CN109912904A - A kind of cable jacket is with easily tearing pvc material and preparation method thereof - Google Patents
A kind of cable jacket is with easily tearing pvc material and preparation method thereof Download PDFInfo
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- CN109912904A CN109912904A CN201910161761.8A CN201910161761A CN109912904A CN 109912904 A CN109912904 A CN 109912904A CN 201910161761 A CN201910161761 A CN 201910161761A CN 109912904 A CN109912904 A CN 109912904A
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Abstract
The invention discloses a kind of cable jackets to tear pvc material with easy, by weight, it can also include carbon fiber 12-20 parts, 10-15 parts of silicone grease, 3-10 parts of glass fibre including 90-115 parts of polyvinyl chloride resin, 45-58 parts of dioctyl terephthalate, 95-110 parts of nanometer calcium, 4.6-5.4 parts of calcium zinc stabilizer, 0.8-1.3 parts of in-lubricant, 0.5-1.2 parts of external lubricant；Preparation step includes: that carbon fiber, silicone grease and glass fibre are premixed 5-10min, revolving speed 300-500r/min under low speed, obtains mixture A；Into mixture A, by surplus stock, the mixed at high speed under 900-1000r/min obtains mixture B to 120-135 DEG C for addition；By mixture B, blending extrusion, granulation, extrusion temperature are 140-160 DEG C in double rank extruding granulators, and cable jacket is made with easy and tears pvc material；Pvc material of the invention has easily tears characteristic along longitudinal direction, and the sheath of cable is made of this kind of material, in the actual installation process of cable, so that sheath is easily peeled off, thus reduces labor intensity, improves the mounting and installation efficiency of cable.
Description
Technical field
The present invention relates to the technical field of cable, in particular to a kind of cable jacket tears pvc material and its system with easy
Preparation Method.
Background technique
The insulating layer that cable generally includes internal core and is wrapped in outside core, wherein core is by several or several
Group conductor strand forms, for the transmission of conductive or signal, insulating layer for core to be isolated, avoid core leak electricity or signal scatter and disappear it is dry
It disturbs.As needed, the outside of insulating layer is usually also wrapped on armor, filled layer, anti-interference layer etc..The outermost layer of cable is usual
It is additionally provided with sheath, sheath plays the role of protecting internal core, insulating layer isostructural, and pvc material is to prepare sheath
Common used material.
In the actual installation process of cable, need to remove the sheath of cable, in order to the connection of route.However, mesh
The sheath removing of preceding cable is usually more difficult, on the one hand, increases the labor intensity of operator, on the other hand, is greatly reduced
The efficiency of cable mounting and installation.So being one of the important directions of line cable industry development for the exploitation for easily tearing sheath material.
It is existing to can refer to the Chinese patent application that Authorization Notice No. is CN103509283B, it is blended easily it discloses a kind of
Wire cable material is torn, is made by the raw material of following weight parts: SG-3 polyvinyl chloride 130-140, the pungent vinegar 1.2- of phthalic acid two
1.5, haloflex 6-8, calcium carbonate 10-20, polyethylene wax 3-5, cashew nut shell oil 2-4, antioxidant A W 2.4-3.8, promotor
HOBS 1-2, vulcanizing agent DCBP 1-2, (dimethylamino methyl) phenol of polyisobutene 2-4,2.4.6 mono- or three 1.2-1.5, carbon modified
Fiber 10-20, compounded mix 20-30, titanium dioxide 2-4, silica flour 4-6, triglyceride vinegar 0.4-0.8, epoxystearic acid are pungent
Vinegar 1.4-3.
How further to develop and easily tear sheath material, is still supplement cable manufacturing, abundant market, promotes cable row
One of the important measures that industry further develops.
Summary of the invention
In view of the shortcomings of the prior art, the purpose of the present invention one is: providing a kind of cable jacket with easily tearing polyvinyl chloride material
Material has and easily tears characteristic along longitudinal direction, the sheath of cable is made of this kind of material, in the actual installation process of cable, so that shield
Set is easily peeled off, and thus reduces labor intensity, improves the mounting and installation efficiency of cable.
The first purpose of this invention has the technical scheme that
A kind of cable jacket includes following components by weight with easily pvc material is torn: 90-115 parts of polyvinyl chloride resin,
45-58 parts of dioctyl terephthalate, 95-110 parts of nanometer calcium, 4.6-5.4 parts of calcium zinc stabilizer, 0.8-1.3 parts of in-lubricant,
0.5-1.2 parts of external lubricant.
By using above scheme, polyvinyl chloride resin is the main component in proportion of the invention；Dioctyl terephthalate seat
As the plasticizer in proportion of the invention, have heat-resisting, cold-resistant, difficult volatilization, anti-extraction, flexibility and electrical insulation capability good etc.
Advantage；Calcium zinc stabilizer is synthesized for main component using special combination process by calcium salt, zinc salt, lubricant, antioxidant etc., no
But the toxic stabilizer such as can replace lead cadmium salt class and organic tin, and have fairly good thermal stability, photostability and
The transparency and the features such as tinting strength, tinting power, processing performance are good, thermostabilization is good, nontoxic.
Interior lubrication can reduce the lubrication of polymer molecule interchain internal friction, good with the compatibility of polymer, can be with
It evenly spreads between strand, to reduce the interior friction of strand, improves the mobility of polymer, to improve polychlorostyrene second
The uniformity of the matrix of alkene material when tearing, can reduce being adhered between different component, to improve pvc material
Tear resistance, convenient for the installation of cable.
Compatibility between external lubricant and PVC base system is smaller, on the one hand, raw in the processing of pvc material
During production, lubricant molecular layer can be formed in interface, to reduce polymer from the interior shifting of polymer to surface
Being adhered between production equipment body；On the other hand, when producing cable jacket using pvc material of the invention, outside
Lubricant can be transferred to the inner surface and the outer surface of sheath, to further increase the tearability of sheath.
In pvc material provided by the invention, filler using nanometer calcium as pvc material, and substantially mention
The addition of weight percent of the high nanometer calcium in pvc material, nanometer calcium can cooperate with other components, and effectively mention
The tearability energy of high pvc material of the invention.
Said components proportion of the invention is succinct, can work in coordination between each component.With preferable synergy.It is real
Number is tested it was demonstrated that the cable jacket of said ratio has with easily pvc material is torn and easily tears characteristic along longitudinal direction, by this kind of material
The sheath of cable is made, in the actual installation process of cable, so that sheath is easily peeled off, thus reduces labor intensity, improves
The mounting and installation efficiency of cable.
The present invention is further arranged to: further including 0.1-0.25 parts of colorant.
The present invention is further arranged to: including following components by weight: 100 parts of polyvinyl chloride resin, terephthalic acid (TPA)
50 parts of dioctyl ester, 100 parts of nanometer calcium, 5 parts of calcium zinc stabilizer, 1 part of in-lubricant, 1 part of external lubricant, 0.2 part of colorant.
The present invention is further arranged to: further including having following components: 12-20 parts of carbon fiber, 10-15 parts of silicone grease, glass fibers
3-10 parts of dimension.
By using above scheme, carbon fiber has that high intensity, high-modulus, high-flexibility, creep is small, corrosion-resistant, density
The excellent performances such as low, high temperature resistant, glass fibre have preferable compression strength, heat resistance, corrosion resistance.Carbon fiber and glass fibers
The addition of dimension can be played the role of reinforcing the binding performance between nanometer calcium and PVC base system, thus improve polychlorostyrene second
The mechanical property of alkene material.Moreover, because the addition of carbon fiber and glass fibre is also beneficial to improve the resistance to of pvc material
High temperature ageing performance.
The present invention is further arranged to: the carbon fiber, glass fibre diameter be 5-8 μm, length is 50-100 μ
m。
The present invention is further arranged to: by weight, the in-lubricant selects Solsperse 2000.
The present invention is further arranged to: the external lubricant selects paraffin.
The present invention is further arranged to: the calcium zinc stabilizer selects CZ-3 type calcium zinc stabilizer.
The present invention is further arranged to: the polyvinyl chloride resin selects polyvinyl chloride resin SG-8.
The purpose of the present invention two is: a kind of above-mentioned cable jacket preparation method for easily tearing pvc material is provided,
Include following preparation step:
Carbon fiber, silicone grease and glass fibre are premixed 5-10min by S1 under low speed, and revolving speed 300-500r/min is mixed
Object A；
S2, into mixture A, by surplus stock, mixed at high speed is mixed to 120-135 DEG C under 900-1000r/min for addition
Object B；
S3, by mixture B, blending extrusion, granulation, extrusion temperature are 140-160 DEG C in double rank extruding granulators, and cable is made
Sheath tears pvc material with easy.
In conclusion the invention has the following advantages:
1, pvc material of the invention has easily tears characteristic along longitudinal direction, the sheath of cable is made of this kind of material, in cable
Actual installation process in so that sheath is easily peeled off, thus reduce labor intensity, improve the mounting and installation efficiency of cable；
2, pvc material of the invention has preferable mechanical property and heat resistant performance, is suitable for higher using temperature
Installation environment；
3, proportion of the invention is simple, concise in technology, is easy to the quality control being mass produced.
Specific embodiment
Invention is further described in detail below.
Embodiment 1
A kind of cable jacket with easily tearing pvc material,
It by weight, include following components: 90 parts of polyvinyl chloride resin, 45 parts of dioctyl terephthalate, 95 parts of nanometer calcium, calcium
4.6 parts of zinc stabilizer, 0.8 part of in-lubricant, 0.5 part of external lubricant, 0.1 part of colorant；
The in-lubricant selects Solsperse 2000；The external lubricant selects paraffin；The calcium zinc stabilizer selects CZ-3 type calcium
Zinc stabilizer；The polyvinyl chloride resin selects polyvinyl chloride resin SG-8；Colorant selects colour carbon black；
Preparation method includes following preparation step:
S1, by each raw material, mixed at high speed obtains mixture B to 120 DEG C under 900r/min；
S2, by mixture B, blending extrusion, granulation, extrusion temperature are 140 DEG C in double rank extruding granulators, and cable jacket is made
Pvc material is torn with easy.
Embodiment 2
A kind of cable jacket with easily tearing pvc material,
By weight, include following components: 100 parts of polyvinyl chloride resin, 50 parts of dioctyl terephthalate, 100 parts of nanometer calcium,
5 parts of calcium zinc stabilizer, 1 part of in-lubricant, 1 part of external lubricant, 0.2 part of colorant；
The in-lubricant selects Solsperse 2000；The external lubricant selects paraffin；The calcium zinc stabilizer selects CZ-3 type calcium
Zinc stabilizer；The polyvinyl chloride resin selects polyvinyl chloride resin SG-8；Colorant selects colour carbon black；
Preparation method includes following preparation step:
S1, by each raw material, mixed at high speed obtains mixture B to 130 DEG C under 950r/min；
S2, by mixture B, blending extrusion, granulation, extrusion temperature are 150 DEG C in double rank extruding granulators, and cable jacket is made
Pvc material is torn with easy.
Embodiment 3
A kind of cable jacket with easily tearing pvc material,
By weight, include following components: 115 parts of polyvinyl chloride resin, 58 parts of dioctyl terephthalate, 110 parts of nanometer calcium,
5.4 parts of calcium zinc stabilizer, 1.3 parts of in-lubricant, 1.2 parts of external lubricant, 0.25 part of colorant；
The in-lubricant selects Solsperse 2000；The external lubricant selects paraffin；The calcium zinc stabilizer selects CZ-3 type calcium
Zinc stabilizer；The polyvinyl chloride resin selects polyvinyl chloride resin SG-8；Colorant selects colour carbon black；
Preparation method includes following preparation step:
S1, by each raw material, mixed at high speed obtains mixture B to 135 DEG C under 1000r/min；
S2, by mixture B, blending extrusion, granulation, extrusion temperature are 160 DEG C in double rank extruding granulators, and cable jacket is made
Pvc material is torn with easy.
Embodiment 4
A kind of cable jacket with easily pvc material is torn, with embodiment 2 the difference is that: raw material further includes having with the following group
Point: 12 parts of carbon fiber, 10 parts of silicone grease, 3 parts of glass fibre；The carbon fiber, glass fibre diameter be 5 μm, length is
50μm。
Preparation method includes following preparation step:
Carbon fiber, silicone grease and glass fibre are premixed under low speed 5min, revolving speed 300r/min, obtain mixture A by S1；
S2, into mixture A, by surplus stock, the mixed at high speed under 900r/min obtains mixture B to 120 DEG C for addition；
S3, by mixture B, blending extrusion, granulation, extrusion temperature are 140 DEG C in double rank extruding granulators, and cable jacket is made
Pvc material is torn with easy.
Embodiment 5
A kind of cable jacket with easily pvc material is torn, with embodiment 2 the difference is that: further include having following components:
15 parts of carbon fiber, 12 parts of silicone grease, 5 parts of glass fibre；The carbon fiber, glass fibre diameter be 6 μm, length is 80 μ
m。
Preparation method includes following preparation step:
Carbon fiber, silicone grease and glass fibre are premixed under low speed 7min, revolving speed 400r/min, obtain mixture A by S1；
S2, into mixture A, by surplus stock, the mixed at high speed under 950r/min obtains mixture B to 130 DEG C for addition；
S3, by mixture B, blending extrusion, granulation, extrusion temperature are 150 DEG C in double rank extruding granulators, and cable jacket is made
Pvc material is torn with easy.
Embodiment 6
A kind of cable jacket with easily pvc material is torn, with embodiment 2 the difference is that: further include having following components:
20 parts of carbon fiber, 15 parts of silicone grease, 10 parts of glass fibre；The carbon fiber, glass fibre diameter be 8 μm, length is 100
μm。
Preparation method includes following preparation step:
Carbon fiber, silicone grease and glass fibre are premixed under low speed 10min, revolving speed 500r/min, obtain mixture A by S1；
S2, into mixture A, by surplus stock, the mixed at high speed under 1000r/min obtains mixture B to 135 DEG C for addition；
S3, by mixture B, blending extrusion, granulation, extrusion temperature are 160 DEG C in double rank extruding granulators, and cable jacket is made
Pvc material is torn with easy.
Comparative example 1
Common commercially available sheath pvc material.
Performance detection
For the pvc material to embodiment 1-6 and the preparation of comparative example 1: according to the regulation of GB2951.11-2008, carrying out
Senile experiment, experiment condition are as follows: experiment condition is 100 DEG C × 168h；Tearing detection longitudinal tear difficulty manually, grade of difficulty point
For 1-10, rank is higher, is more difficult to tear；Above-mentioned testing result is as shown in table 1.
1 performance test results of table
According to table 1 as can be seen that compared to comparative example 1, the pvc material of embodiment 1-6 preparation is more easily torn along longitudinal direction
It splits, that is, has and easily tear characteristic along longitudinal direction, the sheath of cable is made of pvc material of the invention, in the actual installation of cable
In the process, so that sheath is easily peeled off, labor intensity is thus reduced, improves the mounting and installation efficiency of cable.
Furthermore embodiment 1-6 preparation pvc material by 100 DEG C × 168h aging after, tensile strength and break
It splits elongation and changes unobvious, and the stretching of the common commercially available sheath pvc material in comparative example 1 compared with before aging
There is decline by a relatively large margin in intensity and elongation at break.It is good that this illustrates that pvc material prepared by the present invention has
The characteristic of heat resistant is particularly suitable for the higher installation site of use environment temperature.
The addition that comparative example 2,4-6 can be seen that carbon fiber, silicone grease and glass fibre can be obviously improved polychlorostyrene second
The heat resistant performance of alkene material, meanwhile, the influence to the longitudinal tear difficulty of pvc material is little.
Above-mentioned specific embodiment is only explanation of the invention, is not limitation of the present invention, art technology
Personnel can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as
All by the protection of Patent Law in scope of the presently claimed invention.
Claims (10)
1. a kind of cable jacket tears pvc material with easy, which is characterized in that include following components by weight: PVC
90-115 parts of resin, 45-58 parts of dioctyl terephthalate, 95-110 parts of nanometer calcium, 4.6-5.4 parts of calcium zinc stabilizer, interior profit
0.8-1.3 parts of lubrication prescription, 0.5-1.2 parts of external lubricant.
2. a kind of cable jacket according to claim 1 tears pvc material with easy, it is characterised in that: further include coloring
0.1-0.25 parts of agent.
3. a kind of cable jacket according to claim 2 tears pvc material with easy, which is characterized in that by weight
Meter, includes following components: 100 parts of polyvinyl chloride resin, 50 parts of dioctyl terephthalate, 100 parts of nanometer calcium, calcium zinc stabilizer 5
Part, 1 part of in-lubricant, 1 part of external lubricant, 0.2 part of colorant.
4. a kind of cable jacket according to claim 1 is with easily tearing pvc material, it is characterised in that: further include have with
Lower component: 12-20 parts of carbon fiber, 10-15 parts of silicone grease, 3-10 parts of glass fibre.
5. a kind of cable jacket according to claim 4 tears pvc material with easy, it is characterised in that: the carbon fiber
Dimension, glass fibre diameter be 5-8 μm, length is 50-100 μm.
6. a kind of cable jacket according to claim 1 tears pvc material with easy, it is characterised in that: by weight
Meter, the in-lubricant select Solsperse 2000.
7. a kind of cable jacket according to claim 1 tears pvc material with easy, it is characterised in that: the outer lubrication
Paraffin is selected in agent.
8. a kind of cable jacket according to claim 1 tears pvc material with easy, it is characterised in that: the calcium zinc is steady
Determine agent and selects CZ-3 type calcium zinc stabilizer.
9. a kind of cable jacket according to claim 1 tears pvc material with easy, it is characterised in that: the PVC tree
Rouge selects polyvinyl chloride resin SG-8.
10. a kind of cable jacket described in claim 4 or 5 preparation method for easily tearing pvc material, which is characterized in that
Include following preparation step:
Carbon fiber, silicone grease and glass fibre are premixed 5-10min by S1 under low speed, and revolving speed 300-500r/min is mixed
Object A；
S2, into mixture A, by surplus stock, mixed at high speed is mixed to 120-135 DEG C under 900-1000r/min for addition
Object B；
S3, by mixture B, blending extrusion, granulation, extrusion temperature are 140-160 DEG C in double rank extruding granulators, and cable is made
Sheath tears pvc material with easy.
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| Application Number | Priority Date | Filing Date | Title |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910161761.8A CN109912904A (en) | 2019-03-04 | 2019-03-04 | A kind of cable jacket is with easily tearing pvc material and preparation method thereof |
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| CN109912904A true CN109912904A (en) | 2019-06-21 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146096A (en) * | 2013-03-11 | 2013-06-12 | 远东电缆有限公司 | PVC (Polyvinyl chloride) environment-friendly transparent sheath material for electric wire |
| CN107325450A (en) * | 2017-08-09 | 2017-11-07 | 安徽杰奥电气有限公司 | A kind of stretch-proof polyvinyl chloride cable sheathing compound |
| CN107674347A (en) * | 2017-11-15 | 2018-02-09 | 湖州荣吴索道运输服务有限公司 | A kind of preparation method of high temperature resistant weather-resistance flame-retardant cable jacket material |
| CN108410083A (en) * | 2018-02-07 | 2018-08-17 | 安徽剑峰通讯科技有限公司 | A kind of inside cable sheath material |
| CN108727741A (en) * | 2018-06-22 | 2018-11-02 | 桂林国际电线电缆集团有限责任公司 | A kind of high temperature resistant environment-protective easily tears PVC sheath CABLE MATERIALS and preparation method thereof |
-
2019
- 2019-03-04 CN CN201910161761.8A patent/CN109912904A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146096A (en) * | 2013-03-11 | 2013-06-12 | 远东电缆有限公司 | PVC (Polyvinyl chloride) environment-friendly transparent sheath material for electric wire |
| CN107325450A (en) * | 2017-08-09 | 2017-11-07 | 安徽杰奥电气有限公司 | A kind of stretch-proof polyvinyl chloride cable sheathing compound |
| CN107674347A (en) * | 2017-11-15 | 2018-02-09 | 湖州荣吴索道运输服务有限公司 | A kind of preparation method of high temperature resistant weather-resistance flame-retardant cable jacket material |
| CN108410083A (en) * | 2018-02-07 | 2018-08-17 | 安徽剑峰通讯科技有限公司 | A kind of inside cable sheath material |
| CN108727741A (en) * | 2018-06-22 | 2018-11-02 | 桂林国际电线电缆集团有限责任公司 | A kind of high temperature resistant environment-protective easily tears PVC sheath CABLE MATERIALS and preparation method thereof |
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Application publication date: 20190621 |