CN109810479A - A kind of insulating materials for plastic stator - Google Patents

A kind of insulating materials for plastic stator Download PDF

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Publication number
CN109810479A
CN109810479A CN201811564671.5A CN201811564671A CN109810479A CN 109810479 A CN109810479 A CN 109810479A CN 201811564671 A CN201811564671 A CN 201811564671A CN 109810479 A CN109810479 A CN 109810479A
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CN
China
Prior art keywords
parts
insulating materials
heat
glass fibre
antistatic agent
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Pending
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CN201811564671.5A
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Chinese (zh)
Inventor
刘跃
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Hefei Xu Hong Plastic Products Co Ltd
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Hefei Xu Hong Plastic Products Co Ltd
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Priority to CN201811564671.5A priority Critical patent/CN109810479A/en
Publication of CN109810479A publication Critical patent/CN109810479A/en
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Abstract

A kind of insulating materials for plastic stator, is made of the raw material of following parts by weight: 20~30 parts of PBT resin, 10~16 parts of PET resin, 6~10 parts of glass fibre, 5~9 parts of silica, 1~3 part of graphene, 1~2 part of paraffin, 1~5 part of antistatic agent, 2~4 parts of heat-resisting material.The invention has the benefit that joined antistatic agent in the present invention, substantially increase the antistatic property of insulating materials, the glass fibre of addition has good insulating properties, heat resistance, corrosion resistance and mechanical strength, and graphene improves the disadvantage that glass fibre wears no resistance, property is crisp;Raw material used in the present invention is easy to get environmental protection, and preparation method is simple, and production cost is low.

Description

A kind of insulating materials for plastic stator
Technical field
The invention belongs to the plastic fields of stator, and in particular to a kind of insulating materials for plastic stator.
Background technique
Plastic stator refer to it is with insulating materials that stator is plastic in each phase of stator, in order to play to motor transport The insulating effect of electric current when turning.
Electrical insulating material is by the definition of 2900.5 regulation insulating materials of standard GB/T: " for making device electrical The material of upper insulation ".The material that namely electric current can be prevented to pass through.Its resistivity is very high, usually 10~10 Ω m's In range.Such as in motor, turn-to-turn is isolated and is kept apart with the stator core of ground connection by the insulating materials around conductor, to protect Demonstrate,prove the safe operation of motor.
It generally requires for the insulating materials in the plastic technique of stator with good insulating capacity and heat-resisting ability, But sometimes when workshop air is relatively dry, stator covered material is easy to produce electrostatic, and the wear-resisting equal objects of material Rationality can be poor;Existing stator covered material cost of material is high, and production method is complicated, high production cost, not environmentally.
Summary of the invention
Technical problem to be solved by the present invention lies in: sometimes when workshop air is relatively dry, stator is plastic Material is easy to produce electrostatic, and the physical properties such as wear-resisting of material are poor.For this purpose, providing a kind of insulation for plastic stator Material.
In order to solve the above technical problems, the technical solution of the present invention is as follows:
A kind of insulating materials for plastic stator, is made of the raw material of following parts by weight: 20~30 parts of PBT resin, PET tree 10~16 parts of rouge, 6~10 parts of glass fibre, 5~9 parts of silica, 1~3 part of graphene, 1~2 part of paraffin, antistatic agent 1~ 5 parts, 2~4 parts of heat-resisting material.
Preferably, be made of the raw material of following parts by weight: 20 parts of PBT resin, 10 parts of PET resin, 6 parts of glass fibre, 5 parts of silica, 1 part of graphene, 1 part of paraffin, 1 part of antistatic agent, 2 parts of heat-resisting material.
Preferably, be made of the raw material of following parts by weight: 30 parts of PBT resin, 16 parts of PET resin, 10 parts of glass fibre, 9 parts of silica, 3 parts of graphene, 2 parts of paraffin, 5 parts of antistatic agent, 4 parts of heat-resisting material.
Preferably, be made of the raw material of following parts by weight: 25 parts of PBT resin, 13 parts of PET resin, 8 parts of glass fibre, 7 parts of silica, 2 parts of graphene, 1.5 parts of paraffin, 3 parts of antistatic agent, 3 parts of heat-resisting material.
Preferably, the antistatic agent is anionic antistatic agents.
Preferably, the anionic antistatic agents are any one in sodium alkyl sulfonate or nabam.
Preferably, the heat-resisting material is aluminium nitride, boron carbide, silicon carbide, boron nitride, silicon nitride according to mass fraction Than the mixture for 1:1.5:1:1.5:1.
PBT, also referred to as polybutylene terephthalate (PBT), belong to polyester series, are by 1.4-pbt butanediol and to benzene two Formic acid (PTA) or terephthalate (DMT) polycondensation form, and translucent to not via milky made of program is kneaded Transparent, crystalline thermoplastic polyester's resin.PBT is referred to as thermoplastic polyester or saturated polyester together with PET.With following excellent Point: excellent mechanical performance, high mechanical strength, fatigue durability and dimensionally stable are good.Creep is also small, these performances are in hot conditions Under also seldom change;Production PBT consumed by energy be it is minimum in engineering plastics, this is tight for the energy in world wide In the case where lacking, have a very important significance;Heat-resistant aging is excellent, and enhanced Undterwriter's Laboratory temperature index reaches 120~140 DEG C, in addition, outdoor long-term ageing is also fine;Solvent resistant is good, unstressed cracking;PBT is easy to fire-retardant, up to UL94V-0 grades, by In good with the affine performance of fire retardant, so being easy the fire-retardant grade of exploitation response type or addition type.Flame retardant products are in electronic apparatus It is widely applied in industry;Excellent electric property, volume resistivity and dielectric strength are high, and arc resistance is excellent, hygroscopicity It is minimum, under moist and hot environment, it is also able to maintain electric performance stablity, is the ideal material for manufacturing electronics, electric parts;Yi Cheng Type processing and secondary operation, easy-to-use conventional equipment injection molding or extrusion molding.Since crystallization rate is fast, good fluidity, mold temperature also compares Other Engineering material requirements is low, only needs when processing thin wall parts several seconds, also only needs 40~60s to big component;It is mechanical Property stabilizes that tensile strength is similar to tensile modulus and nylon, coefficient of friction is small that self-lubricity, water absorption rate are low, electrical resistance is of fine quality Good, dimensional stability is good, resistance to chemical reagents, oil resistivity are splendid.
PET plastic has good optical property and weatherability, and amorphous PET plastic has good optical clear Property.In addition PET plastic has excellent abrasion performance frictional property and dimensional stability and electrical insulating property.The bottle that PET is made into has strong Degree is big, the transparency is good, nontoxic, impermeable, light weight, production efficiency height etc. thus receive and be widely applied.
Glass fibre is a kind of inorganic non-metallic material haveing excellent performance, many kinds of, and advantage is good insulating, heat resistance By force, corrosion resistance is good, high mechanical strength, but the disadvantage is that property is crisp, wearability is poor.It is pyrophillite, quartz sand, lime stone, white Seven kinds of marble, bechilite, boromagnesite ores are raw material through caused by the techniques systems such as high temperature melting, wire drawing, doff, woven fabric, list The diameter of silk is several microns to twenties microns, is equivalent to the 1/20~1/5 of a hairline, every bundle fiber precursor is all It is made of hundreds of even thousands of monofilament.Glass fibre is typically used as the reinforcing material in composite material, electrically insulating material and Heat-insulating material, the national economy every field such as circuit substrate.Glass fibre is added in the present invention, considerably increases this hair Insulating properties, heat resistance, corrosion resistance and the mechanical strength of the bright insulating materials.
Silica is added in rubber, and the wear resistance of rubber can be improved.It can change while tire drag can be reduced The wearability and anti-slippery of kind tire.It is mentioned using the sizing material tensile strength, tearing strength, wearability etc. of silica It is high.Silica is added in the present invention can be enhanced the physics such as the wearability of insulating materials of the present invention, tensile strength Performance.
Antistatic agent (ASA) generally all has the feature of surfactant, and polar group and non-polar group are simultaneous in structure And there is it.For plastics mainly in adding type antistatic agent, what interior adding type ASA was unevenly distributed in the polymer, when adding When being added to certain amount, the surface of composite material will form the film that one layer of hydrophilic radical arranges outward, while internal ASA energy The defect of film layer is supplemented to surface penetration;Therefore the compatibility of ASA and polymer just forms contradictory two aspect, phase Capacitive can make to slow down to appearance seepage velocity well, it is difficult to surface layer ASA loss be replenished in time, otherwise material can be made prematurely to lose again Lose antistatic property.The Combination between Masterbatch raw material can be improved in paraffin, and ductility can play reconciliation wherein and make With paraffin is added in the present invention can make the antistatic property of antistatic agent will not premature loss.
Heat-resisting material includes refractory material and heat proof material, has inorganic compound, also there is macromolecule polymer material.It is resistance to Fiery material typically refers to the inorganic material for being resistant to 1580 DEG C of temperatures above.They be build kiln, combustion chamber and other need it is resistance to The construction material of high temperature.Generally make raw material with quartz sand, clay, magnesite, dolomite etc. and be made, thermostable heat-isolating applies Expect that will is contained, is a kind of component inorganic coating, heatproof amplitude can inhibit height in -80~1800 DEG C, thermal coefficient 0.03W/m.K High temp objects can be kept 70% heat not lose by the heat radiation and conduction heat of warm object and cryogenic object.
8mm thermostable heat-isolating coating is coated in 1100 DEG C of body surfaces, body surface temperature can be from 1100 DEG C It is reduced within 100 DEG C.In addition there are also the spies such as insulation, light-weight, easy for construction, long service life for thermostable heat-isolating coating Point, it is also possible to do the use of inorganic material high temperature-resistant acid-resistant alkali glue crosslinking agent, attachment object is secured.Such as refractory cement, magnesia brick.From wide It is said in justice, inorganic refractory, heat proof material refer to that the hardness of these compounds is high, brittleness is good, resistance to chemical corrosion is good, Er Qierong O'clock in 1500 or more, such as high temp glass, refractory material is also belonged to.
Mainly be divided to metallic and nonmetallic compounds and it is nonmetallic between two class of compound.The former as tungsten, molybdenum, tantalum, niobium, vanadium, chromium, The boride of the refractory metals such as titanium, zirconium and rare earth metal, carbide, nitride, silicide, phosphide and sulfide etc.;Afterwards Person such as boron carbide, silicon carbide, boron nitride, silicon nitride, boron phosphide, phosphatization silicon etc..
The latter has epochmaking purposes, can be used as high-temperature refractory (such as abrasive material, mold, nozzle, pyrometer couple set Pipe), heat proof material (structural detail, the nuclear engineering material, heating element of such as rocket), (such as pyrometer couple ignites electrical material Electrode), additionally it is used as chemical resistant material and hard material etc..Heat-resistant polymer can be used as high-temperature resistant membrane insulation material Material, high-temperature fibre, high-temperature resistant coating, high-temperature-resistant adhesive etc..According to the time resistant to high temperature, but divide moment heat-resisting material and The heat-resisting material of long period.The former is resistant to several seconds to a few minutes at 1000~10000 DEG C.Wherein ablator is also resistance to height Adiabator.Such as at 300~600 DEG C, it is able to maintain its mechanical strength, resistant to chemical etching etc. in air.
The heat-resisting quantity of insulating materials not only can be improved in heat-resisting material, moreover it is possible to improve the corrosion resistance of insulating materials.
The invention has the benefit that joined antistatic agent in the present invention, the antistatic of insulating materials is substantially increased The glass fibre of performance, addition has good insulating properties, heat resistance, corrosion resistance and mechanical strength, and graphene improves glass The disadvantage that glass fibre abrasion is poor, property is crisp;Raw material used in the present invention is easy to get environmental protection, and preparation method is simple, and production cost is low.
Specific embodiment
The effect of to make to structure feature of the invention and being reached, has a better understanding and awareness, to preferable Embodiment cooperation detailed description, is described as follows:
Embodiment 1
A kind of insulating materials for plastic stator, is made of the raw material of following parts by weight: 20 parts of PBT resin, PET resin 10 Part, 6 parts of glass fibre, 5 parts of silica, 1 part of graphene, 1 part of paraffin, 1 part of antistatic agent, 2 parts of heat-resisting material.
The antistatic agent be anionic antistatic agents, specifically, the anionic antistatic agents be sodium alkyl sulfonate or Any one in nabam.
It according to mass parts ratio is 1 that the heat-resisting material, which is aluminium nitride, boron carbide, silicon carbide, boron nitride, silicon nitride: The mixture of 1.5:1:1.5:1.
Embodiment 2
A kind of insulating materials for plastic stator, is made of the raw material of following parts by weight: 30 parts of PBT resin, PET resin 16 Part, 10 parts of glass fibre, 9 parts of silica, 3 parts of graphene, 2 parts of paraffin, 5 parts of antistatic agent, 4 parts of heat-resisting material.
Other embodiments and embodiment 1 are identical.
Embodiment 3
A kind of insulating materials for plastic stator, is made of the raw material of following parts by weight: 25 parts of PBT resin, PET resin 13 Part, 8 parts of glass fibre, 7 parts of silica, 2 parts of graphene, 1.5 parts of paraffin, 3 parts of antistatic agent, 3 parts of heat-resisting material.
Other embodiments and embodiment 1 are identical.
Described in above-described embodiment 1 to 3 for plastic stator insulating materials the preparation method comprises the following steps:
(1) it after being melted at 1000~1200 DEG C after mixing the PBT resin of above-mentioned parts by weight, PET resin, is cooled to At 800~900 DEG C, molten mixture is obtained;
(2) be added into fusant above-mentioned parts by weight glass fibre, silica and heat-resisting material mixing after it is abundant It is crushed to the sieving of 150 mesh, obtains pulverulent mixture, for use;
(3) temperature for keeping above-mentioned molten mixture is 800~900 DEG C, and molten mixture is added in above-mentioned pulverulent mixture In, stirring is sufficiently mixed uniformly to the two, and the paraffin of above-mentioned parts by weight is slowly added in whipping process;
(4) antistatic agent of above-mentioned parts by weight is slowly added in mixture in step (3), be thoroughly mixed it is uniform it Afterwards, the temperature of cooling final mixture is to 100~120 DEG C, and pelletizer is added and is granulated to get the insulating materials.
In the plastic technique of stator, the proper amount of insulating materials need to be only chosen, be added after high-temperature fusion Injection molding machine carries out the injection molding of stator, can obtain required plastic stator.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and Improvement is both fallen in the range of claimed invention.The present invention claims protection scope by appended claims and its Equivalent defines.

Claims (7)

1. a kind of insulating materials for plastic stator, it is characterised in that: be made of the raw material of following parts by weight: PBT resin 20~30 parts, 10~16 parts of PET resin, 6~10 parts of glass fibre, 5~9 parts of silica, 1~3 part of graphene, paraffin 1~2 Part, 1~5 part of antistatic agent, 2~4 parts of heat-resisting material.
2. a kind of insulating materials for plastic stator according to claim 1, it is characterised in that: by following parts by weight Raw material composition: 20 parts of PBT resin, 10 parts of PET resin, 6 parts of glass fibre, 5 parts of silica, 1 part of graphene, 1 part of paraffin, 1 part of antistatic agent, 2 parts of heat-resisting material.
3. a kind of insulating materials for plastic stator according to claim 1, it is characterised in that: by following parts by weight Raw material composition: 30 parts of PBT resin, 16 parts of PET resin, 10 parts of glass fibre, 9 parts of silica, 3 parts of graphene, paraffin 2 Part, 5 parts of antistatic agent, 4 parts of heat-resisting material.
4. a kind of insulating materials for plastic stator according to claim 1, it is characterised in that: by following parts by weight Raw material composition: 25 parts of PBT resin, 13 parts of PET resin, 8 parts of glass fibre, 7 parts of silica, 2 parts of graphene, paraffin 1.5 Part, 3 parts of antistatic agent, 3 parts of heat-resisting material.
5. a kind of insulating materials for plastic stator according to any one of claim 1 to 4, it is characterised in that: institute Stating antistatic agent is anionic antistatic agents.
6. a kind of insulating materials for plastic stator according to claim 5, it is characterised in that: the anion resists quiet Electric agent is any one in sodium alkyl sulfonate or nabam.
7. a kind of insulating materials for plastic stator according to any one of claim 1 to 4, it is characterised in that: institute It according to mass parts ratio is 1:1.5:1:1.5:1 that state heat-resisting material, which be aluminium nitride, boron carbide, silicon carbide, boron nitride, silicon nitride, Mixture.
CN201811564671.5A 2018-12-20 2018-12-20 A kind of insulating materials for plastic stator Pending CN109810479A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040389A (en) * 2019-12-18 2020-04-21 佛山科学技术学院 High-temperature-resistant degradable plastic material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709659A (en) * 2012-09-30 2014-04-09 青岛欣展塑胶有限公司 Glass fiber reinforced PBT/PET alloy material
CN107474499A (en) * 2017-08-15 2017-12-15 利威光源零件(厦门)有限公司 A kind of heat conductive flame-retarding PET/PBT composites and the lamp holder being made from it

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709659A (en) * 2012-09-30 2014-04-09 青岛欣展塑胶有限公司 Glass fiber reinforced PBT/PET alloy material
CN107474499A (en) * 2017-08-15 2017-12-15 利威光源零件(厦门)有限公司 A kind of heat conductive flame-retarding PET/PBT composites and the lamp holder being made from it

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040389A (en) * 2019-12-18 2020-04-21 佛山科学技术学院 High-temperature-resistant degradable plastic material
CN111040389B (en) * 2019-12-18 2022-04-26 佛山科学技术学院 High-temperature-resistant degradable plastic material

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Application publication date: 20190528