CN109862637A - A kind of anti-deicing electric heating device and preparation method with graphene-carbon nano tube composite material - Google Patents
A kind of anti-deicing electric heating device and preparation method with graphene-carbon nano tube composite material Download PDFInfo
- Publication number
- CN109862637A CN109862637A CN201910047184.XA CN201910047184A CN109862637A CN 109862637 A CN109862637 A CN 109862637A CN 201910047184 A CN201910047184 A CN 201910047184A CN 109862637 A CN109862637 A CN 109862637A
- Authority
- CN
- China
- Prior art keywords
- graphene
- carbon nano
- composite material
- nano tube
- tube composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 68
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 67
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 67
- 238000005485 electric heating Methods 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 31
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 16
- 229920001721 polyimide Polymers 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 9
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000005538 encapsulation Methods 0.000 claims description 3
- 238000007731 hot pressing Methods 0.000 claims description 3
- 238000003698 laser cutting Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000007772 electrode material Substances 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 230000005611 electricity Effects 0.000 abstract description 3
- 238000009826 distribution Methods 0.000 abstract description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229960000935 dehydrated alcohol Drugs 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- -1 graphite Alkene Chemical class 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses a kind of anti-deicing electric heating devices and preparation method with graphene-carbon nano tube composite material, the electric heating device is using polyimide film as substrate, uniformly distributed one layer of strip for heating or latticed graphene-carbon nano tube composite material form graphene-carbon nano tube composite material layer in substrate, graphene-carbon nano tube composite material layer both ends are provided with electrode, and one layer of graphene film layer for being used for insulating heat-conductive is laid on graphene-carbon nano tube composite material layer.For the present invention using graphene-carbon nano tube composite material as conductive exothermal source, heating rate is fast compared to tradition electricity plus silk heating；For graphene film layer as Heat Conduction Material, surface temperature distribution compares traditional electric heating wire heating more evenly；Electric heating device is arranged in leading edge of a wing position, when work is powered using constant current or constant pressure source, and anti-de-icing work can be effectively carried out under different ice-formation conditions by changing output power.
Description
Technical field
The present invention relates to the anti-deicing technical fields of aircraft, and in particular to a kind of with graphene-carbon nano tube composite material
Anti- deicing electric heating device and preparation method.
Background technique
Aircraft icing is always one of the chief threat of aviation safety.Aircraft table in ground shutdown status and flight course
Face can all freeze, and mainly icing position includes wing, propeller, radome, windscreen, engine lip, control surface to aircraft
Deng.The anti-deicing of aircraft wing at present mainly uses the anti-deicing system of hot gas, and heating efficiency is low, and can reduce motor power.
After electric aircraft theory proposes, there is an urgent need to develop the anti-de-icing method of more energy-efficient electric heating.
In the modern anti-deicing system of electric heating, mostly uses resistance wire as heater element, kept away by way of partition heating
Exempt to generate central hot spot.Traditional electric heating system rate of heat addition is slow, takes a long time heating wing cover, and heating region
Non-uniform temperature.
Summary of the invention
Goal of the invention: in order to overcome above-mentioned the deficiencies in the prior art, the present invention provides a kind of to be received with graphene-carbon
The anti-deicing electric heating device and preparation method of mitron composite material, make full use of graphene-carbon nano tube composite material performance
Anti- de-icing work is carried out, it is slow to solve traditional electric heating rate of heat addition, and adds for easy to operate, simple process and effect is obvious
The problem of thermal region non-uniform temperature.
Technical solution: a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material of the present invention, the electricity add
Heat structure is using polyimide film as substrate, and uniformly distributed one layer of strip for heating or latticed graphene-carbon are received in the substrate
Mitron composite material forms graphene-carbon nano tube composite material layer, and graphene-carbon nano tube composite material layer both ends are equal
It is provided with electrode, one layer of graphene film layer for being used for insulating heat-conductive is laid on the graphene-carbon nano tube composite material layer,
The graphene film layer has biadhesive.
Further, the electrode material is the conductive silver paste containing 1%~5% Graphene powder.
Further, the substrate with a thickness of 200~500 μm.
Further, the graphene-carbon nano tube composite material is strip, and 10~30mm of width, length is less than
1000mm。
Further, the first insulation is equipped between the graphene-carbon nano tube composite material layer and graphene film layer
Layer, first thickness of insulating layer are 20~50 μm；The graphene film layer is equipped with second insulating layer, second insulation
For layer with a thickness of 30 μm, the material of first insulating layer and second insulating layer is polyimide film.
The present invention also provides a kind of preparation sides of anti-deicing electric heating device with graphene-carbon nano tube composite material
Method, comprising steps of
(1) by the way of laser cutting that graphene-carbon nano tube composite material cutting is into strips or latticed, simultaneously
Guarantee edge impulse- free robustness；
(2) strip or latticed graphene-carbon nano tube composite material are evenly distributed with as substrate using polyimide film
Graphene-carbon nano tube composite material layer is formed on the substrate；
(3) graphene-carbon nano tube composite material layer both ends are uniformly coated with conductive silver paste as electrode, to conductive silver paste
It is laid with the copper strips with connecting terminal on surface after solidification, and carries out energization test；
(4) one layer of graphene film layer for being used for insulating heat-conductive, stone will be laid on graphene-carbon nano tube composite material layer
Black alkene film layer has biadhesive；
(5) above structure marginal portion is packaged using high temperature hot pressing machine, obtains electric heating device.
Further, encapsulation carries out under vacuum conditions in the step (5), excludes air between each layer, applies pressure
Guarantee that each layer bonding is reliable.
Further, it is equipped between graphene-carbon nano tube composite material layer and graphene film layer in the step (4)
First insulating layer, graphene film layer are equipped with second insulating layer, and the material of first insulating layer and second insulating layer is
Polyimide film.
Compared with prior art, the present invention having following technical effect that
1, the present invention is using graphene-carbon nano tube composite material as conductive exothermal source, and heating rate is compared to tradition electricity
Add silk heating fast, energy consumption compares traditional electric heating low 20%~40%；
2, ground experiment is verified the heating structure and can be worked normally at -70~300 DEG C, and improving electric heating, to prevent and kill off ice environment suitable
It should be able to power；
3, the advantage for making full use of graphene-carbon nano tube composite material conductive exothermal fast is laid with one layer of graphene film
Layer is used as Heat Conduction Material, and it is thermally conductive more uniform that surface temperature distribution compares traditional electric heating wire；
It 4, is mode in parallel, more when using strip graphene-carbon nano tube composite material inside the electric heating device
Item remains to work normally in the case where damaging, and improves aircraft icing guard system safety；
5, the present invention uses layer flexible structure, can fit closely with aircraft skin, effectively improve heat transfer efficiency.
Electric heating device of the present invention is arranged in leading edge of a wing position, and when work is powered using constant current or constant pressure source, leads to
Anti- de-icing work can effectively be carried out under different ice-formation conditions by crossing change output power, have equipment it is simple, it is easy to operate and
The advantages such as effect is obvious, great prepare with scale prospect.
Detailed description of the invention
Fig. 1 is scheme of installation inside wing cover；
Fig. 2 is electric heating device schematic diagram of the present invention；
Fig. 3 is that strip graphene-carbon nano tube composite material layer is laid with schematic diagram；
Fig. 4 is that latticed graphene-carbon nano tube composite material layer is laid with schematic diagram.
Specific embodiment
The present invention is described further with reference to the accompanying drawings and examples:
As shown in Figures 1 to 4, a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material of the present invention,
The electric heating device 2 is arranged in 1 leading edge position of wing, electric heating device 2 and 1 covering inner surface of aircraft wing by riveting or glues
Knot mode is combined closely, and guarantees that contact is firm.
Electric heating device 2 is divided into three layers, first using polyimide film as substrate 5, substrate 5 with a thickness of 200~500 μ
m；Uniformly distributed one layer of graphene-carbon nano tube composite material for heating forms graphene-carbon nano tube composite material in substrate 5
Layer 4, graphene-carbon nano tube composite material layer 4 with a thickness of 20 μm, simultaneously because 1 leading edge ice sheet of wing is thick when aircraft freezes
Degree is uneven, and the shape of graphene-carbon nano tube composite material is cut into strip or latticed by laser, can be by changing between strip
Away from different zones heating power is controlled under conditions of heating power is constant with netted pore size, anti-deicing energy consumption is reduced；When
Graphene-carbon nano tube composite material is strip, and 10~30mm of width, length is less than 1000mm；
4 both ends of graphene-carbon nano tube composite material layer are provided with electrode 7, and 7 material of electrode is to contain 1%~5% stone
The conductive silver paste of black alkene powder；One layer of graphene film for being used for insulating heat-conductive is laid on graphene-carbon nano tube composite material layer 4
Layer 6, graphene film layer 6 is with a thickness of 30 μm, lateral thermal coefficient 500~1300W/mK, longitudinal 10~15W/ of thermal coefficient
MK, insulation performance is good, while graphene film layer 6 has biadhesive, and graphene-carbon nano tube composite material layer 4
The first insulating layer 8,8 material polyimide film of the first insulating layer, with a thickness of 20~50 μ are additionally provided between graphene film layer 6
m；Graphene film layer 6 is equipped with second insulating layer 9,9 material polyimide film of second insulating layer, with a thickness of 30 μm；Due to stone
The biadhesive of black alkene film layer 6 can guarantee that the first insulating layer 8 and second insulating layer 9 bond reliably.
It is powered using constant current or constant voltage source 3 by serial or parallel connection mode when work, can be had by changing output power
Effect carries out anti-de-icing work under different ice-formation conditions, measures through test: 3 size of current of constant-current supply is 10~50A, surface
Heating temperature is 60~150 DEG C, and power needed for every square meter graphene-carbon nano tube composite material layer 4 is 600~800W, required
Power is much smaller than existing electric heating system.
A kind of preparation method of the anti-deicing electric heating device with graphene-carbon nano tube composite material of the present invention, including
Step:
(1) by the way of laser cutting that graphene-carbon nano tube composite material cutting is into strips or latticed, simultaneously
Guarantee that edge impulse- free robustness, resistance error are no more than 5%；
(2) using polyimide film as substrate 5, strip or latticed graphene-carbon nano tube composite material is equal
Cloth forms graphene-carbon nano tube composite material layer 4 on substrate 5；
(3) 4 both ends of graphene-carbon nano tube composite material layer are uniformly coated with conductive silver paste as electrode 7, to conductive silver
It starches and is laid with the copper strips with connecting terminal on surface after solidifying, and carry out energization test；
(4) one layer of graphene film layer 6 for being used for insulating heat-conductive will be laid on graphene-carbon nano tube composite material layer 4,
Graphene film layer 6 has biadhesive, and the is equipped between graphene-carbon nano tube composite material layer 4 and graphene film layer 6
One insulating layer 8, graphene film layer 6 are equipped with second insulating layer 9, and the material of the first insulating layer 8 and second insulating layer 9 is poly-
Acid imide film；
(5) above structure marginal portion is packaged using high temperature hot pressing machine, encapsulation carries out under vacuum conditions, excludes
Air between each layer applies pressure and guarantees that each layer bonding is reliable, obtains electric heating device.
Wherein the present invention in graphene-carbon nano tube composite material the preparation method is as follows:
1) graphene microchip is dispersed in dehydrated alcohol and water mixed solution under ultrasonication, is configured to graphite
Alkene content is the dispersion liquid of 0.1mg/ml；
2) ferrocene and thiophene are added in the scattered dispersion liquid of step 1), ultrasound 15 minutes evenly dispersed.Two cyclopentadienyls
Iron and graphene mass ratio are 10:1, and thiophene and graphene mass ratio are 2:1.
3) dispersion liquid prepared in step 2) is put into the stainless steel water thermal response of polytetrafluoroethyllining lining under stiring
In kettle.12h, after reaction, cooled to room temperature are reacted at 200 DEG C.Reaction product separating, washing, drying, for use.
4) reaction product dried in step 3) is added in corundum crucible, is deposited by chemical vapour deposition technique
Carbon source, deposition reaction area include three humidity provinces, respectively gasification zone, the first flat-temperature zone and the second flat-temperature zone, deposition reaction area
Vacuumize, gasification zone temperature then risen to 600 DEG C, the first flat-temperature zone and the second flat-temperature zone temperature rise to 1400 DEG C, then to
Deposition reaction area is passed through the argon gas and hydrogen of 1L/mim, and it is 1:1 that argon gas and hydrogen, which are passed through volume ratio,.It is being passed through argon gas and hydrogen
It is full of entire reaction compartment after 4min, dehydrated alcohol is then passed through to reaction zone by syringe pump, charge velocity 20ml/min,
React 60min.After the reaction was completed, stop heating, close hydrogen, when the temperature in the furnace chamber all drops to room temperature, close
Argon gas.It opens furnace chamber and takes out reaction product, obtain graphene-carbon nano tube composite material.
Claims (8)
1. a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material, it is characterised in that: the electric heating device
Using polyimide film as substrate, uniformly distributed one layer of strip for heating or latticed graphene-carbon nano tube are multiple in the substrate
Condensation material forms graphene-carbon nano tube composite material layer, and graphene-carbon nano tube composite material layer both ends are provided with
Electrode is laid with one layer of graphene film layer for being used for insulating heat-conductive, the stone on the graphene-carbon nano tube composite material layer
Black alkene film layer has biadhesive.
2. a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material according to claim 1, special
Sign is: the electrode material is the conductive silver paste containing 1%~5% Graphene powder.
3. a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material according to claim 1, special
Sign is: the substrate with a thickness of 200~500 μm.
4. a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material according to claim 1, special
Sign is: the graphene-carbon nano tube composite material is strip, and 10~30mm of width, length is less than 1000mm.
5. a kind of anti-deicing electric heating device with graphene-carbon nano tube composite material according to claim 1, special
Sign is: between the graphene-carbon nano tube composite material layer and graphene film layer be equipped with the first insulating layer, described first
Thickness of insulating layer is 20~50 μm；The graphene film layer is equipped with second insulating layer, and the second insulating layer is with a thickness of 30 μ
The material of m, first insulating layer and second insulating layer is polyimide film.
6. a kind of preparation method of the anti-deicing electric heating device with graphene-carbon nano tube composite material, which is characterized in that packet
Include step:
(1) by the way of laser cutting that graphene-carbon nano tube composite material cutting is into strips or latticed, guarantee simultaneously
Edge impulse- free robustness；
(2) strip or latticed graphene-carbon nano tube composite material are evenly arranged on as substrate by base using polyimide film
Graphene-carbon nano tube composite material layer is formed on bottom；
(3) graphene-carbon nano tube composite material layer both ends are uniformly coated with conductive silver paste as electrode, solidified to conductive silver paste
It is laid with the copper strips with connecting terminal on surface afterwards, and carries out energization test；
(4) one layer of graphene film layer for being used for insulating heat-conductive, graphene will be laid on graphene-carbon nano tube composite material layer
Film layer has biadhesive；
(5) above structure marginal portion is packaged using high temperature hot pressing machine, obtains electric heating device.
7. a kind of system of anti-deicing electric heating device with graphene-carbon nano tube composite material according to claim 6
Preparation Method, it is characterised in that: encapsulation carries out under vacuum conditions in the step (5).
8. a kind of system of anti-deicing electric heating device with graphene-carbon nano tube composite material according to claim 6
Preparation Method, it is characterised in that: set between graphene-carbon nano tube composite material layer and graphene film layer in the step (4)
There is the first insulating layer, graphene film layer is equipped with second insulating layer, and the material of first insulating layer and second insulating layer is equal
For polyimide film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910047184.XA CN109862637A (en) | 2019-01-18 | 2019-01-18 | A kind of anti-deicing electric heating device and preparation method with graphene-carbon nano tube composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910047184.XA CN109862637A (en) | 2019-01-18 | 2019-01-18 | A kind of anti-deicing electric heating device and preparation method with graphene-carbon nano tube composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109862637A true CN109862637A (en) | 2019-06-07 |
Family
ID=66895099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910047184.XA Pending CN109862637A (en) | 2019-01-18 | 2019-01-18 | A kind of anti-deicing electric heating device and preparation method with graphene-carbon nano tube composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109862637A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110481793A (en) * | 2019-07-12 | 2019-11-22 | 中国人民解放军空军工程大学 | A kind of new electrically heating ice shape regulation method and anti-freeze type aircraft |
| CN110481795A (en) * | 2019-09-11 | 2019-11-22 | 山东大学 | A kind of graphene composite material ice preventing and removing device for helicopter rotors and production method |
| CN111105895A (en) * | 2019-10-21 | 2020-05-05 | 珠海烯蟀科技有限公司 | Method and device for supplying power by using silver paste as high borosilicate graphene layer |
| CN111231376A (en) * | 2019-12-03 | 2020-06-05 | 惠阳航空螺旋桨有限责任公司 | Electric heating unit die and method for preparing electric heating unit assembly by using same |
| CN112124600A (en) * | 2020-09-30 | 2020-12-25 | 中航(成都)无人机系统股份有限公司 | Anti-icing and deicing coating of composite wing |
| CN112629093A (en) * | 2021-03-09 | 2021-04-09 | 中国空气动力研究与发展中心低速空气动力研究所 | Method for removing ice growing on surface of film hot knife and model |
| CN112920704A (en) * | 2019-12-05 | 2021-06-08 | 中车唐山机车车辆有限公司 | Electric heating coating paint, electric heating skin and ice and snow prevention system |
| CN113597032A (en) * | 2021-08-10 | 2021-11-02 | 北京航空航天大学 | Compatible stealth anti-icing material and preparation method and application thereof |
| CN114524080A (en) * | 2022-02-18 | 2022-05-24 | 中国航发北京航空材料研究院 | Carbon nanotube film electrothermal composite material skin structure for preventing and removing ice and preparation method thereof |
| CN116061459A (en) * | 2021-12-02 | 2023-05-05 | 江西九由航空装备有限公司 | Method for paving electric heating sheet on quadric surface |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107613589A (en) * | 2017-10-23 | 2018-01-19 | 南京旭羽睿材料科技有限公司 | A kind of graphene heating film |
| CN207035290U (en) * | 2017-06-09 | 2018-02-23 | 浙江冬日暖阳电热科技有限公司 | Heating floor |
| CN108069420A (en) * | 2017-11-24 | 2018-05-25 | 江苏先丰纳米材料科技有限公司 | A kind of preparation method of graphene/graphene oxide-carbon nano tube compound material |
| CN108417291A (en) * | 2018-02-08 | 2018-08-17 | 浙江正泰太阳能科技有限公司 | Conductive silver paste for solar cell and preparation method thereof and solar cell |
-
2019
- 2019-01-18 CN CN201910047184.XA patent/CN109862637A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN207035290U (en) * | 2017-06-09 | 2018-02-23 | 浙江冬日暖阳电热科技有限公司 | Heating floor |
| CN107613589A (en) * | 2017-10-23 | 2018-01-19 | 南京旭羽睿材料科技有限公司 | A kind of graphene heating film |
| CN108069420A (en) * | 2017-11-24 | 2018-05-25 | 江苏先丰纳米材料科技有限公司 | A kind of preparation method of graphene/graphene oxide-carbon nano tube compound material |
| CN108417291A (en) * | 2018-02-08 | 2018-08-17 | 浙江正泰太阳能科技有限公司 | Conductive silver paste for solar cell and preparation method thereof and solar cell |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110481793A (en) * | 2019-07-12 | 2019-11-22 | 中国人民解放军空军工程大学 | A kind of new electrically heating ice shape regulation method and anti-freeze type aircraft |
| CN110481795A (en) * | 2019-09-11 | 2019-11-22 | 山东大学 | A kind of graphene composite material ice preventing and removing device for helicopter rotors and production method |
| CN111105895A (en) * | 2019-10-21 | 2020-05-05 | 珠海烯蟀科技有限公司 | Method and device for supplying power by using silver paste as high borosilicate graphene layer |
| CN111231376A (en) * | 2019-12-03 | 2020-06-05 | 惠阳航空螺旋桨有限责任公司 | Electric heating unit die and method for preparing electric heating unit assembly by using same |
| CN112920704A (en) * | 2019-12-05 | 2021-06-08 | 中车唐山机车车辆有限公司 | Electric heating coating paint, electric heating skin and ice and snow prevention system |
| CN112124600A (en) * | 2020-09-30 | 2020-12-25 | 中航(成都)无人机系统股份有限公司 | Anti-icing and deicing coating of composite wing |
| CN112629093A (en) * | 2021-03-09 | 2021-04-09 | 中国空气动力研究与发展中心低速空气动力研究所 | Method for removing ice growing on surface of film hot knife and model |
| CN112629093B (en) * | 2021-03-09 | 2021-07-02 | 中国空气动力研究与发展中心低速空气动力研究所 | Method for removing ice growing on surface of film hot knife and model |
| CN113597032A (en) * | 2021-08-10 | 2021-11-02 | 北京航空航天大学 | Compatible stealth anti-icing material and preparation method and application thereof |
| CN116061459A (en) * | 2021-12-02 | 2023-05-05 | 江西九由航空装备有限公司 | Method for paving electric heating sheet on quadric surface |
| CN114524080A (en) * | 2022-02-18 | 2022-05-24 | 中国航发北京航空材料研究院 | Carbon nanotube film electrothermal composite material skin structure for preventing and removing ice and preparation method thereof |
| CN114524080B (en) * | 2022-02-18 | 2024-04-09 | 中国航发北京航空材料研究院 | Composite material skin structure with carbon nano tube film for electrothermal ice prevention and deicing and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109862637A (en) | A kind of anti-deicing electric heating device and preparation method with graphene-carbon nano tube composite material | |
| CN103291560A (en) | Anti-icing method of carbon crystal and wind power generator anti-icing system employing method | |
| CN107097478A (en) | A kind of Ceramic Tiles with heating function and preparation method thereof | |
| CN110510102B (en) | Attachable self-resistance heating/super-hydrophobic integrated gradient film material | |
| CN105491695A (en) | Two-dimensional nano carbon heating body, and flexible electric heating module and preparation method therefor | |
| CN105856586A (en) | Icing protection system for wind turbine blade with graphene electrothermal films | |
| CN109068412A (en) | A kind of containing graphene and the water nano heating film of carbon nanotube and preparation method thereof | |
| CN104477892A (en) | Preparation method of flake graphene and flake graphene device prepared by same | |
| CN203362411U (en) | Carbon crystal anti-icing system for aerogenerator | |
| CN212227196U (en) | Ceramic tile structure warms up graphite alkene | |
| CN108016622A (en) | A kind of anti-icing method and device of active aircraft | |
| CN109532138A (en) | A kind of electric heating of high-efficiency soft is anti-/ deicing plied timber | |
| CN104875894A (en) | Dielectric barrier discharge plasma anti-icing device and method | |
| CN208704264U (en) | A kind of face heater for refrigerator defrost | |
| CN107057575B (en) | One kind preventing/deicing system for extreme environment naval vessel surface low power consuming electric heating | |
| Wu et al. | Effect of carbon fiber bundles spacing on composites and their electrothermal and anti/deicing properties | |
| CN204993909U (en) | Graphite alkene adds hotting mask | |
| CN210206286U (en) | Automatic heating spraying gun body | |
| CN112572808A (en) | Double-layer anti-icing and electric heating structure and wing adopting same | |
| CN115334701B (en) | Heater and preparation method and application thereof | |
| CN217741932U (en) | Heating structure | |
| CN207513766U (en) | A kind of wind generator set blade deicing system | |
| CN219499566U (en) | Graphene fiber electric heating device | |
| CN107605670A (en) | A kind of wind generator set blade deicing system | |
| CN208106668U (en) | A kind of wind electricity blade appearance facial mask structure heating deicing system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200413 Address after: Yudaojie Qinhuai District of Nanjing City, Jiangsu Province, No. 29 210016 Applicant after: Nanjing University of Aeronautics and Astronautics Applicant after: JIANGSU XFNANO MATERIALS TECH Co.,Ltd. Address before: Yudaojie Qinhuai District of Nanjing City, Jiangsu Province, No. 29 210016 Applicant before: Nanjing University of Aeronautics and Astronautics |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190607 |