CN109907364A - A kind of cigarette incuding alcohol vapour - Google Patents

A kind of cigarette incuding alcohol vapour Download PDF

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Publication number
CN109907364A
CN109907364A CN201910301161.7A CN201910301161A CN109907364A CN 109907364 A CN109907364 A CN 109907364A CN 201910301161 A CN201910301161 A CN 201910301161A CN 109907364 A CN109907364 A CN 109907364A
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CN
China
Prior art keywords
alcohol vapour
substrate
cigarette
alcohol
sense film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910301161.7A
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Chinese (zh)
Inventor
张霞
韩熠
李寿波
赵伟
巩效伟
李廷华
朱东来
陈永宽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Tobacco Yunnan Industrial Co Ltd
Original Assignee
China Tobacco Yunnan Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Tobacco Yunnan Industrial Co Ltd filed Critical China Tobacco Yunnan Industrial Co Ltd
Priority to CN201910301161.7A priority Critical patent/CN109907364A/en
Publication of CN109907364A publication Critical patent/CN109907364A/en
Pending legal-status Critical Current

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Abstract

The present invention discloses a kind of cigarette that can incude alcohol vapour, it includes tobacco segment (1) and filter segment (2), and the filter segment (2) has alcohol vapour reaction diaphragm (3) far from the end face of the tobacco segment (1);The alcohol vapour reaction diaphragm (3) includes: substrate (31), the sense film (32) on the substrate (31), the hole (33) for penetrating the substrate (31) and the sense film (32);The sense film (32) is the mixture layer of Nile red and polymer, and the sense film (32) is located at side of the substrate (31) far from the filter segment (2).The present invention is using Cigarette as the carrier of the alcohol vapour reaction diaphragm (3), the alcohol vapour reaction diaphragm (3) is fixed on Cigarette filter segment (2), applied to the occasion for smoking and drinking while carrying out, under the premise of not influencing smoking, the alcohol vapour that exhalation can be monitored in real time is horizontal, to control drinking amount in time.

Description

A kind of cigarette incuding alcohol vapour
Technical field:
The invention belongs to technical field of cigarettes, and in particular to one kind can incude the cigarette of alcohol vapour.
Background technique:
Spirits culture does not go downhill permanently always for thousands of years in China or even the world, especially often there is that so-called " tobacco and wine are not in China Break up the family " saying, from the point of view of communication exchange, tobacco and wine can open interpersonal estrangement, from the point of view of science, Have certain scientific basis, existing research shows: the alcohol in wine can make one to germinate tired meaning and the nicotine in cigarette can then be offset Alcohol bring tired out sense, the reason is that nicotine can weaken the sleep of alcohol by stimulating the brain region reaction of basal forebrain Inducing action.But meanwhile there is also the bad habit such as urge the guests to drink, indulge in excessive drinking in the culture of Chinese wine table, only China 1 year 2016 is just because indulging in excessive drinking Dead nearly 710,000 people.The generation of tragedy also has inherent reason in addition to external reason, i.e., many people are resistant to the alcohol of oneself Amount is not known or only ambiguous understanding, and ethanol tolerance is related with the catabolism ability of alcohol in vivo, because Alcohol catabolism ability in different human bodies is different, so different people is different to the tolerance of alcohol, especially for It is liquor-saturated easily to there is nausea and vomiting, stupor discomfort etc. after drinking by internal alcohol dehydrogenase and the lower people of acetaldehyde-dehydrogenase enzyme level Wine symptom works as metabolic water in addition, the dosis tolerata of alcohol can also change under different environment and different emotion influences When flat decline, a large amount of ethyl alcohol can enter lung and brain, can contain a large amount of alcohol vapours in expiration.When there are malaise symptoms Before, majority are difficult to monitor internal alcohol content in time and stop drinking immediately, there is idea of leaving things to chance in addition, as a result cause excess It drinks or indulges in excessive drinking.Not only affect the normal communication with people, it is often more important that seriously endanger health or even threat to life peace Entirely.
Although alcohol tester commercially available at present, prevailing price is expensive and volume is larger, test method Relatively cumbersome, also to carry such equipment in occasion of drinking seems not-so-practical.
Therefore, the simpler alcohol vapour for realizing real time monitoring exhalation is horizontal, is people to control drinking amount in time It is desired.
In order to solve problem above, the present invention is proposed.
Summary of the invention:
The present invention provides a kind of cigarette that can incude alcohol vapour comprising tobacco segment 1 and filter segment 2, the filter segment 2 End face far from the tobacco segment 1 has alcohol vapour reaction diaphragm 3;
The alcohol vapour reaction diaphragm 3 includes: substrate 31, the sense film 32 on the substrate 31, penetrates the substrate 31 and the sense film 32 hole 33;
The sense film 32 is the mixture layer of Nile red and polymer, and the sense film 32 is located at the substrate 31 far Side from the filter segment 2.
Preferably, the substrate 31 is selected from polyester film thin slice, and the polyester film is polyethylene terephthalate type polyester Film or polybutylene terephthalate type polyester film.
Preferably, the polymer includes but is not limited to cellulose, dimethyl silicone polymer, polystyrene, poly- methyl-prop E pioic acid methyl ester, polycaprolactone, polyvinylpyrrolidone.
Wherein, the alcohol vapour reaction diaphragm 3 with a thickness of several hundred microns to one millimeter;The thickness of the sense film 32 It is tens microns to several hundred microns.
Wherein, Nile red is solvatochromic dyes, and with the polar variation of environment, emission peak has big wavelength position It moves.Nile red dissolves in various solvents, and photochemical stability is good, there is strong fluorescence peak, there is strong molar absorptivity, can incude ethyl alcohol Isopolarity substance.Especially for the polar solvent or solvent vapo(u)r between pH4-9, Nile red absorbs light and emits the color of light It is fixed and unrelated with pH.Meanwhile Nile red dissolves in polymer substrate, the mixture of Nile red and polymer can be formed solely Special induction region and the effect of various steam molecules generate different fluorescence responses.
Wherein, the effect of the polymer includes: that (1) permeates steam to be incuded, and by taking dimethyl silicone polymer as an example, is seeped The larger free volume that permeability is formed between macromolecular chain from the rotational freedom of siloxanes key therein;(2) described Polymer is adsorbable and steam to be incuded is concentrated as absorption phase, also steam is allowed to diffuse to other than polymer substrate, generation can Inverse response;(3) by the competition of Nile red and steam to be incuded to reaction site on polymer, substitution reaction or hydrogen bond occurs Bonding, to make the fluorescence emission wavelengths of Nile red that red shift or blue shift occur, visually can direct feel to the sense film The color change of 32 front and backs, the depth for changing color directly reflect the height of levels of ethanol in steam;(4) by described poly- The selection of 32 manufacturing process of selection, 32 film thickness of the sense film and the sense film of object material type is closed, it is controllable described The sensitivity and selectivity of alcohol vapour reaction diaphragm 3.
Wherein, the cigarette for incuding alcohol vapour preparation method the following steps are included:
(1) Nile red and the polymer are dissolved in the organic solvents such as toluene, ethyl alcohol or chloroform, Buddhist nun sieve is made The red mixed solution with polymer;
(2) directly the mixed solution of Nile red described in step (1) and polymer is coated in polyester film sheet substrate, Then it is dried at room temperature for, it is made to form the sense film 32 on the substrate 31;
(3) it will form that the sense film 32 is cut into diameter and Cigarette diameter is similar on the substrate 31 obtained above Sequin and punch 33, obtain the alcohol vapour reaction diaphragm 3;
(4) the alcohol vapour reaction diaphragm 3 is pressed into cigarette filter tip manufacturing process and is fixed on the filter segment 2 End face far from the tobacco segment 1, and the sense film 32 is located at side of the substrate 31 far from the filter segment 2.
Wherein, the mixed solution of Nile red described in step (1) and polymer can also be passed through into layer in the step (2) Pressure technology is laminated on polyester film thin slice, is then dried at room temperature for, it is made to form the sense film 32 on the substrate 31, The polyester film is the film of inertia and light transmission.The compound of the substrate 31 and the sense film 32 that are obtained using this method Stability and mechanical strength it is higher, pass through the polymer that keeps engineering properties unstable and the stable polyester film thin slice of engineering properties In conjunction with stable sense film 32 can be obtained.The compound of the substrate 31 and the sense film 32 is that have certain mechanical strength Flexible membrane, convenient for being integrated into cigarette filter section 2.
It, can be while aspirating cigarette or every mouthful of cigarette interval of suction, with mouth against the ethyl alcohol in use process Steam reaction diaphragm 3 is blown, the alcohol vapour contact induction film 32 of exhalation, and typically, so that originally orange, (Nile red absorbs wave It is long to be located at green area) sense film 32 color change occurs, the color of variation (connects from Chinese red to peony with alcohol vapour After touch, launch wavelength is moved to Chinese red region), the ethanol vapor concentration of the depth of discoloration and the time of discoloration and exhalation has It closes.After alcohol vapour slow evaporation, due to the variation of launch wavelength, color is gradually brought to orange.The sense film 32 The manufacturing method of the color and the alcohol vapour reaction diaphragm 3 that change after the color and induction ethyl alcohol of body and personal visual color Resolution capability is related.The purpose of the punching of alcohol vapour reaction diaphragm 3 33 is the normal suction in order to not influence cigarette.It is described The diameter of alcohol vapour reaction diaphragm 3 can be adjusted according to the diameter of Cigarette.
Wherein, monitoring difinite quality or sxemiquantitative/quantitative measure of the alcohol vapour reaction diaphragm 3 to drinking amount.It is described Qualitative method is the weight by intuitively observing variation and the variation of 32 color of sense film tentatively to judge drinking amount How much;Sxemiquantitative/the quantitative approach needs to establish colorimetric assay relationship, is carried out pair by colorimetric card with the color of variation Than being determined with sxemiquantitative/quantification, to monitor drinking amount, avoiding excessive consumption of alcohol or excessive drinking.
Compared with the existing technology, the invention has the following advantages:
1, the present invention makes alcohol vapour reaction diaphragm 3, using Nile red dye as fluorescence discoloration inductive material with cigarette cigarette The alcohol vapour reaction diaphragm 3 is fixed on Cigarette filter segment by the carrier of alcohol vapour reaction diaphragm 3 described in Zhi Zuowei 2, applied to the occasion for smoking and drinking while carrying out, under the premise of not influencing smoking, the ethyl alcohol that can monitor exhalation in real time steams Carbonated drink is flat, to control drinking amount in time.
2, sensitivity of the sense film 32 of the present invention using Nile red dye as fluorescence discoloration inductive material, to alcohol vapour Good with selectivity, response time and turnaround time are shorter, can quickly incude the levels of ethanol of exhalation;Meanwhile second of the present invention The a part of alcohol steam reaction diaphragm 3 as Cigarette has expanded cigarette in the case where not influencing the normal smoking conditions of Cigarette The function of cigarette realizes smoking and the combination of alcohol testing function, and the cigarette that can incude alcohol vapour does not need additionally Detection device, it is easy to carry.
3, the method that the cigarette of the present invention for incuding alcohol vapour incudes alcohol vapour in real time is simple, it is only necessary to blow Movement can be carried out detection, and the manufacturing method of the alcohol vapour reaction diaphragm 3 is simple, low in cost, light weight, volume It is small, it is easy to integrated with Cigarette filter segment 2.
Detailed description of the invention
The schematic diagram of the compound of Fig. 1 substrate of the present invention and sense film.
Fig. 2 present invention can incude the schematic diagram of the cigarette of alcohol vapour.
The title of appended drawing reference in the description of the drawings are as follows: 1- tobacco segment;2- filter segment;3- alcohol vapour reaction diaphragm;31- Substrate;32- sense film;The hole 33-.
Specific embodiment
The present invention is described in further details with attached drawing with reference to embodiments, embodiment is only limitted to illustrate the present invention, Rather than limitation of the invention.
The present embodiment is the cigarette that one kind can incude alcohol vapour comprising tobacco segment 1 and filter segment 2, the filter segment 2 End face far from the tobacco segment 1 has alcohol vapour reaction diaphragm 3;
The alcohol vapour reaction diaphragm 3 includes: substrate 31, the sense film 32 on the substrate 31, penetrates the substrate 31 and the sense film 32 hole 33;
The sense film 32 is the mixture layer of Nile red and polymer, and the sense film 32 is located at the substrate 31 far Side from the filter segment 2.
The substrate 31 is selected from polyethylene terephthalate type polyester film;The polymer is dimethyl silicone polymer.
Wherein, the alcohol vapour reaction diaphragm 3 with a thickness of 300 microns;The sense film 32 with a thickness of 80 microns.
Wherein, the effect of the polymer includes: that (1) permeates steam to be incuded, and by taking dimethyl silicone polymer as an example, is seeped The larger free volume that permeability is formed between macromolecular chain from the rotational freedom of siloxanes key therein;(2) described Polymer is adsorbable and steam to be incuded is concentrated as absorption phase, also steam is allowed to diffuse to other than polymer substrate, generation can Inverse response;(3) by the competition of Nile red and steam to be incuded to reaction site on polymer, substitution reaction or hydrogen bond occurs Bonding, to make the fluorescence emission wavelengths of Nile red that red shift or blue shift occur, visually can direct feel to the sense film The color change of 32 front and backs, the depth for changing color directly reflect the height of levels of ethanol in steam;(4) by described poly- The selection of 32 manufacturing process of selection, 32 film thickness of the sense film and the sense film of object material type is closed, it is controllable described The sensitivity and selectivity of alcohol vapour reaction diaphragm 3.
Wherein, the cigarette for incuding alcohol vapour preparation method the following steps are included:
(1) Nile red and the polymer are dissolved in the organic solvents such as toluene, ethyl alcohol or chloroform, Buddhist nun sieve is made The red mixed solution with polymer;
(2) directly the mixed solution of Nile red described in step (1) and polymer is coated in polyester film sheet substrate, Then it is dried at room temperature for, it is made to form the sense film 32 on the substrate 31;
(3) it will form that the sense film 32 is cut into diameter and Cigarette diameter is similar on the substrate 31 obtained above Sequin and punch 33, obtain the alcohol vapour reaction diaphragm 3;
(4) the alcohol vapour reaction diaphragm 3 is pressed into cigarette filter tip manufacturing process and is fixed on the filter segment 2 End face far from the tobacco segment 1, and the sense film 32 is located at side of the substrate 31 far from the filter segment 2.
It, can be while aspirating cigarette or every mouthful of cigarette interval of suction, with mouth against the ethyl alcohol in use process Steam reaction diaphragm 3 is blown, the alcohol vapour contact induction film 32 of exhalation, and typically, so that originally orange, (Nile red absorbs wave It is long to be located at green area) sense film 32 color change occurs, the color of variation (connects from Chinese red to peony with alcohol vapour After touch, launch wavelength is moved to Chinese red region), the ethanol vapor concentration of the depth of discoloration and the time of discoloration and exhalation has It closes.After alcohol vapour slow evaporation, due to the variation of launch wavelength, color is gradually brought to orange.The sense film 32 The manufacturing method of the color and the alcohol vapour reaction diaphragm 3 that change after the color and induction ethyl alcohol of body and personal visual color Resolution capability is related.The purpose that the alcohol vapour reaction diaphragm 3 punches is the normal suction in order to not influence cigarette.The second The diameter of alcohol steam reaction diaphragm 3 can be adjusted according to the diameter of Cigarette.

Claims (4)

1. the cigarette that one kind can incude alcohol vapour, which is characterized in that it includes tobacco segment (1) and filter segment (2), the filter tip Section (2) has alcohol vapour reaction diaphragm (3) far from the end face of the tobacco segment (1);
The alcohol vapour reaction diaphragm (3) include: substrate (31), the sense film (32) on the substrate (31), penetrate it is described The hole (33) of substrate (31) and the sense film (32);
The sense film (32) is the mixture layer of Nile red and polymer, and the sense film (32) is located at the substrate (31) Side far from the filter segment (2).
2. the cigarette according to claim 1 for incuding alcohol vapour, which is characterized in that the substrate (31) is selected from polyester Film thin slice, the polyester film are polyethylene terephthalate type polyester film or polybutylene terephthalate type polyester film.
3. the cigarette according to claim 1 for incuding alcohol vapour, which is characterized in that the polymer includes fiber Element, dimethyl silicone polymer, polystyrene, polymethyl methacrylate, polycaprolactone or polyvinylpyrrolidone.
4. the cigarette according to claim 1 for incuding alcohol vapour, which is characterized in that the alcohol vapour reaction diaphragm (3) with a thickness of several hundred microns to one millimeter;The sense film (32) with a thickness of tens microns to several hundred microns.
CN201910301161.7A 2019-04-15 2019-04-15 A kind of cigarette incuding alcohol vapour Pending CN109907364A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910301161.7A CN109907364A (en) 2019-04-15 2019-04-15 A kind of cigarette incuding alcohol vapour

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910301161.7A CN109907364A (en) 2019-04-15 2019-04-15 A kind of cigarette incuding alcohol vapour

Publications (1)

Publication Number Publication Date
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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH462692A (en) * 1965-11-12 1968-09-15 Lorillard Co P Filter for tobacco products and method for its manufacture
WO1989006912A1 (en) * 1988-01-28 1989-08-10 Blockers C A Inc Process for manufacturing cigarettes employing preselected alcohols
US20020076822A1 (en) * 2000-12-14 2002-06-20 Levitsky Igor A. Fluorescence-based method for detecting of basic gases
US20030032197A1 (en) * 2001-04-04 2003-02-13 Levitsky Igor A. Method of signal amplification in multi-chromophore luminescence sensors
CN101762572A (en) * 2010-01-28 2010-06-30 北京交通大学 Ratio fluorescent nano hydrogel for pH value sensing and preparation method thereof
CN203986134U (en) * 2014-08-04 2014-12-10 张银虎 The multifunction electronic tobacco rod of tool alcohol screen test and charge function
CN105492502A (en) * 2013-04-01 2016-04-13 伦斯莱尔工艺研究院 Organic phosphor-functionalized nanoparticles and compositions comprising the same
CN205333657U (en) * 2015-10-27 2016-06-22 深圳市杰仕博科技有限公司 Multifunctional alcohol tester
US20180228218A1 (en) * 2017-02-10 2018-08-16 Nuvoton Technology Corporation Multifunctional electronic cigarette and multifunctional portable electronic device
CN109603779A (en) * 2018-12-29 2019-04-12 中国烟草总公司郑州烟草研究院 A kind of pH response type cigarette discoloration adsorbent material and preparation method thereof, cigarette filter

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH462692A (en) * 1965-11-12 1968-09-15 Lorillard Co P Filter for tobacco products and method for its manufacture
WO1989006912A1 (en) * 1988-01-28 1989-08-10 Blockers C A Inc Process for manufacturing cigarettes employing preselected alcohols
US20020076822A1 (en) * 2000-12-14 2002-06-20 Levitsky Igor A. Fluorescence-based method for detecting of basic gases
US20030032197A1 (en) * 2001-04-04 2003-02-13 Levitsky Igor A. Method of signal amplification in multi-chromophore luminescence sensors
CN101762572A (en) * 2010-01-28 2010-06-30 北京交通大学 Ratio fluorescent nano hydrogel for pH value sensing and preparation method thereof
CN105492502A (en) * 2013-04-01 2016-04-13 伦斯莱尔工艺研究院 Organic phosphor-functionalized nanoparticles and compositions comprising the same
CN203986134U (en) * 2014-08-04 2014-12-10 张银虎 The multifunction electronic tobacco rod of tool alcohol screen test and charge function
CN205333657U (en) * 2015-10-27 2016-06-22 深圳市杰仕博科技有限公司 Multifunctional alcohol tester
US20180228218A1 (en) * 2017-02-10 2018-08-16 Nuvoton Technology Corporation Multifunctional electronic cigarette and multifunctional portable electronic device
CN109603779A (en) * 2018-12-29 2019-04-12 中国烟草总公司郑州烟草研究院 A kind of pH response type cigarette discoloration adsorbent material and preparation method thereof, cigarette filter

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DONG LI,ET AL: "Microsystems for optical gas sensing incorporating the solvatochromic dye Nile Red" *

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Application publication date: 20190621