CN109929163A - A kind of Novel X-shaped section seal - Google Patents

A kind of Novel X-shaped section seal Download PDF

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Publication number
CN109929163A
CN109929163A CN201711348148.4A CN201711348148A CN109929163A CN 109929163 A CN109929163 A CN 109929163A CN 201711348148 A CN201711348148 A CN 201711348148A CN 109929163 A CN109929163 A CN 109929163A
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CN
China
Prior art keywords
novel
shaped section
carbon black
section seal
agent
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Pending
Application number
CN201711348148.4A
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Chinese (zh)
Inventor
孙兆全
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GUANGZHOU CITY BANSHANG RUBBER PRODUCT CO Ltd
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GUANGZHOU CITY BANSHANG RUBBER PRODUCT CO Ltd
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Priority to CN201711348148.4A priority Critical patent/CN109929163A/en
Publication of CN109929163A publication Critical patent/CN109929163A/en
Pending legal-status Critical Current

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Abstract

A kind of Novel X-shaped section seal, percentage component by weight are as follows: hydrogenated nitrile-butadiene rubber 42-43%, softening agent 2-3%, carbon black 50-51%, bridging agent 1-2%, cross-linking aid 0.5-1%, anti-aging agent 0.5-1% flows antiflatulent 0.05-0.1%, processing aid 1-1.5%;Completely cut off sulfide in the raw material mixed process of Novel X-shaped section quartering hammer sealing element.Reduce the maintenance cost in equipment manufacturing costs and quality guarantee period.The number for reducing replacement sealing element for the terminal client for using quartering hammer, there is better ageing resistance, while reducing maintenance cost and improving production efficiency.So that the low temperature resistant temperature of sealing ring is dropped to -40 DEG C, improves equipment in the use ability of extremely frigid zones.

Description

A kind of Novel X-shaped section seal
Technical field
The present invention relates to mechanical fitting field more particularly to a kind of quartering hammer sealing elements.
Background technique
Mechanical sealing member belongs to one of accurate, more complicated Mechanical Fundamentals element of structure, is various pump classes, reaction synthesis The critical component of the equipment such as kettle, turbocompressor, submersible motor.
The physical characteristic of natural rubber.Natural rubber elasticity with higher at normal temperature, slightly band plasticity, it is very good to have Mechanical strength, hysteresis loss is small, and in multiple deformation, heat is low, therefore its flexible resistance is also fine, and because is non-pole Property rubber, so electrical insulation capability is good.
The power resources of hydraulic breaking hammer are the pressure oil of the pumping plant offer of excavator or loading machine, it can build excavating The soil in the stone and rock crevice of floating is more effectively cleared up in the effect on object basis.Selecting the principle of hydraulic breaking hammer is Most suitable hydraulic breaking hammer is selected according to the environment of excavator model, operation.
Existing quartering hammer sealing element is all the fluorubber manufacture production used, and finished product is at high price, and fluorubber Product low temperature tolerance ability is poor, and minimum preferable use temperature is -20 DEG C, and ageing resistance is poor, is not suitable for quartering hammer and dislikes Bad use environment.It eventually leads to equipment manufacturer and increases manufacturing cost, also increase maintenance of equipment cost.
Summary of the invention
To solve the above-mentioned problems, the present invention adopts the following technical scheme:
A kind of Novel X-shaped section seal, the percentage group of the Novel X-shaped section quartering hammer sealing element by weight Part are as follows: hydrogenated nitrile-butadiene rubber 42-43%, softening agent 2-3%, carbon black 50-51%, bridging agent 1-2%, cross-linking aid 0.5-1%, Anti-aging agent 0.5-1% flows antiflatulent 0.05-0.1%, processing aid 1-1.5%;Novel X-shaped section quartering hammer sealing element Completely cut off sulfide in raw material mixed process.
Preferably, softening agent is adipic acid two [2- (2- Butoxyethoxy) ethyl ester].
Preferably, bridging agent is cumyl peroxide.
Preferably, cross-linking aid is Triallyl isocyanurate.
Preferably, bis- (the α α-dimethylbenzyl) diphenylamines of anti-aging agent 4.4 '-.
Preferably, flowing antiflatulent is the mixture of hydrocarbon and surfactant.
Preferably, processing aid is stearic acid or wax.
Preferably, carbon black is made of N990 carbon black and N550 carbon black, and N990 carbon black and N550 carbon black mass account for component respectively The 29-30% and 21-22% of gross mass.
The beneficial effects of the present invention are:
Improve sealing element low temperature tolerance ability, ageing resistance and durability.It reduces and sets when it is applied to quartering hammer Maintenance cost in standby manufacturing cost and quality guarantee period reduces time of replacement sealing element for the terminal client for using quartering hammer Number reduces maintenance cost and improves work efficiency, so that the low temperature resistant temperature of sealing ring is dropped to -40 DEG C, improve equipment and exist The use ability of extremely frigid zones.
Specific embodiment
The present invention is further detailed below:
A kind of Novel X-shaped section seal, the percentage component of composition formula by weight are as follows: hydrogenated nitrile-butadiene rubber 42-43%, softening agent 2-3%, carbon black 50-51%, bridging agent 1-2%, cross-linking aid 0.5-1%, anti-aging agent 0.5-1%, stream Dynamic antiflatulent 0.05-0.1%, processing aid 1-1.5%.
It needs to completely cut off sulfidic material completely in a kind of raw material mixed process of above-mentioned Novel X-shaped section seal.
It is agglomerating by being mixed in all material used device;With mill gluing equipment by the thin pass-out piece of pockets of material at needs Thickness, then by cutting apparatus, the weight of needs is cut into, then sealing system is produced with particular manufacturing craft and vulcanization of rubber equipment Product.
The softening agent for consolidating cryogenic property is added in hydrogenated nitrile-butadiene rubber, hydrogenated nitrile-butadiene rubber low temperature tolerance ability is enable to reach To -40 DEG C.
Embodiment 1
Hydrogenated nitrile-butadiene rubber 42.34%, adipic acid two [2- (2- Butoxyethoxy) ethyl ester] 2.95%, carbon black N990 29.64%, carbon black N550 21.17%, cumyl peroxide 1.06%, Triallyl isocyanurate 0.64%, 4.4 '- Bis- (α α-dimethylbenzyl) diphenylamines 0.85% flow antiflatulent PW 0.08%, polyethylene wax 1.27%.
Embodiment 2
Hydrogenated nitrile-butadiene rubber 42%, adipic acid two [2- (2- Butoxyethoxy) ethyl ester] 2%, carbon black N990 30%, charcoal Black N550 21%, cumyl peroxide 1.4%, Triallyl isocyanurate 1%, 4.4 '-bis- (α α-dimethylbenzyls) Diphenylamines 1% flows antiflatulent PW 0.1%, polyethylene wax 1.5%.
Embodiment 3
Hydrogenated nitrile-butadiene rubber 43%, adipic acid two [2- (2- Butoxyethoxy) ethyl ester] 2%, carbon black N990 29%, charcoal Black N550 22%, cumyl peroxide 1.95%, Triallyl isocyanurate 0.5%, 4.4 '-bis- (α alpha-alpha-dimethyl benzyls Base) diphenylamines 0.5%, flows antiflatulent PW 0.05%, polyethylene wax 1%.
Embodiment 4
Hydrogenated nitrile-butadiene rubber 42%, adipic acid two [2- (2- Butoxyethoxy) ethyl ester] 3%, carbon black N990 29%, charcoal Black N550 21%, cumyl peroxide 2%, Triallyl isocyanurate 1%, 4.4 '-bis- (α α-dimethylbenzyls) two Aniline 0.5% flows antiflatulent PW 0.1%, polyethylene wax 1.4%.
Embodiment 5
Hydrogenated nitrile-butadiene rubber 43%, adipic acid two [2- (2- Butoxyethoxy) ethyl ester] 3%, carbon black N990 29%, charcoal Black N550 21%, cumyl peroxide 1%, Triallyl isocyanurate 1%, 4.4 '-bis- (α α-dimethylbenzyls) two Aniline 0.5% flows antiflatulent PW 0.1%, polyethylene wax 1.4%.
Burn-in test is carried out to embodiment 1-5, every group of embodiment set 3 finished products, respectively high temperature, low temperature and at room temperature into Row test:
The hardness (shore) of finished product is first tested before ageing, and finished product is then placed in a timing in the ageing oven set Between, the hardness (shore) of finished product is tested after taking-up;By hardness number comparison before and after aging, change rate is calculated, hardness change is got over Small then its ageing resistance is stronger.
Test condition is as shown in the table:
1 embodiment test condition of table
Test result is as follows shown in table:
2 embodiment ageing test result of table
Above-mentioned test result shows that ageing resistance in the case where high/low temperature of finished product made of formula of the invention compares It is relatively strong, more adverse circumstances are adapted to applied to quartering hammer sealing element.
In order to preferably show the features of the present invention, several groups of comparative experimentss are carried out, here is several groups of comparative experimentss Test result:
Sample 1: hydrogenated nitrile-butadiene rubber 42.34%, softening agent 2.95%, carbon black N990 29.64%, carbon black N550 21.17%, bridging agent 1.06%, cross-linking aid 0.64%, anti-aging agent 0.85%, flowing antiflatulent 0.08%, processing aid 1.27%.
Sample 2: fluorubber 42.34%, softening agent 2.95%, carbon black N990 29.64%, carbon black N550 21.17%, frame Bridge agent 1.06%, cross-linking aid 0.64%, anti-aging agent 0.85% flow antiflatulent 0.08%, processing aid 1.27%.
Sample 3: hydrogenated nitrile-butadiene rubber 35%, softening agent 5%, carbon black N990 31%, carbon black N550 22%, bridging agent 2%, cross-linking aid 1%, anti-aging agent 1% flows antiflatulent 1%, processing aid 2%.
Sample 4: hydrogenated nitrile-butadiene rubber 50%, softening agent 2.5%, carbon black N990 26%, carbon black N550 19%, bridging agent 1%, cross-linking aid 0.5%, anti-aging agent 0.5% flows antiflatulent 0.00%, processing aid 0.5%.
Sample 5: fluorubber 50%, softening agent 2.5%, carbon black N990 26%, carbon black N550 19%, bridging agent 1% are handed over Join auxiliary agent 0.5%, anti-aging agent 0.5% flows antiflatulent 0.00%, processing aid 0.5%.
Sample 6: hydrogenated nitrile-butadiene rubber 42.34%, softening agent 0.5%, carbon black N990 30.64%, carbon black N550 22.62%, bridging agent 1.06%, cross-linking aid 0.64%, anti-aging agent 0.85%, flowing antiflatulent 0.08%, processing aid 1.27%.
Sample 7: hydrogenated nitrile-butadiene rubber 42.34%, softening agent 5%, carbon black N990 28.64%, carbon black N550 20.02%, bridging agent 1.06%, cross-linking aid 0.64%, anti-aging agent 0.85%, flowing antiflatulent 0.08%, processing aid 1.27%.
The model that the component of above-mentioned sample 1-7 is chosen are as follows: softening agent model TP95, carbon black are two kinds of types of N990 and N550 Number mixture, bridging agent model DCP, cross-linking aid model TAIC, anti-aging agent model 445, flow antiflatulent model For PW, processing aid model AC617.
Performance detection is carried out to quartering hammer sealing ring made of sample 1-7 component formula, testing result is as shown in the table:
3 each group properties of sample parameter list of table
In the present invention, by selecting suitable raw material, the proportion of each raw material is adjusted, keeps a kind of above-mentioned Novel X-shaped section close Sealing has that good resistance to low temperature, compression set is small, fuel oil resistance performance is good, sealed reliable, uses the long spy that waits so long Property.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (8)

1. a kind of Novel X-shaped section seal, it is characterised in that: its percentage component by weight are as follows:
Hydrogenated nitrile-butadiene rubber 42-43%,
Softening agent 2-3%,
Carbon black 50-52%,
Bridging agent 1-2%,
Cross-linking aid 0.5-1%,
Anti-aging agent 0.5-1%,
Antiflatulent 0.05-0.1% is flowed,
Processing aid 1-1.5%;
Completely cut off sulfide in the raw material mixed process of the Novel X-shaped section quartering hammer sealing element.
2. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the softening agent is adipic acid Two [2-(2- Butoxyethoxy) ethyl ester].
3. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the bridging agent is peroxide Change diisopropylbenzene (DIPB).
4. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the cross-linking aid is triolefin Propyl isocyanuric acid ester.
5. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the anti-aging agent is 4.4 '-bis- (α α-dimethylbenzyl) diphenylamines.
6. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the flowing antiflatulent is carbon The mixture of hydrogen compound and surfactant.
7. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the processing aid is tristearin Acid or wax.
8. a kind of Novel X-shaped section seal according to claim 1, it is characterised in that: the carbon black is by N990 carbon black It is formed with N550 carbon black, the quality of the N990 carbon black and N550 carbon black accounts for the 29-30% and 21-22% of component gross mass respectively.
CN201711348148.4A 2017-12-15 2017-12-15 A kind of Novel X-shaped section seal Pending CN109929163A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112980067A (en) * 2021-03-01 2021-06-18 深圳市鑫华煦橡胶制品有限公司 Temperature-resistant hydrogenated nitrile rubber

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002176A (en) * 2010-12-02 2011-04-06 天津鹏翎胶管股份有限公司 Hydrogenated nitrile-butadiene rubber composition
CN106084367A (en) * 2016-06-13 2016-11-09 安徽越天特种车桥有限公司 A kind of automobile hub bearing sealing ring and preparation method thereof
CN106188692A (en) * 2016-07-30 2016-12-07 北京化工大学 A kind of wind-power electricity generation special (purpose) rubber sealing strip sizing material and preparation technology thereof
CN106543505A (en) * 2016-12-09 2017-03-29 南阳天密封股份有限公司 A kind of high-performance acrylonitrile butadiene packing material and preparation method thereof
CN107002881A (en) * 2014-11-28 2017-08-01 爱尔铃克铃尔股份公司 Seal and the method for manufacturing seal

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002176A (en) * 2010-12-02 2011-04-06 天津鹏翎胶管股份有限公司 Hydrogenated nitrile-butadiene rubber composition
CN107002881A (en) * 2014-11-28 2017-08-01 爱尔铃克铃尔股份公司 Seal and the method for manufacturing seal
CN106084367A (en) * 2016-06-13 2016-11-09 安徽越天特种车桥有限公司 A kind of automobile hub bearing sealing ring and preparation method thereof
CN106188692A (en) * 2016-07-30 2016-12-07 北京化工大学 A kind of wind-power electricity generation special (purpose) rubber sealing strip sizing material and preparation technology thereof
CN106543505A (en) * 2016-12-09 2017-03-29 南阳天密封股份有限公司 A kind of high-performance acrylonitrile butadiene packing material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112980067A (en) * 2021-03-01 2021-06-18 深圳市鑫华煦橡胶制品有限公司 Temperature-resistant hydrogenated nitrile rubber

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Application publication date: 20190625