CN109882336A - A kind of impulse turbine - Google Patents

A kind of impulse turbine Download PDF

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Publication number
CN109882336A
CN109882336A CN201910178392.3A CN201910178392A CN109882336A CN 109882336 A CN109882336 A CN 109882336A CN 201910178392 A CN201910178392 A CN 201910178392A CN 109882336 A CN109882336 A CN 109882336A
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wall
sound
runner
impulse turbine
water
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CN201910178392.3A
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CN109882336B (en
Inventor
吕文娟
宋文武
石建伟
符杰
黄宗柳
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Xihua University
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Xihua University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/20Hydro energy

Abstract

The invention discloses a kind of impulse turbines, including chassis cavity, chassis cavity outer wall two sides are fixedly connected with casing outer wall, the casing outer wall inner wall side is fixedly connected with sound absorbing layer, sound absorbing layer outer wall side and chassis cavity outer wall are formed with the first sound insulation chamber, the outer wall of the sound absorbing layer outer wall other side and casing outer wall is formed with the second sound insulation chamber, the surrounding of the chassis cavity bottom is fixedly connected with nylon gauze pad, the chassis cavity is internally provided with runner, the runner side is provided with the first water inlet pipe and the second water inlet pipe, the chassis cavity inner hub location is connected with water wheel axle, the water wheel axle outer surface is fixedly connected with runner, second water inlet pipe is fixedly connected with the second jet pipe close to one end of runner, the present invention relates to turbine technology fields.The impulse turbine has achieved the purpose that reduce water flow noise, can reduce the noise of impulse turbine, safeguard the environment of surrounding.

Description

A kind of impulse turbine
Technical field
The present invention relates to turbine technology field, specially a kind of impulse turbine.
Background technique
Impulse turbine is that the free jet with kinetic energy is drawn by means of special water distributor, rushes at runner bucket, Make runner rotation acting, to complete a kind of hydraulic prime mover that water energy is converted into mechanical energy.Impulse turbine is suitable for The power station of high water head, small flow, the water from pressure pipeline is converted to high-speed jet by it after nozzle, tangential impact runner, Runner rotation is pushed, so that generator amature rotation power generation is driven, it is opposite with runner with the jet stream that works in impulse turbine The difference of position and workmanship number, can be divided into tangential wheel, inclined-jet turbine and crossflow turbine, since water flow is Impact, so explosive force is big, the noise generated for environment is also big.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, it the present invention provides a kind of impulse turbine, provides a kind of reduction water flow and makes an uproar The impulse turbine of sound.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of impulse turbine, including machine Shell inner cavity, chassis cavity outer wall two sides are fixedly connected with casing outer wall, and the casing outer wall inner wall side is fixedly connected with Sound absorbing layer, sound absorbing layer outer wall side and chassis cavity outer wall are formed with the first sound insulation chamber, the sound absorbing layer outer wall other side It is formed with the second sound insulation chamber with the outer wall of casing outer wall, the surrounding of the chassis cavity bottom is fixedly connected with nylon gauze pad, institute It states chassis cavity and is internally provided with runner, the runner side is provided with the first water inlet pipe and the second water inlet pipe.
Preferably, the chassis cavity inner hub location is connected with water wheel axle, and the water wheel axle outer surface is fixedly connected There is runner.
Preferably, first water inlet pipe is fixedly connected with the first jet pipe close to one end of runner.
Preferably, second water inlet pipe is fixedly connected with the second jet pipe close to one end of runner.
Preferably, the one end of first water inlet pipe and the second water inlet pipe far from runner is fixed is communicated with water delivery general pipeline.
Preferably, reservoir and tail water slot, the nylon gauze pad outer wall side and reservoir inner wall are provided on the downside of the runner It is flexibly connected.
Preferably, sound-absorbing coating is provided on the sound absorbing layer, the sound-absorbing coating is prepared by sound deadening coating, described The formula of sound deadening coating are as follows: 30~50 parts of EVA resins, 5~8 parts of metal organic framework compound solution, 6~10 parts of polylactic acid.
Preferably, the sound deadening coating the preparation method comprises the following steps: each component is mixed well, then successively carry out ultrasonic vibration Dispersion and microwave concussion dispersion are to get required sound deadening coating.
Preferably, the polylactic acid is nano silica-polylactic acid.
Preferably, the metal organic framework compound solution the preparation method comprises the following steps: metal inorganic salt is dissolved in organic molten In agent, it is to be dissolved completely after, be added organic ligand reaction, after fully reacting, reactant is separated by solid-liquid separation, then solid is answered It is dissolved in identical organic solvent to get required metal organic framework compound solution.
(3) beneficial effect
The present invention provides a kind of impulse turbines.Have it is following the utility model has the advantages that
1, the impulse turbine is fixedly connected with casing outer wall, casing outer wall inner wall by chassis cavity outer wall two sides Side is fixedly connected with sound absorbing layer, and sound absorbing layer outer wall side and chassis cavity outer wall are formed with the first sound insulation chamber, sound absorbing layer outer wall The outer wall of the other side and casing outer wall is formed with the second sound insulation chamber, and the surrounding of chassis cavity bottom is fixedly connected with nylon gauze pad, Chassis cavity is internally provided with runner, and runner side is provided with the first water inlet pipe and the second water inlet pipe, has reached reduction water flow and has made an uproar The purpose of sound, after water impact runner, water flow can splash everywhere, splash on the inner wall of reservoir, since reservoir inner wall is Rigidity, it is easy to generate noise, be close to nylon gauze pad in inner wall surface, nylon gauze pad is that have many mesh, can be evacuated Water flow reduces the sound that water flow directly impacts rigid material, and the service life of nylon gauze pad is long, and chassis cavity can make an uproar to water flow Sound carries out preliminary isolation, and for noise transmission at sound absorbing layer inner wall, sound-absorbing layer material is that have many sound-absorption holes, to sound into The reflection of row repeatedly, achievees the purpose that noise reduction, and wherein casing outer wall plays one in the external world and protects to sound absorbing layer, carries out to noise The effect being further isolated, the first sound insulation chamber and the second sound insulation chamber are the mesh for using air as acoustic isolation medium and realizing auxiliary noise , the noise of impulse turbine can be reduced, safeguards the environment of surrounding.
2, it the present invention also provides a kind of sound deadening coating that sound-absorbing effect is excellent, can further help to reduce impact type water The noise of turbine.After sound wave enters in the hole of material, sound can be gradually converted into thermal energy, to reach the effect of sound-absorbing (noise reduction) Fruit, material of the general acoustic absorptivity greater than 0.2 may be used as sound-absorbing material.There are a large amount of holes, holes inside this kind of material requirements Gap is tiny and uniform in material internal difference, while requiring to be interconnected between each hole.The suction of sound deadening coating provided by the invention Sonic system number is up to 0.88, excellent sound absorbing.
3, metal-organic framework materials have been used in sound deadening coating provided by the invention.Metal-organic framework materials are a kind of Novel porous materials, porosity height, large specific surface area, have more research in terms of storing with transport agent at present, but without Any application by sound-absorbing.Meanwhile metal organic framework solid material is difficult to be uniformly dispersed in a solvent, and makes after mixing Standby sol solution (silica solution such as in the prior art) can not be attached to the body surface of required film well, attach reliability It is low, it is difficult to directly as the component of sound deadening coating or sound deadening coating carry out using.The present invention provides several new metals are organic Framework material and preparation method, and creatively use EVA resin as paint-based bottom, it is shaken and is divided jointly using ultrasound and microwave Scattered mode ensure that the dispersing uniformity of metal-organic framework materials in the substrate, and the coating adhesion finally obtained is excellent, Sound-absorbing effect is excellent.
4, nano silica-polylactic acid has been used in sound deadening coating provided by the invention.Nano silica partial size is small, Large specific surface area is easy to reunite, if be directly appended in polylactic acid, does not simply fail to enhance its comprehensive performance, can make it instead Performance decline.In addition, nano-silica surface has active silicone hydroxyl, is connected between adjacent hydroxyl groups with hydrogen bond, be easy to elecrtonegativity Atom mutually adsorb so that silica surface is hydrophilic, it is difficult to be uniformly dispersed in organic phase.Therefore, it is necessary to first to nanometer two Silica is modified.The present invention is modified nano silica while preparing polylactic acid, in SnCl2Catalysis Under, silica, silane coupling agent, lactide and toluene react jointly, disperse in polylactic acid in guarantee silica Uniformity in the case where, also improve the performance of polylactic acid itself.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention;
Fig. 2 is partial structural diagram of the present invention.
In figure: 1 chassis cavity, 2 casing outer walls, 3 sound absorbing layers, 4 first sound insulation chambers, 5 second sound insulation chambers, 6 nylon gauze pads, 7 Water wheel axle, 8 runners, 9 water delivery general pipeline, 10 first water inlet pipes, 11 first jet pipes, 12 second water inlet pipes, 13 second jet pipes, 14 tail water Slot, 15 reservoirs.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution referring to FIG. 1-2: a kind of impulse turbine, including chassis cavity 1, machine 1 outer wall two sides of shell inner cavity are fixedly connected with casing outer wall 2, and 2 inner wall side of casing outer wall is fixedly connected with sound absorbing layer 3, sound absorbing layer 3 Outer wall side and 1 outer wall of chassis cavity are formed with the first sound insulation chamber 4, the outer wall shape of the sound absorbing layer 3 outer wall other side and casing outer wall 2 At there is the second sound insulation chamber 5, the surrounding of 1 bottom of chassis cavity is fixedly connected with nylon gauze pad 6, and chassis cavity 1, which is internally provided with, to be turned Wheel 8,8 side of runner is provided with the first water inlet pipe 10 and the second water inlet pipe 12, has achieved the purpose that reduce water flow noise.
1 inner hub location of chassis cavity is connected with water wheel axle 7, and 7 outer surface of water wheel axle is fixedly connected with runner 8, impact The fixed structure of the formula hydraulic turbine.
First water inlet pipe 10 is fixedly connected with the first jet pipe 11 close to one end of runner 8, enhances the impact force of water flow.
Second water inlet pipe 12 is fixedly connected with the second jet pipe 13 close to one end of runner 8, enhances the impact force of water flow.
The one end of first water inlet pipe 10 and the second water inlet pipe 12 far from runner 8 is fixed to be communicated with water delivery general pipeline 9, carries out unification Water inlet.
Reservoir 15 and tail water slot 14 are provided on the downside of runner 8,6 outer wall side of nylon gauze pad and 15 inner wall activity of reservoir connect It connects, forms compatible environment.
In use, water flow can splash everywhere, on the inner wall for splashing reservoir 15, due to water after water impact runner 8 15 inner wall of library is rigid, it is easy to be generated noise, is close to nylon gauze pad 6 in inner wall surface, nylon gauze pad 6 is that have many nets Hole can evacuate water flow, the sound that water flow directly impacts rigid material be reduced, and the service life of nylon gauze pad 6 is long, in casing Chamber 1 can carry out preliminary isolation to water flow noise, and for noise transmission at 3 inner wall of sound absorbing layer, 3 material of sound absorbing layer has many suctions Sound hole carries out reflection repeatedly to sound, achievees the purpose that noise reduction, wherein casing outer wall 2 plays one to sound absorbing layer 3 in the external world Protection, to the effect that noise is further isolated, the first sound insulation chamber 4 and the second sound insulation chamber 5 are to use air as sound insulation Jie Matter realizes the purpose of auxiliary noise, can reduce the noise of impulse turbine.
Preferred scheme are as follows: use special porous sound absorbing coating as sound-absorbing material on the sound absorbing layer 3.The sound-absorbing Coating is formed by porous sound absorbing coating preparation.The formula of the sound deadening coating are as follows: 30~50 parts of EVA resins, 5~8 parts of metals have Machine framework compound solution, 6~10 parts of polylactic acid.
Wherein, described, metal organic framework compound solution the preparation method comprises the following steps: metal inorganic salt is dissolved in organic solvent In, it adds organic ligand and is reacted, product is separated by solid-liquid separation after the reaction was completed, solid is again dissolved in organic solvent In to get required metal organic framework compound solution.In embodiment provided by the invention, organic solvent is specially ethyl alcohol.
The polylactic acid is preferably nano silica-polylactic acid.The nano silica is easy to reunite, it is difficult to disperse Uniformly, therefore when preparing nano silica-polylactic acid, also nano silica is modified simultaneously.Method particularly includes: By 1 part of nano grade silica particles, 0.3~0.6 part of silane coupling agent (KH-550), 0.2~0.5 part of SnCl2, 25~30 part third Lactide is dissolved in 280~320 parts of toluene, after mixing, is heated to 165 DEG C, is reacted 16h, after complete reaction, natural cooling is right Reactant is separated by solid-liquid separation, and the solid matter of acquisition is dissolved in acetone, is prepared as 8% solution, then into the solution by Deionized water is gradually added, the volume of the deionized water of addition is 6 times of the liquor capacity, and floccule is precipitated;It isolates cotton-shaped Object, then be washed with deionized 3~5 times, vacuum drying is at 45 DEG C to get the nano silica-polylactic acid.
Below with reference to specific embodiment, the preparation method and effect of sound deadening coating are further explained.
Embodiment one: influence of the metal organic framework compound to sound deadening coating performance
1,5 groups of sound deadening coatings, the formula of each group sound deadening coating are as follows: 32 parts of EVA resins, 6 parts of organic bones of metal are prepared Frame compound solution, 8 parts of polylactic acid.Each component is mixed well, the ultrasonic vibration 10min at 22kHz, then at 2450MHz Microwave shakes 10min to get each group sound deadening coating.Using pure EVA resin, as blank control group;The organic bone of metal is not added Frame compound solution, using 32 parts of EVA resins and 12 parts of polylactic acid, as positive controls.
Wherein, the polylactic acid the preparation method comprises the following steps: by 1 part of nano grade silica particles, 0.5 part of silane coupling agent, 0.3 Part SnCl2, 28 parts of lactides be dissolved in 300 parts of toluene, after mixing, be heated to 165 DEG C, react 16h, after complete reaction, from It is so cooling, reactant is separated by solid-liquid separation, the solid matter of acquisition is dissolved in acetone, is prepared as 8% solution, then to this Deionized water is gradually added into solution, the volume of the deionized water of addition is 6 times of the liquor capacity, and floccule is precipitated;Point Floccule is separated out, then is washed with deionized 3 times, vacuum drying is at 45 DEG C to get the poly- cream of the nano silica- Acid.
The specific preparation parameter of the metal organic framework compound solution is as shown in table 1.The metal inorganic salt is molten In ethyl alcohol, it is to be dissolved completely after, the organic ligand is added, is warming up to required temperature, ultrasonic vibration reaction, fully reacting Afterwards, reactant is separated by solid-liquid separation, then solid redissolution is molten to get required metal organic framework compound in ethyl alcohol Liquid;When redissolution, the quality of ethyl alcohol is 10 times that reaction generates solid masses.
1 design parameter of table shows table
2, each group coating is prepared as to the coating of 0.2mm thickness using czochralski method, is absorbed sound after dry using Reverberation room method detection Coefficient, general acoustic absorptivity > 0.2 are regarded as sound-absorbing material.In addition each group coating is applied to 5cm × 5cm × 0.3cm respectively Steel plate on, at room temperature dry 2h, formed 0.2mm thickness coating.Each group steel plate is soaked in 0.5h in water, it is apparent to take out observation Character.
Each group effect is as shown in table 2.
2 each group acoustic absorptivity of table is shown
Group Acoustic absorptivity Waterproofness
Group 1 0.88 Bubble-free, peeling, cracking
Group 2 0.62 Bubble-free, peeling, cracking
Group 3 0.43 Bubble-free, peeling, cracking
Group 4 0.54 Bubble-free, peeling, cracking
Group 5 0.59 Bubble-free, peeling, cracking
Positive controls 0.32 Bubble-free, peeling, cracking
Blank control group 0.13 Bubble-free, peeling, cracking
Embodiment two: influence of the polylactic acid to sound deadening coating performance
1, in addition to the preparation of polylactic acid, 12 groups of sound deadening coatings are prepared using one group 1 of embodiment of method, wherein each group is inhaled Polylactic acid prepares as shown in table 3 in sound coating, and the numerical value in table refers to the parts by weight of the component.Using pure EVA resin, as Blank control group;Polylactic acid is not added, using 32 parts of EVA resins and 10 parts of metal organic framework compound solution, as the positive Control group.
3 design parameter of table shows table
2, effect detection is carried out to each group by the method for embodiment one, the results are shown in Table 4.
4 effect of table is shown
Group Acoustic absorptivity Waterproofness
Group 1 0.33 Bubble-free, peeling, cracking
Group 2 0.87 Bubble-free, peeling, cracking
Group 3 0.65 Bubble-free, peeling, cracking
Group 4 0.61 Bubble-free, peeling, cracking
Group 5 0.43 Bubble-free, peeling, cracking
Group 6 0.62 Bubble-free, peeling, cracking
Group 7 0.68 Bubble-free, peeling, cracking
Group 8 0.31 Bubble-free, peeling, cracking
Group 9 0.69 Bubble-free, peeling, cracking
Group 10 0.72 Bubble-free, peeling, cracking
Group 11 0.73 Bubble-free, peeling, cracking
Group 12 0.69 Bubble-free, peeling, cracking
Positive controls 0.35 Bubble-free, peeling, cracking
Blank control group 0.12 Bubble-free, peeling, cracking
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions.By sentence " element limited including one ..., it is not excluded that There is also other identical elements in the process, method, article or apparatus that includes the element ".
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (10)

1. a kind of impulse turbine, including chassis cavity (1), it is characterised in that: chassis cavity (1) the outer wall two sides are fixed It is connected with casing outer wall (2), casing outer wall (2) the inner wall side is fixedly connected with sound absorbing layer (3), and the sound absorbing layer (3) is outside Wall side and chassis cavity (1) outer wall are formed with the first sound insulation chamber (4), sound absorbing layer (3) the outer wall other side and casing outer wall (2) outer wall is formed with the second sound insulation chamber (5), and the surrounding of chassis cavity (1) bottom is fixedly connected with nylon gauze pad (6), The chassis cavity (1) is internally provided with runner (8), runner (8) side be provided with the first water inlet pipe (10) and second into Water pipe (12).
2. a kind of impulse turbine according to claim 1, it is characterised in that: chassis cavity (1) inside center Position is connected with water wheel axle (7), and water wheel axle (7) outer surface is fixedly connected with runner (8).
3. a kind of impulse turbine according to claim 1, it is characterised in that: first water inlet pipe (10) is close to be turned One end of wheel (8) is fixedly connected with the first jet pipe (11).
4. a kind of impulse turbine according to claim 1, it is characterised in that: second water inlet pipe (12) is close to be turned One end of wheel (8) is fixedly connected with the second jet pipe (13).
5. a kind of impulse turbine according to claim 1, it is characterised in that: first water inlet pipe (10) and second Water inlet pipe (12) is communicated with water delivery general pipeline (9) far from one end fixation of runner (8).
6. a kind of impulse turbine according to claim 1, it is characterised in that: be provided with water on the downside of the runner (8) Library (15) and tail water slot (14), nylon gauze pad (6) the outer wall side are flexibly connected with reservoir (15) inner wall.
7. a kind of impulse turbine according to claim 1, it is characterised in that: be provided with suction on the sound absorbing layer (3) Sound coating, the sound-absorbing coating are prepared by sound deadening coating, the formula of the sound deadening coating are as follows: 30~50 parts of EVA resins, 5 ~8 parts of metal organic framework compound solution, 6~10 parts of polylactic acid.
8. a kind of impulse turbine according to claim 7, it is characterised in that: the preparation method of the sound deadening coating Are as follows: each component is mixed well, carries out ultrasonic vibration dispersion and microwave concussion dispersion successively then to get required sound deadening coating.
9. a kind of impulse turbine according to claim 7, it is characterised in that: the polylactic acid is nanometer titanium dioxide Silicon-polylactic acid.
10. a kind of impulse turbine according to claim 7, it is characterised in that: the metal organic framework compound Solution the preparation method comprises the following steps: metal inorganic salt is dissolved in organic solvent, it is to be dissolved completely after, organic ligand reaction is added, instead After answering completely, reactant is separated by solid-liquid separation, then solid redissolution is had in identical organic solvent to get required metal Machine framework compound solution.
CN201910178392.3A 2019-03-11 2019-03-11 Impulse turbine Active CN109882336B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2256933Y (en) * 1995-03-23 1997-06-25 北京当代复合材料有限公司 Silencer casing
CN2383036Y (en) * 1999-06-17 2000-06-14 淄博电力实业总公司 Water showering silencer
CN101379068A (en) * 2006-02-10 2009-03-04 巴斯夫欧洲公司 Process for preparing porous organic framework materials
CN101519526A (en) * 2008-10-10 2009-09-02 兰州理工大学 Method for preparing polylactic acid/nanometer silicon dioxide composite material
CN201963451U (en) * 2011-02-28 2011-09-07 重庆云河水电股份有限公司 Negative-pressure breaking device for base of impacting type water turbine
CN202360284U (en) * 2011-10-29 2012-08-01 湖南零陵恒远发电设备有限公司 Double-layer enclosure for impulse turbine
US20140213832A1 (en) * 2013-01-31 2014-07-31 Basf Se Stable Spherical, Porous Metal-Organic Framework Shaped Bodies For Gas Storage And Gas Separation
CN106875934A (en) * 2017-03-30 2017-06-20 歌尔股份有限公司 Metal organic frame sound-absorbing part and sound-producing device module
WO2018036997A1 (en) * 2016-08-23 2018-03-01 Basf Se Composite materials

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2256933Y (en) * 1995-03-23 1997-06-25 北京当代复合材料有限公司 Silencer casing
CN2383036Y (en) * 1999-06-17 2000-06-14 淄博电力实业总公司 Water showering silencer
CN101379068A (en) * 2006-02-10 2009-03-04 巴斯夫欧洲公司 Process for preparing porous organic framework materials
CN101519526A (en) * 2008-10-10 2009-09-02 兰州理工大学 Method for preparing polylactic acid/nanometer silicon dioxide composite material
CN201963451U (en) * 2011-02-28 2011-09-07 重庆云河水电股份有限公司 Negative-pressure breaking device for base of impacting type water turbine
CN202360284U (en) * 2011-10-29 2012-08-01 湖南零陵恒远发电设备有限公司 Double-layer enclosure for impulse turbine
US20140213832A1 (en) * 2013-01-31 2014-07-31 Basf Se Stable Spherical, Porous Metal-Organic Framework Shaped Bodies For Gas Storage And Gas Separation
WO2018036997A1 (en) * 2016-08-23 2018-03-01 Basf Se Composite materials
CN106875934A (en) * 2017-03-30 2017-06-20 歌尔股份有限公司 Metal organic frame sound-absorbing part and sound-producing device module

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