CN109928574A - A kind of sanitary wastewater processing method - Google Patents
A kind of sanitary wastewater processing method Download PDFInfo
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- CN109928574A CN109928574A CN201910150805.7A CN201910150805A CN109928574A CN 109928574 A CN109928574 A CN 109928574A CN 201910150805 A CN201910150805 A CN 201910150805A CN 109928574 A CN109928574 A CN 109928574A
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Abstract
The present invention relates to a kind of sanitary wastewater processing methods, belong to technical field of waste water processing.The present invention passes through first utilizes filtering removal large granular impurity, separate tank is recycled to be separated by solid-liquid separation, and realize the preliminary exposition to organic matter in waste water, then it is being mixed with liquid is adjusted, reduce peculiar smell therein, then it is mixed with hybrid particles, on the one hand waste water can further be filtered, on the other hand it can effectively improve the activity of waste water itself, enhance Self-regulation ability, then by being adsorbed using clast to grease therein, and improve the cleaning capacity to waste water, and nutrition can be rapidly depleted using cyanobacteria, the characteristics of quickly being bred, further consumption is carried out to the organic matter in waste water to utilize, to complete the processing to lavatory waste water, treated to solving the problems, such as current sanitary wastewater, and sewage is difficult to reach discharge standard.
Description
Technical field
The present invention relates to a kind of sanitary wastewater processing methods, belong to technical field of waste water processing.
Background technique
Existing lavatory (toilet) has more functions, clothes of such as having a bath, wash one's hands or do washing, it should be noted that one
Point, it is closely bound up with water for no matter carrying out which kind of activity in the bathroom, and then has a large amount of sewage and generate.It is existing
Toilet in the sewage that generates be directly to be discharged in sewer by pipeline, not only cause a large amount of of water resource in this way
Waste, new challenge is also proposed to the ability to bear of downcomer;More importantly the change that the sewage in sewer carries
It learns substance and damage difficult to the appraisal often is caused to environment.
Contain a large amount of pollutant in sanitary wastewater, and the smell is awful, if direct emission will affect environment, in rural area lavatory
Institute's sewage can be used for the fertilising of crops, but in city, sanitary wastewater discharge has to reach discharge standard by processing
After can discharge, feces of toilet sewage because its biodegradability height, in the prior art, at the beginning of UNITANK is the last century 90's
Start application sewage treatment process, the technology combine SBR, traditional activated sludge process, three working position method it is excellent
Point overcomes SBR intermittent water inflow, and the land occupation of three ditch formulas is big, the disadvantage more than Traditional Method equipment.The technique is once proposition just by the industry
Favor, but due to the technique automatic control in terms of requirement it is relatively high, there is no application in this small-sized processing system of sanitary wastewater.
Currently, the processing method to sanitary wastewater mainly uses microbial method to handle it.But microbial method exists
The problem of limit it in the application of some special dimensions.There are the problem of have: using microbial method processing sanitary wastewater dress
It sets and is unable to plug and play, microorganism needs the culture that professional carries out 3-14 days time, dirty before microculture completion
Water is unable to qualified discharge;Device intermittent duty using microbial method processing sanitary wastewater is inconvenient, period out of service, micro- life
Object, which needs nutrients, maintains activity;Treatment process cannot eliminate the stink of sanitary wastewater, and easily breed mosquitos and flies, generate hygienic issues;
And all there are the following problems for nearly all strain currently in use at present: microorganism fungus kind is single, and composite flora is few;Microorganism
Activity is low, and power of regeneration is weak, needs to be continuously replenished;Adaptation low for indoles mass degradation power in excrement, to inorganic salts
Property difference etc..So many places handle sewage nearby, then by treated, sewage is directly discharged into neighbouring rivers, lake
In, processing mode is simple, and treated, and sewage is difficult to reach discharge standard, and long-term discharge will lead to water PH value, COD content mistake
Height, destroys the biobalance of water ecosystem, and will cause water eutrophication, therefore is badly in need of a kind of sanitary wastewater processing side
Method, it is present to solve the problems, such as.
Summary of the invention
The technical problems to be solved by the invention: for current sanitary wastewater, treated that sewage is difficult to reaches discharge mark
Standard, long-term discharge will lead to water pH value, COD too high levels, destroy water body, and will cause that water eutrophication is excessively high to ask
Topic, the present invention provides a kind of sanitary wastewater processing methods.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of sanitary wastewater processing method, the processing method include the following steps:
(1) sanitary wastewater is filtered, collects filtrate, puts the filtrate into and carry out settle and separate in separate tank, collect separating liquid,
Separating liquid, adjusting liquid are mixed 80:1~4 by volume, in 40~45 DEG C of agitating and heatings, heat preservation;
(2) it after wait keep the temperature, stands, filtering obtains pretreatment sanitary wastewater, and pretreatment sanitary wastewater and hybrid particles are pressed matter
Amount is mixed than 12~15:3, is stirred at 40~50 DEG C, is stood, and filtering obtains two degree of processing sanitary wastewaters;
(3) cement bottom of pond portion laying depth be 40~60cm clast, be added two degree of processing sanitary wastewaters flood clast 60~
90cm is stirred, and according to every square metre of 30~40g, is carried out plantation cyanobacteria and is filtered after plantation 3~5 days, sterilization is completed
Sanitary wastewater processing.
Separate tank in the step (1) are as follows: long 3~4m, wide 1~2cm, bottom are equipped with the slope at 20~25 ° of inclination angle, tiltedly
The height of top of the slope portion connection is 70~80cm, and the height of slope bottom connection is 1.5~2.0m, and every 30~50cm in separate tank
Place separation membrane.
The separation membrane the preparation method comprises the following steps:
A. according to parts by weight, 180~190 parts of ethanol solutions, 30~40 parts of styrene, 28~32 parts of N- isopropyl acrylamides are taken
Amine, 16~19 parts of additives, 15~20 parts of chain-transferring agents, 3~8 parts of initiators, first by ethanol solution, styrene, N- isopropyl
Base acrylamide, chain-transferring agent and initiator are put into reaction kettle, using nitrogen protection, are preheated at 50~55 DEG C;
B. wait preheat after, be warming up to 90~95 DEG C, be stirred to react, be cooled to 60~65 DEG C, additive is added, stirring is protected
Temperature is cooled to room temperature, and material is collected out in discharging;
C. it will mix in material, tetrahydrofuran 1:2~3 in mass ratio out, and collect mixture, mixture, methanol are pressed into quality
It is mixed than 1:2~5, is placed in -2~2 DEG C of standings, filtered, collect filter residue;
D. by filter residue,
In the step A additive the preparation method comprises the following steps: by europium nitrate, titanium dioxide, platinum nitrate 4:1:1~3 in mass ratio into
Row mixing, collects mixture A, then mixture A is mixed with ethanol solution, salicylic acid 8~10:18:3 in mass ratio, i.e.,
Obtain additive.
The step A Chain transfer agent the preparation method comprises the following steps: according to parts by weight, taking 170~180 parts of ethanol solutions, 30
~40 parts of acrylate, 23~26 parts of dodecyl trithiocarbonates, 5~8 parts of azo-bis-isobutyl cyanides, 3~6 parts of surface-actives
Agent is put into reaction kettle, using nitrogen protection, is stirred to react at 60~80 DEG C, and discharging, evaporative removal ethyl alcohol, tetrahydrofuran is washed
It washs, petroleum ether precipitation, collects sediment to get chain-transferring agent.
The surfactant is dodecyl polyoxyethylene ether sodium sulfovinate, any one in cocounut oil acyl single ethanol amide
Kind.
Initiator is azo-bis-isobutyl cyanide in the step A, dibenzoyl peroxide 8:1 in mass ratio is mixed.
Liquid is adjusted in the step (1) is prepared as arsanilic acid, ammonium hydroxide and ferrous sulfate 4:13~16:2~5 in mass ratio
It mixes.
Hybrid particles are by carbon nanotube, vermiculite, quartz sand and cobblestone 7:3:6:4 in mass ratio in the step (2)
~12 are mixed to get hybrid particles.
Clast is that bamboo scraps, wheat stalk and soya-bean cake 5:3~8:3 in mass ratio are crushed to get broken in the step (3)
Bits.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention by the effect of initiator by being carried out using acrylate, dodecyl trithiocarbonate as raw material
Reaction, is prepared Macromolecular chain transfer agent, then again mixes it with styrene, n-isopropyl acrylamide, pass through
Initiator and the effect for making chain-transferring agent by oneself, are polymerize, and Block copolymer is formed, and addition is added in the synthesis process
Agent is formed ligand under the action of salicylic effect, is tied with Block copolymer by europium, the platinum in additive
It closes, while carried titanium dioxide, is finally formed a film using water droplet method, form it into honeycomb film, in use, passed through
Decomposed can be carried out to organic matter therein using the property of Block copolymer itself, while can adsorbed therein micro-
Secondary element, and in the effect of metallic element and titanium dioxide, effectively facilitate the decomposition of macromolecular substances;
(2) present invention is first by recycling separate tank to be separated by solid-liquid separation, and realize using filtering removal large granular impurity
To the preliminary exposition of organic matter in waste water, then by its with adjust liquid mixing, reduce peculiar smell therein, then by its with
Hybrid particles are mixed, and on the one hand can further be filtered to waste water, on the other hand can effectively improve waste water certainly
The activity of body enhances Self-regulation ability, then by being adsorbed using clast to grease therein, and improves to waste water
Cleaning capacity, and nutrition can be rapidly depleted using cyanobacteria, the characteristics of quickly breeding, to the organic matter in waste water
It carries out further consumption to utilize, to complete the processing to lavatory waste water.
Specific embodiment
Additive the preparation method comprises the following steps: europium nitrate, titanium dioxide, platinum nitrate 4:1:1~3 in mass ratio are mixed,
Mixture A is collected, then mixture A is mixed with 1.2mol/L ethanol solution, salicylic acid 8~10:18:3 in mass ratio, i.e.,
Obtain additive.
Chain-transferring agent the preparation method comprises the following steps: according to parts by weight, taking 170~180 parts of 1.2mol/L ethanol solutions, 30~40
Part acrylate, 23~26 parts of dodecyl trithiocarbonates, 5~8 parts of azo-bis-isobutyl cyanides, 3~6 parts of surfactants,
It is put into reaction kettle, using nitrogen protection, is stirred to react 8h at 60~80 DEG C, discharge, evaporative removal ethyl alcohol, tetrahydrofuran is washed
It washs, petroleum ether precipitation, collects sediment to get chain-transferring agent.
The surfactant is dodecyl polyoxyethylene ether sodium sulfovinate, any one in cocounut oil acyl single ethanol amide
Kind.
Initiator is azo-bis-isobutyl cyanide in the step A, dibenzoyl peroxide 8:1 in mass ratio is mixed.
The separation membrane the preparation method comprises the following steps:
A. according to parts by weight, 180~190 parts of ethanol solutions, 30~40 parts of styrene, 28~32 parts of N- isopropyl acrylamides are taken
Amine, 16~19 parts of additives, 15~20 parts of chain-transferring agents, 3~8 parts of initiators, first by ethanol solution, styrene, N- isopropyl
Base acrylamide, chain-transferring agent and initiator are put into reaction kettle, using nitrogen protection, in 50~55 DEG C of preheating 1h;
B. wait preheat after, be warming up to 90~95 DEG C, be stirred to react 9h, be cooled to 60~65 DEG C, additive is added, stirring is protected
Warm 4h, is cooled to room temperature, and material is collected out in discharging;
C. it will mix in material, tetrahydrofuran 1:2~3 in mass ratio out, and collect mixture, mixture, methanol are pressed into quality
It is mixed than 1:2~5, is placed in -2~2 DEG C of standing 13h, filtered, collect filter residue;
D. it by filter residue, ethanol solution and petroleum ether 1:3~5:3 in mass ratio, is mixed, collects mixed object, under nitrogen atmosphere,
Mixed object is taken to be added drop-wise to 1 cm2Substrate of glass on, in the case where nitrogen flow rate is 50 DEG C of environment of 1.5 L/min, when ethanol solution and
After petroleum ether volatilization completely, film forming matter is collected to get separation membrane.
Separate tank are as follows: long 3~4m, wide 1~2cm, bottom are equipped with the slope at 20~25 ° of inclination angle, connect at the top of slope
Height is 70~80cm, and the height of slope bottom connection is 1.5~2.0m, and every 30~50cm places separation membrane in separate tank.
Arsanilic acid, ammonium hydroxide and ferrous sulfate 4:13~16:2~5 in mass ratio that are prepared as adjusting liquid mix.
Hybrid particles are to mix carbon nanotube, vermiculite, quartz sand and cobblestone 7:3:6:4~12 in mass ratio,
Up to hybrid particles.
Clast is that bamboo scraps, wheat stalk and soya-bean cake 5:3~8:3 in mass ratio are crushed to get clast.
A kind of sanitary wastewater processing method, the processing method include the following steps:
(1) sanitary wastewater is filtered, collects filtrate, puts the filtrate into and carry out settle and separate in separate tank, collect separating liquid,
Separating liquid, adjusting liquid are mixed 80:1~4 by volume, in 40~45 DEG C of agitating and heatings, keep the temperature 6h;
(2) after wait keep the temperature, 2h is stood, filtering obtains pretreatment sanitary wastewater, and pretreatment sanitary wastewater is pressed with hybrid particles
12~15:3 of mass ratio mixing, is stirred at 40~50 DEG C, stands 3h, and filtering obtains two degree of processing sanitary wastewaters;
(3) cement bottom of pond portion laying depth be 40~60cm clast, be added two degree of processing sanitary wastewaters flood clast 60~
90cm is stirred 8h, according to every square metre of 30~40g, carries out plantation cyanobacteria and filters after plantation 3~5 days, sterilization is that is, complete
It is handled at sanitary wastewater.
Embodiment 1
Additive the preparation method comprises the following steps: europium nitrate, titanium dioxide, platinum nitrate 4:1:3 in mass ratio are mixed, collect mixing
Object A, then mixture A is mixed with 1.2mol/L ethanol solution, salicylic acid 10:18:3 in mass ratio to get additive.
Chain-transferring agent the preparation method comprises the following steps: according to parts by weight, taking 180 parts of 1.2mol/L ethanol solutions, 40 parts of acrylic acid
Ester, 26 parts of dodecyl trithiocarbonates, 8 parts of azo-bis-isobutyl cyanides, 6 parts of surfactants, are put into reaction kettle, use nitrogen
Gas shielded is stirred to react 8h at 80 DEG C, discharging, evaporative removal ethyl alcohol, and tetrahydrofuran washing, petroleum ether precipitation collects sediment,
Up to chain-transferring agent.
Surfactant is dodecyl polyoxyethylene ether sodium sulfovinate.
Initiator is azo-bis-isobutyl cyanide, dibenzoyl peroxide 8:1 in mass ratio is mixed.
Separation membrane the preparation method comprises the following steps:
A. according to parts by weight, 190 parts of ethanol solutions, 40 parts of styrene, 32 parts of n-isopropyl acrylamide, 19 parts of additions are taken
Agent, 20 parts of chain-transferring agents, 8 parts of initiators by ethanol solution, styrene, n-isopropyl acrylamide, chain-transferring agent and draw first
Hair agent is put into reaction kettle, using nitrogen protection, in 55 DEG C of preheating 1h;
B. wait preheat after, be warming up to 95 DEG C, be stirred to react 9h, be cooled to 65 DEG C, be added additive, stirring heat preservation 4h is cold
But to room temperature, material is collected out in discharging;
C. it will go out material, tetrahydrofuran 1:3 in mass ratio mix, and collect mixture, by mixture, methanol in mass ratio 1:
5 are mixed, and 2 DEG C of standing 13h are placed in, and filter residue is collected in filtering;
D. it by filter residue, ethanol solution and petroleum ether 1:5:3 in mass ratio, is mixed, collects mixed object and take under nitrogen atmosphere
Mixed object is added drop-wise to 1 cm2Substrate of glass on, nitrogen flow rate be 1.5 L/min 50 DEG C of environment under, when ethanol solution and stone
After oily ether volatilization completely, film forming matter is collected to get separation membrane.
Separate tank are as follows: long 4m, wide 2cm, bottom are equipped with the slope at 25 ° of inclination angle, and the height connected at the top of slope is 80cm,
The height of slope bottom connection is 2.0m, and every 50cm places separation membrane in separate tank.
Arsanilic acid, ammonium hydroxide and the ferrous sulfate 4:16:5 in mass ratio that is prepared as adjusting liquid are mixed.
Hybrid particles be by carbon nanotube, vermiculite, quartz sand and cobblestone 7:3:6:12 in mass ratio mix to get
Hybrid particles.
Clast is that bamboo scraps, wheat stalk and soya-bean cake 5:8:3 in mass ratio are crushed to get clast.
A kind of sanitary wastewater processing method, the processing method include the following steps:
(1) sanitary wastewater is filtered, collects filtrate, puts the filtrate into and carry out settle and separate in separate tank, collect separating liquid,
By separating liquid, adjusting liquid, 80:4 is mixed by volume, in 45 DEG C of agitating and heatings, keeps the temperature 6h;
(2) after wait keep the temperature, 2h is stood, filtering obtains pretreatment sanitary wastewater, and pretreatment sanitary wastewater is pressed with hybrid particles
Mass ratio 15:3 mixing, is stirred at 50 DEG C, stands 3h, and filtering obtains two degree of processing sanitary wastewaters;
(3) it is 60cm clast in cement bottom of pond portion laying depth, two degree of processing sanitary wastewaters is added and flood clast 90cm, stirring is mixed
8h is closed, according to every square metre of 40g, plantation cyanobacteria is carried out and is filtered after plantation 5 days, sterilization, the i.e. processing of completion sanitary wastewater.
Embodiment 2
Additive the preparation method comprises the following steps: europium nitrate, titanium dioxide, platinum nitrate 4:1:2 in mass ratio are mixed, collect mixing
Object A, then mixture A is mixed with 1.2mol/L ethanol solution, salicylic acid 9:18:3 in mass ratio to get additive.
Chain-transferring agent the preparation method comprises the following steps: according to parts by weight, taking 175 parts of 1.2mol/L ethanol solutions, 35 parts of acrylic acid
Ester, 25 parts of dodecyl trithiocarbonates, 6 parts of azo-bis-isobutyl cyanides, 5 parts of surfactants, are put into reaction kettle, use nitrogen
Gas shielded is stirred to react 8h at 70 DEG C, discharging, evaporative removal ethyl alcohol, and tetrahydrofuran washing, petroleum ether precipitation collects sediment,
Up to chain-transferring agent.
Surfactant is cocounut oil acyl single ethanol amide.
Initiator is azo-bis-isobutyl cyanide, dibenzoyl peroxide 8:1 in mass ratio is mixed.
The separation membrane the preparation method comprises the following steps:
A. according to parts by weight, 185 parts of ethanol solutions, 35 parts of styrene, 30 parts of n-isopropyl acrylamide, 18 parts of additions are taken
Agent, 18 parts of chain-transferring agents, 6 parts of initiators by ethanol solution, styrene, n-isopropyl acrylamide, chain-transferring agent and draw first
Hair agent is put into reaction kettle, using nitrogen protection, in 53 DEG C of preheating 1h;
B. wait preheat after, be warming up to 93 DEG C, be stirred to react 9h, be cooled to 63 DEG C, be added additive, stirring heat preservation 4h is cold
But to room temperature, material is collected out in discharging;
C. it material, tetrahydrofuran 1:2.5 in mass ratio will mix out, and collect mixture, in mass ratio by mixture, methanol
1:4 is mixed, and 0 DEG C of standing 13h is placed in, and filter residue is collected in filtering;
D. it by filter residue, ethanol solution and petroleum ether 1:4:3 in mass ratio, is mixed, collects mixed object and take under nitrogen atmosphere
Mixed object is added drop-wise to 1 cm2Substrate of glass on, nitrogen flow rate be 1.5 L/min 50 DEG C of environment under, when ethanol solution and stone
After oily ether volatilization completely, film forming matter is collected to get separation membrane.
Separate tank are as follows: long 3.5m, wide 1.5cm, bottom are equipped with the slope at 23 ° of inclination angle, and the height connected at the top of slope is
75cm, the height of slope bottom connection are 1.8m, and every 40cm places separation membrane in separate tank.
Arsanilic acid, ammonium hydroxide and the ferrous sulfate 4:15:4 in mass ratio that is prepared as adjusting liquid are mixed.
Hybrid particles be by carbon nanotube, vermiculite, quartz sand and cobblestone 7:3:6:8 in mass ratio mix to get
Hybrid particles.
Clast is that bamboo scraps, wheat stalk and soya-bean cake 5:6:3 in mass ratio are crushed to get clast.
A kind of sanitary wastewater processing method, the processing method include the following steps:
(1) sanitary wastewater is filtered, collects filtrate, puts the filtrate into and carry out settle and separate in separate tank, collect separating liquid,
By separating liquid, adjusting liquid, 80:3 is mixed by volume, in 43 DEG C of agitating and heatings, keeps the temperature 6h;
(2) after wait keep the temperature, 2h is stood, filtering obtains pretreatment sanitary wastewater, and pretreatment sanitary wastewater is pressed with hybrid particles
Mass ratio 13:3 mixing, is stirred at 45 DEG C, stands 3h, and filtering obtains two degree of processing sanitary wastewaters;
(3) it is 45cm clast in cement bottom of pond portion laying depth, two degree of processing sanitary wastewaters is added and flood clast 80cm, stirring is mixed
8h is closed, according to every square metre of 35g, plantation cyanobacteria is carried out and is filtered after plantation 4 days, sterilization, the i.e. processing of completion sanitary wastewater.
Embodiment 3
Additive the preparation method comprises the following steps: europium nitrate, titanium dioxide, platinum nitrate 4:1:1 in mass ratio are mixed, collect mixing
Object A, then mixture A is mixed with 1.2mol/L ethanol solution, salicylic acid 8:18:3 in mass ratio to get additive.
Chain-transferring agent the preparation method comprises the following steps: according to parts by weight, taking 170 parts of 1.2mol/L ethanol solutions, 30 parts of acrylic acid
Ester, 23 parts of dodecyl trithiocarbonates, 5 parts of azo-bis-isobutyl cyanides, 3 parts of surfactants, are put into reaction kettle, use nitrogen
Gas shielded is stirred to react 8h at 60 DEG C, discharging, evaporative removal ethyl alcohol, and tetrahydrofuran washing, petroleum ether precipitation collects sediment,
Up to chain-transferring agent.
Surfactant is dodecyl polyoxyethylene ether sodium sulfovinate.
Initiator is azo-bis-isobutyl cyanide, dibenzoyl peroxide 8:1 in mass ratio is mixed.
Separation membrane the preparation method comprises the following steps:
A. according to parts by weight, 180 parts of ethanol solutions, 30 parts of styrene, 28 parts of n-isopropyl acrylamide, 16 parts of additions are taken
Agent, 15 parts of chain-transferring agents, 3 parts of initiators by ethanol solution, styrene, n-isopropyl acrylamide, chain-transferring agent and draw first
Hair agent is put into reaction kettle, using nitrogen protection, in 50 DEG C of preheating 1h;
B. wait preheat after, be warming up to 90 DEG C, be stirred to react 9h, be cooled to 60 DEG C, be added additive, stirring heat preservation 4h is cold
But to room temperature, material is collected out in discharging;
C. it will go out material, tetrahydrofuran 1:2 in mass ratio mix, and collect mixture, by mixture, methanol in mass ratio 1:
2 are mixed, and -2 DEG C of standing 13h are placed in, and filter residue is collected in filtering;
D. it by filter residue, ethanol solution and petroleum ether 1:3:3 in mass ratio, is mixed, collects mixed object and take under nitrogen atmosphere
Mixed object is added drop-wise to 1 cm2Substrate of glass on, nitrogen flow rate be 1.5 L/min 50 DEG C of environment under, when ethanol solution and stone
After oily ether volatilization completely, film forming matter is collected to get separation membrane.
Separate tank are as follows: long 3m, wide 1cm, bottom are equipped with the slope at 20 ° of inclination angle, and the height connected at the top of slope is 70cm,
The height of slope bottom connection is 1.5m, and every 30cm places separation membrane in separate tank.
Arsanilic acid, ammonium hydroxide and the ferrous sulfate 4:13:2 in mass ratio that is prepared as adjusting liquid are mixed.
Hybrid particles be by carbon nanotube, vermiculite, quartz sand and cobblestone 7:3:6:4 in mass ratio mix to get
Hybrid particles.
Clast is that bamboo scraps, wheat stalk and soya-bean cake 5:3~8:3 in mass ratio are crushed to get clast.
A kind of sanitary wastewater processing method, the processing method include the following steps:
(1) sanitary wastewater is filtered, collects filtrate, puts the filtrate into and carry out settle and separate in separate tank, collect separating liquid,
By separating liquid, adjusting liquid, 80:1 is mixed by volume, in 40 DEG C of agitating and heatings, keeps the temperature 6h;
(2) after wait keep the temperature, 2h is stood, filtering obtains pretreatment sanitary wastewater, and pretreatment sanitary wastewater is pressed with hybrid particles
Mass ratio 12:3 mixing, is stirred at 40 DEG C, stands 3h, and filtering obtains two degree of processing sanitary wastewaters;
(3) it is 40cm clast in cement bottom of pond portion laying depth, two degree of processing sanitary wastewaters is added and flood clast 60cm, stirring is mixed
8h is closed, according to every square metre of 30g, plantation cyanobacteria is carried out and is filtered after plantation 3 days, sterilization, the i.e. processing of completion sanitary wastewater.
Comparative example 1: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking separation membrane.
Comparative example 2: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking hybrid particles.
Comparative example 3: traditional bioanalysis.
It by the sanitary wastewater processing method of above-described embodiment and comparative example, is tested respectively, takes test water sample 200ml,
Raw water COD is 20200mg/L, pH value 6.82.It is handled respectively with the sanitary wastewater processing method of embodiment and comparative example, detects it
Last pH value, COD content, obtain that the results are shown in Table 1.
Table 1:
In summary, sanitary wastewater processing method effect of the invention is more preferable as can be seen from Table 1, is worth of widely use, above
Described is only preferred mode of the invention, is not intended to limit the invention, all within the spirits and principles of the present invention, made
Any modification, equivalent substitution, improvement and etc. should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of sanitary wastewater processing method, which is characterized in that the processing method includes the following steps:
(1) sanitary wastewater is filtered, collects filtrate, puts the filtrate into and carry out settle and separate in separate tank, collect separating liquid,
Separating liquid, adjusting liquid are mixed 80:1~4 by volume, in 40~45 DEG C of agitating and heatings, heat preservation;
(2) it after wait keep the temperature, stands, filtering obtains pretreatment sanitary wastewater, and pretreatment sanitary wastewater and hybrid particles are pressed matter
Amount is mixed than 12~15:3, is stirred at 40~50 DEG C, is stood, and filtering obtains two degree of processing sanitary wastewaters;
(3) cement bottom of pond portion laying depth be 40~60cm clast, be added two degree of processing sanitary wastewaters flood clast 60~
90cm is stirred, and according to every square metre of 30~40g, is carried out plantation cyanobacteria and is filtered after plantation 3~5 days, sterilization is completed
Sanitary wastewater processing.
2. sanitary wastewater processing method according to claim 1, which is characterized in that separate tank in the step (1) are as follows: long
3~4m, wide 1~2cm, bottom are equipped with the slope at 20~25 ° of inclination angle, and the height connected at the top of slope is 70~80cm, slope
The height of bottom connection is 1.5~2.0m, and every 30~50cm places separation membrane in separate tank.
3. sanitary wastewater processing method according to claim 2, which is characterized in that the separation membrane the preparation method comprises the following steps:
A. according to parts by weight, 180~190 parts of ethanol solutions, 30~40 parts of styrene, 28~32 parts of N- isopropyl acrylamides are taken
Amine, 16~19 parts of additives, 15~20 parts of chain-transferring agents, 3~8 parts of initiators, first by ethanol solution, styrene, N- isopropyl
Base acrylamide, chain-transferring agent and initiator are put into reaction kettle, using nitrogen protection, are preheated at 50~55 DEG C;
B. wait preheat after, be warming up to 90~95 DEG C, be stirred to react, be cooled to 60~65 DEG C, additive is added, stirring is protected
Temperature is cooled to room temperature, and material is collected out in discharging;
C. it will mix in material, tetrahydrofuran 1:2~3 in mass ratio out, and collect mixture, mixture, methanol are pressed into quality
It is mixed than 1:2~5, is placed in -2~2 DEG C of standings, filtered, collect filter residue;
D. it by filter residue, petroleum ether, ethanol solution and petroleum ether 1:3~5:3 in mass ratio, is mixed, mixed object is collected, in nitrogen
Under atmosphere, mixed object is taken to be added drop-wise in the substrate of glass of 1 cm2, in the case where nitrogen flow rate is 50 DEG C of environment of 1.5 L/min, works as ethyl alcohol
After solution and petroleum ether volatilization completely, film forming matter is collected to get separation membrane.
4. sanitary wastewater processing method according to claim 3, which is characterized in that the preparation of additive in the step A
Method are as follows: europium nitrate, titanium dioxide, platinum nitrate 4:1:1~3 in mass ratio are mixed, collect mixture A, then will mixing
Object A is mixed with ethanol solution, salicylic acid 8~10:18:3 in mass ratio to get additive.
5. sanitary wastewater processing method according to claim 3, which is characterized in that the system of the step A Chain transfer agent
Preparation Method are as follows: according to parts by weight, take 170~180 parts of ethanol solutions, 30~40 parts of acrylate, 23~26 parts of dodecyls
Trithiocarbonate, 5~8 parts of azo-bis-isobutyl cyanides, 3~6 parts of surfactants, are put into reaction kettle, using nitrogen protection,
60~80 DEG C are stirred to react, discharging, evaporative removal ethyl alcohol, tetrahydrofuran washing, and petroleum ether precipitation collects sediment to get chain
Transfer agent.
6. sanitary wastewater processing method according to claim 5, which is characterized in that the surfactant is dodecyl
Any one in polyethenoxy ether sodium sulfovinate, cocounut oil acyl single ethanol amide.
7. sanitary wastewater processing method according to claim 3, which is characterized in that initiator is azo in the step A
Two isobutyl cyanogen, dibenzoyl peroxide 8:1 in mass ratio are mixed.
8. sanitary wastewater processing method according to claim 1, which is characterized in that adjust the system of liquid in the step (1)
It is standby to be mixed for arsanilic acid, ammonium hydroxide and ferrous sulfate 4:13~16:2~5 in mass ratio.
9. sanitary wastewater processing method according to claim 1, which is characterized in that hybrid particles are in the step (2)
Carbon nanotube, vermiculite, quartz sand and cobblestone 7:3:6:4~12 in mass ratio are mixed to get hybrid particles.
10. sanitary wastewater processing method according to claim 1, which is characterized in that clast is bamboo in the step (3)
Bits, wheat stalk and soya-bean cake 5:3~8:3 in mass ratio are crushed to get clast.
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