CN1098456A - Woollen blanket printing thickener and preparation method thereof - Google Patents
Woollen blanket printing thickener and preparation method thereof Download PDFInfo
- Publication number
- CN1098456A CN1098456A CN 93108349 CN93108349A CN1098456A CN 1098456 A CN1098456 A CN 1098456A CN 93108349 CN93108349 CN 93108349 CN 93108349 A CN93108349 A CN 93108349A CN 1098456 A CN1098456 A CN 1098456A
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- CN
- China
- Prior art keywords
- weight ratio
- thickener
- present
- concentration
- sesbania gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Coloring (AREA)
- Paper (AREA)
Abstract
The present invention is a kind of printing in textiles thickener that contains plant seed glue and preparation method thereof.Its main component is: oxidation sesbania gum powder, Chinese honey locust rubber powder and acrylic compounds synthetic thickening agent; The preparation method of oxidation sesbania gum is: in ethanol or methanol solution, use hydrogen peroxide oxidation having under the sodium metasilicate existence condition, reaction temperature is controlled at 30～60 ℃, 20～120 minutes reaction time.Thickener of the present invention is particularly suitable for the stamp of woollen blanket uniform thickness type fabric, and it is easy to have a paste producing, and the paste making rate height is difficult for advantages such as sticking stamp half tone.
Description
The present invention relates to a kind of printing in textiles thickener and preparation method thereof.
Printing gum plays an important role to the stamp product quality as the important auxiliary agent of printing in textiles.Printing woollen blanket is big series products in the printing textile, needs to consume a large amount of printing gums.At present needleless printing gum that the Woollen blanket printing characteristics are developed still mainly prolongs with calico printing thickener synthetic gum tragacanth, though that this thickener has with dyestuff, auxiliary agent compatibility is good, paste making rate is than advantages such as height, but it is poor to permeate, and Dry Sack is bright-coloured inadequately, easily imbibition, water-soluble relatively poor, the paste producing time is longer, and is not anticorrosion.Plant seed glue printing gum newly developed in recent years mainly is at silk, top-weight fabric characteristics such as cotton are developed, there is infiltration well though improve back application on woollen blanket a little, advantages such as washing, slurrying is easy, simultaneously reflect that also paste making rate is low, consumption is big, and viscosity Da Yi causes sticking net plug net, problems such as the pigment ghost image rings vividness, and dust is big.
The object of the invention is to overcome the deficiency of existing printing gum, and a kind of thickener of suitable Woollen blanket printing is provided.
The invention provides a kind of novel printing gum and preparation method thereof, the Main Ingredients and Appearance of thickener of the present invention is: through the sesbania gum of oxidation processes, and Chinese honey locust rubber powder and synthetic thickening agent.It basic composition is (identical by weight): modification (oxidation) sesbania gum powder 30-50 part, Chinese honey locust rubber powder (when preparing burden into 1% concentration, viscosity should reach more than the 700cp) 40-60 part, acrylic compounds synthetic thickening agent 5-10 part.The preparation method is as follows: with viscosity is 25 ℃ of the 1000-3000cp(1% aqueous solution, NDJ-1 type viscosimeter records) sesbania gum powder 100-300 part be added in the ethanol or methanol solution of 100-300 part 80-95% concentration, back adding hydrogen peroxide 10-40 part stirs, be heated to 30-60 ℃, add sodium silicate solution 20-50 part of 20-25% concentration and NaOH 20-50 part of 30% concentration then, the control temperature was 30-60 ℃ of reaction 20-120 minute under stirring state, after suction filtration separates, ethanol 200-500 part wash agitation with 85-90% concentration adds H simultaneously
2SO
4Or HCl is neutralized to PH=6.5-7, stirred 60-100 minute, again with 90-95% concentration ethanol washing 20 minutes, after suction filtration separates, through the sesbania gum powder oven dry of reaction, pulverize, make basic modification sesbania gum powder.Then with this modification sesbania gum powder 30-50 part, Chinese honey locust rubber powder (viscosity should reach more than the 700cp when 1% concentration) 40-60 part, acrylic compounds synthetic thickening agent 5-10 part and an amount of preservative agent can adopt benzoic acid or Sodium Benzoate, and proportioning is 3-10 part.Also can add an amount of bleeding agent in the thickener of the present invention, diffusant, deep-dyeing agent or defoamer according to user's needs.
The embodiment of the invention is as follows:
Prescription: (unit: gram)
Sesbania gum powder: 100
Ethanol: 300
Hydrogen peroxide: 30
NaOH: 20
Sodium metasilicate: 26
Chinese honey locust rubber powder: 183
KG-201 thickener: 16.5
Benzoic acid: 13.0
Reaction temperature: 45 ℃
Reaction time: 1 hour
Technological process:
With viscosity is that sesbania gum powder 100 gram of 1500cp adds in the ethanolic solution of 300 grams, 95% concentration, back adding hydrogen peroxide 30 grams stir, the reaction bulb temperature is controlled at 45 ℃, add sodium silicate solution 26 grams of 40% concentration and sodium hydroxide solution 20 grams of 30% concentration again, continue the control temperature at 45 ℃, stirring state reacted 60 minutes down, suction filtration separates then, the rubber powder that suction filtration is done is put into the ethanol 300 gram wash agitation of 85% concentration again, dripping sulfuric acid solution simultaneously, to be neutralized to PH be 7, continue to stir 60 minutes, suction filtration separates then, use the alcohol wash agitation secondary of 90% and 95% concentration again, each 20 minutes, the rubber powder that last suction filtration obtains is dried in 60 ℃ of baking ovens, be crushed to more than 150 orders, make basic modified glue powder.
Again these basic modified glue powder 100 grams are pieced together with synthetic thickening agent 16.5 grams and benzoic acid 13 grams with Chinese honey locust rubber powder 183 grams and mixed, in mortar, grind well, promptly make thickener of the present invention.
Thickener of the present invention is particularly suitable for the stamp of woollen blanket uniform thickness type fabric, and it is easy to have a paste producing, only needs to stir in the cold water high speed can use in 2-4 hour; The paste making rate height generally about 2.5%, has only the 1/2-2/3 of other thickener consumption; Be difficult for sticking stamp web plate, printing need not be cleaned web plate continuously, improves the quality of products greatly, output, reduces labour intensity; The thickener pigment is more shallow, and compatibility is good, deposits stablely, and the no dust phenomenon that overflows has the rheological characteristic and the flowability of suitable Woollen blanket printing characteristics simultaneously, thereby makes the blanket products of printing bright in luster, permeates, and is soft, clear-cut, and bulk complexion pool is evenly.
The performance evaluation table:
| Performance | Outward appearance | Viscosity during 2.5% concentration | Percentage of impurity % | Gelatinization point | Gelatinization time | Ionic type |
| Index | Light yellow particulate | 10,000 cp | 2.4-2.8 | Normal temperature | 2-4 hour | Nonionic or utmost point weak anionic type |
| Mobile PVI value | Embrace water-based (cm) | Compatibility (changing %) | Take off the paste rate | Shelf stability |
| 0.60 | 0.15 | ＜15% | ＞95% | Deposited 7-10 days but the powdery long preservation is aqueous |
Claims (5)
1, a kind of printing in textiles thickener that contains plant seed glue, feature of the present invention is: its Main Ingredients and Appearance comprises oxidation sesbania gum powder 30-50 part (weight ratio), Chinese honey locust rubber powder 40-60 part (weight ratio), acrylic acid synthetic thickening agent 5-10 part (weight ratio).
2, thickener as claimed in claim 1, feature of the present invention is: wherein used Chinese honey locust rubber powder viscosity when 1% concentration should reach more than the 700cp.
3, thickener as claimed in claim 1, feature of the present invention is: wherein add benzoic acid or Sodium Benzoate 3-10 part (weight ratio).
4, a kind of manufacture method of modification sesbania gum, feature of the present invention is: sesbania gum powder 100-300 part (weight ratio) is added in the ethanol or methanol solution of 100-300 part (weight ratio) 80-95% concentration, back adding hydrogen peroxide 10-40 part stirs, be heated to 30-60 ℃, add sodium silicate solution 20-50 part (weight ratio) of 20-25% concentration and NaOH 20-50 part (weight ratio) of 30% concentration then, reaction temperature is controlled at 30-60 ℃, reaction time 20-120 minute.
5, method as claimed in claim 4, feature of the present invention is: wherein used sesbania gum powder, records viscosity with NDJ-1 type viscosimeter and should be 1000～3000cp in the time of 25 ℃ at 1% aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93108349 CN1033599C (en) | 1993-08-03 | 1993-08-03 | Woollen blanket printing thickener and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93108349 CN1033599C (en) | 1993-08-03 | 1993-08-03 | Woollen blanket printing thickener and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1098456A true CN1098456A (en) | 1995-02-08 |
| CN1033599C CN1033599C (en) | 1996-12-18 |
Family
ID=4987101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93108349 Expired - Fee Related CN1033599C (en) | 1993-08-03 | 1993-08-03 | Woollen blanket printing thickener and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1033599C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106368007A (en) * | 2016-08-30 | 2017-02-01 | 浙江正宇纺织印染基地有限公司 | Environment-friendly printing gum and preparing method thereof |
| CN107419565A (en) * | 2017-07-28 | 2017-12-01 | 阳信诺瑞织品有限公司 | A kind of ink-jet printed technique of wool carpet |
-
1993
- 1993-08-03 CN CN 93108349 patent/CN1033599C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106368007A (en) * | 2016-08-30 | 2017-02-01 | 浙江正宇纺织印染基地有限公司 | Environment-friendly printing gum and preparing method thereof |
| CN107419565A (en) * | 2017-07-28 | 2017-12-01 | 阳信诺瑞织品有限公司 | A kind of ink-jet printed technique of wool carpet |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033599C (en) | 1996-12-18 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |