CN109868090A - A kind of preparation method of antistripping paper laminated adhesive - Google Patents
A kind of preparation method of antistripping paper laminated adhesive Download PDFInfo
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- CN109868090A CN109868090A CN201910124768.2A CN201910124768A CN109868090A CN 109868090 A CN109868090 A CN 109868090A CN 201910124768 A CN201910124768 A CN 201910124768A CN 109868090 A CN109868090 A CN 109868090A
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Abstract
The invention discloses a kind of preparation methods of antistripping paper laminated adhesive, belong to field of adhesive technology.The present invention mixes chitosan with water, and after standing swelling, heating stirring dissolution is subsequently added into sodium metaperiodate, and heating stirring reaction obtains modification of chitosan liquid；By bamboo fibre, biogas slurry, sucrose, water mixed fermentation filters, freezes, crush, and sieving obtains modified fibre；Modification of chitosan liquid and terephthalaldehyde are stirred, are subsequently added into modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, curing agent, modified additive, plants essential oil, shellfish shell powder, pollen, phosphatide, tar is stirred to get antistripping paper laminated adhesive.Antistripping paper laminated adhesive provided by the invention has mechanical property and water resistance, is with a wide range of applications.
Description
Technical field
The invention discloses a kind of preparation methods of antistripping paper laminated adhesive, belong to field of adhesive technology.
Background technique
Laminating paper is to utilize adhesive by bidirectional stretching polypropylene film (abbreviation BOPP) or mylar (PET) and paper
Matter printed matter is laminating together, is an important technology in packaging industry.It combines the advantages of paper and plastics, to make
Printed matter surface is brighter smooth, and color is more bright-coloured and rich in three-dimensional sense, while also acting as moisture-proof, antifouling, anti-fake, folding
The effects of wear-resisting, is widely used in decorative building material, packaging material, hard-cover books, products propaganda advertisement or specification etc..Paper covers
Adhesive used in closing is known as the laminating adhesive of paper, abbreviation paper laminated adhesive.Traditional laminated adhesive is mostly organic solvent class,
Preparation and use process have a large amount of solvents (such as toluene, gasoline, vinyl acetate), and solvent, which volatilizees, causes serious dirt in air
Dye and harm, and high production cost, work under hard conditions.
The mankind more and more recognize the importance of environmental protection and sustainable development in recent years, facilitate aqueous adhesive
It rapidly develops.More and more producers use aqueous laminated adhesive stick, have many advantages, such as nontoxic, tasteless, pollution-free, at low cost
It is particularly subject to pay close attention to, to substitute the solvent type laminated adhesive of high pollution.Most widely used aqueous laminated adhesive mainly has currently on the market
3 class copolymer emulsion of pure C, vinegar third and phenylpropyl alcohol, wherein the third product of vinegar is with its easy cleaning, simple production process, and batch products quality is steady
It is fixed, it is especially cheap, and be widely used.What dosage was more in emulsion-type paper laminated adhesive is acrylate and vinyl acetate emulsion.But water
Newborn type laminated adhesive there is also such as tacks lower, water resistance and alkali resistance is poor, adhesive strength is not high, poor storage stability etc. lacks
Point affects emulsion type laminated adhesive product and promotes and apply in the market, hinders the overall development of paper laminated adhesive, product
The raising of performance and technology.The performance for improving emulsion adhesive becomes the research emphasis of aqueous laminated adhesive, has researcher using altogether
For poly- method using VAc as hard monomer, BA, EHA are soft monomer, and AA, VV-10, HPA are that function monomer synthesizes vinyl acetate-acrylic ester copolymerization emulsion,
Optimize reaction condition, improves the properties of the third laminated adhesive of vinegar.Have studied glass transition temperature, function monomer, emulsifier and initiation
Influence of the amount of agent to emulsion property characterizes its structure using Fourier infrared spectrograph.Vinyl acetate and propylene
The copolymer of acid esters is linear polymer, by be added function monomer copolymerization, can be improved the degree of cross linking and lotion cohesive strength,
Creep resisting ability, to improve its adhesive strength.Functional monomer dosage can not be excessive, otherwise can make the reticular structure of polymer
Increase, hinders the movement of molecule segment, be decreased obviously its flexibility and water resistance, emulsion gel rate also will increase.As a result table
When the glass transition temperature of bright the third polymerized emulsion of vinegar is 23.14 DEG C or so, glue film has preferable adhesive effect to paper；Emulsification
When agent dosage is the 2% of monomer total amount, lotion is creamy white, and has apparent homogeneous blue light, and lotion properties are attained by use
It is required that；When function monomer is the 10% of monomer total amount, peel strength, the water resistance of glue film can meet requirement.
Therefore, how to improve traditional paper laminated adhesive mechanical property and the bad disadvantage of water resistance, to obtain higher synthesis
The paper laminated adhesive of performance is that it is promoted and applies, meets industrial production demand urgent problem to be solved.
Summary of the invention
The present invention solves the technical problem of: it is bad for traditional paper laminated adhesive mechanical property and water resistance
Problem provides a kind of preparation method of antistripping paper laminated adhesive.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
(1) chitosan is mixed with water 1:50~1:100 in mass ratio, after standing swelling, heating stirring dissolution is subsequently added into shell
The sodium metaperiodate that 0.02~0.03 times of glycan quality, heating stirring reaction, obtains modification of chitosan liquid；
(2) according to parts by weight, by 20~30 parts of bamboo fibres, 1~2 part of biogas slurry, 1~2 portion of sucrose, 30~50 parts of water mixing hairs
Ferment filters, and freezes, and crushes, and crosses the sieve of 300 mesh, obtains modified fibre；
(3) according to parts by weight, 40~60 parts of modification of chitosan liquid are successively taken, 3~5 parts of terephthalaldehydes, 5~8 parts modified fine
Dimension, 20~30 parts of alkalescent phenol resins, 3~5 parts of ammonium hydroxide, 5~8 parts of emulsifiers, 3~5 parts of curing agent, 2~3 parts of modified additions
Agent, 2~3 parts of plants essential oils, 2~3 parts of shellfish shell powder, 2~3 parts of pollen, 2~3 parts of phosphatide, 2~3 parts of tar gather modified shell
Liquid glucose and terephthalaldehyde are stirred, and are subsequently added into modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, and curing agent changes
Property additive, plants essential oil, shellfish shell powder, pollen, phosphatide, tar are stirred to get antistripping paper laminated adhesive.
The preparation process of step (3) described alkalescent phenol resin are as follows: according to parts by weight, 30~40 parts of glutaraldehydes are molten
Liquid, 10~20 parts of sodium hydroxide solutions, 30~40 parts of hydroquinone constant temperature are stirred to react, and glutaraldehyde solution volume is added in cooling
0.2~0.3 times of ethylene urea constant temperature is stirred to react, and 0.1~0.2 times of glutaraldehyde solution volume of silane coupling agent is added in cooling
KH-550 constant temperature is stirred to react, cooling, is continued constant temperature and is stirred to react to get alkalescent phenol resin.
Step (3) emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate, ammonium lauryl sulfate, dodecyl
Ammonium sulfate, coconut acyl methyl taurine sodium, any one in ethoxylated dodecyl alcohol carboxylic acid sodium or 1-isobutyl-3,5-dimethylhexylphosphoric acid.
Step (3) curing agent is dihexyl triamine, any one in diethylaminopropylamine or triethylene tetramine.
The preparation process of step (3) described modified additive are as follows: stir diatomite and hydrochloric acid 1:10~1:20 in mass ratio
Reaction is mixed, is filtered, is washed, it is dry, single treatment diatomite is obtained, according to parts by weight, by 20~30 parts of single treatment diatomite,
10~20 parts of cornstarch, 0.1~0.2 part of yeast, 20~30 parts of water mixed fermentations, filtering dry, pulverize, and cross 120 purposes
Sieve, charing, obtains secondary treatment diatomite, secondary treatment diatomite and low-melting alloy 5:1~10:1 in mass ratio is heated mixed
Ball milling is closed to get modified additive.
Step (3) plants essential oil is Rosemary Oil, lemon, Peppermint essential oil, cinnamon essential oil, thyme essence
Any one in oil, clove oil, Lavender, rose ethereal oil, jasmine essential oil, camellia essential oil or saussurea involucrata essential oil.
Step (3) the shellfish shell powder is oyster shell powder, any one in mussel shell powder or flower clam shell powder.
Step (3) pollen is Schisandra chinensis pollen, lotus powder, and camellia pollen is any one in pollen pini or Flos Rosae Rugosas pollen
Kind.
Step (3) phosphatide is milk phosphatide, any one in peanut phosphatide or yolk phospholipid.
Step (3) tar is any one in coalite tar or medium temperature coal tar.
The beneficial effects of the present invention are:
(1) present invention passes through modified fibre, modification of chitosan liquid and plants essential oil, firstly, in modified fibre preparation process, benefit
The enzyme generated with microorganism in biogas slurry decomposes the organic matter in bamboo fibre, so that the gap between bamboo fibre and bamboo fibre increases, from
And be conducive to moisture and enter bamboo fibre, it is then passed through freezing, so that the gap moisture between bamboo fibre and bamboo fibre build-ups ice, then is passed through
Ball mill ball milling is crossed, so that ice crystal is under pressure and ruptures, so that bamboo fibre splits into the fibrous crystal palpus of micro/nano level, it is micro-nano
The fibrous crystal palpus draw ratio with higher of grade, after being added in system, so that the mechanical property of system gets a promotion, in modification
In the preparation process of chitosan liquid, the hydroxyl in chitosan molecule chain by sodium periodate oxidation at hydroxyl, in use,
Under heating and alkaline condition, it is anti-that aldol condensation occurs for the hydroxyl of aldehyde radical and modified fibre surface on modification of chitosan strand
It answers, then by the way that terephthalaldehyde is added dropwise, so that it is modified chitosan crosslinked, so that modified fibre is implanted into modified chitosan crosslinked net
Network, so that the intensity of System forming cross-linked network gets a promotion, after effect of the matrix by external force, fiber passes through existingization
Bonding provides powerful bridging traction, and with the increase of external force, system deformation increases, and fiber relies on friction cohesive force not
Disconnected consumption absorbs energy, so that the mechanical property of system is further promoted, meanwhile, plants essential oil can occupy shell
Glycan molecule chain activity hydroxy group, so that the water resistance of system gets a promotion, in addition, the modified fibre size that the present invention uses
It is smaller, therefore be easier to stretch in the base, in the case where identical fibre volume, so that the packed density of system is higher, thus
So that the mechanical property of system is further promoted；
(2) present invention is by addition modified additive, during the preparation process, firstly, diatomite and hydrochloric acid are stirred to react, so that
Porosity in diatomite gets a promotion, then, by single treatment diatomite, cornstarch, yeast, water mixed fermentation, yeast
A large amount of carbon dioxide is generated in metabolic process, so that starch milk is expanding, so that the diatomite in system obtains further
Dispersion, then, under the high temperature conditions, so that the organic matter in system carbonizes, then by secondary treatment diatomite and low-melting alloy
Mixing and ball milling, so that low-melting alloy is able to enter in modified additive, so that low melting point conjunction is expired in the filling in modified additive
Gold, in use, the low-melting alloy fusing in system, and be dispersed in system, low-melting alloy is dispersed in system,
After low-melting alloy solidification, so that metallurgical bonding is formed in system, so that the mechanical property of system gets a promotion.
Specific embodiment
According to parts by weight, the glutaraldehyde solution for being 40~50% by 30~40 parts of mass fractions, 10~20 parts of mass fractions
For 20~30% sodium hydroxide solution, 30~40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is surveyed
It is 76~78 DEG C in temperature in fast constant temperature blender with magnetic force, under the conditions of revolving speed is 300~500r/min, constant temperature is stirred to react 3~
After 4h, temperature in single-necked flask is down to 60~62 DEG C, then 0.2~0.3 times of glutaraldehyde solution volume is added into single-necked flask
Ethylene urea, in temperature be 60~62 DEG C, revolving speed be 300~500r/min under the conditions of, after constant temperature is stirred to react 40~60min,
Temperature in single-necked flask is down to 50~52 DEG C, 0.1~0.2 times of glutaraldehyde solution volume of silicon is then added into single-necked flask
Alkane coupling agent KH-550 is 50~52 DEG C in temperature, under the conditions of revolving speed is 300~500r/min, constant temperature is stirred to react 40~
Temperature in single-necked flask is down to 40~42 DEG C by 50min, is 40~42 DEG C in temperature, revolving speed is 300~500r/min condition
Under, continue constant temperature and is stirred to react 20~30min to get alkalescent phenol resin；The salt for being 20~30% by diatomite and mass fraction
Acid 1:10~1:20 in mass ratio is placed in reaction kettle, under the conditions of revolving speed is 400~600r/min, it is stirred to react 40~
60min obtains mixture slurry, then filters mixture slurry, obtains filter residue, is then connect residue washing 5~8 times with deionized water
The filter residue after washing is placed in baking oven, it is dry to constant weight under the conditions of temperature is 105~110 DEG C, obtain single treatment diatom
Soil, according to parts by weight, by 20~30 parts of single treatment diatomite, 10~20 parts of cornstarch, 0.1~0.2 part of yeast, 20~
30 parts of water are placed in fermentation cauldron, in temperature be 30~50 DEG C, revolving speed be 400~600r/min under the conditions of, mixed fermentation 3~5 days,
Must ferment mixed liquor, then filter fermentation mixed liquor, obtain No. 1 filter cake, then No. 1 filter cake is placed in baking oven, be in temperature
It is dry to dry No. 1 filter cake to constant weight under the conditions of 105~110 DEG C, then dry No. 1 filter cake is placed in ball mill and is crushed, mistake
The sieve of 120 mesh obtains ball milling material, and then ball milling material is placed in retort, and is filled with the rate of 60~90mL/min into furnace
Nitrogen, in temperature be 750~850 DEG C under the conditions of, carbonize 2~3h, obtain secondary treatment diatomite, by secondary treatment diatomite with it is low
Melting alloy 5:1~10:1 in mass ratio is placed in ball mill, under the conditions of temperature is 120~160 DEG C, heats mixing and ball milling 40
~60min is to get modified additive；Chitosan and water 1:50~1:100 in mass ratio are placed in a beaker, and stirred with glass bar
Mix 10~20min, after standing 3~5h of swelling, place the beaker digital display and test the speed in constant temperature blender with magnetic force, in temperature be 90~95
DEG C, under the conditions of revolving speed is 400~600r/min, heating stirring dissolves 40~60min, and chitosan mass is then added into beaker
0.02~0.03 times of sodium metaperiodate is 90~95 DEG C in temperature, and under the conditions of revolving speed is 400~600r/min, heating stirring is anti-
40~60min is answered, modification of chitosan liquid is obtained；According to parts by weight, by 20~30 parts of bamboo fibres, 1~2 part of biogas slurry, 1~2 part of sugarcane
Sugar, 30~50 parts of water mixing are placed in fermentation cauldron, are under the conditions of revolving speed is 100~200r/min, to mix in 30~35 DEG C in temperature
Fermentation 3~5 days is closed, fermentation mixture is obtained, then fermentation mixture is filtered, No. 2 filter cakes is obtained, No. 2 filter cakes is then placed in liquid
It is freezed in nitrogen, material must be freezed, then freezing material is placed in ball mill and is crushed, the sieve of 300 mesh is crossed, obtains modified fibre；By weight
Number meter successively takes 40~60 parts of modification of chitosan liquid, 3~5 parts of terephthalaldehydes, 5~8 parts of modified fibres, 20~30 parts of alkali
Property phenolic resin, the ammonium hydroxide that 3~5 parts of mass fractions are 20~30%, 5~8 parts of emulsifiers, 3~5 parts of curing agent, 2~3 parts of modifications
Additive, 2~3 parts of plants essential oils, 2~3 parts of shellfish shell powder, 2~3 parts of pollen, 2~3 parts of phosphatide, 2~3 parts of tar will be modified
Chitosan liquid and terephthalaldehyde are placed in batch mixer, under the conditions of revolving speed is 400~600r/min, it is stirred 40~
60min, is then added modified fibre into batch mixer, alkalescent phenol resin, ammonium hydroxide, emulsifier, curing agent, modified additive,
Plants essential oil, shellfish shell powder, pollen, phosphatide, tar, under the conditions of revolving speed is 400~600r/min, it is stirred 40~
60min is to get antistripping paper laminated adhesive.The emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate, dodecyl sulphur
Sour ammonium, ammonium lauryl sulfate, coconut acyl methyl taurine sodium, ethoxylated dodecyl alcohol carboxylic acid sodium or 1-isobutyl-3,5-dimethylhexylphosphoric acid
In any one.The curing agent is dihexyl triamine, any one in diethylaminopropylamine or triethylene tetramine.It is described
Plants essential oil is Rosemary Oil, lemon, Peppermint essential oil, cinnamon essential oil, thyme essential oil, clove oil, lavender essence
Any one in oil, rose ethereal oil, jasmine essential oil, camellia essential oil or saussurea involucrata essential oil.The shellfish shell powder is oyster shell
Powder, any one in mussel shell powder or flower clam shell powder.The pollen be Schisandra chinensis pollen, lotus powder, camellia pollen, pollen pini or
Any one in Flos Rosae Rugosas pollen.The phosphatide is milk phosphatide, any one in peanut phosphatide or yolk phospholipid.The coke
Oil is any one in coalite tar or medium temperature coal tar.The low-melting alloy is bismuth tin alloy, each in bismuth tin alloy
Constituent mass content are as follows: bismuth accounts for 51%(ω), tin accounts for 30%(ω), lead accounts for 8%(ω), indium accounts for 11%(ω).
Example 1
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；Diatomite is placed in the hydrochloric acid 1:20 in mass ratio that mass fraction is 30% and is reacted
In kettle, under the conditions of revolving speed is 600r/min, it is stirred to react 60min, mixture slurry is obtained, then filters mixture slurry, must be filtered
Residue washing 8 times are then then placed in the filter residue after washing in baking oven with deionized water by slag, in temperature be 110 DEG C of conditions
Under, it is dry to constant weight, single treatment diatomite is obtained, according to parts by weight, by 30 parts of single treatment diatomite, 20 parts of corns form sediment
Powder, 0.2 part of yeast, 30 parts of water are placed in fermentation cauldron, in temperature be 50 DEG C, revolving speed be 600r/min under the conditions of, mixed fermentation 5
It, obtains fermentation mixed liquor, then filters fermentation mixed liquor, obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven, Yu Wendu
It is dry to dry No. 1 filter cake to constant weight under the conditions of 110 DEG C, then dry No. 1 filter cake is placed in ball mill and is crushed, cross 120
Purpose sieve, obtains ball milling material, then ball milling material is placed in retort, and be filled with nitrogen into furnace with the rate of 90mL/min, in
Under the conditions of temperature is 850 DEG C, 3h is carbonized, secondary treatment diatomite is obtained, secondary treatment diatomite and low-melting alloy are pressed into quality
It is placed in ball mill than 10:1, under the conditions of temperature is 160 DEG C, heats mixing and ball milling 60min to get modified additive；By shell
Glycan is placed in a beaker with water 1:100 in mass ratio, and stirs 20min with glass bar, after standing swelling 5h, places the beaker number
It is 95 DEG C in temperature in the aobvious constant temperature blender with magnetic force that tests the speed, under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, connects
0.03 times of chitosan mass of sodium metaperiodate is added into beaker, be 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, add
60min is reacted in thermal agitation, obtains modification of chitosan liquid；According to parts by weight, by 30 parts of bamboo fibres, 2 parts of biogas slurries, 2 portions of sucrose, 50 parts
Water mixing is placed in fermentation cauldron, is in 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, mixed fermentation 5 days, must ferment mixing
Fermentation mixture is then filtered, obtains No. 2 filter cakes, then No. 2 filter cakes are placed in liquid nitrogen and are freezed, must freeze material, then will by material
Freezing material, which is placed in ball mill, to be crushed, and is crossed the sieve of 300 mesh, is obtained modified fibre；According to parts by weight, successively take 60 parts of modified shells poly-
Liquid glucose, 5 parts of terephthalaldehydes, 8 parts of modified fibres, 30 parts of alkalescent phenol resins, the ammonium hydroxide that 5 parts of mass fractions are 30%, 8 parts of creams
Agent, 5 parts of curing agent, 3 parts of modified additives, 3 parts of plants essential oils, 3 parts of shellfish shell powder, 3 parts of pollen, 3 parts of phosphatide, 3 parts of tar,
Modification of chitosan liquid and terephthalaldehyde are placed in batch mixer, under the conditions of revolving speed is 600r/min, are stirred 60min,
Then modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, curing agent, modified additive, plant essence are added into batch mixer
Oil, shellfish shell powder, pollen, phosphatide, tar are stirred 60min under the conditions of revolving speed is 600r/min to get antistripping paper
Mould laminated adhesive.The emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate.The curing agent is dihexyl triamine.The plant
Object essential oil is Rosemary Oil.The shellfish shell powder is oyster shell powder.The pollen is Schisandra chinensis pollen.The phosphatide is milk
Phosphatide.The tar is coalite tar.The low-melting alloy is bismuth tin alloy, each component mass content in bismuth tin alloy
Are as follows: bismuth accounts for 51%(ω), tin accounts for 30%(ω), lead accounts for 8%(ω), indium accounts for 11%(ω).
Example 2
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；Chitosan and water 1:100 in mass ratio are placed in a beaker, and stirred with glass bar
20min after standing swelling 5h, places the beaker digital display and tests the speed in constant temperature blender with magnetic force, is 95 DEG C in temperature, revolving speed is
Under the conditions of 600r/min, heating stirring dissolves 60min, and 0.03 times of chitosan mass of sodium metaperiodate is then added into beaker,
It is 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, heating stirring reacts 60min, obtains modification of chitosan liquid；In parts by weight
Meter, by 30 parts of bamboo fibres, 2 parts of biogas slurries, 2 portions of sucrose, it is in 35 DEG C in temperature, revolving speed is that 50 parts of water mixing, which are placed in fermentation cauldron,
Under the conditions of 200r/min, mixed fermentation 5 days, fermentation mixture is obtained, then fermentation mixture is filtered, No. 2 filter cakes is obtained, then will
No. 2 filter cakes are placed in liquid nitrogen and freeze, and must freeze material, and then freezing material is placed in ball mill and is crushed, the sieve of 300 mesh is crossed, must change
Property fiber；According to parts by weight, 60 parts of modification of chitosan liquid, 5 parts of terephthalaldehydes, 8 parts of modified fibres, 30 parts of alkalinity are successively taken
Phenolic resin, the ammonium hydroxide that 5 parts of mass fractions are 30%, 8 parts of emulsifiers, 5 parts of curing agent, 3 parts of plants essential oils, 3 parts of shellfish shell powder, 3
Modification of chitosan liquid and terephthalaldehyde are placed in batch mixer by part pollen, 3 parts of phosphatide, 3 parts of tar, in revolving speed be 600r/
Under the conditions of min, it is stirred 60min, is then added modified fibre into batch mixer, alkalescent phenol resin, ammonium hydroxide, emulsifier,
Curing agent, plants essential oil, pollen, phosphatide, tar are stirred 60min under the conditions of revolving speed is 600r/min to get anti-stripping
From paper laminated adhesive.The emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate.The curing agent is dihexyl triamine.Institute
Stating plants essential oil is Rosemary Oil.The shellfish shell powder is oyster shell powder.The pollen is Schisandra chinensis pollen.The phosphatide is
Milk phosphatide.The tar is coalite tar.
Example 3
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；Diatomite is placed in the hydrochloric acid 1:20 in mass ratio that mass fraction is 30% and is reacted
In kettle, under the conditions of revolving speed is 600r/min, it is stirred to react 60min, mixture slurry is obtained, then filters mixture slurry, must be filtered
Residue washing 8 times are then then placed in the filter residue after washing in baking oven with deionized water by slag, in temperature be 110 DEG C of conditions
Under, it is dry to constant weight, single treatment diatomite is obtained, according to parts by weight, by 30 parts of single treatment diatomite, 20 parts of corns form sediment
Powder, 0.2 part of yeast, 30 parts of water are placed in fermentation cauldron, in temperature be 50 DEG C, revolving speed be 600r/min under the conditions of, mixed fermentation 5
It, obtains fermentation mixed liquor, then filters fermentation mixed liquor, obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven, Yu Wendu
It is dry to dry No. 1 filter cake to constant weight under the conditions of 110 DEG C, then dry No. 1 filter cake is placed in ball mill and is crushed, cross 120
Purpose sieve, obtains ball milling material, then ball milling material is placed in retort, and be filled with nitrogen into furnace with the rate of 90mL/min, in
Under the conditions of temperature is 850 DEG C, 3h is carbonized, secondary treatment diatomite is obtained, secondary treatment diatomite and low-melting alloy are pressed into quality
It is placed in ball mill than 10:1, under the conditions of temperature is 160 DEG C, heats mixing and ball milling 60min to get modified additive；By weight
Number meter is measured, by 30 parts of bamboo fibres, 2 parts of biogas slurries, 2 portions of sucrose, 50 parts of water mixing are placed in fermentation cauldron, be in 35 DEG C in temperature,
Under the conditions of revolving speed is 200r/min, mixed fermentation 5 days, fermentation mixture is obtained, then fermentation mixture is filtered, obtains No. 2 filter cakes,
Then No. 2 filter cakes are placed in liquid nitrogen and are freezed, material must be freezed, then freezing material is placed in ball mill and is crushed, 300 purposes are crossed
Sieve, obtains modified fibre；According to parts by weight, according to 5 parts of terephthalaldehydes, 8 parts of modified fibres, 30 parts of alkalescent phenol resins, 5 parts of matter
The ammonium hydroxide that amount score is 30%, 8 parts of emulsifiers, 5 parts of curing agent, 3 parts of modified additives, 3 parts of plants essential oils, 3 parts of shellfish shell powder, 3
Terephthalaldehyde is placed in batch mixer by part pollen, 3 parts of phosphatide, 3 parts of tar, and under the conditions of revolving speed is 600r/min, stirring is mixed
60min is closed, modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, curing agent, modified addition are then added into batch mixer
Agent, plants essential oil, shellfish shell powder, pollen, phosphatide, tar, in revolving speed be 600r/min under the conditions of, be stirred 60min to get
Antistripping paper laminated adhesive.The emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate.The curing agent is dihexyl three
Amine.The plants essential oil is Rosemary Oil.The shellfish shell powder is oyster shell powder.The pollen is Schisandra chinensis pollen.It is described
Phosphatide is milk phosphatide.The tar is coalite tar.The low-melting alloy is bismuth tin alloy, each component in bismuth tin alloy
Mass content are as follows: bismuth accounts for 51%(ω), tin accounts for 30%(ω), lead accounts for 8%(ω), indium accounts for 11%(ω).
Example 4
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；Diatomite is placed in the hydrochloric acid 1:20 in mass ratio that mass fraction is 30% and is reacted
In kettle, under the conditions of revolving speed is 600r/min, it is stirred to react 60min, mixture slurry is obtained, then filters mixture slurry, must be filtered
Residue washing 8 times are then then placed in the filter residue after washing in baking oven with deionized water by slag, in temperature be 110 DEG C of conditions
Under, it is dry to constant weight, single treatment diatomite is obtained, according to parts by weight, by 30 parts of single treatment diatomite, 20 parts of corns form sediment
Powder, 0.2 part of yeast, 30 parts of water are placed in fermentation cauldron, in temperature be 50 DEG C, revolving speed be 600r/min under the conditions of, mixed fermentation 5
It, obtains fermentation mixed liquor, then filters fermentation mixed liquor, obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven, Yu Wendu
It is dry to dry No. 1 filter cake to constant weight under the conditions of 110 DEG C, then dry No. 1 filter cake is placed in ball mill and is crushed, cross 120
Purpose sieve, obtains ball milling material, then ball milling material is placed in retort, and be filled with nitrogen into furnace with the rate of 90mL/min, in
Under the conditions of temperature is 850 DEG C, 3h is carbonized, secondary treatment diatomite is obtained, secondary treatment diatomite and low-melting alloy are pressed into quality
It is placed in ball mill than 10:1, under the conditions of temperature is 160 DEG C, heats mixing and ball milling 60min to get modified additive；By shell
Glycan is placed in a beaker with water 1:100 in mass ratio, and stirs 20min with glass bar, after standing swelling 5h, places the beaker number
It is 95 DEG C in temperature in the aobvious constant temperature blender with magnetic force that tests the speed, under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, connects
0.03 times of chitosan mass of sodium metaperiodate is added into beaker, be 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, add
60min is reacted in thermal agitation, obtains modification of chitosan liquid；According to parts by weight, by 30 parts of bamboo fibres, 2 parts of biogas slurries, 2 portions of sucrose, 50 parts
Water mixing is placed in fermentation cauldron, is in 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, mixed fermentation 5 days, must ferment mixing
Fermentation mixture is then filtered, obtains No. 2 filter cakes, then No. 2 filter cakes are placed in liquid nitrogen and are freezed, must freeze material, then will by material
Freezing material, which is placed in ball mill, to be crushed, and is crossed the sieve of 300 mesh, is obtained modified fibre；According to parts by weight, successively take 60 parts of modified shells poly-
Liquid glucose, 5 parts of terephthalaldehydes, 8 parts of modified fibres, 30 parts of alkalescent phenol resins, the ammonium hydroxide that 5 parts of mass fractions are 30%, 8 parts of creams
Agent, 5 parts of curing agent, 3 parts of modified additives, 3 parts of shellfish shell powder, 3 parts of pollen, 3 parts of phosphatide, 3 parts of tar, by modification of chitosan
Liquid and terephthalaldehyde are placed in batch mixer, under the conditions of revolving speed is 600r/min, 60min are stirred, then to batch mixer
Middle addition modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, curing agent, modified additive, shellfish shell powder, pollen, phosphatide,
Tar is stirred 60min under the conditions of revolving speed is 600r/min to get antistripping paper laminated adhesive.The emulsifier is ten
Dialkyl group alcohol polyethenoxy ether sodium sulfate.The curing agent is dihexyl triamine.The shellfish shell powder is oyster shell powder.The flower
Powder is Schisandra chinensis pollen.The phosphatide is milk phosphatide.The tar is coalite tar.The low-melting alloy is the conjunction of bismuth tin
Gold, each component mass content in bismuth tin alloy are as follows: bismuth accounts for 51%(ω), tin accounts for 30%(ω), lead accounts for 8%(ω), indium accounts for 11%(ω).
Example 5
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；Diatomite is placed in the hydrochloric acid 1:20 in mass ratio that mass fraction is 30% and is reacted
In kettle, under the conditions of revolving speed is 600r/min, it is stirred to react 60min, mixture slurry is obtained, then filters mixture slurry, must be filtered
Residue washing 8 times are then then placed in the filter residue after washing in baking oven with deionized water by slag, in temperature be 110 DEG C of conditions
Under, it is dry to constant weight, single treatment diatomite is obtained, according to parts by weight, by 30 parts of single treatment diatomite, 20 parts of corns form sediment
Powder, 0.2 part of yeast, 30 parts of water are placed in fermentation cauldron, in temperature be 50 DEG C, revolving speed be 600r/min under the conditions of, mixed fermentation 5
It, obtains fermentation mixed liquor, then filters fermentation mixed liquor, obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven, Yu Wendu
It is dry to dry No. 1 filter cake to constant weight under the conditions of 110 DEG C, then dry No. 1 filter cake is placed in ball mill and is crushed, cross 120
Purpose sieve, obtains ball milling material, then ball milling material is placed in retort, and be filled with nitrogen into furnace with the rate of 90mL/min, in
Under the conditions of temperature is 850 DEG C, 3h is carbonized, secondary treatment diatomite is obtained, secondary treatment diatomite and low-melting alloy are pressed into quality
It is placed in ball mill than 10:1, under the conditions of temperature is 160 DEG C, heats mixing and ball milling 60min to get modified additive；By shell
Glycan is placed in a beaker with water 1:100 in mass ratio, and stirs 20min with glass bar, after standing swelling 5h, places the beaker number
It is 95 DEG C in temperature in the aobvious constant temperature blender with magnetic force that tests the speed, under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, connects
0.03 times of chitosan mass of sodium metaperiodate is added into beaker, be 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, add
60min is reacted in thermal agitation, obtains modification of chitosan liquid；According to parts by weight, by 30 parts of bamboo fibres, 2 parts of biogas slurries, 2 portions of sucrose, 50 parts
Water mixing is placed in fermentation cauldron, is in 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, mixed fermentation 5 days, must ferment mixing
Fermentation mixture is then filtered, obtains No. 2 filter cakes, then No. 2 filter cakes are placed in liquid nitrogen and are freezed, must freeze material, then will by material
Freezing material, which is placed in ball mill, to be crushed, and is crossed the sieve of 300 mesh, is obtained modified fibre；According to parts by weight, successively take 60 parts of modified shells poly-
Liquid glucose, 5 parts of terephthalaldehydes, 8 parts of modified fibres, 30 parts of alkalescent phenol resins, the ammonium hydroxide that 5 parts of mass fractions are 30%, 8 parts of creams
Agent, 5 parts of curing agent, 3 parts of modified additives, 3 parts of plants essential oils, 3 parts of pollen, 3 parts of phosphatide, 3 parts of tar, by modification of chitosan
Liquid and terephthalaldehyde are placed in batch mixer, under the conditions of revolving speed is 600r/min, 60min are stirred, then to batch mixer
Middle addition modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, curing agent, modified additive, plants essential oil, pollen, phosphatide,
Tar is stirred 60min under the conditions of revolving speed is 600r/min to get antistripping paper laminated adhesive.The emulsifier is ten
Dialkyl group alcohol polyethenoxy ether sodium sulfate.The curing agent is dihexyl triamine.The plants essential oil is Rosemary Oil.It is described
Pollen is Schisandra chinensis pollen.The phosphatide is milk phosphatide.The tar is coalite tar.The low-melting alloy is bismuth tin
Alloy, each component mass content in bismuth tin alloy are as follows: bismuth accounts for 51%(ω), tin accounts for 30%(ω), lead accounts for 8%(ω), indium accounts for 11%
(ω).
Example 6
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；Diatomite is placed in the hydrochloric acid 1:20 in mass ratio that mass fraction is 30% and is reacted
In kettle, under the conditions of revolving speed is 600r/min, it is stirred to react 60min, mixture slurry is obtained, then filters mixture slurry, must be filtered
Residue washing 8 times are then then placed in the filter residue after washing in baking oven with deionized water by slag, in temperature be 110 DEG C of conditions
Under, it is dry to constant weight, single treatment diatomite is obtained, according to parts by weight, by 30 parts of single treatment diatomite, 20 parts of corns form sediment
Powder, 0.2 part of yeast, 30 parts of water are placed in fermentation cauldron, in temperature be 50 DEG C, revolving speed be 600r/min under the conditions of, mixed fermentation 5
It, obtains fermentation mixed liquor, then filters fermentation mixed liquor, obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven, Yu Wendu
It is dry to dry No. 1 filter cake to constant weight under the conditions of 110 DEG C, then dry No. 1 filter cake is placed in ball mill and is crushed, cross 120
Purpose sieve, obtains ball milling material, then ball milling material is placed in retort, and be filled with nitrogen into furnace with the rate of 90mL/min, in
Under the conditions of temperature is 850 DEG C, 3h is carbonized, secondary treatment diatomite is obtained, secondary treatment diatomite and low-melting alloy are pressed into quality
It is placed in ball mill than 10:1, under the conditions of temperature is 160 DEG C, heats mixing and ball milling 60min to get modified additive；By shell
Glycan is placed in a beaker with water 1:100 in mass ratio, and stirs 20min with glass bar, after standing swelling 5h, places the beaker number
It is 95 DEG C in temperature in the aobvious constant temperature blender with magnetic force that tests the speed, under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, connects
0.03 times of chitosan mass of sodium metaperiodate is added into beaker, be 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, add
60min is reacted in thermal agitation, obtains modification of chitosan liquid；According to parts by weight, 60 parts of modification of chitosan liquid are successively taken, 5 parts to benzene two
Formaldehyde, 30 parts of alkalescent phenol resins, the ammonium hydroxide that 5 parts of mass fractions are 30%, 8 parts of emulsifiers, 5 parts of curing agent, 3 parts of modified additions
Agent, 3 parts of plants essential oils, 3 parts of shellfish shell powder, 3 parts of pollen, 3 parts of phosphatide, 3 parts of tar, by modification of chitosan liquid and terephthalaldehyde
It is placed in batch mixer, under the conditions of revolving speed is 600r/min, is stirred 60min, alkaline phenol formaldehyde is then added into batch mixer
Resin, ammonium hydroxide, emulsifier, curing agent, modified additive, plants essential oil, shellfish shell powder, pollen, phosphatide, tar are in revolving speed
Under the conditions of 600r/min, 60min is stirred to get antistripping paper laminated adhesive.The emulsifier is dodecyl alcohol polyoxy
Ethylene ether sodium sulfate.The curing agent is dihexyl triamine.The plants essential oil is Rosemary Oil.The shellfish shell powder is male
Oyster shells.The pollen is Schisandra chinensis pollen.The phosphatide is milk phosphatide.The tar is coalite tar.The eutectic
Point alloy is bismuth tin alloy, each component mass content in bismuth tin alloy are as follows: bismuth accounts for 51%(ω), tin accounts for 30%(ω), lead accounts for 8%
(ω), indium account for 11%(ω).
Comparative example
According to parts by weight, the glutaraldehyde solution for being 50% by 40 parts of mass fractions, the sodium hydroxide that 20 parts of mass fractions are 30%
Solution, 40 parts of hydroquinones are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, Yu Wen
Degree is 78 DEG C, and under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 4h, temperature in single-necked flask is down to 62 DEG C, then to
0.3 times of glutaraldehyde solution volume of ethylene urea is added in single-necked flask, in temperature be 62 DEG C, under the conditions of revolving speed is 500r/min,
After constant temperature is stirred to react 60min, temperature in single-necked flask is down to 52 DEG C, glutaraldehyde solution body is then added into single-necked flask
The silane resin acceptor kh-550 of 0.2 times of product is 52 DEG C in temperature, and under the conditions of revolving speed is 500r/min, constant temperature is stirred to react
Temperature in single-necked flask is down to 42 DEG C by 50min, is 42 DEG C in temperature, under the conditions of revolving speed is 500r/min, is continued constant temperature stirring
30min is reacted to get alkalescent phenol resin；According to parts by weight, 5 parts of terephthalaldehydes are successively taken, 30 parts of alkalescent phenol resins,
The ammonium hydroxide that 5 parts of mass fractions are 30%, 8 parts of emulsifiers, 5 parts of curing agent, 3 parts of pollen, 3 parts of phosphatide, 3 parts of tar gather modified shell
Liquid glucose and terephthalaldehyde are placed in batch mixer, under the conditions of revolving speed is 600r/min, 60min are stirred, then to mixing
Be added alkalescent phenol resin in machine, ammonium hydroxide, emulsifier, curing agent, pollen, phosphatide, tar, in revolving speed be 600r/min condition
Under, 60min is stirred to get antistripping paper laminated adhesive.The emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate.
The curing agent is dihexyl triamine.The pollen is Schisandra chinensis pollen.The phosphatide is milk phosphatide.The tar is low temperature
Coal tar.
The resulting antistripping paper laminated adhesive of example 1 to 6 and comparative example product are subjected to performance detection, specific detection method
It is as follows:
1. mechanical property: it is measured according to GB/T2791 standard, laminated adhesive obtained is coated uniformly on BOPP plastic foil,
Thin-film width be (25 ± 0.5) mm, overlay on white duplex board, after be clipped in 2 pieces of glass plates, be placed in drying box constant temperature at 40 DEG C
10min after being placed at room temperature for for 24 hours, tests T-type peel strength on electronic tensile machine；
2. water resistance: surface is filled and impregnates about 10d under the drying test sample plate room temperature of test specimen in water, observation film whether there is or not
It falls off, wrinkles, it is eclipsed, phenomena such as blistering.
Specific testing result is as shown in table 1:
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | Comparative example |
| T-type peel strength/(N/mm) | 0.212 | 0.193 | 0.173 | 0.151 | 0.148 | 0.130 | 0.081 |
| Water resistance | Stablize | Corrugation, blistering | It is eclipsed | Blistering | Blistering | Corrugation, blistering | It falls off, wrinkles |
By 1 testing result of table it is found that the antistripping paper laminated adhesive of technical solution of the present invention preparation has excellent mechanical property
And the characteristics of water resistance, it has broad prospects in the development of paper laminated adhesive industry.
Claims (10)
1. a kind of preparation method of antistripping paper laminated adhesive, it is characterised in that specific preparation process is as follows:
(1) chitosan is mixed with water 1:50~1:100 in mass ratio, after standing swelling, heating stirring dissolution is subsequently added into shell
The sodium metaperiodate that 0.02~0.03 times of glycan quality, heating stirring reaction, obtains modification of chitosan liquid；
(2) according to parts by weight, by 20~30 parts of bamboo fibres, 1~2 part of biogas slurry, 1~2 portion of sucrose, 30~50 parts of water mixing hairs
Ferment filters, and freezes, and crushes, and crosses the sieve of 300 mesh, obtains modified fibre；
(3) according to parts by weight, 40~60 parts of modification of chitosan liquid are successively taken, 3~5 parts of terephthalaldehydes, 5~8 parts modified fine
Dimension, 20~30 parts of alkalescent phenol resins, 3~5 parts of ammonium hydroxide, 5~8 parts of emulsifiers, 3~5 parts of curing agent, 2~3 parts of modified additions
Agent, 2~3 parts of plants essential oils, 2~3 parts of shellfish shell powder, 2~3 parts of pollen, 2~3 parts of phosphatide, 2~3 parts of tar gather modified shell
Liquid glucose and terephthalaldehyde are stirred, and are subsequently added into modified fibre, alkalescent phenol resin, ammonium hydroxide, emulsifier, and curing agent changes
Property additive, plants essential oil, shellfish shell powder, pollen, phosphatide, tar are stirred to get antistripping paper laminated adhesive.
2. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
The preparation process of alkalescent phenol resin are as follows: according to parts by weight, by 30~40 parts of glutaraldehyde solutions, 10~20 parts of sodium hydroxides are molten
Liquid, 30~40 parts of hydroquinone constant temperature are stirred to react, and 0.2~0.3 times of glutaraldehyde solution volume of ethylene urea constant temperature is added in cooling
It is stirred to react, cools down, 0.1~0.2 times of glutaraldehyde solution volume of silane resin acceptor kh-550 constant temperature is added and is stirred to react, drops
Temperature continues constant temperature and is stirred to react to get alkalescent phenol resin.
3. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Emulsifier is dodecyl alcohol polyoxyethylene ether sodium sulfate, ammonium lauryl sulfate, ammonium lauryl sulfate, coconut acyl methyl ox
Sodium sulfonate, any one in ethoxylated dodecyl alcohol carboxylic acid sodium or 1-isobutyl-3,5-dimethylhexylphosphoric acid.
4. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Curing agent is dihexyl triamine, any one in diethylaminopropylamine or triethylene tetramine.
5. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
The preparation process of modified additive are as follows: diatomite and hydrochloric acid 1:10~1:20 in mass ratio are stirred to react, filtered, is washed, is done
It is dry, single treatment diatomite is obtained, according to parts by weight, and by 20~30 parts of single treatment diatomite, 10~20 parts of cornstarch,
0.1~0.2 part of yeast, 20~30 parts of water mixed fermentations, filtering dry, pulverize, and cross the sieve of 120 mesh, and charing obtains secondary treatment
Diatomite adds secondary treatment diatomite and low-melting alloy 5:1~10:1 in mass ratio heating mixing and ball milling to get modified
Agent.
6. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Plants essential oil is Rosemary Oil, lemon, Peppermint essential oil, cinnamon essential oil, thyme essential oil, clove oil, lavender essence
Any one in oil, rose ethereal oil, jasmine essential oil, camellia essential oil or saussurea involucrata essential oil.
7. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Shellfish shell powder is oyster shell powder, any one in mussel shell powder or flower clam shell powder.
8. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Pollen is Schisandra chinensis pollen, lotus powder, camellia pollen, any one in pollen pini or Flos Rosae Rugosas pollen.
9. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Phosphatide is milk phosphatide, any one in peanut phosphatide or yolk phospholipid.
10. a kind of preparation method of antistripping paper laminated adhesive according to claim 1, it is characterised in that: step (3) is described
Tar is any one in coalite tar or medium temperature coal tar.
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| CN104293241A (en) * | 2014-09-24 | 2015-01-21 | 安徽省中彩印务有限公司 | Water-based laminated adhesive for presswork water-based lamination and preparation method thereof |
| CN108084923A (en) * | 2017-12-04 | 2018-05-29 | 朱东洋 | A kind of preparation method of paper laminated adhesive |
| CN108383492A (en) * | 2018-03-12 | 2018-08-10 | 江苏新亿源环保科技有限公司 | A kind of preparation method of ceramic material |
| CN108442173A (en) * | 2018-02-10 | 2018-08-24 | 戴琪 | A kind of preparation method of modification of chitosan glue used in paper-making |
| CN109054662A (en) * | 2018-07-25 | 2018-12-21 | 佛山皖阳生物科技有限公司 | A kind of water-resistant type starch base trademark adhesive |
| CN109233522A (en) * | 2018-09-28 | 2019-01-18 | 佛山齐安建筑科技有限公司 | A kind of building material surface fireproof coating |
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2019
- 2019-02-20 CN CN201910124768.2A patent/CN109868090A/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293241A (en) * | 2014-09-24 | 2015-01-21 | 安徽省中彩印务有限公司 | Water-based laminated adhesive for presswork water-based lamination and preparation method thereof |
| CN108084923A (en) * | 2017-12-04 | 2018-05-29 | 朱东洋 | A kind of preparation method of paper laminated adhesive |
| CN108442173A (en) * | 2018-02-10 | 2018-08-24 | 戴琪 | A kind of preparation method of modification of chitosan glue used in paper-making |
| CN108383492A (en) * | 2018-03-12 | 2018-08-10 | 江苏新亿源环保科技有限公司 | A kind of preparation method of ceramic material |
| CN109054662A (en) * | 2018-07-25 | 2018-12-21 | 佛山皖阳生物科技有限公司 | A kind of water-resistant type starch base trademark adhesive |
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Application publication date: 20190611 |