CN109881233A - A kind of preparation method of aluminum alloy curtain walls - Google Patents
A kind of preparation method of aluminum alloy curtain walls Download PDFInfo
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- CN109881233A CN109881233A CN201910272830.2A CN201910272830A CN109881233A CN 109881233 A CN109881233 A CN 109881233A CN 201910272830 A CN201910272830 A CN 201910272830A CN 109881233 A CN109881233 A CN 109881233A
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- aluminum alloy
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Abstract
The present invention provides a kind of production method of aluminum alloy curtain walls, and 0.3 ~ 0.5 μm of surface roughness Ra, Rz1.4 ~ 2.4 μm, same roughness Ra difference≤0.1 μm for rolling up upper any position, the aluminum alloy coiled materials of difference≤0.6 μm Rz are made first;Then by aluminium coiled material through rolling anodic oxidation production line continuous anodic oxidation, and it is directly cut to after anodic oxidation the curtain wall panel of required scale lengths.Direct cutting plate after coiled material anode of the present invention, production process surface contusion defect is few, and qualification rate is high and reduces production cost;And after control rough overshoot and internal grain, it is effectively ensured without glossiness and presentation quality after the anodic oxidation under chemical polishing processing.Make present invention production is lower to have the characteristics that high-efficient, at low cost, presentation quality is uniform and stable, has broad application prospects.
Description
Technical field
The invention belongs to the preparation fields of construction material, and in particular to a kind of production method of aluminum alloy curtain walls.
Background technique
With the rapid expansion in city, high buildings and large mansions are in a compact mass, and the exterior wall cleaning of skyscraper annoyings each object always
Industry management company: using glass outer wall, is easy pollution;Building load is significantly increased in glittering and translucent marble;Traditional plastic-aluminum is multiple
There is kindling hidden danger in plywood.So gradually begin to use in the market anticorrosion, it is durable, bear dirty, the sun that light weight and environmental protection are beautiful
Pole aoxidizes curtain wall.
In existing aluminium alloy curtain wall board fabrication method, as patent CN105177328 A discloses a kind of curtain wall aluminium
Sheet alloy manufacture craft is made after anode using die-casting process and obtains the good curtain wall aluminum alloy plate materials of durability, but piece
Material production efficiency is low, simultaneously because it is produced using die-casting process, color difference is easy to appear under low temperature anode, therefore surface sophistication is not
It is good;On the other hand, sheet material anode will also be possible to occur changing because of anode parameter between batch or tank liquor concentration, cause color difference difference,
Seriously affect the color difference consistency of appearance.Patent CN105040064A discloses a kind of preparation method of novel aluminum alloy, leads to
Cross chemical polishing processing before anode and obtain expected low surface roughness, thus guarantee anode oxide film at film uniformity, be
The high gloss of its anode oxide film is improved, aluminium increases electrophoretic process technique, but the process chemistry after anodic oxidation
Polishing and electrophoretic process time are long, and roughness is unstable, extend the production time and influence efficiency, while changing and throwing liquid and electrophoresis groove liquid
Discharge is the factor that adversely ball is protected.
Summary of the invention
The object of the present invention is to provide a kind of opposite conventional anodization Aluminum curtain wall plate high production efficiency, anodic oxidation
The production method of the more environmentally protective curtain wall aluminum alloy sheets and strips of process can inexpensive, quickly, environmentally friendlyly produce
The stable curtain wall product of anode appearance quality out.
To achieve the above object, the technical solution under the present invention is:
A kind of production method of aluminum alloy curtain walls, specific steps are as follows:
1) after semi-continuous casting, the big plate ingot for meeting curtain wall and using of acquisition, ingot casting ingredient according to the intensity that finally uses and
Appearance configuration;
2) surface roughness is obtained after necessary sawing, milling face, homogenization, hot rolling, cold rolling, heat treatment and cold rolling after
Within Ra0.3 ~ 0.5 μm, Rz1.4 ~ 2.4 μm, same roughness Ra difference≤0.1 μm for rolling up upper any position, Rz difference≤0.6 μ
M, length-width ratio≤2 of surface microscopic crystal grain, the aluminum alloy coiled materials of 900 ~ 2300mm of width;
3) above-mentioned coiled material is produced on continuous coiled material anodic oxidation production line, the preparatory alkali cleaning of aluminium, then in anode tank liquor
Electrochemical reaction occurs as the cathode being continuously arranged on the anode of electrode, with machine column, and ultimately forms fine and close anodic oxidation
Film, the curtain wall panel products of size needed for then cutting plate is made after drying;
Dirty in order to remove surface in step 3), the alkali cleaning time is 10 ~ 90s, preferably 20 ~ 50s, and in order to quickly be formed enough
The anode oxidation membrane of thickness, anode tank liquor temperature need to be controlled at 3 ~ 10 DEG C, guarantee low temperature anodic oxygen erosion consumption effect
Rate reduces, and preferably 5 ~ 8 DEG C;And control 1 ~ 2.0A/dm of current density2, it is therefore intended that the consistency for improving anode micro porous guarantees to make
With the corrosion resistance of process Anodic Oxide Film, preferably 1.2 ~ 1.3A/dm2, and cooperate the reasonable machine column speed of 10 ~ 50m/min
Production;
Remarkable advantage of the invention is:
(1) the aluminum alloy curtain walls preparation method under the present invention is compared with conventional curtain wall plate preparation method, due to surface roughness
The control of Ra value is moderate, dampens seldom, improves caused by the surface intercalated dislocation of product after substrate manufacturing process and anodic oxidation
The stability of surface quality and final qualification rate;And the directly life of cutting plate acquisition final products after being produced by continuous anodic oxidation
Production mode is greatly shortened production process, further improves overall acceptability rate, is conducive to continue to reduce production cost.
(2) pass through the length-width ratio of control Rz value and aluminum substrate internal grain, the gloss of the oxidation film after promoting product anode
Degree and uniformity make the product under the present invention under conditions of without chemical polishing, obtain with low surface roughness aluminium through short
When chemical polishing after the anode appearance after anodic oxidation again after anodic oxidation or general roughness aluminium through a long time chemical polishing
Effect is suitable, more environmentally-friendly efficient;
(3) present invention is due to using directly cutting plate after coiled material continuous anodic oxidation to obtain finished product, Opposite blade anode production efficiency
Significant increase is obtained, energy-saving and environmental protection of the present invention, presentation quality are excellent, have a vast market foreground.
Detailed description of the invention
The anode appearance effect of product under Fig. 1 present invention;
The anode appearance effect of product under Fig. 2 comparative example.
Specific embodiment
Further to disclose without limiting the present invention, invention herein is described in further detail below in conjunction with example.
Embodiment 1
A kind of production method of aluminum alloy curtain walls uses low liquid level casting technology that specification is made as 650 × 1350 × 8000mm
Big plate ingot, alloying component are as follows: as mass fraction, Si0.12%, Fe0.35%, Cu0.1%, Mn0.05%, Mg0.5%, Cr0.1,
Zn0.2%, remaining is inevitably rolling and Al.Ingot casting is placed in after sawing 400mm end to end and upper and lower surface milling face 20mm
Homogenizing annealing in heating furnace, annealing schedule are 500 DEG C of heat preservation 10h, and the hot rolling blank of 5.0mm, base are made after subsequent hot rolling
Expect camber 0.5%.
The process route of cold rolling section is as follows: 5.0-3.0-2.0- heat treatment -1.5.
The rolling reduction of finished product cold rolling pass is 25%, and heat treating regime is 340 DEG C/2h, the product surface of cold rolling finished product
0.35 μm of roughness Ra, Rz1.8 μm, the Ra difference of any position is 0.1 μm, and Rz difference is 0.6 μm, surface microscopic crystal grain length and width
Than being 2.
Above-mentioned coiled material is produced on anodic oxidation production line, under speed of production 30m/min, alkali cleaning time 20s, tank liquor temperature
10 DEG C of degree, current density 1.5A/dm2, product 20 μm of oxidation film film thickness after anode, through sealing of hole and drying after, be cut into 2440mm
The plate of length, surface gloss 156Gu, bad lost length 120m, can meet the actual use demand of skyscraper end to end.
Embodiment 2
A kind of production method of aluminum alloy curtain walls uses low liquid level casting technology that specification is made as 520 × 1700 × 6000mm
Big plate ingot, alloying component are as follows: as mass fraction, Si0.3%, Fe0.7%, Cu0.05%, Mn0.2%, Mg1.1%, Cr0.02,
Zn0.11%, remaining is inevitably rolling and Al.Ingot casting is placed in after sawing 300mm end to end and upper and lower surface milling face 15mm
Homogenizing annealing in heating furnace, annealing schedule are 450 DEG C of heat preservation 20h, and the hot rolling blank of 10.0mm, heat are made after subsequent hot rolling
Rolling stock camber 0.2%.
The process route of cold rolling section is as follows: 10.0-7.0- heat treatment -6.0.
The rolling reduction of finished product cold rolling pass is 14%, and heat treating regime is 340 DEG C/2h, the product surface of cold rolling finished product
0.5 μm of roughness Ra, Rz2.4 μm, the Ra difference of any position is 0.05 μm, and Rz difference is 0.4 μm, surface microscopic crystal grain length and width
Than being 1.5.
Above-mentioned coiled material is produced on anodic oxidation production line, under speed of production 10m/min, alkali cleaning time 80S, tank liquor temperature
5 DEG C of degree, current density 1.0A/dm2, product 50 μm of oxidation film film thickness after anode, after sealing of hole and drying, being cut into length is
The plate of 1200mm long, surface gloss 180Gu, bad lost length 150m can meet the actual use need of skyscraper end to end
It asks.
Embodiment 3
A kind of production method of aluminum alloy curtain walls uses low liquid level casting technology that specification is made as 560 × 1400 × 3600mm
Big plate ingot, alloying component are as follows: as mass fraction, Si0.05%, Fe0.08%, Cu0.02%, Mn0.08%, Mg0.9%,
Cr0.03, Zn0.05%, remaining is inevitably rolling and Al.Ingot casting mills face 10mm through sawing 200mm end to end and upper and lower surface
Afterwards, it is placed in homogenizing annealing in heating furnace, annealing schedule is 530 DEG C of heat preservation 4h, and the hot rolling base of 8.0mm is made after subsequent hot rolling
Material, hot rolling blank camber 1.0%.
The process route of cold rolling section is as follows: 8.0-5.0-2.8- heat treatment -2.0.
The rolling reduction of finished product cold rolling pass is 29%, and heat treating regime is 340 DEG C/2h, the product surface of cold rolling finished product
0.30 μm of roughness Ra, Rz1.4 μm, the Ra difference of any position is 0.06 μm, and Rz difference is 0.2 μm, and surface microscopic crystal grain is long
Wide ratio is 1.3.
Above-mentioned coiled material is produced on anodic oxidation production line, under speed of production 50m/min, alkali cleaning time 30s, tank liquor temperature
8 DEG C of degree, current density 1.2A/dm2, product 45 μm of oxidation film film thickness after anode, through sealing of hole and drying after, be cut into 3600mm long
Material, surface gloss 182Gu, bad lost length 128m can meet the actual use demand of skyscraper end to end, anode effect
Fruit is as shown in Figure 1.
Comparative example 1
The aluminum alloy curtain walls of domestic certain aluminium manufacturer production, use low liquid level casting technology that big plate ingot is made, alloying component meets
The regulation of 5005 alloys in GB3190, ingot casting obtain the hot rolling blank of sotck thinkness 5.0mm after milling face, heating and hot rolling,
The process route of cold rolling section is as follows:
5.0-3.0-2.0- finished products
The product surface roughness of cold rolling finished product is not controlled and is required, and surface microscopic crystal grain strip is Filamentous.It is carried out after its cutting plate
60S chemical polishing (pollution environment and injury operator's body), 25 μ of anode oxide film film thickness is made in then anodic oxidation again
M, the curtain wall panel of surface gloss 140Gu, end to end and process dampens bad lost length 180m or more, can only be used as general curtain
Wall outside plate uses.
Comparative example 2
The aluminum alloy curtain walls of domestic certain aluminium manufacturer production, use low liquid level casting technology that big plate ingot is made, alloying component meets
The regulation of 5005 alloys in GB3190, ingot casting obtain the hot rolling blank of sotck thinkness 8.0mm after milling face, heating and hot rolling,
The process route of cold rolling section is as follows:
8.0-5.0- heat treatment -3.0
The product surface roughness of cold rolling finished product is not controlled and is required, surface microscopic crystal grain length-width ratio 4.0.Through acid after its cutting plate
The curtain wall panel of 25 μm of anode oxide film film thickness, surface gloss 110Gu is made, end to end and mistake in alkali cleaning, then anodic oxidation again
Journey dampens bad lost length 180m or more, can only be used as general curtain wall outside plate and use, anode effect is as shown in Figure 2.
Used herein a specific example illustrates the principle and implementation of the invention, and above embodiments are said
It is bright to be served only for facilitating the understanding of the method and its core concept of the invention.It should be pointed out that for the ordinary skill people of the art
Member for, without departing from the principle of the present invention, can with several improvements and modifications are made to the present invention, these improve and
Modification is also fallen within the protection scope of the claims of the present invention.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, is all covered by the present invention.
Claims (5)
1. a kind of production method of aluminum alloy curtain walls, which comprises the following steps:
1) aluminium base: the big plate ingot that will be obtained through semi-continuous casting is made, through necessary sawing, milling face, homogenization, hot rolling, cold
Roll, be heat-treated and cold rolling after, obtain Ra0.3 ~ 0.5 μm, Rz1.4 ~ 2.4 μm, with roll up the roughness Ra difference of upper any position≤
0.1 μm, difference≤0.6 μm Rz, length-width ratio≤2 of surface microscopic crystal grain, the aluminum alloy coiled materials of 900 ~ 2300mm of width;
2) production of curtain wall aluminium plate product: above-mentioned coiled material is produced on continuous coiled material anodic oxidation production line, anode time root
Increase and decrease according to the thickness requirement of anode oxide film, the cutting plate after necessary drying of the product after anodic oxidation, size needed for obtaining
The product of specification.
2. a kind of production method of aluminum alloy curtain walls according to claim 1, it is characterised in that: hot rolling described in step 1)
Blank camber≤1.0% afterwards, roll for cold rolling surface roughness Rz1.5 ~ 2.0 μm.
3. a kind of production method of aluminum alloy curtain walls according to claim 1, it is characterised in that: step 2 anodic oxidation
It is preceding to be not necessarily to carry out chemical polishing processing to aluminium.
4. a kind of production method of aluminum alloy curtain walls according to claim 1, it is characterised in that: step 2 anodic oxidation
Temperature be 3 ~ 10 DEG C, 12 ± 3V of voltage, 1.0 ~ 2.0A/dm of electric current2。
5. a kind of production method of aluminum alloy curtain walls according to claim 1, it is characterised in that: sun described in step 2
Pole aoxidizes in flowchart process, 10 ~ 50m/min of machine column speed;20 μm of anodic oxidation film thickness or more after anode.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030057100A1 (en) * | 2001-09-27 | 2003-03-27 | Yar-Ming Wang | Method of producing bright anodized finishes for high magnesium, aluminum alloys |
JP2008095165A (en) * | 2006-10-16 | 2008-04-24 | Ykk Ap株式会社 | Aluminum material or aluminum alloy material, and building material product using the same |
CN106435684A (en) * | 2016-08-31 | 2017-02-22 | 佛山市南海双成金属表面技术有限公司 | Aluminum coil non-contact continuous anodizing technique |
CN106906390A (en) * | 2017-03-28 | 2017-06-30 | 山东南山铝业股份有限公司 | Aluminium alloy anode oxide plate and its production method |
CN109207805A (en) * | 2018-11-28 | 2019-01-15 | 中铝瑞闽股份有限公司 | A kind of preparation method of curtain wall aluminium alloy strips |
-
2019
- 2019-04-04 CN CN201910272830.2A patent/CN109881233B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030057100A1 (en) * | 2001-09-27 | 2003-03-27 | Yar-Ming Wang | Method of producing bright anodized finishes for high magnesium, aluminum alloys |
JP2008095165A (en) * | 2006-10-16 | 2008-04-24 | Ykk Ap株式会社 | Aluminum material or aluminum alloy material, and building material product using the same |
CN106435684A (en) * | 2016-08-31 | 2017-02-22 | 佛山市南海双成金属表面技术有限公司 | Aluminum coil non-contact continuous anodizing technique |
CN106906390A (en) * | 2017-03-28 | 2017-06-30 | 山东南山铝业股份有限公司 | Aluminium alloy anode oxide plate and its production method |
CN109207805A (en) * | 2018-11-28 | 2019-01-15 | 中铝瑞闽股份有限公司 | A kind of preparation method of curtain wall aluminium alloy strips |
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