CN109879537A - Water quality monitoring purification method - Google Patents

Water quality monitoring purification method Download PDF

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Publication number
CN109879537A
CN109879537A CN201910201280.5A CN201910201280A CN109879537A CN 109879537 A CN109879537 A CN 109879537A CN 201910201280 A CN201910201280 A CN 201910201280A CN 109879537 A CN109879537 A CN 109879537A
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China
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water
monitored
water source
biosensor
water quality
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CN201910201280.5A
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Chinese (zh)
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刘莉娜
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Tianjin Yu Chi Testing Technology Co Ltd
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Tianjin Yu Chi Testing Technology Co Ltd
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  • Water Treatment By Sorption (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Activated Sludge Processes (AREA)

Abstract

The present invention relates to a kind of water quality monitoring purification methods according to sequencing the following steps are included: step (1): different biosensors is arranged in needing the water source monitored and is monitored to the harmful components in water source, water source sample is periodically taken by triolein SPMD method, the pathogen in water is monitored using PCR detection method;Step (2): the water source parameter detected according to step (1), to sequentially adding flocculant and biological adsorption agent in water source;Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter when being reduced to the half of First Determination, water treatment agent is added.The present invention is monitored water quality using Measurement for Biotechnique, have the advantages that environmentally protective and secondary pollution will not be caused to environment, preliminary purification is carried out to water quality by biological adsorption agent and microbial flocculant again, advanced treating is carried out by water treatment agent again, there is at low cost, environmental-friendly and treatment effect clear advantage.

Description

Water quality monitoring purification method
Technical field
The invention belongs to water quality monitorings and purification techniques field, and in particular to a kind of water quality monitoring purification method.
Background technique
Water quality monitoring is type, the concentration and variation tendency of each pollutant of pollutant in monitoring and measurement water body, comments The process of valence water quality condition.Monitoring range is very extensive, including is not contaminated and contaminated natural water (river, river, lake, sea And underground water) and various industrial water drainages etc..Main monitoring project can be divided into two major classes: one kind is reflection water quality condition Overall target, such as temperature, coloration, turbidity, pH value, conductivity, suspended matter, dissolved oxygen, COD and biochemical oxygen demand (BOD); Another kind of is some noxious materials, such as phenol, cyanogen, arsenic, lead, chromium, cadmium, mercury and organic agricultural chemicals.For objective appraisal rivers and sea The situation of foreign-water matter needs the measurement for carrying out flow velocity and flow in addition to above-mentioned monitoring project sometimes.
Currently, China's water environment water quality monitoring technology achieves the development of fast speed, current China's water quality monitoring technology Mainly based on physical and chemical monitoring technology, including chemical method, electrochemical process, atomic absorption spectrophotometry, ion selective electrode method, The chromatography of ions, gas chromatography, plasma emission spectroscopy (ICP-AES) method etc..Wherein, ion selective electrode method is (fixed Property, it is quantitative), also universal quilt in chemical method (gravimetric method, volumetric precipitation method and spectrophotometry) water quality routine monitoring at home and abroad Using.Biological monitoring in recent years, remote sensing monitoring technology have been also applied in water quality monitoring.
And currently used water quality monitoring and processing mainly pass through physical processing techniques and chemical treatment method, and in object Reason processing technique can not advanced treating water body and chemical treatment method may bring the risk of secondary environmental pollution.
Summary of the invention
To solve problems of the prior art, the present invention provides a kind of water quality monitoring purification method, according to successively suitable Sequence the following steps are included:
Step (1): different biosensors is set in needing the water source monitored, the harmful components in water source is carried out Monitoring is periodically taken water source sample by triolein SPMD method, is supervised using PCR detection method to the pathogen in water It surveys;
Step (2): the water source parameter detected according to step (1), to sequentially adding flocculant and biological adsorption in water source Agent;
Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter be reduced to and survey for the first time When fixed half, water treatment agent is added.
Preferably, in step (1), the concrete operations of triolein SPMD method are as follows: at sampler under water 1m Fixed, lasting 5d, then withdraws sampler under water.
In any of the above-described scheme preferably, in step (1), the biosensor includes: heavy metal biological sensing Device, BOD biosensor, ammonia biosensor, nitrous acid biosensor, Alcohol Biosensor, methane biosensor With bacteria concentration biosensor.
In any of the above-described scheme preferably, in step (3), the water treatment agent includes each component of following number: 20-25 parts of diatomite, 15-20 parts of ferric trichloride, 20-30 parts of nano-aluminium oxide, 40-60 parts of plant ash, chitosan 40-60 Part.
In any of the above-described scheme preferably, the nano-aluminium oxide is made up of hydro-thermal method, and utilizes outstanding Floating particles semar technique is fixed on the chitosan.
In any of the above-described scheme preferably, the flocculant is biological flocculant, and the biological flocculant includes sugar Albumen, polysaccharide, protein, cellulose and DNA are made by the microbial fermentations such as bacterium, fungi, extracting, refining.
In any of the above-described scheme preferably, the biological adsorption agent includes biological activated carbon and biozeolite.
The technology of PCR detection water quality is to control DNA sequence dna needed for temperature carrys out rapid amplifying based on DNA thermal denaturation principle To detect the pathogen of water body.With conventional environment microorganism compared with complicated, cumbersome detection technique, because of its high sensitivity, specifically Property detection speed good, that water quality pathogen can be greatlyd improve, and operate it is convenient, observation number can be obtained in the short time According to, therefore the technology has preferable development prospect in terms of water quality pathogen detection.
Biosensor is mainly made of biosensor and signal transduction device, and wherein biosensor is predominantly micro- The substances such as biology, cellular component and its metabolite are made;Biosensor is mainly quick by conductor translation, amplification biology Sensing unit reacts generated signal to respective environment to realize the detection to environment specificity substance concentration.With traditional physics Unlike sensor, biosensor has highly sensitive, low cost, early period without pre-processing and can continuously examine online The advantages such as survey.Therefore biosensor also has relatively broad application in terms of water quality detection.More biology is applied at present Sensor relates generally to the measurement such as heavy metal, BOD, ammonia, nitrous acid, ethyl alcohol, methane and bacteria concentration in water body.
Microbial flocculant, which refers to, utilizes the metabolite caused by microorganism in nature with settleability, such as albumen The natural polymers organic matter such as matter, polysaccharide, cellulose handles polluted-water, is mainly used for improving sludge settling, go High-enriched organics etc. except suspended particulate, the removal food in sewage, in the sewage such as livestock products and dyestuff.Compared to inorganic flocculation Agent, microbial flocculant is efficient, easily separated and be not easy to cause environment secondary pollution, thus have in water environment pollution processing compared with Good application prospect.
Biological adsorption agent, which refers to, breeds microorganism on the carrier surface loose porous, with good adsorption properties, thus Obtain having concurrently the material of absorption and decomposition to purify water.Now widely used biological adsorption agent can be divided into biological work Property charcoal and biozeolite.BAC Technology is bred and is enriched with to microorganism in activated carbon surface, and the technology is not only The service life that active carbon can be extended improves the adsorption capacity of active carbon, the pollutant in the water body that also can effectively degrade.
The invention has the benefit that the present invention is monitored water quality using Measurement for Biotechnique, have environmentally protective And the advantages of secondary pollution will not being caused to environment, then water quality is carried out tentatively by biological adsorption agent and microbial flocculant Purification, then advanced treating is carried out by water treatment agent, there is at low cost, environmental-friendly and treatment effect clear advantage.
Specific embodiment
In order to be further understood that summary of the invention of the invention, the present invention is elaborated below in conjunction with specific embodiment.
Embodiment one
The present invention provides a kind of water quality monitoring purification method, according to sequencing the following steps are included:
Step (1): different biosensors is set in needing the water source monitored, the harmful components in water source is carried out Monitoring, it is raw by heavy metal biological sensor, BOD biosensor, ammonia biosensor, nitrous acid biosensor, ethyl alcohol Heavy metal, BOD, ammonia, nitrous acid, ethyl alcohol, first in object sensor, methane biosensor and bacteria concentration biosensor monitoring water The content of alkane and bacterium, then will periodically be fixed at sampler under water 1m, lasting 5d, then withdraws sampler and is taken under water Water is monitored the pathogen in water using PCR detection method;
Step (2): the water source parameter detected according to step (1), to sequentially adding in water source, biological flocculant, biology are living Property charcoal and biozeolite, passing through biological flocculant improves sludge settling, the suspended particulate in removal sewage, removal food, poultry High-enriched organics in the sewage such as production and dyestuff, then pass through the pollutant in biological activated carbon and biozeolite degradation water body;
Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter be reduced to and survey for the first time When fixed half, water treatment agent is added;The water treatment agent includes each component of following number: 20 parts of diatomite, tri-chlorination 15 parts of iron, 20 parts of nano-aluminium oxide, 40 parts of plant ash, 40 parts of chitosan, wherein the nano-aluminium oxide passes through water Thermal method is made, and is fixed on the chitosan using suspended particulate semar technique.
Embodiment two
The present invention provides a kind of water quality monitoring purification method, according to sequencing the following steps are included:
Step (1): different biosensors is set in needing the water source monitored, the harmful components in water source is carried out Monitoring, it is raw by heavy metal biological sensor, BOD biosensor, ammonia biosensor, nitrous acid biosensor, ethyl alcohol Heavy metal, BOD, ammonia, nitrous acid, ethyl alcohol, first in object sensor, methane biosensor and bacteria concentration biosensor monitoring water The content of alkane and bacterium, then will periodically be fixed at sampler under water 1m, lasting 5d, then withdraws sampler and is taken under water Water is monitored the pathogen in water using PCR detection method;
Step (2): the water source parameter detected according to step (1), to sequentially adding in water source, biological flocculant, biology are living Property charcoal and biozeolite, passing through biological flocculant improves sludge settling, the suspended particulate in removal sewage, removal food, poultry High-enriched organics in the sewage such as production and dyestuff, then pass through the pollutant in biological activated carbon and biozeolite degradation water body;
Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter be reduced to and survey for the first time When fixed half, water treatment agent is added;The water treatment agent includes each component of following number: 22 parts of diatomite, tri-chlorination 16 parts of iron, 23 parts of nano-aluminium oxide, 45 parts of plant ash, 45 parts of chitosan, wherein the nano-aluminium oxide passes through water Thermal method is made, and is fixed on the chitosan using suspended particulate semar technique.
Embodiment three
The present invention provides a kind of water quality monitoring purification method, according to sequencing the following steps are included:
Step (1): different biosensors is set in needing the water source monitored, the harmful components in water source is carried out Monitoring, it is raw by heavy metal biological sensor, BOD biosensor, ammonia biosensor, nitrous acid biosensor, ethyl alcohol Heavy metal, BOD, ammonia, nitrous acid, ethyl alcohol, first in object sensor, methane biosensor and bacteria concentration biosensor monitoring water The content of alkane and bacterium, then will periodically be fixed at sampler under water 1m, lasting 5d, then withdraws sampler and is taken under water Water is monitored the pathogen in water using PCR detection method;
Step (2): the water source parameter detected according to step (1), to sequentially adding in water source, biological flocculant, biology are living Property charcoal and biozeolite, passing through biological flocculant improves sludge settling, the suspended particulate in removal sewage, removal food, poultry High-enriched organics in the sewage such as production and dyestuff, then pass through the pollutant in biological activated carbon and biozeolite degradation water body;
Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter be reduced to and survey for the first time When fixed half, water treatment agent is added;The water treatment agent includes each component of following number: 23 parts of diatomite, tri-chlorination 18 parts of iron, 25 parts of nano-aluminium oxide, 50 parts of plant ash, 50 parts of chitosan, wherein the nano-aluminium oxide passes through water Thermal method is made, and is fixed on the chitosan using suspended particulate semar technique.
Example IV
The present invention provides a kind of water quality monitoring purification method, according to sequencing the following steps are included:
Step (1): different biosensors is set in needing the water source monitored, the harmful components in water source is carried out Monitoring, it is raw by heavy metal biological sensor, BOD biosensor, ammonia biosensor, nitrous acid biosensor, ethyl alcohol Heavy metal, BOD, ammonia, nitrous acid, ethyl alcohol, first in object sensor, methane biosensor and bacteria concentration biosensor monitoring water The content of alkane and bacterium, then will periodically be fixed at sampler under water 1m, lasting 5d, then withdraws sampler and is taken under water Water is monitored the pathogen in water using PCR detection method;
Step (2): the water source parameter detected according to step (1), to sequentially adding in water source, biological flocculant, biology are living Property charcoal and biozeolite, passing through biological flocculant improves sludge settling, the suspended particulate in removal sewage, removal food, poultry High-enriched organics in the sewage such as production and dyestuff, then pass through the pollutant in biological activated carbon and biozeolite degradation water body;
Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter be reduced to and survey for the first time When fixed half, water treatment agent is added;The water treatment agent includes each component of following number: 24 parts of diatomite, tri-chlorination 19 parts of iron, 28 parts of nano-aluminium oxide, 55 parts of plant ash, 55 parts of chitosan, wherein the nano-aluminium oxide passes through water Thermal method is made, and is fixed on the chitosan using suspended particulate semar technique.
Embodiment five
The present invention provides a kind of water quality monitoring purification method, according to sequencing the following steps are included:
Step (1): different biosensors is set in needing the water source monitored, the harmful components in water source is carried out Monitoring, it is raw by heavy metal biological sensor, BOD biosensor, ammonia biosensor, nitrous acid biosensor, ethyl alcohol Heavy metal, BOD, ammonia, nitrous acid, ethyl alcohol, first in object sensor, methane biosensor and bacteria concentration biosensor monitoring water The content of alkane and bacterium, then will periodically be fixed at sampler under water 1m, lasting 5d, then withdraws sampler and is taken under water Water is monitored the pathogen in water using PCR detection method;
Step (2): the water source parameter detected according to step (1), to sequentially adding in water source, biological flocculant, biology are living Property charcoal and biozeolite, passing through biological flocculant improves sludge settling, the suspended particulate in removal sewage, removal food, poultry High-enriched organics in the sewage such as production and dyestuff, then pass through the pollutant in biological activated carbon and biozeolite degradation water body;
Step (3): the step of repeating step (1), it is to be monitored go out water source in harmful components parameter be reduced to and survey for the first time When fixed half, water treatment agent is added;The water treatment agent includes each component of following number: 25 parts of diatomite, tri-chlorination 20 parts of iron, 30 parts of nano-aluminium oxide, 60 parts of plant ash, 60 parts of chitosan, wherein the nano-aluminium oxide passes through water Thermal method is made, and is fixed on the chitosan using suspended particulate semar technique.
It will be apparent to those skilled in the art that water quality monitoring purification method of the invention includes aforementioned present invention specification Summary of the invention and specific embodiment part, as space is limited and to keep specification concise without these combining each side constituted Case describes one by one.All within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include Within protection scope of the present invention.

Claims (7)

1. a kind of water quality monitoring purification method, according to sequencing the following steps are included:
Step (1): being arranged different biosensors in needing the water source monitored and be monitored to the harmful components in water source, Water source sample is periodically taken by triolein SPMD method, the pathogen in water is monitored using PCR detection method;
Step (2): the water source parameter detected according to step (1), to sequentially adding flocculant and biological adsorption agent in water source;
Step (3): repeat step (1) the step of, it is to be monitored go out water source in harmful components parameter be reduced to First Determination When half, water treatment agent is added.
2. water quality monitoring purification method according to claim 1, which is characterized in that in step (1), semipermeable membrane is passively adopted The concrete operations of sample method are as follows: will be fixed at sampler under water 1m, lasting 5d, then withdraws sampler under water.
3. water quality monitoring purification method according to claim 1, which is characterized in that in step (1), the biosensor It include: heavy metal biological sensor, BOD biosensor, ammonia biosensor, nitrous acid biosensor, alcohol biological biography Sensor, methane biosensor and bacteria concentration biosensor.
4. water quality monitoring purification method according to claim 1, which is characterized in that in step (3), the water treatment agent packet Include each component of following number: 20-25 parts of diatomite, 15-20 parts of ferric trichloride, 20-30 parts of nano-aluminium oxide, plant ash 40-60 parts, 40-60 parts of chitosan.
5. water quality monitoring purification method according to claim 4, which is characterized in that the nano-aluminium oxide passes through water Thermal method is made, and is fixed on the chitosan using suspended particulate semar technique.
6. water quality monitoring purification method according to claim 1, which is characterized in that the flocculant is biological flocculant, The biological flocculant includes glycoprotein, polysaccharide, protein, cellulose and DNA, by microbial fermentations such as bacterium, fungies, is taken out Mention, refine be made.
7. water quality monitoring purification method according to claim 1, which is characterized in that the biological adsorption agent includes that biology is living Property charcoal and biozeolite.
CN201910201280.5A 2019-03-18 2019-03-18 Water quality monitoring purification method Pending CN109879537A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110615550A (en) * 2019-08-12 2019-12-27 中原环资科技有限公司 Water recycling technology for fine garbage sorting process
CN113816535A (en) * 2021-11-22 2021-12-21 山东国润东华环境技术有限公司 Sedimentation tank for industrial water circulation treatment

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103695540A (en) * 2013-12-13 2014-04-02 常熟理工学院 Method for detecting lead ions based on combination of fluorescence quantitative PCR (polymerase chain reaction) and nuclease GR-5
CN107973485A (en) * 2017-11-07 2018-05-01 浙江师范大学 A kind of holiday village sewage treatment intelligent control system
KR20180132273A (en) * 2017-06-02 2018-12-12 주식회사 아쿠아테크 Automatic Control System of Coagulation and Flocculation
CN109187895A (en) * 2018-07-03 2019-01-11 河南工学院 A kind of float type water monitoring device for sewage treatment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103695540A (en) * 2013-12-13 2014-04-02 常熟理工学院 Method for detecting lead ions based on combination of fluorescence quantitative PCR (polymerase chain reaction) and nuclease GR-5
KR20180132273A (en) * 2017-06-02 2018-12-12 주식회사 아쿠아테크 Automatic Control System of Coagulation and Flocculation
CN107973485A (en) * 2017-11-07 2018-05-01 浙江师范大学 A kind of holiday village sewage treatment intelligent control system
CN109187895A (en) * 2018-07-03 2019-01-11 河南工学院 A kind of float type water monitoring device for sewage treatment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110615550A (en) * 2019-08-12 2019-12-27 中原环资科技有限公司 Water recycling technology for fine garbage sorting process
CN113816535A (en) * 2021-11-22 2021-12-21 山东国润东华环境技术有限公司 Sedimentation tank for industrial water circulation treatment

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Application publication date: 20190614