CN109914105A - A kind of environment-friendly type garment material finishing auxiliaries - Google Patents
A kind of environment-friendly type garment material finishing auxiliaries Download PDFInfo
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- CN109914105A CN109914105A CN201711313486.4A CN201711313486A CN109914105A CN 109914105 A CN109914105 A CN 109914105A CN 201711313486 A CN201711313486 A CN 201711313486A CN 109914105 A CN109914105 A CN 109914105A
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Abstract
The present invention relates to a kind of environment-friendly type garment material finishing auxiliaries, are made of dimethylformamide, diethyl aminoethyl methacrylate, alkyl diphenyl ether disulphonic acid sodium, hexamethylene diisocyanate, N-Methyl pyrrolidone, double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums, water；The mass percent of various substances are as follows: dimethylformamide: 10%~30%, diethyl aminoethyl methacrylate: 2%~6%, alkyl diphenyl ether disulphonic acid sodium: 5%~15%, hexamethylene diisocyanate: 5%~15%, N-Methyl pyrrolidone: 1%~3%, double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums: 2%~6%, remaining is water.Process of the present invention safe and non-toxic can also play good preventive effect to the pilling of cloth, gauffer using the environment-friendly type garment material finishing auxiliaries.
Description
Technical field
The present invention relates to industrial chemicals fields, and in particular to a kind of environment-friendly type garment material finishing auxiliaries.
Background technique finishing auxiliaries are widely used in textile printing and dyeing industry.With the development of society, people are to environmental protection
Increasingly attention, it is many it is high poison and use be stopped to the finishing auxiliaries of environment high pollution, such as contain monoalkyl
The finishing auxiliaries of quaternary ammonium salt are gradually eliminated since toxicity is big, biological degradability is poor etc.；And dialkyl quats salt and alkyl acyl
Though the toxicity of based quaternary ammonium salt is lower than monoalkyl quaternary ammonium salts, its biological degradability is very poor, can kill biological bacteria and easily at sewage
It is absorbed and polluted agricultural land when reason by sludge.
There are some clothings to will appear pilling in prolonged dress, the phenomenon that gauffer.The calcium and magnesium ion and fertilizer dissociated in water
Anion binding in soap or washing powder, raw precipitating are adhered to the surface of towel or clothing, make towel or clothing after cleaning
Be hardened, although and traditional finishing auxiliaries can soften towel or clothing, most softening agents can all have some murder by poisoning objects
The residual of matter can damage people's health significantly.
Summary of the invention
For above-mentioned problem, the purpose of the present invention is to provide a kind of environment-friendly type garment material finishing auxiliaries, the environmental protection
Type garment material finishing auxiliaries are process using non-toxic material, can be used in softening when cloth processing, can also be to clothing
Clothes, the hardening of cloth caused by towel etc. repeatedly washs are softened, which will not be in cloth
Noxious material is remained, when use is more safe.
The technical solution adopted by the present invention to solve the technical problems is: a kind of environment-friendly type garment material finishing auxiliaries, by
Aqueous polyurethane, diethyl aminoethyl methacrylate, alkyl diphenyl ether disulphonic acid sodium, hexamethylene diisocyanate, N-
Methyl pyrrolidone, double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums, water composition；The mass percent of various substances
Are as follows: dimethylformamide: 10%~30%, diethyl aminoethyl methacrylate: 2%~6%, alkyl diphenyl ether disulphonic acid
Sodium: 5%~15%, hexamethylene diisocyanate: 5%~15%, N-Methyl pyrrolidone: 1%~3%, double ox ester group second
Ester group hydroxyethyl methyl sulfate methyl ammonium: 2%~6%, remaining is water.
Further, the production method of environment-friendly type garment material finishing auxiliaries, including following production stage: (1) to 30 DEG C
Diethyl aminoethyl methacrylate, double ox ester group ethoxycarbonyl hydroxyethyl methyls are proportionally sequentially added in~50 DEG C of water
Sulfate methyl ammonium, stirring to solvent are completely dissolved；(2) temperature for keeping 30 DEG C~50 DEG C of water, is added hexa-methylene diisocyanate
Ester stirs evenly；(3) mixed solution described in step 2 is heated to 60 DEG C~70 DEG C, dimethylformamide is added, stirring is equal
It is even；(4) 60 DEG C~70 DEG C of water in step 3 of temperature is kept proportionally to sequentially add alkyl diphenyl ether disulphonic acid sodium, N- first
Base pyrrolidones, stirs evenly；(5) gained mixed liquor 30~50 minutes in step 4 are stood；(6) after cooling under nitrogen environment
Encapsulation saves.
Further, with the following functions in above-mentioned material:
(1) dimethylformamide: a kind of transparency liquid, energy and water and most of organic solvent dissolve each other.It is the normal of chemical reaction
Use solvent.It is both a kind of industrial chemicals that purposes is extremely wide and a kind of fine solvent having many uses.It can be used for polyacrylonitrile fibre
The synthesis of the wet spinning silks, polyurethane of synthetic fibers such as dimension；It is film-made for plastics；It can also remove the paint stripper of paint-removing；It can also
The pigment for dissolving certain low solubilities makes the characteristics of pigment is with dyestuff.
(2) diethyl aminoethyl methacrylate: a kind of highly-water-soluble liquid monomer has good cementability, extensively
Applied to rows such as fiber industry, coatings industry, paper industry, water process, plastic, rubber industry, detergent and surfactants
Industry.
(3) alkyl diphenyl ether disulphonic acid sodium: white to yellowish powdery or particle, it is nontoxic, tasteless, there are a small amount of stimulation, energy
It is dissolved in water, there is brilliant dispersibility, resistance to hard water, bleach-resistant agent ability etc..Make anion levelling agent, Buddhist nun in dyestuff
Make dye leveller in dragon printing and dyeing, makees wetting agent, coupling agent and stabilizer in detergent.
(4) hexamethylene diisocyanate: stablize under normal temperature and pressure, avoid oxide, acids, amine, highly basic, alcohols, water
Contact.Slightly pungent odour, it is inflammable.Insoluble in cold water, it is dissolved in the organic solvents such as benzene, toluene, chlorobenzene.Photostability is preferable,
Volatility is big, and toxicity is big.This product is using wider aliphatic isocyanate in polyurethane industrial, mainly for the production of polyurethane painting
Material, elastomer, adhesive, textile finshing agent etc., aviation, weaving, foamed plastics, coating, in terms of also have width
Wide application.
(5) N-Methyl pyrrolidone: colourless transparent oil liquid, micro- smell for having amine.It can be with water, alcohol, ether, ester, ketone, halogen
It dissolves each other for hydrocarbon, aromatic hydrocarbons and castor oil.This product is important industrial chemicals, is that the polarity that a kind of selectivity is strong and stability is good is molten
Agent, have toxicity is low, boiling point is high, dissolving power is strong, nonflammable, biodegradable, recoverable, using it is safe and be suitable for it is more
The advantages that kind formula purposes.The medium of solvent for the polymer and polymerization reaction, such as engineering plastics and aramid fiber.In addition also
Pesticide, medicine and detergent etc. can be used in.
(6) double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums: there is excellent flexibility, emulsibility and antistatic
Property；It is biodegradable, nontoxic non-stimulated, safety and sanitation；Most promising product in the civilian fabric softener of cation of new generation
Kind；It is widely used in civilian softener, antistatic agent, hair conditioner, automobile cleaning agent etc..Especially suitable for cotton, hair, terylene, nitrile
The final finishing of the fiber yarns such as synthetic fibre and fabric.
The beneficial effects of the present invention are: the environment-friendly type garment material finishing auxiliaries can be each to chemical fibre, cotton spinning, silk weaving etc.
Class cloth is softened well, and nonhazardous when which uses has aromatic odor, can be used as
It is a kind of top grade cloth softening agent use, and the environment-friendly type garment material finishing auxiliaries can in life because of many reasons
Caused by cloth hardening, softened, process safety nonhazardous, can be with using the environment-friendly type garment material finishing auxiliaries
Pilling to cloth, gauffer play good preventive effect.
Specific embodiment
Below with reference to embodiment, the present invention is further described.Embodiment 1
Environment-friendly type garment material finishing auxiliaries in the present embodiment, including dimethylformamide, methacrylic acid diethylamino
Ethyl ester, alkyl diphenyl ether disulphonic acid sodium, hexamethylene diisocyanate, N-Methyl pyrrolidone, double ox ester group ethoxycarbonyl hydroxyl second
Ylmethyl sulfate methyl ammonium, water；The mass percent of various substances are as follows: including dimethylformamide: 10%, methacrylic acid two
Ethylamino ethyl ester: 2%, alkyl diphenyl ether disulphonic acid sodium: 5%, hexamethylene diisocyanate: 5%, N- crassitude
Ketone: 1%, double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums: 2%, remaining is water.
The production method of the environment-friendly type garment material finishing auxiliaries, it is characterised in that: including following production stage: (1)
Diethyl aminoethyl methacrylate, double ox ester group ethoxycarbonyl hydroxyethyl methyls are proportionally sequentially added into 30 DEG C of water
Sulfate methyl ammonium, stirring to solvent are completely dissolved；(2) hexamethylene diisocyanate stirring is added in the temperature for keeping 50 DEG C of water
Uniformly；(3) mixed solution described in step 2 is heated to 60 DEG C, dimethylformamide is added, stirs evenly；(4) it keeps
70 DEG C of water of temperature proportionally sequentially adds alkyl diphenyl ether disulphonic acid sodium, N-Methyl pyrrolidone in step 3, and stirring is equal
It is even；(5) gained mixed liquor 30 minutes in step 4 are stood；(6) it encapsulates and saves under nitrogen environment after cooling.
Embodiment 2
Environment-friendly type garment material finishing auxiliaries in the present embodiment, including dimethylformamide, methacrylic acid diethylamino
Ethyl ester, alkyl diphenyl ether disulphonic acid sodium, hexamethylene diisocyanate, N-Methyl pyrrolidone, double ox ester group ethoxycarbonyl hydroxyl second
Ylmethyl sulfate methyl ammonium, water；The mass percent of various substances are as follows: including dimethylformamide: 30%, methacrylic acid two
Ethylamino ethyl ester: 6%, alkyl diphenyl ether disulphonic acid sodium: 15%, hexamethylene diisocyanate: 15%, N- crassitude
Ketone: 3%, double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums: 6%, remaining is water.
The production method of the environment-friendly type garment material finishing auxiliaries, it is characterised in that: including following production stage: (1)
Diethyl aminoethyl methacrylate, double ox ester group ethoxycarbonyl hydroxyethyl methyls are proportionally sequentially added into 50 DEG C of water
Sulfate methyl ammonium, stirring to solvent are completely dissolved；(2) hexamethylene diisocyanate stirring is added in the temperature for keeping 50 DEG C of water
Uniformly；(3) mixed solution described in step 2 is heated to 70 DEG C, dimethylformamide is added, stirs evenly；(4) it keeps
70 DEG C of water of temperature proportionally sequentially adds alkyl diphenyl ether disulphonic acid sodium, N-Methyl pyrrolidone in step 3, and stirring is equal
It is even；(5) gained mixed liquor 50 minutes in step 4 are stood；(6) it encapsulates and saves under nitrogen environment after cooling.
Claims (2)
1. a kind of environment-friendly type garment material finishing auxiliaries, it is characterised in that: by dimethylformamide, methacrylic acid diethyl
Amino ethyl ester, alkyl diphenyl ether disulphonic acid sodium, hexamethylene diisocyanate, N-Methyl pyrrolidone, double ox ester group ethoxycarbonyies
Hydroxyethyl methyl sulfate methyl ammonium, water composition；The mass percent of various substances are as follows: dimethylformamide: 10%~30%, first
Base acrylic acid diethylamino ethyl ester: 2%~6%, alkyl diphenyl ether disulphonic acid sodium: 5%~15%, hexa-methylene diisocyanate
Ester: 5%~15%, N-Methyl pyrrolidone: 1%~3%, double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums: 2%~
6%, remaining is water.
2. environment-friendly type garment material finishing auxiliaries according to claim 1, it is characterised in that: production method includes following raw
It produces step: (1) proportionally sequentially adding diethyl aminoethyl methacrylate, double ox esters into 30 DEG C~50 DEG C of water
Base ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammonium, stirring to solvent are completely dissolved；(2) temperature for keeping 30 DEG C~50 DEG C of water, adds
Enter hexamethylene diisocyanate to stir evenly；(3) mixed solution described in step 2 is heated to 60 DEG C~70 DEG C, be added
Dimethylformamide stirs evenly；(4) 60 DEG C~70 DEG C of water in step 3 of temperature is kept proportionally to sequentially add alkyl
Diphenyl oxide disulfonate, N-Methyl pyrrolidone, stir evenly；(5) gained mixed liquor 30~50 minutes in step 4 are stood；
(6) it encapsulates and saves under nitrogen environment after cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711313486.4A CN109914105A (en) | 2017-12-12 | 2017-12-12 | A kind of environment-friendly type garment material finishing auxiliaries |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711313486.4A CN109914105A (en) | 2017-12-12 | 2017-12-12 | A kind of environment-friendly type garment material finishing auxiliaries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109914105A true CN109914105A (en) | 2019-06-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711313486.4A Withdrawn CN109914105A (en) | 2017-12-12 | 2017-12-12 | A kind of environment-friendly type garment material finishing auxiliaries |
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| Country | Link |
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| CN (1) | CN109914105A (en) |
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- 2017-12-12 CN CN201711313486.4A patent/CN109914105A/en not_active Withdrawn
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| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190621 |