CN109851168A - A kind of A2The improvement of/O technique - Google Patents

A kind of A2The improvement of/O technique Download PDF

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Publication number
CN109851168A
CN109851168A CN201910108354.0A CN201910108354A CN109851168A CN 109851168 A CN109851168 A CN 109851168A CN 201910108354 A CN201910108354 A CN 201910108354A CN 109851168 A CN109851168 A CN 109851168A
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pond
ammonia
lattice
water
tank
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CN201910108354.0A
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CN109851168B (en
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张建中
梁爽
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Environmental Protection Institute of Light Industry
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Environmental Protection Institute of Light Industry
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Abstract

The invention discloses a kind of A2The improvement of/O technique is made of anaerobic pond, anoxic pond, aerobic tank, secondary settling tank, recoil pond, medium sediment pool, suction ammonia pond, equalization pond, the heavy pond of nitre, nitrification tank and buffer pool;The suction ammonia pond is two lattice or more, and every lattice are respectively independent;Suction-operated using zeolite to ammonia nitrogen, ammonia nitrogen absorption in sewage is come out, individually nitrifies and regenerate zeolite, so that nitrifying process independently carries out, carbon source loss is avoided, so that the utilization efficiency of carbon source is improved, simultaneously, the denitrification percent being difficult to improve by reflux ratio limitation is avoided, so that denitrification percent is improved.

Description

A kind of A2The improvement of/O technique
Technical field
The present invention relates to a kind of sewage disposal system more particularly to a kind of sewage treatment A2/ O technique.
Background technique
A2/ O technique is the classical technique of sewage treatment, and Fig. 2 of Figure of description is shown in process flow.The technological advantage is very It is more, but also have deficiency.Most important deficiency has at 3 points: first is that both denitrogenation and dephosphorization are it is not possible that while optimal;First is that denitrogenation Removal rate is difficult to greatly improve again, first is that carbon source is nervous.
For this purpose, technical staff is to A2/ O technique, has done a large amount of improvement, there is preposition denitration A2/ O, inversion A2/O、 The techniques such as UCT, Phoredox.
This patent zeolite adsorbs the characteristic of ammonia nitrogen, to A2A kind of improvement has also been made in/O technique.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of A2The improvement of/O technique, it is characterised in that: by anaerobic pond, Anoxic pond, secondary settling tank, recoil pond, medium sediment pool, inhales ammonia pond, equalization pond, the heavy pond of nitre, nitrification tank and buffer pool composition at aerobic tank;Institute It states and inhales ammonia pond for more than two lattice, every lattice are respectively independent;Sewage is run according to the following steps:
Step 1, sewage enter anaerobic pond and carry out corresponding biochemical process;After reacted, the mixed liquor in anaerobic pond enters Anoxic pond carries out corresponding biochemical process;After reacted, the medium sediment pool that is mixed into anoxic pond is separated by solid-liquid separation;
Step 2, the water that medium sediment pool is isolated, into the lattice inhaled in ammonia pond;The mud that medium sediment pool is isolated, entrance are aerobic Pond;
Step 3 inhales ammonia Chi Zhongyou zeolite, carries out after zeolite adsorbs ammonia nitrogen into aerobic tank into the water for inhaling ammonia pond;
Step 4, the water outlet ammonia-nitrogen content of ammonia pond water inlet lattice is inhaled in monitoring, when it reaches setting value (i.e. when adsorption saturation), Stop intaking to this lattice, another lattice water inlet is turned to, to keep the continuous of water inlet;By the water in equalization pond, it is pumped into and inhales in ammonia pond That lattice of adsorption saturation displace the water of the inside, and the water displaced carries out nitration reaction into nitrification tank, mixed after nitrification Liquid is closed, after nitre sinks pond separation of solid and liquid, mud reflux, water enters equalization pond, then is pumped into and inhales ammonia pond, circulation is formed, up to inhaling ammonia Stop recycling after the completion of zeolite regeneration in pond;Then, by the water in pond that recoils, this lattice for inhaling ammonia pond is pumped into, replaces, wash it In contain glass gall, and enter buffer pool;Enter anoxic pond for glass gall is contained in buffer pool, carries out corresponding biochemical process;It completes again That raw, displacement, washing lattice, stand for standby use;
Inhaling ammonia pond is two lattice or more, and every lattice successive carries out suction ammonia, regeneration, displacement, washing, spare and inhale being circulated throughout for ammonia again Journey reaches the result of continuous processing sewage;
Step 5, in step 3 after the water for inhaling ammonia enters aerobic tank, together with the sludge that medium sediment pool is isolated, good In oxygen pond, aerobic reaction is carried out, mixed liquor enters secondary settling tank and is separated by solid-liquid separation, the water separated, and overflows by recoil pond Stream discharge, the mud separated, a return anaerobic pond, a part are used as excess sludge discharge system.
Compared with existing treatment process, A2The beneficial effect of/O process modification is: nitrifying process independently being carried out, is avoided Carbon source loss, so that the utilization efficiency of carbon source is improved, meanwhile, avoid the denitrogenation being difficult to improve by reflux ratio limitation Rate, so that denitrification percent is improved.
Detailed description of the invention
Fig. 1 is the process flow diagram of the embodiment of the present invention.Fig. 2 is classical A2The flow diagram of/O technique.
Specific embodiment
Embodiment:
The present embodiment, by anaerobic pond 1, anoxic pond 2, aerobic tank 3, secondary settling tank 4, recoil pond 5, in sink 6, inhale ammonia pond 7, current stabilization Pond 8, the heavy pond 9 of nitre, nitrification tank 10 and buffer pool 11 form;The suction ammonia pond 7 is two lattice or more, and every lattice are respectively independent;Sewage is pressed Following steps operation:
Step 1, sewage enter anaerobic pond 1 and carry out corresponding biochemical process;In anaerobic pond 1, mainly progress anaerobism is released The reaction of phosphorus after the sludge that secondary settling tank 4 flows back releases phosphorus herein, is ready for its aerobic phosphorus absorption.After reacted, in anaerobic pond 1 Mixed liquor enter anoxic pond 2 and carry out corresponding biochemical process;In anoxic pond 2, what is be substantially carried out is denitrification denitrogenation reaction, The nitrate nitrogen come in from buffer pool, using organic carbon source, is reduced to N under the action of denitrifying bacterium2.After reacted, anoxic The medium sediment pool 6 that is mixed into pond is separated by solid-liquid separation;
Step 2, the water that medium sediment pool 6 is isolated, into the lattice inhaled in ammonia pond 7;The mud that medium sediment pool 6 is isolated enters Aerobic tank 3;
Step 3, inhale ammonia pond 7 in have zeolite, zeolite has obligate suction-operated to ammonia nitrogen, therefore, into inhale ammonia pond 7 water, Ammonia nitrogen therein will be adsorbed by zeolite, in this way, realizing the separation of ammonia nitrogen and sewage;Sewage after separating ammonia nitrogen, is entered Oxygen pond 3;
The water outlet ammonia-nitrogen content of the water inlet of ammonia pond 7 lattice, (the i.e. adsorption saturation when it reaches setting value are inhaled in step 4, monitoring When), stop intaking to this lattice, another lattice water inlet is turned to, to keep the continuous of water inlet;By the water in equalization pond 8, it is pumped into and inhales ammonia pond That lattice of adsorption saturation in 7, displace the water of the inside, and the water displaced carries out nitration reaction, nitre into nitrification tank 10 Mixed liquor after change, after nitre sinks the separation of solid and liquid of pond 9, mud reflux, water enters equalization pond 8, then is pumped into and inhales ammonia pond 7, and formation follows Ring, until stopping recycling after the completion of inhaling the zeolite regeneration in ammonia pond 7;Then, by the water in pond 5 that recoils, it is pumped into this for inhaling ammonia pond 7 Lattice replace, wash therein containing glass gall, and enter buffer pool 11;Enter anoxic pond 2 for glass gall is contained in buffer pool 11, carries out anti- The Nitrification;Complete that lattice of regeneration, displacement, washing, stand for standby use;
It is a kind of ion-exchange reactions that zeolite, which adsorbs ammonia nitrogen, and there are following balances:
Adsorption process, reaction carry out to the right.After adsorption saturation, when water in equalization pond 8 is introduced suction ammonia pond 7, due to current stabilization Water in pond 8 comes from nitrification tank 10, and therefore, the water in equalization pond 8 is free of NH4 +, in this way, inhaling the NH in ammonia pond 74 +Concentration will It reduces, reaction carries out to the left, i.e. NH in zeolite4 +Desorption.The NH of desorption4 +, into after nitrification tank, it is oxidized to NO2 -Or NO3 -, therefore, the NH in continuous cyclic process, in water4 +Constantly reduce, and the NH in zeolite4 +Then constantly desorb, because This, zeolite is regenerated.After zeolite regeneration, the water in ammonia pond 7 is inhaled, is become containing glass gall, therefore, devised with recoil pond 5 In water, replaced, wash enter buffer pool 11, in this way, inhale ammonia pond 7 in, both be free of ammonia, also be free of nitre, reached original State, for next time inhale ammonia get ready.
Inhaling ammonia pond is two lattice or more, and every lattice successive carries out suction ammonia, regeneration, displacement, washing, spare and inhale being circulated throughout for ammonia again Journey reaches the result of continuous processing sewage;
Step 5, in step 3 after the water for inhaling ammonia enters aerobic tank 3, the sludge that medium sediment pool 6 is isolated together, good In oxygen pond 3, aerobic reaction is carried out, mixed liquor enters secondary settling tank 4 and is separated by solid-liquid separation, the water separated, by pond 5 of recoiling Overflow discharge, the mud separated, a return anaerobic pond 1, a part are used as excess sludge discharge system.
Above embodiments are only exemplary embodiment of the present invention, are not used in the limitation present invention, protection scope of the present invention It is defined by the claims.Those skilled in the art can within the spirit and scope of the present invention make respectively the present invention Kind modification or equivalent replacement, this modification or equivalent replacement also should be regarded as being within the scope of the present invention.

Claims (1)

1. a kind of A2The improvement of/O technique, it is characterised in that: by anaerobic pond, anoxic pond, aerobic tank, secondary settling tank, recoil pond, in sink Ammonia pond, equalization pond, the heavy pond of nitre, nitrification tank and buffer pool composition are inhaled in pond;The suction ammonia pond is two lattice or more, and every lattice are respectively independent; Sewage is run according to the following steps:
Step 1, sewage enter anaerobic pond and carry out corresponding biochemical process;After reacted, the mixed liquor in anaerobic pond enters anoxic Pond carries out corresponding biochemical process;After reacted, the medium sediment pool that is mixed into anoxic pond is separated by solid-liquid separation;
Step 2, the water that medium sediment pool is isolated, into the lattice inhaled in ammonia pond;The mud that medium sediment pool is isolated, into aerobic tank;
Step 3 inhales ammonia Chi Zhongyou zeolite, carries out after zeolite adsorbs ammonia nitrogen into aerobic tank into the water for inhaling ammonia pond;
Step 4, the water outlet ammonia-nitrogen content of ammonia pond water inlet lattice is inhaled in monitoring, when it reaches setting value (i.e. when adsorption saturation), is stopped It intakes to this lattice, another lattice water inlet is turned to, to keep the continuous of water inlet;By the water in equalization pond, it is pumped into the absorption inhaled in ammonia pond That lattice of saturation, displace the water of the inside, and the water displaced carries out nitration reaction, the mixing after nitrification into nitrification tank Liquid, after nitre sinks pond separation of solid and liquid, mud reflux, water enters equalization pond, then is pumped into and inhales ammonia pond, circulation is formed, up to inhaling ammonia pond Stop recycling after the completion of interior zeolite regeneration;Then, by the water in pond that recoils, this lattice for inhaling ammonia pond are pumped into, displacement, washing are wherein Contain glass gall, and enter buffer pool;Enter anoxic pond for glass gall is contained in buffer pool, carries out corresponding biochemical process;Completion regeneration, That lattice of displacement, washing, stand for standby use;
Inhaling ammonia pond is two lattice or more, and every lattice successive carries out suction ammonia, regeneration, displacement, washing, cyclic process that is spare and inhaling ammonia again, Reach the result of continuous processing sewage;
Step 5, in step 3 after the water for inhaling ammonia enters aerobic tank, together with the sludge that medium sediment pool is isolated, in aerobic tank In, aerobic reaction is carried out, mixed liquor enters secondary settling tank and is separated by solid-liquid separation, the water separated, by recoil pond overflow row It puts, the mud separated, a return anaerobic pond, a part is used as excess sludge discharge system.
CN201910108354.0A 2019-02-13 2019-02-13 A2Improvement of/O process Active CN109851168B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5385947A (en) * 1977-01-05 1978-07-28 Hitachi Ltd Method of treating waste liquid containing nitrogen compounds
CN1715217A (en) * 2004-07-02 2006-01-04 桂林工学院 Process for removing nitrogen and phosphor from sewage capable of being built by separate periods
CN104556572A (en) * 2014-12-26 2015-04-29 江苏艾特克环境工程设计研究院有限公司 Efficient biochemical nitrogen and phosphorus removal method for waste water
CN205740686U (en) * 2016-07-12 2016-11-30 成都市鑫忠源物资有限责任公司 A kind of coking wastewater of iron and steel plant processing means
CN107381958A (en) * 2017-08-22 2017-11-24 轻工业环境保护研究所 Carbon nitrogen divergence type denitrification process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5385947A (en) * 1977-01-05 1978-07-28 Hitachi Ltd Method of treating waste liquid containing nitrogen compounds
CN1715217A (en) * 2004-07-02 2006-01-04 桂林工学院 Process for removing nitrogen and phosphor from sewage capable of being built by separate periods
CN104556572A (en) * 2014-12-26 2015-04-29 江苏艾特克环境工程设计研究院有限公司 Efficient biochemical nitrogen and phosphorus removal method for waste water
CN205740686U (en) * 2016-07-12 2016-11-30 成都市鑫忠源物资有限责任公司 A kind of coking wastewater of iron and steel plant processing means
CN107381958A (en) * 2017-08-22 2017-11-24 轻工业环境保护研究所 Carbon nitrogen divergence type denitrification process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曾永刚、刘艳君、李博主编: "《水污染控制工程》", 30 April 2018, 电子科技大学出版社 *

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