CN109849396A - A kind of shoes surrounding edge manufacture craft and shoes surrounding edge - Google Patents
A kind of shoes surrounding edge manufacture craft and shoes surrounding edge Download PDFInfo
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- CN109849396A CN109849396A CN201910138833.7A CN201910138833A CN109849396A CN 109849396 A CN109849396 A CN 109849396A CN 201910138833 A CN201910138833 A CN 201910138833A CN 109849396 A CN109849396 A CN 109849396A
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- surrounding edge
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Abstract
The present invention relates to shoes surrounding edge technical fields, and in particular to a kind of shoes surrounding edge manufacture craft and shoes surrounding edge, manufacture craft are to carry out raw material using mold hot-forming, shoes surrounding edge are made, a part of edge of the shoes surrounding edge is bevel edge.The present invention has the shoes surrounding edge of bevel edge to pass through, and mold is directly hot-forming, and simple and convenient, conducive to industrialized production, high production efficiency, production cost is extremely low.
Description
Technical field
The present invention relates to shoes surrounding edge technical fields, and in particular to a kind of shoes surrounding edge manufacture craft and shoes surrounding edge.
Background technique
Shoes surrounding edge is one layer of ornamental portion for surrounding side of the sole, for beautifying shoes, in order to which shoes surrounding edge can more gluing shoe
Bottom side generally can be polished into the shape of bevel edge at the edge of shoes surrounding edge, but since the requirement of aesthetic appearance is higher and higher, now
Shoes surrounding edge mostly be irregular shape, it is very big that edge is polished into uniform bevel edge difficulty, and needs manual operation, produce
Product batch wise differences are big.
Summary of the invention
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide a kind of production of shoes surrounding edge
Technique and shoes surrounding edge, there is that the shoes surrounding edge of bevel edge is directly hot-forming by mold, simple and convenient, are conducive to industrialized production.
The purpose of the invention is achieved by the following technical solution:
Raw material are carried out hot-forming, obtained shoes surrounding edge, the shoes surrounding edge by a kind of shoes surrounding edge manufacture craft using mold
A part of edge be bevel edge.
Wherein, hot-forming temperature is 100-200 DEG C, hot pressing time 150-300s.
Further, hot-forming temperature is 120-180 DEG C, hot pressing time 170-280s.
Further, hot-forming temperature is 130-170 DEG C, hot pressing time 200-250s.
Further, hot-forming temperature is 140-160 DEG C, hot pressing time 220-230s.
Further, hot-forming temperature is 150 DEG C, hot pressing time 225s.
A kind of shoes surrounding edge is made of shoes surrounding edge manufacture craft as described above.
Wherein, the raw material be EVA foamed material, TPR foamed material, TPU foamed material and rubber material in extremely
Few one kind.
Preferably, the raw material are EVA foamed material, and the EVA foamed material is made by the following raw material:
Wherein, the raw material by following parts by weight of every parts by weight nanometer silicon rubber is made:
Wherein, the structural formula of the methyl vinyl silicone rubber A are as follows:
Wherein, the chain number α=4000-5000, β=200-300 of the methyl vinyl silicone rubber A.
Special nanometer silicon rubber is added in the present invention in EVA, can improve the elasticity of EVA, recovery, obdurability and
Weatherability, the EVA foamed material abscess quantity that nanometer silicon rubber is added increases and aperture reduces, thus there is low-density, height to return
The characteristic of bullet rate, high tensile and high elongation at tear.
Wherein, the crosslinking agent B is pressed by ethyl orthosilicate, methyl tributanoximo silane and Triallyl isocyanurate
The ratio of weight ratio 1:1-2:1-2 forms.Compounding crosslinking agent B of the invention can improve the cross-linked structure of silicon rubber, improve silicon
The mechanical performance of rubber improves the compatibility of silicon rubber and EVA, the EVA foamed material of final obtained high-mechanical property.
Wherein, the catalyst is stannous methide.
Wherein, the nanometer silicon rubber the preparation method comprises the following steps: by each raw material mix after, 100-120 DEG C at a temperature of it is close
40-60min is refined, rubber master batch is made;Then by rubber master batch physical crushing to nano-scale to get arrive the nano-silicon rubber
Glue.
Wherein, the partial size of the nanometer silicon rubber is 50-70nm.
Wherein, the foaming agent is AC foaming agent.
Wherein, the crosslinking agent A is DCP crosslinking agent.
Wherein, the lubricant is at least one of calcium stearate, zinc stearate and talcum powder.Lubricant is conducive to EVA
The demoulding of foamed material, and calcium stearate and zinc stearate also have the function of that AC foaming agent is promoted to decompose, talcum powder can be made
Improve the molecular structure of foamed material for nucleating agent.Preferably, the lubricant is by zinc stearate and talcum powder by weight 1-
The ratio of 2:1 forms, and expansion rate is more suitable for that the elasticity and toughness of material are preferable.
Wherein, the preparation method of the EVA foamed material includes the following steps:
(1) EVA, nanometer silicon rubber, foaming agent, crosslinking agent and lubricant are weighed by formula ratio and carries out mixing, then carried out
Mill, granulation obtain EVA particle, and the temperature of mixing is 85-95 DEG C, time 4-6min;
(2) the EVA particle is put into foaming mould and carries out moulded from foam to get to the EVA foamed material, foamed
Temperature is 160-180 DEG C.
The beneficial effects of the present invention are: the present invention has the shoes surrounding edge of bevel edge directly hot-forming by mold, and operation is simple
Single convenient, conducive to industrialized production, high production efficiency, production cost is extremely low.
Detailed description of the invention
Fig. 1 is the cross-sectional view of shoes surrounding edge of the invention.
Specific embodiment
For the ease of the understanding of those skilled in the art, make below with reference to 1 couple of present invention of examples and drawings further
Illustrate, the content that embodiment refers to not is limitation of the invention.
Embodiment 1
Raw material are carried out hot-forming, obtained shoes surrounding edge by a kind of shoes surrounding edge manufacture craft using mold, as shown in Figure 1,
A part of edge of the shoes surrounding edge is bevel edge.
Further, hot-forming temperature is 150 DEG C, hot pressing time 225s.
A kind of shoes surrounding edge is made of shoes surrounding edge manufacture craft as described above.
Embodiment 2
Raw material are carried out hot-forming, obtained shoes surrounding edge, the shoes surrounding edge by a kind of shoes surrounding edge manufacture craft using mold
A part of edge be bevel edge.
Further, hot-forming temperature is 130 DEG C, hot pressing time 250s.
A kind of shoes surrounding edge is made of shoes surrounding edge manufacture craft as described above.
Embodiment 3
Raw material are carried out hot-forming, obtained shoes surrounding edge, the shoes surrounding edge by a kind of shoes surrounding edge manufacture craft using mold
A part of edge be bevel edge.
Further, hot-forming temperature is 170 DEG C, hot pressing time 200s.
A kind of shoes surrounding edge is made of shoes surrounding edge manufacture craft as described above.
Embodiment 4
The present embodiment the difference from embodiment 1 is that:
Preferably, the raw material are EVA foamed material, and the EVA foamed material is made by the following raw material:
Wherein, the raw material by following parts by weight of every parts by weight nanometer silicon rubber is made:
Wherein, the structural formula of the methyl vinyl silicone rubber A are as follows:
Wherein, the chain number α=4000-5000, β=200-300 of the methyl vinyl silicone rubber A.
Wherein, the crosslinking agent B is pressed by ethyl orthosilicate, methyl tributanoximo silane and Triallyl isocyanurate
The ratio of weight ratio 1:1.5:1.5 forms.
Wherein, the catalyst is stannous methide.
Wherein, the nanometer silicon rubber the preparation method comprises the following steps: by each raw material mix after, in 110 DEG C of at a temperature of mixing
Rubber master batch is made in 50min;Then by rubber master batch physical crushing to nano-scale to get arrive the nanometer silicon rubber.
Wherein, the partial size of the nanometer silicon rubber is 60nm.
Wherein, the foaming agent is AC foaming agent.
Wherein, the crosslinking aid S is DCP crosslinking agent.
Wherein, the lubricant is made of zinc stearate and talcum powder by weight the ratio of 1.5:1.
Wherein, the preparation method of the EVA foamed material includes the following steps:
(1) EVA, nanometer silicon rubber, foaming agent, crosslinking agent and lubricant are weighed by formula ratio and carries out mixing, then carried out
Mill, granulation obtain EVA particle, and the temperature of mixing is 90 DEG C, time 5min;
(2) the EVA particle is put into foaming mould and carries out moulded from foam to get to the EVA foamed material, foamed
Temperature is 170 DEG C.
Embodiment 5
The present embodiment the difference from embodiment 1 is that:
Preferably, the raw material are EVA foamed material, and the EVA foamed material is made by the following raw material:
Wherein, the raw material by following parts by weight of every parts by weight nanometer silicon rubber is made:
Wherein, the structural formula of the methyl vinyl silicone rubber A are as follows:
Wherein, the chain number α=4000-5000, β=200-300 of the methyl vinyl silicone rubber A.
Wherein, the crosslinking agent B is pressed by ethyl orthosilicate, methyl tributanoximo silane and Triallyl isocyanurate
The ratio of weight ratio 1:1:1 forms.
Wherein, the catalyst is stannous methide.
Wherein, the nanometer silicon rubber the preparation method comprises the following steps: by each raw material mix after, in 100 DEG C of at a temperature of mixing
Rubber master batch is made in 40min;Then by rubber master batch physical crushing to nano-scale to get arrive the nanometer silicon rubber.
Wherein, the partial size of the nanometer silicon rubber is 50nm.
Wherein, the foaming agent is AC foaming agent.
Wherein, the crosslinking agent A is DCP crosslinking agent.
Wherein, the lubricant is made of zinc stearate and talcum powder by weight the ratio of 1:1.
Wherein, the preparation method of the EVA foamed material includes the following steps:
(1) EVA, nanometer silicon rubber, foaming agent, crosslinking agent and lubricant are weighed by formula ratio and carries out mixing, then carried out
Mill, granulation obtain EVA particle, and the temperature of mixing is 85 DEG C, time 4min;
(2) the EVA particle is put into foaming mould and carries out moulded from foam to get to the EVA foamed material, foamed
Temperature is 180 DEG C.
Embodiment 6
The present embodiment the difference from embodiment 1 is that:
Preferably, the raw material are EVA foamed material, and the EVA foamed material is made by the following raw material:
Wherein, the raw material by following parts by weight of every parts by weight nanometer silicon rubber is made:
Wherein, the structural formula of the methyl vinyl silicone rubber A are as follows:
Wherein, chain number α=5000 of the methyl vinyl silicone rubber A, β=300.
Wherein, the crosslinking agent is pressed by ethyl orthosilicate, methyl tributanoximo silane and Triallyl isocyanurate
The ratio of weight ratio 1:2:2 forms.
Wherein, the catalyst is stannous methide.
Wherein, the nanometer silicon rubber the preparation method comprises the following steps: by each raw material mix after, in 120 DEG C of at a temperature of mixing
Rubber master batch is made in 60min;Then by rubber master batch physical crushing to nano-scale to get arrive the nanometer silicon rubber.
Wherein, the partial size of the nanometer silicon rubber is 70nm.
Wherein, the foaming agent is AC foaming agent.
Wherein, the crosslinking agent is DCP crosslinking agent.
Wherein, the lubricant is made of zinc stearate and talcum powder by weight the ratio of 2:1, and expansion rate is more suitable
Preferably, the elasticity and toughness of material are preferable.
Wherein, the preparation method of the EVA foamed material includes the following steps:
(1) EVA, nanometer silicon rubber, foaming agent, crosslinking agent and lubricant are weighed by formula ratio and carries out mixing, then carried out
Mill, granulation obtain EVA particle, and the temperature of mixing is 95 DEG C, time 6min;
(2) the EVA particle is put into foaming mould and carries out moulded from foam to get to the EVA foamed material, foamed
Temperature is 180 DEG C.
Comparative example
The difference of this comparative example and embodiment 4 is:
The nanometer silicon rubber is crushed to obtain by commercially available conventional silicon rubber.
Performance detection is carried out to the EVA foamed material of embodiment 4-6 and comparative example 1, testing result is as follows:
From data as above it is found that EVA foamed material produced by the present invention has low-density, high resilience, high tensile
With the characteristic of high elongation at tear, from the comparison of embodiment 4 and comparative example 1 it is found that nano-silicon rubber of the invention is different from one
As silicon rubber, effective humidification can be played to EVA.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other way,
Do not depart under the premise of present inventive concept it is any obviously replace it is within the scope of the present invention.
Claims (8)
1. a kind of shoes surrounding edge manufacture craft, it is characterised in that: raw material are carried out to hot-forming, obtained shoes surrounding edge using mold,
A part of edge of the shoes surrounding edge is bevel edge.
2. a kind of shoes surrounding edge manufacture craft according to claim 1, it is characterised in that: the raw material are EVA foaming material
At least one of material, TPR foamed material, TPU foamed material and rubber material.
3. a kind of shoes surrounding edge manufacture craft according to claim 1, it is characterised in that: hot-forming temperature is 100-
200 DEG C, hot pressing time 150-300s.
4. a kind of shoes surrounding edge manufacture craft according to claim 3, it is characterised in that: hot-forming temperature is 120-
180 DEG C, hot pressing time 170-280s.
5. a kind of shoes surrounding edge manufacture craft according to claim 3, it is characterised in that: hot-forming temperature is 130-
170 DEG C, hot pressing time 200-250s.
6. a kind of shoes surrounding edge manufacture craft according to claim 3, it is characterised in that: hot-forming temperature is 140-
160 DEG C, hot pressing time 220-230s.
7. a kind of shoes surrounding edge manufacture craft according to claim 3, it is characterised in that: hot-forming temperature is 150 DEG C,
Hot pressing time is 225s.
8. a kind of shoes surrounding edge, it is characterised in that: the shoes surrounding edge manufacture craft described in claim 1-7 any one is made.
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CN102964640A (en) * | 2012-11-09 | 2013-03-13 | 际华三五一四制革制鞋有限公司 | Special rubber welt for rubber double-density shoes and preparation method thereof |
CN105218888A (en) * | 2015-11-13 | 2016-01-06 | 河南荣光鞋业有限公司 | White foxing and manufacture method thereof |
CN108381961A (en) * | 2018-02-09 | 2018-08-10 | 林骏峰 | A kind of secondary forming process preparing high resilience material using E-TPU particles |
CN109082062A (en) * | 2018-06-29 | 2018-12-25 | 扬州朗劲塑胶实业有限公司 | A kind of production of TPR sole foxing and color spray technique |
CN109265759A (en) * | 2017-07-18 | 2019-01-25 | 青岛千里行集团有限公司 | A kind of vulcanized shoes and its production technology of anti-colour migration |
-
2019
- 2019-02-25 CN CN201910138833.7A patent/CN109849396A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102964640A (en) * | 2012-11-09 | 2013-03-13 | 际华三五一四制革制鞋有限公司 | Special rubber welt for rubber double-density shoes and preparation method thereof |
CN105218888A (en) * | 2015-11-13 | 2016-01-06 | 河南荣光鞋业有限公司 | White foxing and manufacture method thereof |
CN109265759A (en) * | 2017-07-18 | 2019-01-25 | 青岛千里行集团有限公司 | A kind of vulcanized shoes and its production technology of anti-colour migration |
CN108381961A (en) * | 2018-02-09 | 2018-08-10 | 林骏峰 | A kind of secondary forming process preparing high resilience material using E-TPU particles |
CN109082062A (en) * | 2018-06-29 | 2018-12-25 | 扬州朗劲塑胶实业有限公司 | A kind of production of TPR sole foxing and color spray technique |
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《皮鞋材料》编写组: "《皮鞋材料》", 31 May 1994, 中国轻工业出版社 * |
冯玉: "《有机硅高分子及其应用》", 30 April 2010, 化学工业出版社 * |
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