CN109853249A - A kind of natural feather care agent and preparation method thereof of the anti-mite of antibacterial - Google Patents
A kind of natural feather care agent and preparation method thereof of the anti-mite of antibacterial Download PDFInfo
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- CN109853249A CN109853249A CN201811438287.0A CN201811438287A CN109853249A CN 109853249 A CN109853249 A CN 109853249A CN 201811438287 A CN201811438287 A CN 201811438287A CN 109853249 A CN109853249 A CN 109853249A
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Abstract
The present invention discloses a kind of natural feather care agent of anti-mite of antibacterial, it is made of the component of following parts by weight: 15-20 parts of isopropanol, 8-12 parts of glycerine, 0.2-0.4 parts of lanthanum chloride, 0.7-1.0 parts of sodium naphthenate, 11-13 parts of deionized water, 2-5 parts of ethylcyclopentenolone, 1-3 parts of 4- halogen trimethylsilylbenzene ethylene, 0.2-0.5 parts of nano ATOs, 5-9 parts of dimethacrylate diethylene glycol (DEG) ester, 4-7 parts of methyl methacrylate, N, 2-5 parts of N- dimethylamino ethyl acrylate, 0.8-1.1 parts of the third rouge of 3- trimethoxy silane acrylic acid, 0.001-0.003 parts of initiator, 34-40 parts of distilled water.A kind of natural feather care agent of the anti-mite of antibacterial provided by the invention, it is environmentally protective, the quality of natural feather can be effectively promoted, and can quickly kill various bacteriums and the acarid on natural feather.
Description
Technical field
The invention belongs to natural feather nursing technique fields, and in particular to a kind of natural feather care agent of the anti-mite of antibacterial and its preparation side
Method.
Background technique
Natural feather is the abdomen grown in geese and ducks, lupine-like villus, and slabbing is feather.Since natural feather is a kind of
Animal protein fiber, the tiny stomata for ten million triangle that gathers on natural feather nodular fibrous, can shrink with temperature change
Expansion, generates temperature adjustment function, and absorbable human body distributes the hot gas of flowing, completely cuts off the invasion of cool ambient air.From the inspection of fluffy degree
Analyzed in survey, natural feather than silk, the heat insulating materials such as cotton will a high grade, for example 450 degree of minimum standard fluffy
90 duck's downs are also more fluffy than silk and cotton good, so natural feather is purely by way of a heat insulating material, its economic value is much high
In other heat insulating materials.But natural feather is during use, bacterium easy to breed and various acarids have seriously affected natural feather
It further uses.
Summary of the invention
The object of the present invention is to provide natural feather care agents of the anti-mite of a kind of antibacterial and preparation method thereof, can effectively kill
The various pathogenic microorganisms and acarid depended on natural feather, promote the quality of natural feather.
The present invention is achieved by the following technical solutions.
A kind of natural feather care agent of the anti-mite of antibacterial, is made: 15-20 parts of isopropanol, glycerine of the component of following parts by weight
8-12 parts, 0.2-0.4 parts of lanthanum chloride, 0.7-1.0 parts of sodium naphthenate, 11-13 parts of deionized water, 2-5 parts of ethylcyclopentenolone,
1-3 parts, 0.2-0.5 parts nano ATOs of 4- halogen trimethylsilylbenzene ethylene, 5-9 parts of dimethacrylate diethylene glycol (DEG) ester, methacrylic acid
4-7 parts of methyl esters, N, 2-5 parts of N- dimethylamino ethyl acrylate, cause 0.8-1.1 parts of the third rouge of 3- trimethoxy silane acrylic acid
0.001-0.003 parts of agent, 34-40 parts of distilled water.
A kind of preparation method of the natural feather care agent of the anti-mite of antibacterial, including following operating procedure:
(1) in deionized water by sodium naphthenate dissolution, it is then heated to 75-80 DEG C, lanthanum chloride is added thereto, stirred
After uniformly, after isothermal holding 30-40min, lanthanum naphthenate is made；
(2) by dimethacrylate diethylene glycol (DEG) ester, methyl methacrylate, N, N- dimethylamino ethyl acrylate, 3- tri-
The third rouge of methoxy silane acrylic acid is added into distilled water, and after being mixed evenly, initiator, reaction treatment 2- are added thereto
After 3 hours, polymerized emulsion is obtained；
(3) isopropanol, glycerine, ethylcyclopentenolone, 4- trimethyl silicon substrate are then sequentially added into polymerized emulsion
After styrene, nano ATO, lanthanum naphthenate, high-speed stirred is uniform, and the natural feather care agent of the anti-mite of antibacterial is made.
It specifically, further include that distillation water quality 1- is added into distilled water before initiator is added in above-mentioned steps (2)
3% emulsifier.
Specifically, the emulsifier is emulsifier op-10.
Specifically, in above-mentioned steps (2), the initiator is isopropyl benzene hydroperoxide, appointing in tert-butyl hydroperoxide
It anticipates one kind.
Specifically, in above-mentioned steps (3), nano ATO is the ratio that tin oxide and antimony oxide are 9:1 according to mass ratio
It is made.
From the above technical scheme, it can be seen that the beneficial effects of the present invention are:
A kind of natural feather care agent of the anti-mite of antibacterial provided by the invention, it is environmentally protective, the quality of natural feather can be effectively promoted,
And it can quickly kill various bacteriums and the acarid on natural feather.The addition of lanthanum naphthenate, it is excellent in compatibility with natural feather, simultaneously
Lanthanum element can effectively inhibit the growth of the bacterium and acarid on natural feather, and on the other hand, lanthanum naphthenate can also to a certain extent
Promote the flexibility of natural feather；Polymerized emulsion provided by the invention, can effectively be promoted the resistance to feltability of natural feather, crease recovery,
Tensile strength, and the antibacterial and antimite ability of natural feather can also be promoted.
Specific embodiment
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.Reality used in the examples
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of natural feather care agent of the anti-mite of antibacterial, is made of the component of following parts by weight: 15 parts of isopropanol, 8 parts of glycerine,
0.2 part of lanthanum chloride, 0.7 part of sodium naphthenate, 11 parts of deionized water, 2 parts of ethylcyclopentenolone, 4- halogen trimethylsilylbenzene ethylene 1
Part, 0.2 part of nano ATO, 5 parts of dimethacrylate diethylene glycol (DEG) ester, 4 parts of methyl methacrylate, N, N- dimethylamino acrylic acid
2 parts of ethyl ester, 0.8 part of the third rouge of 3- trimethoxy silane acrylic acid, 0.001 part of initiator, 34 parts of distilled water.
A kind of preparation method of the natural feather care agent of the anti-mite of antibacterial, including following operating procedure:
(1) in deionized water by sodium naphthenate dissolution, 75 DEG C are then heated to, lanthanum chloride is added thereto, stirring is equal
After even, after isothermal holding 30min, lanthanum naphthenate is made；
(2) by dimethacrylate diethylene glycol (DEG) ester, methyl methacrylate, N, N- dimethylamino ethyl acrylate, 3- tri-
The third rouge of methoxy silane acrylic acid is added into distilled water, and after being mixed evenly, initiator, reaction treatment 2 are added thereto
After hour, polymerized emulsion is obtained；
(3) isopropanol, glycerine, ethylcyclopentenolone, 4- trimethyl silicon substrate are then sequentially added into polymerized emulsion
After styrene, nano ATO, lanthanum naphthenate, high-speed stirred is uniform, and the natural feather care agent of the anti-mite of antibacterial is made.
It specifically, further include that distillation water quality 1% is added into distilled water before initiator is added in above-mentioned steps (2)
Emulsifier.
Specifically, the emulsifier is emulsifier op-10.
Specifically, in above-mentioned steps (2), the initiator is isopropyl benzene hydroperoxide.
Specifically, in above-mentioned steps (3), nano ATO is the ratio that tin oxide and antimony oxide are 9:1 according to mass ratio
It is made.
Embodiment 2
A kind of natural feather care agent of the anti-mite of antibacterial, is made of the component of following parts by weight: 16 parts of isopropanol, 9 parts of glycerine,
0.2 part of lanthanum chloride, 0.8 part of sodium naphthenate, 12 parts of deionized water, 3 parts of ethylcyclopentenolone, 4- halogen trimethylsilylbenzene ethylene 2
Part, 0.3 part of nano ATO, 6 parts of dimethacrylate diethylene glycol (DEG) ester, 6 parts of methyl methacrylate, N, N- dimethylamino acrylic acid
3 parts of ethyl ester, 1.0 parts of the third rouge of 3- trimethoxy silane acrylic acid, 0.002 part of initiator, 36 parts of distilled water.
A kind of preparation method of the natural feather care agent of the anti-mite of antibacterial, including following operating procedure:
(1) in deionized water by sodium naphthenate dissolution, 77 DEG C are then heated to, lanthanum chloride is added thereto, stirring is equal
After even, after isothermal holding 33min, lanthanum naphthenate is made；
(2) by dimethacrylate diethylene glycol (DEG) ester, methyl methacrylate, N, N- dimethylamino ethyl acrylate, 3- tri-
The third rouge of methoxy silane acrylic acid is added into distilled water, and after being mixed evenly, initiator, reaction treatment are added thereto
After 2.2 hours, polymerized emulsion is obtained；
(3) isopropanol, glycerine, ethylcyclopentenolone, 4- trimethyl silicon substrate are then sequentially added into polymerized emulsion
After styrene, nano ATO, lanthanum naphthenate, high-speed stirred is uniform, and the natural feather care agent of the anti-mite of antibacterial is made.
It specifically, further include that distillation water quality 2% is added into distilled water before initiator is added in above-mentioned steps (2)
Emulsifier.
Specifically, the emulsifier is emulsifier op-10.
Specifically, in above-mentioned steps (2), the initiator is isopropyl benzene hydroperoxide.
Specifically, in above-mentioned steps (3), nano ATO is the ratio that tin oxide and antimony oxide are 9:1 according to mass ratio
It is made.
Embodiment 3
A kind of natural feather care agent of the anti-mite of antibacterial, is made: 18 parts of isopropanol, glycerine 10 of the component of following parts by weight
Part, 0.3 part of lanthanum chloride, 0.9 part of sodium naphthenate, 12 parts of deionized water, 4 parts of ethylcyclopentenolone, 4- halogen trimethylsilylbenzene second
2 parts, 0.4 part nano ATO of alkene, 8 parts of dimethacrylate diethylene glycol (DEG) ester, 6 parts of methyl methacrylate, N, N- dimethylamino propylene
3 parts of acetoacetic ester, 1.0 parts of the third rouge of 3- trimethoxy silane acrylic acid, 0.002 part of initiator, 38 parts of distilled water.
A kind of preparation method of the natural feather care agent of the anti-mite of antibacterial, including following operating procedure:
(1) in deionized water by sodium naphthenate dissolution, 78 DEG C are then heated to, lanthanum chloride is added thereto, stirring is equal
After even, after isothermal holding 38min, lanthanum naphthenate is made；
(2) by dimethacrylate diethylene glycol (DEG) ester, methyl methacrylate, N, N- dimethylamino ethyl acrylate, 3- tri-
The third rouge of methoxy silane acrylic acid is added into distilled water, and after being mixed evenly, initiator, reaction treatment are added thereto
After 2.8 hours, polymerized emulsion is obtained；
(3) isopropanol, glycerine, ethylcyclopentenolone, 4- trimethyl silicon substrate are then sequentially added into polymerized emulsion
After styrene, nano ATO, lanthanum naphthenate, high-speed stirred is uniform, and the natural feather care agent of the anti-mite of antibacterial is made.
It specifically, further include that distillation water quality 2% is added into distilled water before initiator is added in above-mentioned steps (2)
Emulsifier.
Specifically, the emulsifier is emulsifier op-10.
Specifically, in above-mentioned steps (2), the initiator is tert-butyl hydroperoxide.
Specifically, in above-mentioned steps (3), nano ATO is the ratio that tin oxide and antimony oxide are 9:1 according to mass ratio
It is made.
Embodiment 4
A kind of natural feather care agent of the anti-mite of antibacterial, is made: 20 parts of isopropanol, glycerine 12 of the component of following parts by weight
Part, 0.4 part of lanthanum chloride, 1.0 parts of sodium naphthenate, 13 parts of deionized water, 5 parts of ethylcyclopentenolone, 4- halogen trimethylsilylbenzene second
3 parts, 0.5 part nano ATO of alkene, 9 parts of dimethacrylate diethylene glycol (DEG) ester, 7 parts of methyl methacrylate, N, N- dimethylamino propylene
5 parts of acetoacetic ester, 1.1 parts of the third rouge of 3- trimethoxy silane acrylic acid, 0.003 part of initiator, 34-40 parts of distillation.
A kind of preparation method of the natural feather care agent of the anti-mite of antibacterial, including following operating procedure:
(1) in deionized water by sodium naphthenate dissolution, 80 DEG C are then heated to, lanthanum chloride is added thereto, stirring is equal
After even, after isothermal holding 40min, lanthanum naphthenate is made；
(2) by dimethacrylate diethylene glycol (DEG) ester, methyl methacrylate, N, N- dimethylamino ethyl acrylate, 3- tri-
The third rouge of methoxy silane acrylic acid is added into distilled water, and after being mixed evenly, initiator, reaction treatment 3 are added thereto
After hour, polymerized emulsion is obtained；
(3) isopropanol, glycerine, ethylcyclopentenolone, 4- trimethyl silicon substrate are then sequentially added into polymerized emulsion
After styrene, nano ATO, lanthanum naphthenate, high-speed stirred is uniform, and the natural feather care agent of the anti-mite of antibacterial is made.
It specifically, further include that distillation water quality 3% is added into distilled water before initiator is added in above-mentioned steps (2)
Emulsifier.
Specifically, the emulsifier is emulsifier op-10.
Specifically, in above-mentioned steps (2), the initiator is tert-butyl hydroperoxide.
Specifically, in above-mentioned steps (3), nano ATO is the ratio that tin oxide and antimony oxide are 9:1 according to mass ratio
It is made.
Comparative example 1
Lanthanum naphthenate is not added, remaining operating procedure is identical with embodiment 1.
Comparative example 2
Polymerized emulsion is not added, remaining operating procedure is identical with embodiment 2.
The natural feather care agent of the anti-mite of antibacterial is made with the method for each embodiment and comparative example respectively, then with it to same a batch
Natural feather product carries out care operation, and test result is as shown in table 1:
A kind of compliance test result of the natural feather care agent of the 1 anti-mite of antibacterial of table
As shown in Table 1, the natural feather care agent of the anti-mite of a kind of antibacterial produced by the present invention, degerming anti-mite significant effect, and
The quality of natural feather can be promoted.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, the art
Those of ordinary skill, within the essential scope of the present invention, variation, change, addition or the replacement made all should belong to the present invention
Protection scope.
Claims (6)
1. a kind of natural feather care agent of the anti-mite of antibacterial, which is characterized in that be made of the component of following parts by weight: isopropanol 15-20
Part, 8-12 parts of glycerine, 0.2-0.4 parts of lanthanum chloride, 0.7-1.0 parts of sodium naphthenate, 11-13 parts of deionized water, ethylcyclopentene
2-5 parts of alcohol ketone, 1-3 parts, 0.2-0.5 parts nano ATOs of 4- halogen trimethylsilylbenzene ethylene, 5-9 parts of dimethacrylate diethylene glycol (DEG) ester,
4-7 parts of methyl methacrylate, N, 2-5 parts of N- dimethylamino ethyl acrylate, 3- trimethoxy silane the third rouge of acrylic acid 0.8-
1.1 parts, 0.001-0.003 parts of initiator, 34-40 parts of distilled water.
2. a kind of preparation method of the natural feather care agent of the anti-mite of antibacterial as described in claim 1, which is characterized in that including following
Operating procedure:
(1) in deionized water by sodium naphthenate dissolution, it is then heated to 75-80 DEG C, lanthanum chloride is added thereto, is stirred evenly
Afterwards, after isothermal holding 30-40min, lanthanum naphthenate is made；
(2) by dimethacrylate diethylene glycol (DEG) ester, methyl methacrylate, N, N- dimethylamino ethyl acrylate, 3- trimethoxy
The third rouge of base silane acrylic acid is added into distilled water, after being mixed evenly, initiator is added thereto, reaction treatment 2-3 is small
Shi Hou obtains polymerized emulsion；
(3) isopropanol, glycerine, ethylcyclopentenolone, 4- halogen trimethylsilylbenzene second are then sequentially added into polymerized emulsion
After alkene, nano ATO, lanthanum naphthenate, high-speed stirred is uniform, and the natural feather care agent of the anti-mite of antibacterial is made.
3. a kind of preparation method of the natural feather care agent of the anti-mite of antibacterial according to claim 2, which is characterized in that above-mentioned step
It suddenly further include the emulsifier that distillation water quality 1-3% is added into distilled water before initiator is added in (2).
4. a kind of preparation method of the natural feather care agent of the anti-mite of antibacterial according to claim 3, which is characterized in that the cream
Agent is emulsifier op-10.
5. a kind of preparation method of the natural feather care agent of the anti-mite of antibacterial according to claim 2, which is characterized in that above-mentioned step
Suddenly in (2), the initiator is isopropyl benzene hydroperoxide, any one in tert-butyl hydroperoxide.
6. a kind of preparation method of the natural feather care agent of the anti-mite of antibacterial according to claim 2, which is characterized in that above-mentioned step
Suddenly in (3), nano ATO is made of tin oxide and antimony oxide according to mass ratio of the ratio of 9:1.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811438287.0A CN109853249A (en) | 2018-11-28 | 2018-11-28 | A kind of natural feather care agent and preparation method thereof of the anti-mite of antibacterial |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811438287.0A CN109853249A (en) | 2018-11-28 | 2018-11-28 | A kind of natural feather care agent and preparation method thereof of the anti-mite of antibacterial |
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Citations (7)
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|---|---|---|---|---|
| JPH0450381A (en) * | 1990-06-13 | 1992-02-19 | Maruhachi Mawata:Kk | High-quality processing of down |
| CN103451957A (en) * | 2013-08-09 | 2013-12-18 | 安徽华强羽绒有限公司 | Sterilizing and mould-proofing down feather nursing agent and preparation method thereof |
| CN106012554A (en) * | 2016-06-02 | 2016-10-12 | 湖州市菱湖重兆金辉丝织厂 | Down jacket antibacterial finishing agent |
| CN107245884A (en) * | 2017-07-31 | 2017-10-13 | 苏州井村服饰有限公司 | A kind of garment material antibiosis and sterilization agent and preparation method thereof |
| CN107574676A (en) * | 2017-09-13 | 2018-01-12 | 苏州贝彩纳米科技有限公司 | The preparation of antibacterial structure color fibre based on fibroin and antibacterial structure color fabric |
| CN108271773A (en) * | 2018-01-11 | 2018-07-13 | 深圳市爱丽客精细化工有限公司 | Composite antibacterial particle, preparation method and application |
| CN108797109A (en) * | 2018-06-27 | 2018-11-13 | 阜南美凯服饰有限公司 | A kind of knitting fabric afterfinish method |
-
2018
- 2018-11-28 CN CN201811438287.0A patent/CN109853249A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0450381A (en) * | 1990-06-13 | 1992-02-19 | Maruhachi Mawata:Kk | High-quality processing of down |
| CN103451957A (en) * | 2013-08-09 | 2013-12-18 | 安徽华强羽绒有限公司 | Sterilizing and mould-proofing down feather nursing agent and preparation method thereof |
| CN106012554A (en) * | 2016-06-02 | 2016-10-12 | 湖州市菱湖重兆金辉丝织厂 | Down jacket antibacterial finishing agent |
| CN107245884A (en) * | 2017-07-31 | 2017-10-13 | 苏州井村服饰有限公司 | A kind of garment material antibiosis and sterilization agent and preparation method thereof |
| CN107574676A (en) * | 2017-09-13 | 2018-01-12 | 苏州贝彩纳米科技有限公司 | The preparation of antibacterial structure color fibre based on fibroin and antibacterial structure color fabric |
| CN108271773A (en) * | 2018-01-11 | 2018-07-13 | 深圳市爱丽客精细化工有限公司 | Composite antibacterial particle, preparation method and application |
| CN108797109A (en) * | 2018-06-27 | 2018-11-13 | 阜南美凯服饰有限公司 | A kind of knitting fabric afterfinish method |
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| Title |
|---|
| 刘树文: "《合成香料技术手册 （第二版）》", 31 January 2009, 中国轻工业出版社 * |
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