CN109896542B - Magnesium-zinc stannate nano composite material and preparation method thereof - Google Patents
Magnesium-zinc stannate nano composite material and preparation method thereof Download PDFInfo
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- CN109896542B CN109896542B CN201910285237.1A CN201910285237A CN109896542B CN 109896542 B CN109896542 B CN 109896542B CN 201910285237 A CN201910285237 A CN 201910285237A CN 109896542 B CN109896542 B CN 109896542B
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- Prior art keywords
- magnesium
- composite material
- zinc stannate
- distilled water
- mixture solution
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- 239000002114 nanocomposite Substances 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims abstract description 21
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229940071182 stannate Drugs 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 12
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012153 distilled water Substances 0.000 claims abstract description 12
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011592 zinc chloride Substances 0.000 claims abstract description 11
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 10
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims abstract description 9
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims abstract description 9
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229940069446 magnesium acetate Drugs 0.000 claims abstract description 7
- 235000011285 magnesium acetate Nutrition 0.000 claims abstract description 7
- 239000011654 magnesium acetate Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000011777 magnesium Substances 0.000 claims description 14
- 239000002244 precipitate Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000007773 negative electrode material Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 abstract description 4
- 239000010406 cathode material Substances 0.000 abstract description 3
- 238000010923 batch production Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 229910003107 Zn2SnO4 Inorganic materials 0.000 description 12
- BHSXLOMVDSFFHO-UHFFFAOYSA-N (3-ethylsulfanylphenyl)methanamine Chemical compound CCSC1=CC=CC(CN)=C1 BHSXLOMVDSFFHO-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 239000002070 nanowire Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011366 tin-based material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- RRXGIIMOBNNXDK-UHFFFAOYSA-N [Mg].[Sn] Chemical compound [Mg].[Sn] RRXGIIMOBNNXDK-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229940097364 magnesium acetate tetrahydrate Drugs 0.000 description 1
- XKPKPGCRSHFTKM-UHFFFAOYSA-L magnesium;diacetate;tetrahydrate Chemical compound O.O.O.O.[Mg+2].CC([O-])=O.CC([O-])=O XKPKPGCRSHFTKM-UHFFFAOYSA-L 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910285237.1A CN109896542B (en) | 2019-04-10 | 2019-04-10 | Magnesium-zinc stannate nano composite material and preparation method thereof |
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CN201910285237.1A CN109896542B (en) | 2019-04-10 | 2019-04-10 | Magnesium-zinc stannate nano composite material and preparation method thereof |
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Publication Number | Publication Date |
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CN109896542A CN109896542A (en) | 2019-06-18 |
CN109896542B true CN109896542B (en) | 2021-03-26 |
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CN201910285237.1A Expired - Fee Related CN109896542B (en) | 2019-04-10 | 2019-04-10 | Magnesium-zinc stannate nano composite material and preparation method thereof |
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106512978A (en) * | 2016-11-29 | 2017-03-22 | 洛阳理工学院 | Method for preparing visible-light response photocatalyst by utilizing nano Zn2SnO4 |
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2019
- 2019-04-10 CN CN201910285237.1A patent/CN109896542B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106512978A (en) * | 2016-11-29 | 2017-03-22 | 洛阳理工学院 | Method for preparing visible-light response photocatalyst by utilizing nano Zn2SnO4 |
Non-Patent Citations (7)
Title |
---|
Characterization of zinc magnesium stannate phosphor fine particles synthesized by electromagnetic wave heating;Mamoru Kitaura等;《Journal of Vacuum Science & Technology B》;20100330;C2C20-C2C25 * |
Elucidating the microwave dielectric properties of (Mg(1−x)Znx)2SnO4 ceramics;Yih-Chien Chen;《Journal of Alloys and Compounds》;20120309;84-89 * |
Hydrothermal synthesis, phase structure, optical and photocatalytic properties of Zn2SnO4 nanoparticles;Monaam Ben Ali等;《Journal of Colloid and Interface Science》;20150709;360-369 * |
Phase structure and the dielectric properties of the (Zn,Mg)2(Ti,Sn)O4 ceramics;Xiangchun Liu等;《Journal of Alloys and Compounds》;20140522;544-548 * |
SnO2与锡酸盐化合物纳米颗粒的合成及其电化学性能研究;余改革;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20140515;B015-72 * |
Structural and humidity sensing characteristics of Zn2−xMgxSnO4 spinels;D. KOVACHEVA等;《JOURNAL OF MATERIALS SCIENCE LETTERS》;20011231;1597-1599 * |
Synthesis of monodisperse single crystal Zn2SnO4 cubes with high lithium storage capacity;Na Feng等;《Materials Letters》;20120223;66-68 * |
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CN109896542A (en) | 2019-06-18 |
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Effective date of registration: 20230112 Address after: No. 1061-5, 1st Floor, Commercial Building, No. 42, Yongwai Donggengli, Dongcheng District, Beijing, 100010 Patentee after: China Magnesium Tongda New Material Technology (Beijing) Co.,Ltd. Address before: Room 2202, 22 / F, Wantong building, No. 3002, Sungang East Road, Sungang street, Luohu District, Shenzhen City, Guangdong Province Patentee before: Shenzhen dragon totem technology achievement transformation Co.,Ltd. Effective date of registration: 20230112 Address after: Room 2202, 22 / F, Wantong building, No. 3002, Sungang East Road, Sungang street, Luohu District, Shenzhen City, Guangdong Province Patentee after: Shenzhen dragon totem technology achievement transformation Co.,Ltd. Address before: 315211, Fenghua Road, Jiangbei District, Zhejiang, Ningbo 818 Patentee before: Ningbo University |
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Effective date of registration: 20230323 Address after: No. 4, Floor 25, Building B, Yongjiu Commercial Building, Nangang District, Harbin, Heilongjiang Province, 150000 (residential) Patentee after: China Magnesium Tongda New Material Technology (Harbin) Co.,Ltd. Address before: No. 1061-5, 1st Floor, Commercial Building, No. 42, Yongwai Donggengli, Dongcheng District, Beijing, 100010 Patentee before: China Magnesium Tongda New Material Technology (Beijing) Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20210326 |