CN109809655A - A kind of textile waste recoverying and utilizing method and device - Google Patents

A kind of textile waste recoverying and utilizing method and device Download PDF

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Publication number
CN109809655A
CN109809655A CN201910269416.6A CN201910269416A CN109809655A CN 109809655 A CN109809655 A CN 109809655A CN 201910269416 A CN201910269416 A CN 201910269416A CN 109809655 A CN109809655 A CN 109809655A
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Prior art keywords
treatment
textile waste
bagasse
pretreating reagent
water
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CN201910269416.6A
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CN109809655B (en
Inventor
张明
郑春光
陈文娟
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Fujian Hong Hong Textile Technology Co Ltd
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Fujian Hong Hong Textile Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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Abstract

The present invention discloses a kind of textile waste recoverying and utilizing method and installation method, includes the following steps: S1: textile waste carries out pre-treatment, obtains pre-treatment water;The pre-treatment is included the mechanical filter successively carried out, is handled and filtered using pretreating reagent;S2: pre-treatment water is sent into conditioning tank, adjusts pH to 4-6;S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard, and the pretreating reagent includes active carbon, bagasse, adsorpting polymerization object, bamboo powder.By the way of pre-treatment, in waste water organic matter and suspended matter tentatively removed, not only the MBR film of subsequent processing is depressurized, but also improve waste water treatment efficiency, reduces cost for wastewater treatment.

Description

A kind of textile waste recoverying and utilizing method and device
Technical field
The invention belongs to water treatment field, it is related to a kind of textile waste recoverying and utilizing method and device.
Background technique
Suspended matter, grease, Soft flocks, surfactant and various dyestuffs etc. are typically contained in textile waste.Tradition The processing mode of activated sludge process are as follows: raw wastewater, grid, homogeneous pond, aeration tank, sludge settling pond, water outlet, but this tradition Biological wastewater treatment technology in, mud-water separation is to complete in secondary settling tank by gravity, separative efficiency dependent on live The settling property of property sludge, settleability is better, and mud-water separation efficiency is higher.And the settleability of sludge depends on the operation of aeration tank Situation, improving sludge settling must be strictly controlled the operating condition of aeration tank, and which has limited the scope of applications of this method.Due to The requirement that secondary settling tank is separated by solid-liquid separation, the sludge of aeration tank cannot maintain higher concentration, generally in 1.5 ~ 3.5g/L or so, thus Limit biochemical reaction rate.
MBR film is now mostly used to be handled, such as license notification number is a kind of weaving disclosed in CN103102048B Wastewater treatment method, but the investment of technique and operating cost are excessively high in MBR membrane process treatment process, and textile printing and dyeing wastewater Water quality characteristic easily leads to fouling membrane, shortens the service life of film.
Summary of the invention
An object of the present disclosure is to provide a kind of textile waste recoverying and utilizing method, by increasing pre-treatment step, to useless Organic matter and suspended matter in water are tentatively removed, and are not only depressurized to the MBR film of subsequent processing, but also improve wastewater treatment effect Rate reduces cost for wastewater treatment.
The present invention adopts the following technical scheme that: a kind of textile waste recoverying and utilizing method includes the following steps:
S1: textile waste carries out pre-treatment, obtains pre-treatment water;
The pre-treatment is included the mechanical filter successively carried out, is handled and filtered using pretreating reagent;
S2: pre-treatment water is sent into conditioning tank, adjusts pH to 4-6;
S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard.
Preferably, the pretreating reagent includes active carbon, bagasse, adsorpting polymerization object, bamboo powder.
Further preferably, weight proportion are as follows: 22-30 parts of activated carbon, 20-25 parts of bagasse, 20-30 parts of adsorpting polymerization object, 12-20 parts of bamboo powder, 3-8 parts of acrylate.
Preferably, the pretreating reagent the preparation method comprises the following steps:
(1) it is 50-120 mesh that active carbon, which is crushed to partial size,;
(2) adsorpting polymerization object is merged, bamboo powder is added, mixed, granular absorption polymer is made;
(3) acrylate is melted, is added in the mixture of active carbon, the bagasse of modification, granular absorption polymer, just plus Enter side stirring, keeps the temperature 30-35min in the case where temperature is 100-120 degrees celsius, microspheric pretreating reagent is made.
In above scheme, the addition of bamboo powder expands the micropore size of adsorpting polymerization object, improves the adsorption effect of polymer; Bagasse itself has adsorption function, and it is capable of forming an attachment skeleton, cooperates the addition of acrylate, is pre-treatment Dosage form connects medium at attachment point and each component, and being conducive to pretreating reagent can exist in waste water with complete adsorbent, begins Adsorbed state is kept eventually.
Preferably, adsorpting polymerization object be using styrene and acrylate as monomer, addition divinylbenzene be crosslinking agent, first Benzene is formed for pore-foaming agent.Polymer is formed by with porous skeleton structure, adsorption effect is good.
Preferably, the partial size of the bamboo powder is 800-1000 microns.The excessive pretreating reagent that will affect of the partial size of bamboo powder exists Stability in waste water is easy spallation, globality poor.
Preferably, the bagasse is modified bagasse, and modified operation are as follows: in acidic environment, 90-98 degrees Celsius High-temperature process 45-60min, improve the toughness of bagasse.
Preferably, the pH of acidic environment is 3-3.5.
Another object of the present invention is to provide for the levitation device in step (1), and pretreating reagent is by levitation device pair Waste water is handled, the levitation device include it is main contain body, contained between body with the master connect by connector it is several A partial volume fills body, and the relative position that the master contains between body and partial volume dress body is variable, and the volume of the main containing body is greater than The volume of described point of containing body.
It in above-mentioned technical proposal, is adsorbed in waste water using suspension arrangement to arrange, the main containing body and the partial volume Receive body can the gravity of itself, the buoyancy of water, the active force of water flow, the main containing body and it is described divide containing body mutually it Between active force under in a certain range non-directional it is mobile, expand the effective use range of adsorbent, and be conducive to collect.
Why select two kinds of containing body that volume is different, is because co-content is not matched compared to the containing body with size It closes and uses, activity is fiercer, more preferable to useless Organic substance in water and molecule adsorption effect.
The main containing body divides containing body to use plastic material with described, light-weight, is able to maintain and is floating in waste water State.
Preferably, there is length difference between different connectors.It can move, guarantee on different depth, different ranges What is adsorbed is comprehensive.
Preferably, connector is rope body.
Preferably, connector is spring rope.
Preferably, the connector and main contain are detachably connected between body and partial volume dress body.
Preferably, the master contain body include the first halfbody and the second halfbody, between surround main accommodating cavity.
Preferably, being detachably connected between the first halfbody and the second halfbody.
Preferably, it is hinged in first position between the first halfbody and the second halfbody, opposite with first position second Snapping at position.
By implementing above-mentioned technical proposal, the present invention has the advantage that:
1. by the way of pre-treatment, in waste water organic matter and suspended matter tentatively removed, both to subsequent processing The decompression of MBR film, and waste water treatment efficiency is improved, reduce cost for wastewater treatment;
2. pretreating reagent provided by the invention, not only adsorption treatment effect is good, but also can be stable in the presence of in waste water;
3. the levitation device of pretreating reagent through the invention is arranged, expand the effective use range of pretreating reagent, at raising Manage efficiency.
Detailed description of the invention
Attached drawing 1 is the structural schematic diagram of levitation device of the invention;
The structural schematic diagram of body is contained based on attached drawing 2.
Specific embodiment
Below by specific embodiment, further details of the technical solution of the present invention.
Embodiment 1:
A kind of textile waste recoverying and utilizing method, includes the following steps:
S1: textile waste carries out pre-treatment, obtains pre-treatment water;
The pre-treatment is included the mechanical filter successively carried out, is handled and filtered using pretreating reagent;Mechanical filter uses grid;
S2: pre-treatment water is sent into conditioning tank, adjusts pH to 4;
S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard.
The pretreating reagent includes 30 parts of activated carbon, 20 parts modified of bagasse, 30 parts of adsorpting polymerization object, partial size 800- 1000 microns of 12 parts of bamboo powder, 5 parts of acrylate.
Adsorpting polymerization object be using styrene and acrylate as monomer, addition divinylbenzene be crosslinking agent, toluene is pore Agent and formed.
Pretreating reagent is made by the steps:
(1) it is 100-120 mesh that active carbon, which is crushed to partial size,;
(2) by polymer fusion, bamboo powder is added, mixes, particulate polymers is made;
(3) acrylate is melted, is added in the mixture of active carbon, the bagasse of modification, particulate polymers, side is just added Stirring keeps the temperature 30min in the case where temperature is 120 degrees celsius, microspheric pretreating reagent is made.
Embodiment 2:
A kind of textile waste recoverying and utilizing method, includes the following steps:
S1: textile waste carries out pre-treatment, obtains pre-treatment water;
The pre-treatment is included the mechanical filter successively carried out, is handled and filtered using pretreating reagent;Mechanical filter uses grid;
S2: pre-treatment water is sent into conditioning tank, adjusts pH;
S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard.
The pretreating reagent includes 22 parts of activated carbon, 25 parts modified of bagasse, 20 parts of adsorpting polymerization object, partial size 800- 1000 microns of 20 parts of bamboo powder, 8 parts of acrylate.
Adsorpting polymerization object be using styrene and acrylate as monomer, addition divinylbenzene be crosslinking agent, toluene is pore Agent and formed.Specific method: acrylate monomer, styrene monomer, crosslinking agent and pore-foaming agent are added sequentially to containing dispersion In the aqueous solution of agent, by suspension polymerization, reaction temperature is 78 DEG C~85 DEG C, and the reaction time is 4~8h.
Pretreating reagent is made by the steps:
(1) it is 50-80 mesh that active carbon, which is crushed to partial size,;
(2) by polymer fusion, bamboo powder is added, mixes, particulate polymers is made;
(3) acrylate is melted, is added in the mixture of active carbon, the bagasse of modification, particulate polymers, side is just added Stirring keeps the temperature 35min in the case where temperature is 120 degrees celsius, microspheric pretreating reagent is made.
The modified operation of modified bagasse are as follows: it in pH is 90 degrees Celsius of high-temperature process 60min in 3.5 acidic environments, Improve the toughness of bagasse.
Embodiment 3:
A kind of textile waste recoverying and utilizing method, includes the following steps:
S1: textile waste carries out pre-treatment, obtains pre-treatment water;
The pre-treatment is included the mechanical filter successively carried out, is handled and filtered using pretreating reagent;Mechanical filter uses grid;
S2: pre-treatment water is sent into conditioning tank, adjusts pH;
S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard.
The pretreating reagent includes 25 parts of activated carbon, 25 parts modified of bagasse, 25 parts of adsorpting polymerization object, partial size 800- 900 microns of 18 parts of bamboo powder, 3 parts of acrylate.
Adsorpting polymerization object be using styrene and acrylate as monomer, addition divinylbenzene be crosslinking agent, toluene is pore Agent and formed.
Pretreating reagent is made by the steps:
(1) it is 80-100 mesh that active carbon, which is crushed to partial size,;
(2) by polymer fusion, bamboo powder is added, mixes, particulate polymers is made;
(3) acrylate is melted, is added in the mixture of active carbon, the bagasse of modification, granular absorption polymer, just plus Enter side stirring, keeps the temperature 30min in the case where temperature is 110 degrees celsius, microspheric pretreating reagent is made.
The modified operation of modified bagasse are as follows: in pH be 95 degrees Celsius of high-temperature process 45min in 3.5 acidic environments.
Embodiment 4:
A kind of textile waste recoverying and utilizing method, includes the following steps:
S1: mechanical filter that textile waste successively carries out is handled using pretreating reagent and is filtered, and pre-treatment water is obtained;Mechanical filter Using grid;
S2: pre-treatment water is sent into conditioning tank, adjusts pH;
S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard.
The pretreating reagent includes 25 parts of activated carbon, 25 parts modified of bagasse, 25 parts of adsorpting polymerization object, partial size 800- 900 microns of 18 parts of bamboo powder, 5 parts of acrylate.
Adsorpting polymerization object be using styrene and acrylate as monomer, addition divinylbenzene be crosslinking agent, toluene is pore Agent and formed.
Pretreating reagent is made by the steps:
(1) it is 80-100 mesh that active carbon, which is crushed to partial size,;
(2) by polymer fusion, bamboo powder is added, mixes, particulate polymers is made;
(3) acrylate is melted, is added in the mixture of active carbon, the bagasse of modification, granular absorption polymer, just plus Enter side stirring, keeps the temperature 30min in the case where temperature is 110 degrees celsius, microspheric pretreating reagent is made.
The modified operation of modified bagasse are as follows: in pH be 95 degrees Celsius of high-temperature process 50min in 3.5 acidic environments.
Pretreating reagent in embodiment all uses levitation device to be placed in corresponding processing pond, including it is main contain body 201, with The master contains and fills body 202 by several partial volumes that 204 spring rope of connector connects between body 201, and the master contains body 201 Relative position between partial volume dress body 202 is variable.The volume of main containing body 201 is greater than the volume for dividing containing body 202, with 2-3 It is advisable again.The main body 201 that contains includes the first halfbody 2011 and the second halfbody 2012, between surround main accommodating cavity, the first halfbody 2011 and second hinged in first position between halfbody 2012, it is carried out in the second place opposite with first position using hasp Snapping.
There is length difference between different connectors 204.
The connector 204 and main contain are detachably connected between body 201 and partial volume dress body 202, can according to need Determine the number of partial volume dress body, dismountable mode can be tied up to using spring rope lead and contain on body 201 by the way of, can also be with The structure similar to key chain is housed at the both ends of spring rope, snaps onto main contain on body and partial volume dress body.
Comparative example 1:
It is with the difference of embodiment 4, pre-treatment only carries out mechanical filter.
Comparative example 2:
It is with the difference of embodiment 4, pretreating reagent uses active carbon.
Comparative example 3:
Be with the difference of embodiment 4, pretreating reagent include 25 parts of activated carbon, 25 parts of adsorpting polymerization object, partial size be 800-900 it is micro- 18 parts of the bamboo powder of rice, 5 parts of acrylate.
Comparative example 4:
It is with the difference of embodiment 4, the pretreating reagent includes 25 parts of activated carbon, 25 parts modified of bagasse, adsorpting polymerization 25 parts of object, 5 parts of acrylate.
Comparative example 5:
It is with the difference of embodiment 4, the pretreating reagent includes 25 parts of activated carbon, 25 parts modified of bagasse, adsorpting polymerization 25 parts of object, 18 parts of bamboo powder that partial size is 800-900 microns.
It is imitated using the processing that the recoverying and utilizing method of embodiment 1-4, comparative example 1-5 handle same volume textile waste Rate compares.(in a manner of bench-scale testing) method are as follows: MBR module is used for the first time, 1 month has been used, has used 6 A month, used 1 year in the case of, the processing time that androgynous ponding is handled, processing the time be start into waste water it is complete to waste water Until carrying out processing discharge by MBR reaction tank entirely.It the results are shown in Table 1.(during 1 month, 6 months, 1 year, the wastewater flow rate of processing, Waste water type and other conditions are all the same)
Time of the different MBR modules using the time of table 1 to wastewater treatment
As it can be seen from table 1 the processing time of embodiment 1-4 is significantly shorter than comparative example 1-5 for the MBR module used for the first time The processing time, without using pre-treatment comparative example 1, the processing time longest more needed.Illustrate pre-treatment in waste water Organic matter and suspended matter are tentatively removed, substantially increase waste water treatment efficiency, and as MBR module uses the time Extend, this effect becomes apparent.
The formation of the pretreating reagent of embodiment 4, comparative example 3-5 is measured, pre-treatment is passed through with the waste water of same volume Coloration, turbidity and the pretreating reagent of water obtained after agent processing same time starts time of spallation as measure object, (since the spallation time refer to the time for occurring rupturing being put into pretreating reagent to pretreating reagent) measurement result such as table 2.
From table 2 it can be seen that treated the waste water of comparative example 3,4,5, that treated is of poor quality than embodiment 4 for quality, and When the spallation time of pretreating reagent in comparative example 3,4,5 is shorter than embodiment 4, the especially spallation of comparative example 3 and comparative example 5 Between.

Claims (10)

1. a kind of textile waste recoverying and utilizing method, which comprises the steps of:
S1: textile waste carries out pre-treatment, obtains pre-treatment water;
The pre-treatment is included the mechanical filter successively carried out, is handled and filtered using pretreating reagent;
S2: pre-treatment water is sent into conditioning tank, adjusts pH to 4-6;
S3: being handled into MBR reaction tank, obtains the water for meeting discharge standard;
The pretreating reagent includes active carbon, bagasse, polymer microballoon, bamboo powder.
2. a kind of textile waste recoverying and utilizing method according to claim 1, which comprises the steps of: preceding place Managing agent includes 22-30 parts of activated carbon, 20-25 parts of bagasse, 20-30 parts of adsorpting polymerization object, 12-20 parts of bamboo powder, acrylate 3-8 Part.
3. a kind of textile waste recoverying and utilizing method according to claim 2, which is characterized in that the preparation of the pretreating reagent Method are as follows:
(1) it is 50-120 mesh that active carbon, which is crushed to partial size,;
(2) adsorpting polymerization object is merged, bamboo powder is added, mixed, granular absorption polymer is made;
(3) acrylate is melted, is added in the mixture of active carbon, the bagasse of modification, granular absorption polymer, just plus Enter side stirring, keeps the temperature 30-35min in the case where temperature is 100-120 degrees celsius, microspheric pretreating reagent is made.
4. a kind of textile waste recoverying and utilizing method according to claim 3, which is characterized in that adsorpting polymerization object is with benzene second Alkene and acrylate are monomer, addition divinylbenzene is crosslinking agent, toluene is pore-foaming agent and is formed.
5. a kind of textile waste recoverying and utilizing method according to claim 1 or claim 2, which is characterized in that the partial size of the bamboo powder It is 800-1000 microns.
6. a kind of textile waste recoverying and utilizing method according to claim 1 or claim 2, which is characterized in that the bagasse is to change Property bagasse, modified operation are as follows: in acidic environment, 90-98 degrees Celsius of high-temperature process 45-60min.
7. a kind of textile waste recoverying and utilizing method according to claim 6, which is characterized in that the pH of acidic environment is 3- 3.5。
8. a kind of levitation device, which is characterized in that contain body including main, contain with the master and connect between body by connector Several partial volumes fill body, and the relative position that the master contains between body and partial volume dress body is variable, and the volume of the main containing body Greater than the volume for dividing containing body.
9. a kind of levitation device according to claim 8, which is characterized in that have length difference between different connectors.
10. a kind of levitation device according to claim 8, which is characterized in that connector is spring rope.
CN201910269416.6A 2019-04-04 2019-04-04 Textile wastewater recycling method and device Active CN109809655B (en)

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CN109809655B CN109809655B (en) 2024-04-30

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040313A (en) * 2010-09-27 2011-05-04 常熟市福亿印花炼染有限公司 Process for treating high-concentration printing and dying waste water
CN104338518A (en) * 2013-08-09 2015-02-11 厦门岩科工业环保有限公司 Adsorbent capable of reducing toxic elements of stainless steel flying ash
CN107640874A (en) * 2017-11-14 2018-01-30 安徽名创新材料科技有限公司 The technique that a kind of MBR is combined processing dyeing waste water with membrane separation process
CN107986553A (en) * 2017-10-25 2018-05-04 安徽凯奇化工科技股份有限公司 A kind of dye wastewater processing system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040313A (en) * 2010-09-27 2011-05-04 常熟市福亿印花炼染有限公司 Process for treating high-concentration printing and dying waste water
CN104338518A (en) * 2013-08-09 2015-02-11 厦门岩科工业环保有限公司 Adsorbent capable of reducing toxic elements of stainless steel flying ash
CN107986553A (en) * 2017-10-25 2018-05-04 安徽凯奇化工科技股份有限公司 A kind of dye wastewater processing system
CN107640874A (en) * 2017-11-14 2018-01-30 安徽名创新材料科技有限公司 The technique that a kind of MBR is combined processing dyeing waste water with membrane separation process

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