conditions.
In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition
Structure.
In the present invention, include the catalyst device in, the catalyst be set as include noble metal catalyst, or
The catalyst be set as include rare earth element catalyst.
It in the present invention, further can selectively select that catalyst corresponding with the reducing agent is made to be set as catalyst A, with
It is different that the corresponding catalyst of the oxidant is set as catalyst B, the catalyst A and the catalyst B, in this case,
Catalyst in the electrochemistry region, which is selectively chosen, is set as the random mixed of the catalyst A and catalyst B
Select the catalyst A for being set as contacting near catalytic domain with closing the catalyst choice in object or the electrochemistry region
The band electrochondria between the catalyst A and the catalyst B can be increased with the mixture of the catalyst B in order to improve efficiency
The mobility of son.
In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode
Point.
It, can be according to the operating temperature of the property and the electrochemistry region of the reducing agent and the oxidant in the present invention
Select different catalyst.
In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.
Electrochemical appliance disclosed in this invention is in use, oxidant alternative selection is set as: oxygen, compression are empty
Gas, oxygen, liquid oxygen, air, liquefied air, fluorine, chlorine, bromine, iodine, ozone, nitric acid, the concentrated sulfuric acid, hypochlorous acid, chromic acid, Peracetic acid,
Perchloric acid, chlorate, nitrate, permanganate, perchlorate, bichromate, Calcium perchlorate, ammonium perchlorate, sodium perchlorate, height
Potassium chlorate, lithium perchlorate, magnesium perchlorate, barium perchlorate, perchloric acid strontium, silver perchlorate, ammonium chlorate, sodium chlorate, potassium chlorate, chloric acid
Magnesium, calcium chlorate, copper chlorate, zinc chlorate, chloric acid thallium, silver chlorate, potassium permanganate, acerdol, barium permanganate, lithium nitrate, nitric acid
Sodium, potassium nitrate, calcium nitrate, cesium nitrate, beryllium nitrate, potassium bromate, zinc bromate, ammonium periodate, calcium iodate, iron iodate, sodium dichromate,
Potassium bichromate, iron chloride, ammonium ceric nitrate, sodium hypochlorite, SODIUM PERCARBONATE, sodium perborate, calcium hypochlorite, sodium dichloro cyanurate,
Copper oxide, di-iron trioxide, sodium peroxide, manganese dioxide, nitrogen dioxide, potassium peroxide, magnesium dioxide, calcium dioxide, peroxide
Change hydrogen, chromium trioxide, strontium dioxide, sodium dioxide, silver oxide, acetone, acrylonitrile, benzaldehyde, dibenzoyl peroxide, benzene
Quinone, carbon tetrabromide are set as chloramines etc.；Reducing agent alternative selection is set as: hydrogen, alkane, alkene, alkynes, aromatic hydrocarbon,
Halogenated hydrocarbons, alcohol compound, phenolic compound, aldehyde compound, ketone compounds, hydroxyl acid compounds, ester type compound,
Sodium, aluminium, zinc, lithium, potassium, magnesium, manganese, carbon, calcium, barium, vanadium, chromium, iron, cobalt, copper, boron, silicon, phosphorus, tin, mercury, lead, carbon dust, coal dust end,
Sulphur, lithium aluminium hydride reduction, diethyl aluminium hydride sodium, sodium borohydride, potassium borohydride, carbon monoxide, hydrogen sulfide, hydrazine, ammonia, hydrogen chloride,
Hydrogen iodide, sulfur dioxide, hydrogen peroxide, vulcanized sodium, stannous chloride, formaldehyde, sulfurous acid, sulfuric acid, oxalic acid, ethyl alcohol, sodium sulfite,
Sodium hydrogensulfite, ferrous sulfate, methanol, natural gas, coal gas, methane, coke, diesel oil, dimethyl ether, kerosene, gasoline, hydrogen one aoxidize
Carbon mix is set as heavy oil etc..
In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several
The identical component of title or substance.
In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field
Part, unit or system etc..
Beneficial effects of the present invention are as follows: the chemical energy device for converting electric energy structure disclosed in this invention is simple, imitates
Rate is high, the service life is long, good reliability.
Detailed description of the invention
Fig. 1: the structural schematic diagram of the embodiment of the present invention 1；
Fig. 2: the structural schematic diagram of the embodiment of the present invention 2；
Fig. 3: the structural schematic diagram of the embodiment of the present invention 3；
Fig. 4: the structural schematic diagram of the embodiment of the present invention 4；
Fig. 5: the structural schematic diagram of the embodiment of the present invention 5；
Fig. 6: the structural schematic diagram of the embodiment of the present invention 6；
In figure: 1 electrochemistry region A, 2 electrochemistry region B, 3 electrolyte, 4 oxidant feed channels, 5 reducing agent feeds are logical
Road, 6 products export channel, 7 electrolyte X, 8 porous conductor regions, 11 electrolyte A, 12 electrolyte B.
Specific embodiment
Embodiment 1
A kind of chemical energy device for converting electric energy, as shown in Figure 1, include electrochemistry region A 1 and electrochemistry region B 2,
Electrolyte 3 is set on the electrochemistry region A 1, and the electrochemistry region B 2 is arranged on the electrolyte 3, the electrolysis
Matter 3 is set as double conductivity type electrolyte, and the electrochemistry region A 1 is connected to setting, the electrochemistry region with oxidant feed channel 4
B 2 is connected to setting with reducing agent feed channel 5, and product is arranged on double conductivity type electrolyte and exports channel 6.
As disposable embodiment, the embodiment of the present invention 1 further can selectively select to make the electrolyte 3 with
Between the electrochemistry region A 1 plane fitting setting, or make include between the electrolyte 3 and the electrochemistry region B 2
At least partly it is bonded curved surface.
Embodiment 2
A kind of chemical energy device for converting electric energy, as shown in Fig. 2, include electrochemistry region A 1 and electrochemistry region B 2,
Electrolyte A 11 is set on the electrochemistry region A 1, electrolyte B 12, the electrochemistry are set on the electrolyte A 11
Region B 2 is arranged on the electrolyte B 12, and the electrochemistry region A 1 is connected to setting with oxidant feed channel 4, described
Electrochemistry region B 2 is connected to setting with reducing agent feed channel 5, and life is arranged between electrolyte A 11 and the electrolyte B 12
Channel 6 is exported at object.
As disposable embodiment, in the specific implementation, be selectively chosen makes the electricity to the embodiment of the present invention 2
Solve plane fitting setting between the matter A 11 and electrolyte B 12；Or the electrolyte A 11 and the electrolyte B 12 is made to exist
It include at least partly being bonded curved surface (to increase the sky of the reaction between the electrolyte A 11 and the electrolyte B 12 at its cooperation
Between, and then increase reaction efficiency).
Embodiment 3
A kind of chemical energy device for converting electric energy, as shown in figure 3, include electrochemistry region A 1 and electrochemistry region B 2,
Electrolyte A 11 is set on the electrochemistry region A 1, electrolyte X 7 is set on the electrolyte A 11, in the electrolysis
Electrolyte B 12 is set on matter X 7, and the electrochemistry region B 2 is arranged on the electrolyte B 12, and the electrolyte X 7 is set
For double conductivity type electrolyte, the electrochemistry region A 1 is connected to setting with oxidant feed channel 4, the electrochemistry region B 2 with
The connection setting of reducing agent feed channel 5, is arranged product on double conductivity type electrolyte and exports channel 6.
As disposable embodiment, in the specific implementation, be selectively chosen makes the electricity to the embodiment of the present invention 3
Plane is bonded setting between the solution matter A 11 and electrolyte X 7；Or make the electrolyte A 11 and the electrolyte X 7 at it
It include at least partly being bonded curved surface at cooperation.
As disposable embodiment, the embodiment of the present invention 3 and its disposable embodiment are selectively chosen
Plane between the electrolyte B 12 and the electrolyte X 7 is set to be bonded setting；Or make the electrolyte B 12 and the electrolysis
Matter X 7 includes at least partly being bonded curved surface at its cooperation.
Embodiment 4
A kind of chemical energy device for converting electric energy, as shown in figure 4, include electrochemistry region A 1 and electrochemistry region B 2,
Electrolyte A 11 is set on the electrochemistry region A 1, porous conductor region 8 is set on the electrolyte A 11, described
Electrolyte B 12 is set on porous conductor region 8, and the electrochemistry region B 2 is arranged on the electrolyte B 12, the electricity
Chemical regions A 1 is connected to setting with oxidant feed channel 4, and the electrochemistry region B 2 is connected to reducing agent feed channel 5 and sets
It sets, product is set on the porous conductor region 8 and exports channel 6, the conductor in the porous conductor region 8 is set as by described
Non-electronic charged particle that oxidant in oxidant feed channel 4 is formed and by the reduction in reducing agent feed channel 5
Dosage form at the conductor that can move on it of non-electronic charged particle.
As disposable embodiment, in the specific implementation, be selectively chosen makes the electricity to the embodiment of the present invention 4
Plane is bonded setting between solution matter A 11 and the porous conductor region 8；Or make the electrolyte A 11 and the porous conductor
Region 8 includes at least partly being bonded curved surface at its cooperation.
As disposable embodiment, the embodiment of the present invention 4 and its disposable embodiment are optionally selected
Selecting makes plane between the electrolyte B 12 and the porous conductor region 8 be bonded setting；Or make the electrolyte B 12 and institute
Stating porous conductor region 8 includes at least partly being bonded curved surface at its cooperation.
Embodiment 5
A kind of chemical energy device for converting electric energy, as shown in figure 5, include electrochemistry region A 1 and electrochemistry region B 2,
Electrolyte A 11 is set on the electrochemistry region A 1, porous conductor region 8 is set on the electrolyte A 11, described
The electrochemistry region B 2 is set on porous conductor region 8, and the electrochemistry region A1 is connected to oxidant feed channel 4 and sets
It sets, the electrochemistry region B 2 is connected to setting with reducing agent feed channel 5, and product is arranged on the porous conductor region 8
Channel 6 is exported, the conductor in the porous conductor region 8 is set as being formed by the oxidant in oxidant feed channel 4 non-
Electronics charged particle and the non-electronic charged particle formed by the reducing agent in reducing agent feed channel 5 can move on it
Dynamic conductor.
Embodiment 6
A kind of chemical energy device for converting electric energy, as shown in fig. 6, include electrochemistry region A 1 and electrochemistry region B 2,
Electrolyte A 11 is set on the electrochemistry region A 1, porous conductor region 8 is set on the electrolyte A 11, described
The electrochemistry region B 2 is set on porous conductor region 8, and the electrochemistry region B 2 is connected to oxidant feed channel 4 and sets
It sets, the electrochemistry region A 1 is connected to setting with reducing agent feed channel 5, and product is arranged on the porous conductor region 8
Channel 6 is exported, the conductor in the porous conductor region 8 is set as being formed by the oxidant in oxidant feed channel 4 non-
Electronics charged particle and the non-electronic charged particle formed by the reducing agent in reducing agent feed channel 5 can move on it
Dynamic conductor.
As disposable embodiment, the embodiment of the present invention 5 and embodiment 6, which are selectively chosen, makes the electrolysis
Plane is bonded setting between matter A 11 and the porous conductor region 8；Or make the electrolyte A11 and the porous conductor region
8 include at least partly being bonded curved surface at its cooperation.
In the specific implementation, the oxidant is selectively chosen is set as oxygen, compression sky to foregoing embodiments of the present invention
Gas, oxygen, liquid oxygen, air, liquefied air etc. have the substance of oxidizing property；The reducing agent, which is selectively chosen, to be set as
Hydrogen, ethyl alcohol, methanol, natural gas, coal gas, methane etc. have the substance of reducing property.
The aforementioned all embodiments of the present invention in specific works, generate the electrochemistry region of electronics by external loading with
Receive the electrochemistry region electric connectivity setting of electronics.
The present invention in the specific implementation, is selectively chosen the setting oxidant feed on oxidant feed channel
It control device (such as control valve) and/or reducing agent feed control device is set on reducing agent feed channel (such as controls
Valve processed).The specific control form of the control device can be controlled according to actual needs.
Description of the invention attached drawing is only a kind of signal, and any technical solution for meeting the application literature record belongs to this
The protection scope of application.
It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention
Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention
It encloses.
Claims (6)
1. a kind of chemical energy device for converting electric energy, including electrochemistry region A (1) and electrochemistry region B (2), it is characterised in that:
Electrolyte (3) are set on the electrochemistry region A (1), the electrochemistry region B (2) is arranged on the electrolyte (3), institute
It states electrolyte (3) and is set as double conductivity type electrolyte, the electrochemistry region A (1) is connected to setting, institute with oxidant feed channel (4)
It states electrochemistry region B (2) and is connected to setting with reducing agent feed channel (5), product is set on double conductivity type electrolyte and is led
Channel (6) out.
2. a kind of chemical energy device for converting electric energy, including electrochemistry region A (1) and electrochemistry region B (2), it is characterised in that:
Electrolyte A (11) are set on the electrochemistry region A (1), electrolyte B (12) are set on the electrolyte A (11), the electricity
Chemical regions B (2) is arranged on the electrolyte B (12), and the electrochemistry region A (1) is connected to oxidant feed channel (4)
Setting, the electrochemistry region B (2) is connected to setting with reducing agent feed channel (5), in electrolyte A (11) and the electrolyte B
(12) product is set between and exports channel (6).
3. a kind of chemical energy device for converting electric energy, including electrochemistry region A (1) and electrochemistry region B (2), it is characterised in that:
Electrolyte A (11) are set on the electrochemistry region A (1), electrolyte X (7) are set on the electrolyte A (11), described
Electrolyte B (12) are set on electrolyte X (7), the electrochemistry region B (2) is arranged on the electrolyte B (12), the electricity
Solution matter X (7) is set as double conductivity type electrolyte, and the electrochemistry region A (1) is connected to setting, the electricity with oxidant feed channel (4)
Chemical regions B (2) is connected to setting with reducing agent feed channel (5), and it is logical that product export is arranged on double conductivity type electrolyte
Road (6).
4. a kind of chemical energy device for converting electric energy, including electrochemistry region A (1) and electrochemistry region B (2), it is characterised in that:
Electrolyte A (11) are set on the electrochemistry region A (1), porous conductor region (8) are set on the electrolyte A (11),
Electrolyte B (12) are set on the porous conductor region (8), the electrochemistry region B (2) is arranged in the electrolyte B (12)
On, the electrochemistry region A (1) is connected to setting with oxidant feed channel (4), and the electrochemistry region B (2) and reducing agent supply
Channel (5) connection setting is sent, product is set on the porous conductor region (8) and exports channel (6), the porous conductor area
The conductor in domain (8) is set as the non-electronic charged particle formed by the oxidant in oxidant feed channel (4) and by described
The conductor that the non-electronic charged particle that reducing agent in reducing agent feed channel (5) is formed can move on it.
5. a kind of chemical energy device for converting electric energy, including electrochemistry region A (1) and electrochemistry region B (2), it is characterised in that:
Electrolyte A (11) are set on the electrochemistry region A (1), porous conductor region (8) are set on the electrolyte A (11),
The electrochemistry region B (2) is set on the porous conductor region (8), and the electrochemistry region A (1) and oxidant feed are logical
Road (4) connection setting, the electrochemistry region B (2) is connected to setting with reducing agent feed channel (5), in the porous conductor area
Product is set on domain (8) and exports channel (6), the conductor of the porous conductor region (8) is set as being led to by the oxidant feed
It non-electronic charged particle that oxidant in road (4) is formed and is formed by the reducing agent in reducing agent feed channel (5)
The conductor that non-electronic charged particle can move on it.
6. a kind of chemical energy device for converting electric energy, including electrochemistry region A (1) and electrochemistry region B (2), it is characterised in that:
Electrolyte A (11) are set on the electrochemistry region A (1), porous conductor region (8) are set on the electrolyte A (11),
The electrochemistry region B (2) is set on the porous conductor region (8), and the electrochemistry region B (2) and oxidant feed are logical
Road (4) connection setting, the electrochemistry region A (1) is connected to setting with reducing agent feed channel (5), in the porous conductor area
Product is set on domain (8) and exports channel (6), the conductor of the porous conductor region (8) is set as being led to by the oxidant feed
It non-electronic charged particle that oxidant in road (4) is formed and is formed by the reducing agent in reducing agent feed channel (5)
The conductor that non-electronic charged particle can move on it.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910233683 | 2019-03-26 | ||
| CN2019102336838 | 2019-03-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109935877A true CN109935877A (en) | 2019-06-25 |
Family
ID=66988704
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201920413007.4U Expired - Fee Related CN209607853U (en) | 2019-03-26 | 2019-03-28 | A kind of chemical energy device for converting electric energy |
| CN201910244618.5A Pending CN109935877A (en) | 2019-03-26 | 2019-03-28 | A kind of chemical energy device for converting electric energy |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201920413007.4U Expired - Fee Related CN209607853U (en) | 2019-03-26 | 2019-03-28 | A kind of chemical energy device for converting electric energy |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN209607853U (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055205A (en) * | 1989-12-27 | 1991-10-09 | 标准石油公司 | Solid multi-component membranes, electrochemical reactor element, electrochemical reactor and the use in oxidizing reaction of film, reactor elements and reactor |
| CN1309820A (en) * | 1998-06-12 | 2001-08-22 | 朱斌 | Fuel cell |
| CN1339842A (en) * | 2000-08-18 | 2002-03-13 | 索尼公司 | Electrochemical device and its operation method |
| CN108604698A (en) * | 2015-12-17 | 2018-09-28 | 法国电力公司 | The integrated proton conductive electrochemical appliance and related methods of production reformed |
-
2019
- 2019-03-28 CN CN201920413007.4U patent/CN209607853U/en not_active Expired - Fee Related
- 2019-03-28 CN CN201910244618.5A patent/CN109935877A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055205A (en) * | 1989-12-27 | 1991-10-09 | 标准石油公司 | Solid multi-component membranes, electrochemical reactor element, electrochemical reactor and the use in oxidizing reaction of film, reactor elements and reactor |
| CN1309820A (en) * | 1998-06-12 | 2001-08-22 | 朱斌 | Fuel cell |
| CN1339842A (en) * | 2000-08-18 | 2002-03-13 | 索尼公司 | Electrochemical device and its operation method |
| CN108604698A (en) * | 2015-12-17 | 2018-09-28 | 法国电力公司 | The integrated proton conductive electrochemical appliance and related methods of production reformed |
Non-Patent Citations (1)
| Title |
|---|
| 赵晓慧等: "Ce0.8Sm0.2O1.9-BaCe0.8Sm0.2O2.9复合电解质的成分对其电化学性能的影响", 《人工晶体学报》, vol. 46, no. 7, pages 1300 - 1306 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN209607853U (en) | 2019-11-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Gu et al. | Atomically dispersed Fe3+ sites catalyze efficient CO2 electroreduction to CO | |
| Liu et al. | Electronic Structure Regulation of Single‐Atom Catalysts for Electrochemical Oxygen Reduction to H2O2 | |
| CN112593251B (en) | Electrochemical reaction device | |
| US4160816A (en) | Process for storing solar energy in the form of an electrochemically generated compound | |
| CN100573984C (en) | The catalyst that is used for fuel battery negative pole | |
| EP1999811A2 (en) | Fuel cells | |
| Qin et al. | Theoretical studies of metal-NC for oxygen reduction and hydrogen evolution reactions in acid and alkaline solutions | |
| Wu et al. | Pulsed electrolysis of carbon dioxide by large‐scale solid oxide electrolytic cells for intermittent renewable energy storage | |
| US8647497B2 (en) | Method and system for hydrogen sulfide removal | |
| MX2012004695A (en) | Fuel cell. | |
| CN209607853U (en) | A kind of chemical energy device for converting electric energy | |
| Huo et al. | Electrodeposition of Ni on MWNTs as a promising catalyst for CO2RR | |
| EP3257971B1 (en) | Hydrogen desorption method | |
| CA2551607C (en) | Method for producing hydrogen and hydrogen producing apparatus used therefor | |
| Zhi et al. | ZIF-67-derived CoP/NC effectively supported Pt nanoparticles for methanol oxidation reaction | |
| KR20170049467A (en) | Process of producing hydrogen and the non-diaphragm hydrogen producing system | |
| US3793081A (en) | Sulfided transition metal fuel cell cathode catalysts | |
| Mao et al. | Facile synthesis of trimetallic Cu 1 Au 0.15 Pd 1.5/C catalyst for ethanol oxidation with superior activity and stability | |
| CN114032570B (en) | Carbon-assisted solid oxide electrolytic cell | |
| US3502506A (en) | Electrochemical cell with tungsten bronze catalyst on anode | |
| WO2003065490A2 (en) | A co-catalyst proton exchange membrane fuel cell utilizing borohydride fuels | |
| CN209993681U (en) | Chemical energy and electric energy conversion device | |
| CN109830787A (en) | A kind of chemical energy device for converting electric energy | |
| Fu et al. | Mechanistic study of Eu single atoms occupying four vacancy centers as potential electrocatalysts for the oxygen reduction reaction | |
| US20090188164A1 (en) | Method and system for hydrogen sulfide removal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |