CN109811357A - The non-centrosymmetrical topology of one kind, superconductor are applied to evolving hydrogen reaction - Google Patents
The non-centrosymmetrical topology of one kind, superconductor are applied to evolving hydrogen reaction Download PDFInfo
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- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 34
- 239000001257 hydrogen Substances 0.000 title claims abstract description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000002887 superconductor Substances 0.000 title claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 38
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- 239000011230 binding agent Substances 0.000 claims abstract description 9
- 238000002604 ultrasonography Methods 0.000 claims abstract description 7
- 230000005518 electrochemistry Effects 0.000 claims abstract description 5
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 4
- 150000002431 hydrogen Chemical class 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 239000006228 supernatant Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000001548 drop coating Methods 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 239000003708 ampul Substances 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical class C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 8
- 150000004780 naphthols Chemical class 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000005984 hydrogenation reaction Methods 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 238000010189 synthetic method Methods 0.000 abstract 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
- 239000004570 mortar (masonry) Substances 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 229910016021 MoTe2 Inorganic materials 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229960004424 carbon dioxide Drugs 0.000 description 2
- 150000004770 chalcogenides Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910004211 TaS2 Inorganic materials 0.000 description 1
- 229910008484 TiSi Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000004630 atomic force microscopy Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N carbon tetrachloride Substances ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The present invention relates to a kind of non-centrosymmetrical topology, superconductor BiPd to be applied to electrochemistry and produce hydrogen and preparation method thereof, belongs to electrochemical technology field.Preparation method is solid-state synthetic method and chemical stripping method, by the way that the Bi of stoichiometric ratio and Pd are sealed in vitreosil pipe, it is synthesized by high-temperature solid, form block materials, then it grinds, ultrasound removing obtains sheeting in the solution, finally by the used load of binder naphthols on carbon paper, laminar production hydrogen material catalyst is obtained.The production hydrogen material of this method preparation is sufficiently stable, and no miscellaneous phase generates, the simultaneously synthesizing production hydrogen material come out production hydrogen activity with higher under -0.5V operating voltage, and energy long-time stable catalysis produces hydrogen.It is produced in the room temperature of hydrogen, Hydrogen collection, the fields such as fuel cell have very big application prospect.
Description
Technical field
The invention belongs to electrochemical technology fields, and in particular to a kind of non-centrosymmetrical topology of chemical component (BiPd),
Superconductor produces hydrogen and preparation method thereof for electrochemistry
Background technique
The burning of traditional energy such as petroleum, coal not only causes problem of environmental pollution, can also generate a large amount of greenhouse gases two
Carbonoxide.And solving the problems, such as this effective ways then is the novel clean energy resource of development and utilization.In numerous clean energy resourcies, hydrogen
The heat that gas completely burned is released is to wait quality gasolines burning exothermic more than 3 times, and the product water after completely burned is not
Any pollution can be caused to environment.In addition to this, hydrogen as energy source also has the advantages such as light weight, source be wide.Currently, preparing hydrogen
Three kinds of common methods include methane reforming, Coal Gasification and electrolysis water.Wherein, the process of methane reforming and Coal Gasification all can
GHG carbon dioxide is generated, secondary pollution can be caused to environment.Only the overall process of electrolysis water is all environmentally protective.And
In the process, catalyst plays the role of vital.Traditional electrolysis water catalyst generally includes the noble metals such as platinum and palladium,
Therefore cost problem often will limit their extensive use.
In recent years, people are dedicated to exploring the elctro-catalyst with low overpotential and high-moisture solution efficiency, and find MoS2
Etc. stratiforms transition metal two chalcogenides (TMD) nano material have substitution business platinum based catalyst potential.In addition, recently
Various transient metal sulfide topology materials are found in succession, such as WTe2(Phys.Rev.B 2016,94), MoTe2
(Phys.Rev.Lett.2016,117,56805), MoxW1-xTe2(Nature Commun.2016,7,10639) etc..More intentionally
Think, 2018, German horse it is general Claudia professor's Felser group be put forward for the first time two chalcogenide of transition metal
Topological material (2H-MoTe2, 1T-TaS2And 1T '-MoTe2) be applied to Photocatalyzed Hydrogen Production (Adv.Mater.2017,29,
1606202), and higher yield is obtained.Next year, Shenyang material science country, Metal Inst., Chinese Academy of Sciences research center are old
Star autumn professor is calculated by the electrocatalytic hydrogen evolution of dirac nodel line semimetal TiSi family, and the electrocatalytic hydrogen evolution for topological material mentions
Theoretical basis has been supplied, and has proposed Topological Quantum catalysis on this basis.BiPd is a kind of non-centrosymmetrical superconductor, it with
The form of II type dirac fermion, carrying superconductivity and topological state.This might mean that BiPd was both likely to be " topological super
Conductor ".Researcher all over the world is attempt to create topological superconductor, because they are expected to have in conventional superconductor
In undiscovered special performance.They can be thermally conductive along its surface, this is possibly used for building thermoelectric device.Topological superconductor is also
The quasi particle of referred to as anyon can be derived.The non-centrosymmetry lattice of BiPd also makes it while having singlet and three lines
The orbit coupling of state, this orbit coupling property can make BiPd carrier density with higher at fermi level, be conducive to
Catalysis.Therefore, it is proposed that existing superconductivity has the BiPd material of topological property to produce hydrogen for electrochemistry simultaneously using this again.
In addition, BiPd compared with Pd simple substance, has the advantage that (1) greatly reduces cost；(2) formation of hydride is reduced, thus
Substantially increase the yield and catalyst stability of hydrogen.
Summary of the invention
For the above defect of the existing technology, the present invention is intended to provide a kind of topology, superconductor material are for electrification
It learns and produces hydrogen and preparation method thereof, the method is simple, and preparation cost is low, and hydrogen generation efficiency is high, and stability is superior.
In order to achieve the above object, the present invention adopts the following technical scheme:
It is a kind of topology, superconduction produce hydrogen material have composition below and thickness:
BiPd
0~100nm of sheet thickness.
A kind of topological, superconduction produces the preparation method of hydrogen material, has technical process below:
(1) corresponding Bi and Pd simple substance is successively weighed according to stoichiometric ratio 1: 1 to be sealed in vitreosil pipe.
(2) then quartz ampoule is put into Minitype box-type furnace, rises to 900 DEG C with the heating rate of 1 DEG C/min, heat preservation one
It, is cooled to 600 DEG C in three days, is put into mixture of ice and water, opens quartz ampoule, and grinding obtains block materials；
(3) a certain amount of block materials are weighed, appropriate and suitable solvent is added, several minutes of ultrasound under certain power,
Supernatant is the sheeting after removing；
(4) naphthols binder is added in the supernatant after ultrasound, several minutes of ultrasound uniformly mixed；
(5) the suitable catalyst solution of drop coating on carbon paper, the flake for obtaining carbon paper load produce hydrogen catalyst.
Compared with prior art, the invention has the following advantages:
(1) topology of the present invention, Chemistry of Superconductors Ma Guangcheng Ding Shiwen property are stablized, and structural property is surveyed in chemical stripping and electrochemistry
Prolonged stability can be kept during examination；
(2) topological, superconductor element composition of the present invention only contains a small amount of noble metal, reduces preparation cost,
Preparation process very simple, preparation condition require low；
(3) topology of preparation method preparation of the present invention, superconductor, sheet thickness can reach nanoscale, have
Biggish specific surface area；
(4) topology of preparation method preparation of the present invention, superconductor BiPd have higher electro-chemical activity.-
10mA cm-2Current density under, the overpotential of BiPd is 186mV, and Tafel slope is 137.5mV dec-1；
(5) topology of preparation method preparation of the present invention, superconductor have good stabilization in electrochemical process
Property, can under certain bias steady operation 10 hours.
Detailed description of the invention
Fig. 1 is X-ray diffraction (XRD) map of the BiPd of the method for the invention preparation, the optical photograph of block materials
And crystal structure schematic diagram；
Fig. 2 is scanning electron microscope map of the BiPd block materials of the present invention in air atmosphere；
Fig. 3 is high-resolution-ration transmission electric-lens map and selected diffraction map of the BiPd thin slice of the present invention in air atmosphere；
Fig. 4 is atomic force microscopy diagram spectrum and its thickness test of the BIPd thin slice of the present invention in air atmosphere；
Fig. 5 is the Electrochemical Characterization of BiPd thin slice of the present invention and BiPd block materials, including linear volt-ampere curve,
Tafel curve, electrochemical impedance spectrogram and electric double layer capacitance spectrogram；
Fig. 6 is the stability test of BiPd thin slice of the present invention.
Specific embodiment
The present invention is furtherd elucidate below by drawings and examples, but protection scope of the present invention is not limited to
Shown content.
Embodiment 1:
Accurate weighing 0.3313g Bi and 0.1686g Pd, and ground uniformly in mortar, then it is sealed in the stone of vacuum
Ying Guanzhong rises to 900 DEG C with the heating rate of 1 DEG C/mim, keeps the temperature one day, be cooled to 600 DEG C within three days, be put into mixture of ice and water
In, grinding obtains BiPd block materials.It takes 10mg BiPd block materials in 1mL DMF, takes supernatant after ultrasonic 30min,
Naphthols binder is added to be uniformly mixed, drop coating proper catalyst solution is in carbon paper surface.Naturally dry is obtained with high electrochemical
Activity and the topology of good electrochemical stability, superconduction BiPd thin slice production hydrogen material.
Embodiment 2:
Accurate weighing 0.3313g Bi and 0.1686g Pd, and ground uniformly in mortar, then it is sealed in the stone of vacuum
Ying Guanzhong rises to 900 DEG C with the heating rate of 1 DEG C/mim, keeps the temperature one day, be cooled to 600 DEG C within three days, be put into mixture of ice and water
In, grinding obtains BiPd block materials.It takes 10mg BiPd block materials in 1mL IPA, takes supernatant after ultrasonic 60min,
Naphthols binder is added to be uniformly mixed, drop coating proper catalyst solution is in carbon paper surface.Naturally dry is obtained with high electrochemical
Activity and the topology of good electrochemical stability, superconduction BiPd thin slice production hydrogen material.
Embodiment 3:
Accurate weighing 0.3313g Bi and 0.1686g Pd, and ground uniformly in mortar, then it is sealed in the stone of vacuum
Ying Guanzhong rises to 900 DEG C with the heating rate of 1 DEG C/mim, keeps the temperature one day, be cooled to 600 DEG C within three days, be put into mixture of ice and water
In, grinding obtains BiPd block materials.It takes 10mg BiPd block materials in 1mL Butanol, takes supernatant after ultrasonic 90min
Liquid is added naphthols binder and is uniformly mixed, and drop coating proper catalyst solution is in carbon paper surface.Naturally dry obtains having high electricity
Chemical activity and the topology of good electrochemical stability, superconduction BiPd thin slice production hydrogen material.
Embodiment 4:
Accurate weighing 0.3313g Bi and 0.1686g Pd, and ground uniformly in mortar, then it is sealed in the stone of vacuum
Ying Guanzhong rises to 900 DEG C with the heating rate of 1 DEG C/mim, keeps the temperature one day, be cooled to 600 DEG C within three days, be put into mixture of ice and water
In, grinding obtains BiPd block materials.Take 10mg BiPd block materials in 1mL CCl4In, supernatant is taken after ultrasonic 120min
Liquid is added naphthols binder and is uniformly mixed, and drop coating proper catalyst solution is in carbon paper surface.Naturally dry obtains having high electricity
Chemical activity and the topology of good electrochemical stability, superconduction BiPd thin slice production hydrogen material.
Embodiment 5:
Accurate weighing 0.3313g Bi and 0.1686g Pd, and ground uniformly in mortar, then it is sealed in the stone of vacuum
Ying Guanzhong rises to 900 DEG C with the heating rate of 1 DEG C/mim, keeps the temperature one day, be cooled to 600 DEG C within three days, be put into mixture of ice and water
In, grinding obtains BiPd block materials.It takes 10mg BiPd block materials in 1mL DMF, takes supernatant after ultrasonic 60min,
Naphthols binder is added to be uniformly mixed, drop coating proper catalyst solution is in carbon paper surface.Naturally dry is obtained with high electrochemical
Activity and the topology of good electrochemical stability, superconduction BiPd thin slice production hydrogen material.
Embodiment 6:
Accurate weighing 0.3313g Bi and 0.1686g Pd, and ground uniformly in mortar, then it is sealed in the stone of vacuum
Ying Guanzhong rises to 900 DEG C with the heating rate of 1 DEG C/mim, keeps the temperature one day, be cooled to 600 DEG C within three days, be put into mixture of ice and water
In, grinding obtains BiPd block materials.It takes 10mg BiPd block materials in 1mL DMF, takes supernatant after ultrasonic 90min,
Naphthols binder is added to be uniformly mixed, drop coating proper catalyst solution is in carbon paper surface.Naturally dry is obtained with high electrochemical
Activity and the topology of good electrochemical stability, superconduction BiPd thin slice production hydrogen material.
Evaluation experimental:
BiPd sheeting is in current density -10mA cm-2Under overpotential be 186mV, Tafel slope 137.5mV
dec-1.At bias -0.5V, BiPd sheeting maintenance -20mA cm always after 8 hours-2Current density, performance do not have
It is decreased obviously.
Claims (4)
1. a kind of non-centrosymmetrical topology, superconductor are applied to electrochemistry and produce hydrogen, it is characterised in that have chemistry below
Formula and sheet thickness:
BiPd
0~100nm of sheet thickness.
2. the preparation method that a kind of non-centrosymmetrical topology, superconduction produce hydrogen material, it is characterised in that have technique below and
Step:
(1) corresponding Bi and Pd is successively weighed according to stoichiometric ratio BiPd to be sealed in vitreosil pipe；
(2) then quartz ampoule is put into Minitype box-type furnace, rises to 900 DEG C with the heating rate of 1 DEG C/min, keeps the temperature one day, three
It is cooled to 600 DEG C and is put into mixture of ice and water, opens quartz ampoule, and grinding obtains block materials；
(3) a certain amount of block materials are weighed, appropriate and suitable solvent is added, several minutes of ultrasound, supernatant under certain power
Liquid is the sheeting after removing；
(4) naphthols binder is added in the supernatant after ultrasound, several minutes of ultrasound uniformly mixed；
(5) on carbon paper the suitable catalyst solution of drop coating to get to carbon paper load flake produce hydrogen catalyst.
3. calcination procedure according to claim 2: 1 DEG C/min of heating, keeps the temperature one day, is cooled to 600 DEG C within three days by 900 DEG C,
It is put into mixture of ice and water.
4. topology made from method described in -2, superconduction sheeting produce hydrogen for electrochemical catalysis according to claim 1
Purposes.
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Family
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111101150A (en) * | 2019-12-02 | 2020-05-05 | 中山大学 | Binary silicon-based hydrogen production material and preparation method thereof |
| WO2022214117A1 (en) * | 2021-04-07 | 2022-10-13 | Koellisch Karsten | Electrolysis with combined superconductor technologies |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103601756A (en) * | 2013-11-06 | 2014-02-26 | 江苏华富储能新技术股份有限公司 | Bismuth metal organic framework material, preparation method and lead storage battery anode additives thereof |
| CN106477629A (en) * | 2016-10-08 | 2017-03-08 | 江苏大学 | A kind of bismuth sulfide classifying nano flower electrode material for super capacitor and preparation method |
-
2019
- 2019-01-09 CN CN201910034398.3A patent/CN109811357A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103601756A (en) * | 2013-11-06 | 2014-02-26 | 江苏华富储能新技术股份有限公司 | Bismuth metal organic framework material, preparation method and lead storage battery anode additives thereof |
| CN106477629A (en) * | 2016-10-08 | 2017-03-08 | 江苏大学 | A kind of bismuth sulfide classifying nano flower electrode material for super capacitor and preparation method |
Non-Patent Citations (3)
| Title |
|---|
| ODYSSEAS PASCHOS等: "Bismuth modified Pd/C as catalysts for hydrogen related reactions", 《ELECTROCHEMISTRY COMMUNICATIONS》 * |
| ZHIXIANG SUN等: "Dirac surface states and nature of superconductivity in Noncentrosymmetric BiPd", 《NATURE COMMUNICATIONS》 * |
| 衷明华等: "《综合化学实验》", 31 August 2014, 暨南大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111101150A (en) * | 2019-12-02 | 2020-05-05 | 中山大学 | Binary silicon-based hydrogen production material and preparation method thereof |
| WO2022214117A1 (en) * | 2021-04-07 | 2022-10-13 | Koellisch Karsten | Electrolysis with combined superconductor technologies |
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