CN109852200A - A kind of high rigidity UV cure wood coatings - Google Patents
A kind of high rigidity UV cure wood coatings Download PDFInfo
- Publication number
- CN109852200A CN109852200A CN201811445980.0A CN201811445980A CN109852200A CN 109852200 A CN109852200 A CN 109852200A CN 201811445980 A CN201811445980 A CN 201811445980A CN 109852200 A CN109852200 A CN 109852200A
- Authority
- CN
- China
- Prior art keywords
- parts
- photoinitiator
- high rigidity
- wood coatings
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high rigidity UV cure wood coatings, its raw material includes: 20-35 parts of epoxy acrylate by weight, 15-28 parts of urethane acrylate, 15-26 parts of phenyl glycidyl ether acrylate, 3-9 parts of reactive diluent, 0.5-1.2 parts of photoinitiator, 3-15 parts of epoxy resin, 3-8.5 parts of aliphatic cyclic amine, 3-10 parts of epoxy hardener, 3-8 parts of modified graphene oxide, 1-2 parts of nano silica, 0.5-1.6 parts of montmorillonite, 0.3-2 parts of 1- pyrene butyric acid, 1-3 parts of silane coupling agent KH-580, 3, 9- diethyl -3, 9- dihydroxymethyl -1, 5, 7, tetra- oxa- loop coil -5 of 11-, 2-5 parts of 5- hendecane, 0.1-1 parts of auxiliary agent.High rigidity UV cure wood coatings proposed by the present invention, hardness and water-tolerant high with the adhesive force of woodenware substrate, Good Heat-resistance.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of high rigidity UV cure wood coatings.
Background technique
Play decoration and protective effect in the surface that woodwork coating is mainly used for wooden articles.Ultraviolet-curing paint be usually by
Prepolymer, diluent and photoinitiator composition have the characteristics that coating is convenient, curing rate is fast and pollution is few, at present by
It is widely used as woodwork coating.But ultraviolet-curing paint be used for woodenware surface when there is also many deficiencies, such as cured film
Hardness is low, poor water resistance, heat resistance is not good enough etc., limit its application in woodwork coating.Therefore it needs to UV light
Change woodwork coating to be modified, to improve its hardness, water resistance and heat resistance.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of high rigidity UV cure wood coatings,
It is high with the adhesive force of woodenware substrate, hardness and water-tolerant, Good Heat-resistance.
A kind of high rigidity UV cure wood coatings proposed by the present invention, raw material includes: propylene oxide by weight
20-35 parts of acid esters, 15-28 parts of urethane acrylate, 15-26 parts of phenyl glycidyl ether acrylate, reactive diluent 3-9
Part, 0.5-1.2 parts of photoinitiator, 3-15 parts of epoxy resin, 3-8.5 parts of aliphatic cyclic amine, 3-10 parts of epoxy hardener, modified oxidized stone
Black alkene 3-8 parts, 1-2 parts of nano silica, 0.5-1.6 parts of montmorillonite, 0.3-2 parts of 1- pyrene butyric acid, silane coupling agent KH-580
1-3 parts, 3,9- diethyl -3,9- dihydroxymethyl -1,5,7,11- tetra- 2-5 parts of oxa- loop coil -5,5- hendecanes, auxiliary agent 0.1-1
Part.
Preferably, the reactive diluent is ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethyl allene
The mixture of acid glycidyl ester, and the shrink of ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethacrylate is sweet
The weight ratio of grease is 3-9:2-7.
Preferably, the photoinitiator is photoinitiator 651, photoinitiator 184, photoinitiator 369, photoinitiator 754
One of or a variety of mixtures.
Preferably, the aliphatic cyclic amine is one of isophorone diamine, 4,4'-, bis- amido dicyclohexyl methyl hydride or two
The mixture of kind.
Preferably, the epoxy hardener is aqueous epoxy curing agent H206B.
Preferably, the modified graphene oxide is prepared according to following technique: by photoinitiator D2959 and succinic acid
Acid anhydride is added in methylene chloride, stirs 20-40min, and 4- methylamino pyridine is then added, 8-13h is reacted at 60-65 DEG C, reacts
After washed, dry, rotary evaporation obtain material A；It adds graphene oxide into water, material A is added after being uniformly dispersed,
And the pH value of regulation system is 5-7, is stirred to react 80-150min at 55-70 DEG C, is filtered, washed, is dried to obtain material B；It will
Material B is added in dimethylformamide, and 120-130 DEG C is warming up to after being uniformly dispersed, and N- methylimidazole is added, tertiary carbon is then added
Acid glycidyl ester is stirred to react 20-45min, cools down, is centrifuged after reaction, washing, being dried to obtain the modified oxidized stone
Black alkene.
Preferably, in the preparation process of modified graphene oxide, photoinitiator D2959, succinic anhydride molar ratio be
1:1；Graphene oxide, material A weight ratio be 1:0.5-0.8；Material B, tertiary carbonic acid glycidyl ester weight ratio be 1:
0.3-0.8。
Preferably, the nano silica is successively to pass through cetyl trimethylammonium bromide and γ-methacryl
The modified nano silica of oxygroup propyl trimethoxy silicane.
Preferably, auxiliary agent is the mixing of one or more of levelling agent, dispersing agent, defoaming agent, adhesion promoter
Object.
High rigidity UV cure wood coatings of the present invention can be according to conventional Paint preparation technology by each raw material
It mixes.
High rigidity UV cure wood coatings of the present invention in raw material, have been specifically chosen epoxy acrylate, poly-
Urethane acrylate, phenyl glycidyl ether acrylate are oligomer, control the content of soft segment in molecule, make coating
Good thermal stability, improved with the adhesive force of a variety of matrixes, hardness increases, high abrasion resistance, while reducing active dilution
The content of agent；In aliphatic cyclic amine addition system, cooperate with epoxy resin, improve the curing rate and hardness of system, and makes gained
Coating color inhibition；Modified graphene oxide, nano silica, in montmorillonite addition system, silane coupling agent KH-580's
It under effect, is uniformly dispersed in system, improves the hardness and strength of coating；In the preparation process of modified graphene oxide,
First using photoinitiator D2959 and succinic anhydride as raw material, the condition of reaction is controlled, makes photoinitiator D2959 and succinic anhydride
It is reacted, has obtained the material A containing carboxyl, the carboxyl and graphene oxide after being mixed with graphene oxide, in material A
Esterification has occurred in the hydroxyl on surface, so that material A to be introduced into the surface of graphene oxide, has obtained material B；Later
Using material B and tertiary carbonic acid glycidyl ester as raw material, the condition of reaction is controlled, makes the carboxyl of surface of graphene oxide in material B
It is reacted with the epoxy group in tertiary carbonic acid glycidyl ester, to will three are combined into one, has obtained modified oxidized stone
Black alkene, is added into system, has space charge force, can generate free radicals under the irradiation of ultraviolet light, cause prepolymer
Solidification crosslinking, participates in the crosslinking curing of film, improves the crosslink density of film, keeps gained film finer and close, improves oxygen
The binding force of graphite alkene and organic cross-linked network improves paint film strength and hardness, while shrinking because introducing versatic acid
Glyceride structure, branched carbon chain improve the hydrophobicity of surface of graphene oxide, hinder the absorption of steam, reduce simultaneously
The content of the labile carboxyl of surface of graphene oxide, the excellent water resistance of imparting coating, while its screen effect, which reduce, to be contained
The collision probability of oxygen groups improves the heat-resisting upper limit, cooperates with 1- pyrene butyric acid, improves the heat resistance of coating, while in system
In be uniformly dispersed, play the dispersion of smaller scale, enhance spatial masking ability, while the hydrophobic structure on its surface is for aqueous
Corrosive medium has certain repulsive force, improves the corrosion resistance of film；In silane coupling agent KH-580 addition system, improve
The compatibility of system, while the solidification of coating can be participated in, it the double bond conversion rate of photocureable coating is improved, reduces light-initiated
The dosage of agent has been formed simultaneously mercapto ether structure, and it is lower that barrier potential is rotated in cross-linked structure, so that product is with tough well
Property, caking property, heat resistance and low water imbibition；3,9- diethyl -3,9- dihydroxymethyls -1,5,7,11- tetra- oxa- loop coils -5,5-
In hendecane addition system, it is decreased obviously the functional group densities of system, and benzene ring structure keeps rigidity to be not susceptible to deformation, because
And lesser volume contraction is shown during photocuring reaction, reduce the cure shrinkage of coating.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of high rigidity UV cure wood coatings proposed by the present invention, raw material includes: propylene oxide by weight
35 parts of acid esters, 15 parts of urethane acrylate, 26 parts of phenyl glycidyl ether acrylate, 3 parts of reactive diluent, photoinitiator
1.2 parts, 3 parts of epoxy resin, 8.5 parts of aliphatic cyclic amine, 3 parts of epoxy hardener, 8 parts of modified graphene oxide, nano silica 1
Part, 1.6 parts of montmorillonite, 0.3 part of 1- pyrene butyric acid, 3 parts of silane coupling agent KH-580,3,9- diethyl -3,9- dihydroxymethyl -1,
5,7,11- tetra- 2 parts of oxa- loop coil -5,5- hendecanes, 1 part of auxiliary agent.
Embodiment 2
A kind of high rigidity UV cure wood coatings proposed by the present invention, raw material includes: propylene oxide by weight
20 parts of acid esters, 28 parts of urethane acrylate, 15 parts of phenyl glycidyl ether acrylate, 9 parts of reactive diluent, photoinitiator
0.5 part, 15 parts of epoxy resin, 3 parts of aliphatic cyclic amine, 10 parts of epoxy hardener, 3 parts of modified graphene oxide, nano silica 2
Part, 0.5 part of montmorillonite, 2 parts of 1- pyrene butyric acid, 1 part of silane coupling agent KH-580,3,9- diethyl -3,9- dihydroxymethyl -1,5,
7,11- tetra- 5 parts of oxa- loop coil -5,5- hendecanes, 0.1 part of auxiliary agent.
Embodiment 3
A kind of high rigidity UV cure wood coatings proposed by the present invention, raw material includes: propylene oxide by weight
31 parts of acid esters, 19 parts of urethane acrylate, 25 parts of phenyl glycidyl ether acrylate, 4 parts of reactive diluent, photoinitiator
1 part, 7 parts of epoxy resin, 8 parts of aliphatic cyclic amine, 5 parts of epoxy hardener, 7 parts of modified graphene oxide, 1.2 parts of nano silica,
1.3 parts of montmorillonite, 0.5 part of 1- pyrene butyric acid, 2.7 parts of silane coupling agent KH-580,3,9- diethyl -3,9- dihydroxymethyl -1,5,
7,11- tetra- 2.8 parts of oxa- loop coil -5,5- hendecanes, 0.8 part of auxiliary agent.
Wherein, the reactive diluent is ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethacrylate
The mixture of ethylene oxidic ester, and ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethyl allene acid glycidyl
The weight ratio of ester is 3:7；
The photoinitiator is photoinitiator 651；
The aliphatic cyclic amine is isophorone diamine；
The epoxy hardener is aqueous epoxy curing agent H206B；
The modified graphene oxide is prepared according to following technique: photoinitiator D2959 and succinic anhydride are added
In methylene chloride, 20min is stirred, 4- methylamino pyridine is then added, 8h is reacted at 65 DEG C, it is washed after reaction, dry
Dry, rotary evaporation obtains material A；It adds graphene oxide into water, material A, and the pH of regulation system is added after being uniformly dispersed
Value is 7, is stirred to react 150min at 55 DEG C, is filtered, washed, is dried to obtain material B；Dimethylformamide is added in material B
In, it is warming up to 120 DEG C after being uniformly dispersed, N- methylimidazole is added, tertiary carbonic acid glycidyl ester is then added, is stirred to react
45min is cooled down after reaction, is centrifuged, washing, being dried to obtain the modified graphene oxide；
In the preparation process of modified graphene oxide, photoinitiator D2959, succinic anhydride molar ratio be 1:1；Oxidation
Graphene, material A weight ratio be 1:0.5；Material B, tertiary carbonic acid glycidyl ester weight ratio be 1:0.8；
The nano silica is successively to pass through cetyl trimethylammonium bromide and γ-methacryloxypropyl
The modified nano silica of trimethoxy silane；
Auxiliary agent is levelling agent.
Embodiment 4
A kind of high rigidity UV cure wood coatings proposed by the present invention, raw material includes: propylene oxide by weight
24 parts of acid esters, 26 parts of urethane acrylate, 17 parts of phenyl glycidyl ether acrylate, 8 parts of reactive diluent, photoinitiator
0.7 part, 12 parts of epoxy resin, 4 parts of aliphatic cyclic amine, 9 parts of epoxy hardener, 4 parts of modified graphene oxide, nano silica 1.8
Part, 0.7 part of montmorillonite, 1.8 parts of 1- pyrene butyric acid, 1.9 parts of silane coupling agent KH-580,3,9- diethyl -3,9- dihydroxymethyl -
1,5,7,11- tetra- 4.3 parts of oxa- loop coil -5,5- hendecane, 0.3 part of auxiliary agent.
Wherein, the reactive diluent is ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethacrylate
The mixture of ethylene oxidic ester, and ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethyl allene acid glycidyl
The weight ratio of ester is 9:2；
The photoinitiator is the mixture of photoinitiator 184, photoinitiator 369；
The aliphatic cyclic amine is bis- amido dicyclohexyl methyl hydride of 4,4'-；
The epoxy hardener is aqueous epoxy curing agent H206B；
The modified graphene oxide is prepared according to following technique: photoinitiator D2959 and succinic anhydride are added
In methylene chloride, 40min is stirred, 4- methylamino pyridine is then added, 13h is reacted at 60 DEG C, it is washed after reaction, dry
Dry, rotary evaporation obtains material A；It adds graphene oxide into water, material A, and the pH of regulation system is added after being uniformly dispersed
Value is 5, is stirred to react 80min at 70 DEG C, is filtered, washed, is dried to obtain material B；Dimethylformamide is added in material B
In, it is warming up to 130 DEG C after being uniformly dispersed, N- methylimidazole is added, tertiary carbonic acid glycidyl ester is then added, is stirred to react
20min is cooled down after reaction, is centrifuged, washing, being dried to obtain the modified graphene oxide；
In the preparation process of modified graphene oxide, photoinitiator D2959, succinic anhydride molar ratio be 1:1；Oxidation
Graphene, material A weight ratio be 1:0.8；Material B, tertiary carbonic acid glycidyl ester weight ratio be 1:0.3；
The nano silica is successively to pass through cetyl trimethylammonium bromide and γ-methacryloxypropyl
The modified nano silica of trimethoxy silane；
Auxiliary agent is the mixture of dispersing agent, adhesion promoter.
Embodiment 5
A kind of high rigidity UV cure wood coatings proposed by the present invention, raw material includes: propylene oxide by weight
29 parts of acid esters, 21 parts of urethane acrylate, 19 parts of phenyl glycidyl ether acrylate, 5 parts of reactive diluent, photoinitiator
1 part, 11 parts of epoxy resin, 7 parts of aliphatic cyclic amine, 8 parts of epoxy hardener, 6 parts of modified graphene oxide, 1.8 parts of nano silica,
1 part of montmorillonite, 1.2 parts of 1- pyrene butyric acid, 2 parts of silane coupling agent KH-580,3,9- diethyl -3,9- dihydroxymethyl -1,5,7,
Tetra- 3.8 parts of oxa- loop coil -5,5- hendecane of 11-, 0.6 part of auxiliary agent.
Wherein, the reactive diluent is ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethacrylate
The mixture of ethylene oxidic ester, and ethoxylated trimethylolpropane triacrylate, bisphenol-A dimethyl allene acid glycidyl
The weight ratio of ester is 6:5；
The photoinitiator is the mixing of photoinitiator 651, photoinitiator 184, photoinitiator 369, photoinitiator 754
Object；
The aliphatic cyclic amine is the mixture of isophorone diamine, bis- amido dicyclohexyl methyl hydride of 4,4'-；
The epoxy hardener is aqueous epoxy curing agent H206B；
The modified graphene oxide is prepared according to following technique: photoinitiator D2959 and succinic anhydride are added
In methylene chloride, 30min is stirred, 4- methylamino pyridine is then added, 11h is reacted at 63 DEG C, it is washed after reaction, dry
Dry, rotary evaporation obtains material A；It adds graphene oxide into water, material A, and the pH of regulation system is added after being uniformly dispersed
Value is 6, is stirred to react 120min at 58 DEG C, is filtered, washed, is dried to obtain material B；Dimethylformamide is added in material B
In, it is warming up to 125 DEG C after being uniformly dispersed, N- methylimidazole is added, tertiary carbonic acid glycidyl ester is then added, is stirred to react
35min is cooled down after reaction, is centrifuged, washing, being dried to obtain the modified graphene oxide；
In the preparation process of modified graphene oxide, photoinitiator D2959, succinic anhydride molar ratio be 1:1；Oxidation
Graphene, material A weight ratio be 1:0.7；Material B, tertiary carbonic acid glycidyl ester weight ratio be 1:0.6；
The nano silica is successively to pass through cetyl trimethylammonium bromide and γ-methacryloxypropyl
The modified nano silica of trimethoxy silane；
Auxiliary agent is the mixture of levelling agent, dispersing agent, defoaming agent, adhesion promoter.
Comparative example 1
With embodiment 5 only difference is that, without containing the modified graphene oxide in embodiment 5.
Comparative example 2
With embodiment 5 only difference is that, the modified graphene oxide in embodiment 5 is replaced with into graphene oxide.
Comparative example 3
With embodiment 5 only difference is that, it is even that the modified graphene oxide in embodiment 5 is replaced with into existing silane
Join agent modified graphene oxide.
The flexibility of cured film is measured according to GB/T 1731-93, coating film flexibility is 1-2 grades in embodiment 1-5；
The hardness of cured film is measured according to GB/T 6739-1996；The pencil hardness of coating film is in 6- in embodiment 1-5
8H；Wherein, the hardness of film is 8H in embodiment 5, and the hardness of film is 3H in comparative example 1, and the hardness of film is in comparative example 2
4H, the hardness of film is 4H in comparative example 3；
The tensile mechanical properties of cured film are measured according to GB/T 1039-199；The stretching of coating film is strong in embodiment 1-5
Degree reaches 5.26MPa or more；The tensile strength of film is 5.73MPa in embodiment 5, and the tensile strength of 1 film of comparative example is
3.62MPa, the tensile strength of 2 film of comparative example are 3.97MPa；The tensile strength of 3 film of comparative example is 4.31MPa；
To in embodiment 1-5 coating film carry out water boiling resistance test, (40 DEG C, 240h), appearance without blistering peel off,
Slightly whiten, adhesive force is 0 grade；And coating paint film appearance has blistering to peel off in comparative example 1-3.
Using the hot property of thermogravimetric analyzer characterization coating；Wherein, the thermal decomposition temperature of embodiment 5 is 456.7 DEG C, comparison
The thermal decomposition temperature of example 1 is 387.5 DEG C, and the thermal decomposition temperature of comparative example 2 is 412.3 DEG C, and the thermal decomposition temperature of comparative example 3 is
427.1℃。
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of high rigidity UV cure wood coatings, which is characterized in that its raw material includes: epoxy acrylate by weight
20-35 parts, 15-28 parts of urethane acrylate, 15-26 parts of phenyl glycidyl ether acrylate, 3-9 parts of reactive diluent,
0.5-1.2 parts of photoinitiator, 3-15 parts of epoxy resin, 3-8.5 parts of aliphatic cyclic amine, 3-10 parts of epoxy hardener, modified graphite oxide
3-8 parts of alkene, 1-2 parts of nano silica, 0.5-1.6 parts of montmorillonite, 0.3-2 parts of 1- pyrene butyric acid, silane coupling agent KH-580 1-
3 parts, 3,9- diethyl -3,9- dihydroxymethyl -1,5,7,11- tetra- 2-5 parts of oxa- loop coil -5,5- hendecanes, 0.1-1 parts of auxiliary agent.
2. high rigidity UV cure wood coatings according to claim 1, which is characterized in that the reactive diluent is second
The mixture of oxygroup trimethylolpropane trimethacrylate, bisphenol-A dimethyl allene acid glycidyl ester, and ethoxylation three
Hydroxymethyl-propane triacrylate, bisphenol-A dimethyl allene acid glycidyl ester weight ratio be 3-9:2-7.
3. high rigidity UV cure wood coatings according to claim 1 or claim 2, which is characterized in that the photoinitiator is
One of photoinitiator 651, photoinitiator 184, photoinitiator 369, photoinitiator 754 or a variety of mixtures.
4. high rigidity UV cure wood coatings described in any one of -3 according to claim 1, which is characterized in that the alicyclic ring
Amine is one of isophorone diamine, bis- amido dicyclohexyl methyl hydride of 4,4'- or two kinds of mixture.
5. high rigidity UV cure wood coatings described in any one of -4 according to claim 1, which is characterized in that the epoxy
Curing agent is aqueous epoxy curing agent H206B.
6. high rigidity UV cure wood coatings described in any one of -5 according to claim 1, which is characterized in that the modification
Graphene oxide is prepared according to following technique: photoinitiator D2959 and succinic anhydride being added in methylene chloride, stirring
Then 20-40min is added 4- methylamino pyridine, 8-13h is reacted at 60-65 DEG C, washed, dry after reaction, rotation
Evaporation obtains material A；It adds graphene oxide into water, material A is added after being uniformly dispersed, and the pH value of regulation system is 5-7,
It is stirred to react 80-150min at 55-70 DEG C, is filtered, washed, is dried to obtain material B；Dimethylformamide is added in material B
In, it is warming up to 120-130 DEG C after being uniformly dispersed, N- methylimidazole is added, tertiary carbonic acid glycidyl ester is then added, is stirred to react
20-45min is cooled down after reaction, is centrifuged, washing, being dried to obtain the modified graphene oxide.
7. high rigidity UV cure wood coatings described in any one of -6 according to claim 1, which is characterized in that in modified oxygen
In the preparation process of graphite alkene, photoinitiator D2959, succinic anhydride molar ratio be 1:1；The weight of graphene oxide, material A
Amount is than being 1:0.5-0.8；Material B, tertiary carbonic acid glycidyl ester weight ratio be 1:0.3-0.8.
8. high rigidity UV cure wood coatings described in any one of -7 according to claim 1, which is characterized in that the nanometer
Silica is successively modified by cetyl trimethylammonium bromide and γ-methacryloxypropyl trimethoxy silane
Nano silica.
9. high rigidity UV cure wood coatings described in any one of -8 according to claim 1, which is characterized in that auxiliary agent is stream
The mixture of one or more of flat agent, dispersing agent, defoaming agent, adhesion promoter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811445980.0A CN109852200A (en) | 2018-11-29 | 2018-11-29 | A kind of high rigidity UV cure wood coatings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811445980.0A CN109852200A (en) | 2018-11-29 | 2018-11-29 | A kind of high rigidity UV cure wood coatings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109852200A true CN109852200A (en) | 2019-06-07 |
Family
ID=66890428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811445980.0A Withdrawn CN109852200A (en) | 2018-11-29 | 2018-11-29 | A kind of high rigidity UV cure wood coatings |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109852200A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112375481A (en) * | 2020-11-20 | 2021-02-19 | 中山市鑫峰光固化材料有限公司 | Energy-saving environment-friendly water-based UV wood paint and preparation method thereof |
| CN112679683A (en) * | 2019-10-18 | 2021-04-20 | 广州大学 | Functionalized graphene oxide modified core-shell structure acrylate emulsion and preparation method thereof |
| CN112694784A (en) * | 2021-01-23 | 2021-04-23 | 四川省隆鑫科技包装有限公司 | Golden low-temperature screen printing ink and preparation method thereof |
| CN112778896A (en) * | 2021-01-12 | 2021-05-11 | 广东大自然家居科技研究有限公司 | Ceramic tile-imitated wood floor and preparation method thereof |
| CN113429855A (en) * | 2021-06-01 | 2021-09-24 | 安徽名士达新材料有限公司 | Environment-friendly woodware paint and preparation method thereof |
| CN114958188A (en) * | 2022-05-31 | 2022-08-30 | 书香门地集团股份有限公司 | Thermochromic water-based UV coating and preparation method thereof |
| CN117965089A (en) * | 2024-03-29 | 2024-05-03 | 广东东方一哥新材料股份有限公司 | UV (ultraviolet) treating agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927971A (en) * | 2006-09-18 | 2007-03-14 | 深圳清华大学研究院 | Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof |
| CN101153127A (en) * | 2007-09-06 | 2008-04-02 | 湖南阳光新材料有限公司 | White composition capable of solidifying by ultraviolet light |
| CN104559685A (en) * | 2014-12-23 | 2015-04-29 | 湖州南浔双林振森实木加工厂 | Preparation method of high-wear-resistance ultraviolet curing coating |
| CN108559110A (en) * | 2018-04-28 | 2018-09-21 | 中国科学院长春应用化学研究所 | A kind of electroactive graphene oxide hydrogel |
-
2018
- 2018-11-29 CN CN201811445980.0A patent/CN109852200A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927971A (en) * | 2006-09-18 | 2007-03-14 | 深圳清华大学研究院 | Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof |
| CN101153127A (en) * | 2007-09-06 | 2008-04-02 | 湖南阳光新材料有限公司 | White composition capable of solidifying by ultraviolet light |
| CN104559685A (en) * | 2014-12-23 | 2015-04-29 | 湖州南浔双林振森实木加工厂 | Preparation method of high-wear-resistance ultraviolet curing coating |
| CN108559110A (en) * | 2018-04-28 | 2018-09-21 | 中国科学院长春应用化学研究所 | A kind of electroactive graphene oxide hydrogel |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112679683A (en) * | 2019-10-18 | 2021-04-20 | 广州大学 | Functionalized graphene oxide modified core-shell structure acrylate emulsion and preparation method thereof |
| CN112375481A (en) * | 2020-11-20 | 2021-02-19 | 中山市鑫峰光固化材料有限公司 | Energy-saving environment-friendly water-based UV wood paint and preparation method thereof |
| CN112778896A (en) * | 2021-01-12 | 2021-05-11 | 广东大自然家居科技研究有限公司 | Ceramic tile-imitated wood floor and preparation method thereof |
| CN112694784A (en) * | 2021-01-23 | 2021-04-23 | 四川省隆鑫科技包装有限公司 | Golden low-temperature screen printing ink and preparation method thereof |
| CN113429855A (en) * | 2021-06-01 | 2021-09-24 | 安徽名士达新材料有限公司 | Environment-friendly woodware paint and preparation method thereof |
| CN114958188A (en) * | 2022-05-31 | 2022-08-30 | 书香门地集团股份有限公司 | Thermochromic water-based UV coating and preparation method thereof |
| CN117965089A (en) * | 2024-03-29 | 2024-05-03 | 广东东方一哥新材料股份有限公司 | UV (ultraviolet) treating agent and preparation method thereof |
| CN117965089B (en) * | 2024-03-29 | 2024-06-04 | 广东东方一哥新材料股份有限公司 | UV (ultraviolet) treating agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109852200A (en) | A kind of high rigidity UV cure wood coatings | |
| CN112639038B (en) | Hard coat composition, polyimide film with hard coat layer, method for producing the same, and image display device | |
| CN115819039B (en) | High-strength environment-friendly artistic micro-cement and preparation method thereof | |
| CN101974289B (en) | Modified polyurethane waterproof paint as well as preparation method and construction method thereof | |
| CN108948989A (en) | A kind of end silylated polyether water-repellent paint and preparation method thereof | |
| CN103642020A (en) | Modified polyester resin as well as coating and application thereof | |
| CN105623493A (en) | Dual-curing unsaturated polyester white primer and preparation method thereof | |
| CN104962130A (en) | Heat-resistant yellow-stain-resistant epoxy acrylate low polymer and preparation method of UV (ultraviolet) ink | |
| CN109796923A (en) | A kind of UV photocuring water-based polyurethane adhesive | |
| CN105802462A (en) | Polyurethane paint for modified PP material and preparation method of paint | |
| CN107602792A (en) | A kind of preparation method of transparent polyurethane | |
| CN111117469A (en) | Solvent-free UV spraying white finish and preparation method thereof | |
| JPS594473A (en) | Painting and finishing method of cement base material | |
| CN109735210A (en) | A kind of ultraviolet-curing paint containing modified carbon nano-tube | |
| CN102212309B (en) | Method for preparing unsaturated polyester polyurethane block copolymer solventless coating | |
| CN117567677A (en) | Water-based hydroxyl acrylic acid dispersoid and preparation method and application thereof | |
| US6399673B1 (en) | Photocurable acrylated chlorinated rubber coatings | |
| CN1082575A (en) | A kind of modified polystyrene coating and manufacture method thereof | |
| CN114213292A (en) | Dual-curable vegetable oil modified isocyanate curing agent and preparation method thereof | |
| CN110643275A (en) | Plastic UV polyurethane acrylate coating and preparation method thereof | |
| EP0163970B1 (en) | Chlorinated or chlorosulfonated ethylene/vinyl acetate copolymer for use in paints | |
| CN110041794A (en) | A kind of toughening type epoxy powder coating | |
| CN110452417A (en) | A kind of modified Nano SiO2And photocuring composite elastic body material | |
| CN107722226A (en) | A kind of preparation method of transparent polyurethane | |
| CN116376420B (en) | Fluorine-containing coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190607 |