CN109896523A - A kind of preparation method of Gorgon fruit based active carbon material - Google Patents
A kind of preparation method of Gorgon fruit based active carbon material Download PDFInfo
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- CN109896523A CN109896523A CN201711312210.4A CN201711312210A CN109896523A CN 109896523 A CN109896523 A CN 109896523A CN 201711312210 A CN201711312210 A CN 201711312210A CN 109896523 A CN109896523 A CN 109896523A
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- gorgon fruit
- fruit shell
- shell particle
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- activator
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Abstract
System's Gorgon fruit based active carbon material preparation method of the present invention, including the following steps: (1) Gorgon fruit shell is cleaned, the impurity on its surface is removed.Gorgon fruit shell after cleaning is put into 100 DEG C of baking ovens for 24 hours, is made it dry.Gorgon fruit shell after drying is crushed, 2~4mm of its partial size is made.(2) Gorgon fruit shell particle and KOH+KCl mixture (activator) solution are pressed into impregnating ratio are as follows: activator (KOH:KCl=3:1,1:1,1:3) quality: Gorgon fruit shell granular mass=4 are sufficiently mixed.Mixture after dipping 20h is placed in 100 DEG C of baking ovens for 24 hours, is made it dry.(3) the Gorgon fruit shell particle after dipping and drying is placed in tube furnace; 700 DEG C are warming up to the heating mechanism of 5 DEG C/min; 800 DEG C are warming up to again with the heating mechanism of 1 DEG C/min; and 2h is kept the temperature at such a temperature; after cool to room temperature with the furnace; it is warming up to the whole nitrogen protection of cooling, to obtain Gorgon fruit based active carbon sample.The advantages that material has large specific surface area, and pore-size distribution level is obvious, at low cost.
Description
Technical field:
The present invention provides a kind of preparation method of Gorgon fruit based active carbon material, belongs to field of charcoal material.
Background technique:
Active carbon is to use containing the material based on charcoal as raw material, made of activated and carbonization, is handled through series of processes
It will form the different flourishing hole of shapes and sizes in the carbon crystal compartment of active carbon afterwards, suction-operated occurs mainly in its hole
The surface of gap.The specific surface area of active carbon is generally up to 500~1700m2/ g, the adsorbance of active carbon not only with specific surface area
It is related, but also depend on the construction and distribution situation in its hole.
The regular pore-size distribution regulation of active carbon and its application study are one of forward position and hot spot of current Carbon Materials research.?
While preparing active carbon with high specific surface area, regulation is oriented to its pore structure, not only facilitates active carbon theoretical system
It is abundant and perfect, and facilitate the professional application approach for further expanding active carbon.In active carbon micro-structure aperture size and
Quantity directly affects the adsorption capacity of active carbon, and research orientation regulation activity charcoal pore-size distribution increases its functionality absorption and makees
With, such as the storage of decolorizing and refining, gas, medicament slow release and electrochemical action, the unique purposes of active carbon is formed, has been obtained wide
The very big concern of big science worker.Mesopore activated carbon makes it be more suitable for fermentation liquid pure because having biggish aperture and Kong Rong
Change, the absorption of natural macromolecular pigment etc.；For microporous activated carbon because having relatively narrow aperture and huge specific surface area, suitable ten are Gao Rong
Porous material is used in the amount small molecules such as capacitor electrode material and formaldehyde, natural gas absorption.
Common active carbon can be divided into wood activated charcoal (such as cocoanut active charcoal, apricot shell active carbon, wood powder by raw material difference
Charcoal etc.), mineral raw material active carbon (various coals and petroleum and its processing product be raw material made of active carbon), other raw materials
Manufactured active carbon (as utilized active carbon made of scrap rubber, waste plastics etc.).In recent years, both at home and abroad with various cheap agricultures
Woods waste is raw material, has carried out the research for preparing wood activated charcoal.Agriculture and forestry organic waste material is easy to get with cheap, material to be filled
The advantages that foot and carbon content rate are high.It effectively utilizes agriculture and forestry organic waste material and prepares active carbon, can not only save material, but also advantageous
In the sustainable use of resource.Agriculture and forestry organic waste material raw material includes: walnut class, bamboo class, stalk class and lignin etc..Isilay
Ozdemir et al. uses grapevine to utilize ZnCl as raw material2Being prepared for specific surface area as activator is 1411m2/ g's
Grapevine matrix activated carbon.In the priming reaction for preparing wood activated charcoal, the various forms of keys that can be formed between substance, from
And various functional groups are generated, therefore, the general absorption property of the wood activated charcoal of different material preparation has larger difference.
Summary of the invention
The purpose of the present invention is to provide a kind of absorbent charcoal material and its preparation method, specifically to be easy to get, it is at low cost
Gorgon fruit shell as carbon precursor, using the mixture (activator) of KOH and KCl as the preparation method of activating agent.
Wherein preparing its partial size of Gorgon fruit shell particle used in Gorgon fruit based active carbon is 2~4mm.
Wherein prepare KOH used in Gorgon fruit based active carbon and KCl mixture (activator) can be prepared into solution with
Just it is sufficiently impregnated.
Wherein prepare Gorgon fruit shell particle used in Gorgon fruit based active carbon and KOH and KCl mixture (activator) solution
Impregnating ratio are as follows: (KOH:KCl=3:1,1:1,1:3) quality: Gorgon fruit shell granular mass=4.
Wherein prepare Gorgon fruit shell particle used in Gorgon fruit based active carbon and KOH and KCl mixture (activator) solution
Dip time be 20h.
The carbonization temperature for wherein preparing the Gorgon fruit shell particle after impregnating and drying used in Gorgon fruit based active carbon is 800
℃。
The warming machine that Gorgon fruit shell particle carbonizes after impregnating and drying used in Gorgon fruit based active carbon is wherein prepared to be made as:
700 DEG C are warming up to the heating mechanism of 5 DEG C/min, then is warming up to 800 DEG C with the heating mechanism of 1 DEG C/min, and at such a temperature
Keep the temperature 2h.
Detailed description of the invention
Gorgon fruit based active carbon absorbent charcoal material nitrogen adsorption desorption curve of Fig. 1 difference activator level than lower preparation
(a) KOH:KCl=3:1；(b) KOH:KCl=1:1；(c) KOH:KCl=1:3
Gorgon fruit based active carbon absorbent charcoal material pore size distribution curve (a) of Fig. 2 difference activator level than lower preparation
KOH:KCl=3:1；(b) KOH:KCl=1:1；(c) KOH:KCl=1:3
Gorgon fruit based active carbon absorbent charcoal material pore structure SEM photograph (a) of Fig. 3 difference activator level than lower preparation
KOH:KCl=3:1；(b) KOH:KCl=1:1；(c) KOH:KCl=1:3
Gorgon fruit based active carbon absorbent charcoal material XRD spectrum (a) KOH:KCl of Fig. 4 difference activator level than lower preparation
=3:1；(b) KOH:KCl=1:1；(c) KOH:KCl=1:3
Specific embodiment:
Below the example technical solution that the present invention is further explained is embodied, but it is not intended to be limited to following implementations
Case.
Embodiment 1
Firstly, Gorgon fruit shell is cleaned, the impurity on its surface is removed.Gorgon fruit shell after cleaning is put into 100 DEG C of baking ovens
In for 24 hours, make it dry.Gorgon fruit shell after drying is put into pulverizer and is crushed, its partial size of treated Gorgon fruit shell should be 2~
4mm.Gorgon fruit shell particle is impregnated into the solution of KOH, KCl mixture (activator), not in order to avoid Gorgon fruit shell particle dipping
Uniformly, the form for gradually adding Gorgon fruit shell particle into activator solution should be used, and is sufficiently stirred in adding procedure, it is real
Existing activator solution is sufficiently mixed with Gorgon fruit shell particle.The wherein impregnating ratio of Gorgon fruit shell particle and activator solution are as follows: activation
Agent (KOH:KCl=3:1) quality: Gorgon fruit shell granular mass=4.After preliminary stirring, by Gorgon fruit shell particle and activator solution
Mixture, which is placed on, to be continued to impregnate on orbital shaker, dip time 20h.It will be according to the Gorgon fruit after regulation dip time dipping
The mixture of shell particle and activator solution is placed in 100 DEG C of baking ovens for 24 hours, is made it dry.By the Gorgon fruit after dipping and drying
Shell particle is placed in nitrogen furnace, is warming up to 700 DEG C with the heating mechanism of 5 DEG C/min, then with the heating mechanism liter of 1 DEG C/min
Temperature keeps the temperature 2h to 800 DEG C at such a temperature.Heat preservation terminates, the Gorgon fruit shell particle furnace cooling in a nitrogen atmosphere after charing
To room temperature, to obtain Gorgon fruit based active carbon sample.
The test of nitrogen adsorption desorption is carried out to obtained Gorgon fruit based active carbon material as a result: specific surface area is
2201.1m2/ g, average pore size 12.6nm, total pore volume 1.382cm3/g。
Embodiment 2
Firstly, Gorgon fruit shell is cleaned, the impurity on its surface is removed.Gorgon fruit shell after cleaning is put into 100 DEG C of baking ovens
In for 24 hours, make it dry.Gorgon fruit shell after drying is put into pulverizer and is crushed, its partial size of treated Gorgon fruit shell should be 2~
4mm.Gorgon fruit shell particle is impregnated into the solution of KOH, KCl mixture (activator), not in order to avoid Gorgon fruit shell particle dipping
Uniformly, the form for gradually adding Gorgon fruit shell particle into activator solution should be used, and is sufficiently stirred in adding procedure, it is real
Existing activator solution is sufficiently mixed with Gorgon fruit shell particle.The wherein impregnating ratio of Gorgon fruit shell particle and activator solution are as follows: activation
Agent (KOH:KCl=1:1) quality: Gorgon fruit shell granular mass=4.After preliminary stirring, by Gorgon fruit shell particle and activator solution
Mixture, which is placed on, to be continued to impregnate on orbital shaker, dip time 20h.It will be according to the Gorgon fruit after regulation dip time dipping
The mixture of shell particle and activator solution is placed in 100 DEG C of baking ovens for 24 hours, is made it dry.By the Gorgon fruit after dipping and drying
Shell particle is placed in nitrogen furnace, is warming up to 700 DEG C with the heating mechanism of 5 DEG C/min, then with the heating mechanism liter of 1 DEG C/min
Temperature keeps the temperature 2h to 800 DEG C at such a temperature.Heat preservation terminates, the Gorgon fruit shell particle furnace cooling in a nitrogen atmosphere after charing
To room temperature, to obtain Gorgon fruit based active carbon sample.
The test of nitrogen adsorption desorption is carried out to obtained Gorgon fruit based active carbon material as a result: specific surface area is
1727.3m2/ g, average pore size 10.9nm, total pore volume 0.943cm3/g。
Embodiment 3
Firstly, Gorgon fruit shell is cleaned, the impurity on its surface is removed.Gorgon fruit shell after cleaning is put into 100 DEG C of baking ovens
In for 24 hours, make it dry.Gorgon fruit shell after drying is put into pulverizer and is crushed, its partial size of treated Gorgon fruit shell should be 2~
4mm.Gorgon fruit shell particle is impregnated into the solution of KOH, KCl mixture (activator), not in order to avoid Gorgon fruit shell particle dipping
Uniformly, the form for gradually adding Gorgon fruit shell particle into activator solution should be used, and is sufficiently stirred in adding procedure, it is real
Existing activator solution is sufficiently mixed with Gorgon fruit shell particle.The wherein impregnating ratio of Gorgon fruit shell particle and activator solution are as follows: activation
Agent (KOH:KCl=1:3) quality: Gorgon fruit shell granular mass=4.After preliminary stirring, by Gorgon fruit shell particle and activator solution
Mixture, which is placed on, to be continued to impregnate on orbital shaker, dip time 20h.It will be according to the Gorgon fruit after regulation dip time dipping
The mixture of shell particle and activator solution is placed in 100 DEG C of baking ovens for 24 hours, is made it dry.By the Gorgon fruit after dipping and drying
Shell particle is placed in nitrogen furnace, is warming up to 700 DEG C with the heating mechanism of 5 DEG C/min, then with the heating mechanism liter of 1 DEG C/min
Temperature keeps the temperature 2h to 800 DEG C at such a temperature.Heat preservation terminates, the Gorgon fruit shell particle furnace cooling in a nitrogen atmosphere after charing
To room temperature, to obtain Gorgon fruit based active carbon sample.
The test of nitrogen adsorption desorption is carried out to obtained Gorgon fruit based active carbon material as a result: specific surface area is
1859.3m2/ g, average pore size 11.9nm, total pore volume 1.087cm3/g。
Claims (6)
1. a kind of preparation method of Gorgon fruit based active carbon material, it is characterised in that: preparation method includes the following steps:
(1) pretreatment of Gorgon fruit shell raw material
Firstly, Gorgon fruit shell is cleaned, the impurity on its surface is removed.Gorgon fruit shell after cleaning is put into 100 DEG C of baking ovens
For 24 hours, it makes it dry.Gorgon fruit shell after drying is put into pulverizer and is crushed, its partial size of treated Gorgon fruit shell should be 2~4mm.
(2) dipping of Gorgon fruit shell particle
Gorgon fruit shell particle is impregnated into the solution of KOH and KCl mixture (activator), not in order to avoid Gorgon fruit shell particle dipping
Uniformly, Gorgon fruit shell particle should be gradually added into activator solution, and is sufficiently stirred in adding procedure, realize activator solution
With being sufficiently mixed for Gorgon fruit shell particle.After preliminary stirring, the mixture of Gorgon fruit shell particle and activator solution is placed on orbit determination
Continue to impregnate on shaking table.It will be placed on according to the mixture of Gorgon fruit shell particle and activator solution after set dip time dipping
In 100 DEG C of baking ovens for 24 hours, it makes it dry.
(3) charing of Gorgon fruit shell particle after impregnating and drying
Gorgon fruit shell particle after dipping and drying is placed in nitrogen furnace, is warming up to required charing according to certain heating mechanism
Temperature, and keep the temperature.Heat preservation terminates, and the Gorgon fruit shell particle after charing cools to room temperature with the furnace in a nitrogen atmosphere, and product is into peracid
It washes, after aqueous solution to neutrality, 100 DEG C of drying in an oven, product is into overpickling, after aqueous solution to neutrality, in an oven
100 DEG C of drying, to obtain Gorgon fruit based active carbon sample.
2. the preparation method of Gorgon fruit based active carbon according to claim 1, it is characterised in that: impregnate required KOH and
The mixture (activator) of KCl can according to circumstances be prepared into solution, so that it is sufficiently impregnated with Gorgon fruit shell particle.
3. the preparation method of Gorgon fruit based active carbon according to claim 1, it is characterised in that: Gorgon fruit shell particle and KOH
With the impregnating ratio of KCl mixture (activator) solution are as follows: (KOH:KCl=3:1,1:1,1:3) quality: Gorgon fruit shell granular mass=
4。
4. the preparation method of Gorgon fruit based active carbon according to claim 1, it is characterised in that: Gorgon fruit shell particle and KOH
Dip time with KCl mixture (activator) solution is 20h.
5. the preparation method of Gorgon fruit based active carbon according to claim 1, it is characterised in that: the Gorgon euryale after impregnating and drying
The carbonization temperature of real shell particle is 800 DEG C.
6. the preparation method of Gorgon fruit based active carbon according to claim 1, it is characterised in that: Gorgon fruit after impregnating and drying
The warming machine of shell particle charing is made as: being warming up to 700 DEG C with the heating mechanism of 5 DEG C/min, then with the heating mechanism liter of 1 DEG C/min
Temperature keeps the temperature 2h to 800 DEG C at such a temperature.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5865748A (en) * | 1981-08-26 | 1983-04-19 | ゼネラル・エレクトリツク・カンパニイ | Composition |
| EP0365850A1 (en) * | 1988-09-28 | 1990-05-02 | Tosoh Corporation | Method for treating an amine-containing waste water |
| CN101780954A (en) * | 2010-01-22 | 2010-07-21 | 核工业西南勘察设计研究院有限公司 | Carbon material with high surface activity and preparation method thereof |
| CN102381703A (en) * | 2011-07-27 | 2012-03-21 | 福建农林大学 | Method for preparing activated carbon by using flax straws |
| CN103408012A (en) * | 2013-08-07 | 2013-11-27 | 江汉大学 | Method for preparing activated carbon from camellia seed waste residues |
| CN104192842A (en) * | 2014-09-27 | 2014-12-10 | 管天球 | Method for preparing walnut shell activated carbon |
-
2017
- 2017-12-07 CN CN201711312210.4A patent/CN109896523A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5865748A (en) * | 1981-08-26 | 1983-04-19 | ゼネラル・エレクトリツク・カンパニイ | Composition |
| EP0365850A1 (en) * | 1988-09-28 | 1990-05-02 | Tosoh Corporation | Method for treating an amine-containing waste water |
| CN101780954A (en) * | 2010-01-22 | 2010-07-21 | 核工业西南勘察设计研究院有限公司 | Carbon material with high surface activity and preparation method thereof |
| CN102381703A (en) * | 2011-07-27 | 2012-03-21 | 福建农林大学 | Method for preparing activated carbon by using flax straws |
| CN103408012A (en) * | 2013-08-07 | 2013-11-27 | 江汉大学 | Method for preparing activated carbon from camellia seed waste residues |
| CN104192842A (en) * | 2014-09-27 | 2014-12-10 | 管天球 | Method for preparing walnut shell activated carbon |
Non-Patent Citations (2)
| Title |
|---|
| 杨莉 等: ""花生壳残渣制备活性炭及吸附性能测定"", 《花生学报》 * |
| 王曙光: ""活性炭材料的结构控制及其超级电容性质"", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
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