CN109794077A - White device is taken off using the flue gas of high-pressure natural gas overbottom pressure and flue gas takes off whitening method - Google Patents

White device is taken off using the flue gas of high-pressure natural gas overbottom pressure and flue gas takes off whitening method Download PDF

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Publication number
CN109794077A
CN109794077A CN201910198179.9A CN201910198179A CN109794077A CN 109794077 A CN109794077 A CN 109794077A CN 201910198179 A CN201910198179 A CN 201910198179A CN 109794077 A CN109794077 A CN 109794077A
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China
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gas
natural gas
pressure
flue gas
condenser
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CN201910198179.9A
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卢作基
黄志伟
王高
钟学进
严旻
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Nanjing Environmental Protection Technology Co Ltd Cs
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Nanjing Environmental Protection Technology Co Ltd Cs
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

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Abstract

The invention belongs to environmental protection and energy saving technical fields, and in particular to a kind of flue gas using high-pressure natural gas overbottom pressure takes off white device and flue gas takes off whitening method.Device includes the condenser being installed in desulfurizing tower smokejack, heater, further includes vortex tube, and the inlet end of the vortex tube is connected with natural gas high pressure pipe network;The cold air end that goes out of the vortex tube is connected with the tube side import of the condenser;The hot gas end that goes out of the vortex tube is connected with the tube side import of the heater.The present invention recycles natural gas overbottom pressure by using vortex tube, and high-pressure natural gas gas is separated into hot and cold two strands of air-flows, respectively as the heat exchange medium of condenser and heater, realizes flue gas cool-down dehumidifying and heating purpose.The present invention largely loses pressure energy as the gas source of vortex tube using the part, significant for reducing the wasting of resources.

Description

White device is taken off using the flue gas of high-pressure natural gas overbottom pressure and flue gas takes off whitening method
Technical field
The invention belongs to environmental protection and energy saving and fume treatment technical fields, and in particular to one kind is suitable for smoke-gas wet desulfurization and inhales The flue gas for receiving tower takes off white device and flue gas takes off whitening method.
Background technique
90% or more unit of China's Desulphurization for Coal-fired Power Plant facility is all made of one gypsum wet sulfur removal technology of lime stone at present, takes off Flue-gas temperature after sulphur is down between 45 DEG C~60 DEG C, and the water capacity of the flue gas come out at this time is substantially at saturation state.Desulfurization Saturation wet flue gas afterwards is discharged, into the lower environment of temperature by chimney, and the water vapour in flue gas can condense into fine droplet shape At wet plume.Environment temperature is lower, humidity is bigger, and drop agglomeration effect is bigger, and white plume is longer, this is also current all wet The all existing universal phenomenon of method desulfurization.Not only perception is bad for the plume of formation, and a large amount of water vapours are also contained in flue gas, and water steams Contain more dissolubility salt, SO in vapour3, gel dust, micronic dust etc., these are all the main components of haze, direct by chimney Discharge, to ambient enviroment, there is also certain pollutions.
In recent years the local governments such as Jiangxi, Hebei, Zhejiang, Shanxi put into effect flue gas successively and take off white policy, standard, administer requirement. Some Domestic steel sintering machine, coking, coal-burning power plant etc. have responded policy and have called and complete gypsum rain and the improvement of coloured plume Engineering.Due to the difference of south and north, east and west region, weather conditions differ greatly, for example mean temperature, humidity, extreme temperature difference are very Greatly, the method and technology of use is also not quite similar.Different, residual heat resources difference that there are also the process flow conditions of each enterprise, investment are wanted Ask different, the desulfurization fume taken disappears the factors such as whitening method difference, and process program is ever-changing and has very big difference, but meets User's requirement is the fundamental requirement of technical solution.The mechanism for being formed and being dissipated according to wet plume, currently used method are concluded are as follows: Flue gas technology, flue gas condensing technology, flue gas first condense the combination technique of thermal technology again and various methods.
Currently used flue gas condensing thermal technology again are as follows: water-cooled condenser is arranged in desulfurization exhaust pass, and condenser shell side is walked Flue gas, tube side walk recirculated cooling water, achieve the purpose that cool-down dehumidification by heat exchange;Steam heater is set before smoke stack emission, Heater shell side walks flue gas, and tube side walks cyclic steam, achievees the purpose that heating by heat exchange.Entire flue gas condensing reheat machine system System process are as follows: the saturation wet flue gas that desulfurizing tower comes out, by cool-down dehumidification, re-forms one compared with low temperature after water-cooled condenser Saturation wet flue gas.Part steam in flue gas is removed, and in the condensation of flue gas condenser heat exchange surface, whereabouts, generation is coagulated It bears water and is recycled.It is sent via power transmission equipment to air cooling compressor and cools by the recirculated water of flue gas, drop Recirculated water after temperature returns water-cooled condenser again, so recycles.Recirculated water serves as coolant media in the process.Before chimney out, Saturation wet flue gas after cool-down dehumidification compared with low temperature is raised to after steam heater heats under conditions of water capacity is constant After assigned temperature, flue gas becomes unsaturated state from saturation state.Finally reach elimination " white cigarette " effect in flue gas outlet.
From the point of view of traditional flue gas condensing again thermal technology and process, water cooling condenser system is in addition to capital equipment flue gas condenser Except, there are also matched cooling water system and powertrain systems.Lead to that entire flue gas condensing system footprint is big, investment is made in this way The immediate problems such as valence height.Along with power consumption, water consume and the flue gas heating system during water-cooled condenser operation use the consumption of steam Amount, normally will also generate a no small operating cost over a year.Therefore, seek a set of land occupation less, system is simple, running cost It is very necessary that white processing equipment is taken off with low smoke-gas wet desulfurization (WFGD) chimney.
Natural gas is the high-efficiency cleaning energy, since the 1980s, China's natural gas proved reserves and sustained production Rapid growth.As all fronts of the pipelines such as transfering natural gas from the west to the east, river gas east are sent, the second west to east gas pipeline project are constructed and put into operation, three lines of transferring natural gas from the west to the east West section, An Nanduan, eastern section, Changsha branch line are constructed and put into operation, and the gas distributing system in a covering whole nation is gradually forming.With China's metallurgy, tubulation, welding and other construction technologies progress, for improve gas transmission ability, increase economic benefit, gas pipeline is not Break and develops to Large Diameter Pipeline, high pressure and other new material new technology directions.Currently, the long-distance conveying of China's pipe natural gas, greatly Mostly use the mode that high-voltage tube is defeated.Natural gas upstream is sent by high pressure pipe network to each city or large-scale user, natural by various regions Gas voltage regulating station is depressurized to middle pressure or low pressure is sent to user and used, and pipe network generates a large amount of pressure energies in pressure reduction, pressure energy Recycling is important link during natural gas transmission and distribution.By taking West-East National Gas Transmission Project as an example, high-pressure natural gas need to be dropped by 10MPa It is even lower to 2MPa~4MPa, and the pressure that end user uses is about 0.4MPa, according to reckoning, gas pressure is by 4MPa Being down to the recyclable maximum pressure of 0.4MPa can be about 322kJ/kg, with 120 × 108m3The displacement of/a calculates, annual such The recyclable maximum pressure of pipe network can be about 3.5 × 1012kJ.If so big potential energy waste be bound to cause it is huge Economic loss.If can be recycled to this, very far-reaching influence will be generated to China's energy industry, be provided for reducing Source waste, Accelerating The Construction resource-conserving and environment-friendly society have great importance.
Summary of the invention
In order to solve the above-mentioned technical problem, the purpose of the present invention is to provide a kind of flue gases using high-pressure natural gas overbottom pressure White device is taken off, natural gas overbottom pressure is recycled by using vortex tube, high-pressure natural gas gas is separated into hot and cold two strands of air-flows, Respectively as the heat exchange medium of condenser and heater, flue gas cool-down dehumidifying and heating purpose are realized.
To realize the above-mentioned technical purpose, the following technical solution is employed by the present invention:
Take off white device using the flue gas of high-pressure natural gas overbottom pressure, including be installed in desulfurizing tower smokejack condenser, with And it is installed in smokejack and the heater between condenser and chimney;Desulfurizing tower outlet discharge flue gas along smokejack according to It is secondary through the shell side of condenser, heater shell side after from chimney be discharged;
It further include vortex tube, the vortex tube has inlet end, out cold air end and out hot gas end;Vortex tube is a kind of structure Very simple energy separation device, it is made of nozzle, minor air cell, separation orifice and cold and hot two end pipe.High-pressure natural gas Gas access nozzle can work.High-pressure natural gas gas expands in nozzle when work, then tangentially with very high speed Direction enters vortex tube.Air-flow when high speed rotation, is separated into total temperature unequal two after vortex transformation in vortex tube Divide air-flow, the gas flow temperature in centre is low, and the gas flow temperature in outer layer position is high, adjusts hot and cold stream ratio, can To obtain best refrigeration effect or heating effect;
The inlet end of the vortex tube is connected with natural gas high pressure pipe network, and vortex tube will be from natural gas high pressure pipe network Natural gas is separated into hot and cold two strands of air-flows;
The cold air end that goes out of the vortex tube is connected with the tube side import of the condenser, the natural gas separated through vortex tube Cold airflow backs into gas distributing system after flowing through the heat exchanger tube of the condenser;When condenser system works, by the cold end pipe of vortex tube Cryogenic natural gas gas out walks condenser tube side, and the flue gas after desulfurization walks condenser shell side.Saturation wet flue gas passes through flue Into condenser, meets low-temperature heat exchange pipe and cooled down by heat exchange.Flue gas after condenser by after cool-down dehumidification by one section of flue Into heater;
The hot gas end that goes out of the vortex tube is connected with the tube side import of the heater, the natural gas separated through vortex tube Thermal current backs into gas distributing system after flowing through the heat exchanger tube of the heater.When heating system works, by the end tube of vortex tube High-temperature natural gas gas out walks heater tube side, walks heater shell side by condensed flue gas.Flue gas is changed with heater Heat pipe contact exchanges heat, is heated to after assigned temperature by smoke stack emission.
Wherein, the gas pressure of the natural gas high pressure pipe network is 2~10Mpa.
The flow direction of flue gas is opposite with the flow direction of natural gas cold airflow in the condenser as a preferred technical solution,.
The flow direction of flue gas is opposite with the flow direction of natural gas thermal current in the heater as a preferred technical solution,.
The material of the condenser is ND steel, two phase stainless steel or titanium alloy etc. as a preferred technical solution,.
The material of the heater is 2205 two phase stainless steels as a preferred technical solution,.
The present invention also provides the above-mentioned flue gases using high-pressure natural gas overbottom pressure to take off whitening method, includes the following steps:
Step 1: high-pressure natural gas gas is separated using the natural gas overbottom pressure of vortex tube recycling natural gas high pressure pipe network At hot and cold two strands of air-flows;
Step 2: being equipped with condenser in desulfurizing tower smokejack, the natural gas cold airflow of vortex tube separation is as condenser Heat exchange medium, exchanged heat by condenser, realize the cool-down dehumidification of flue gas, flow back into pipe with the natural gas cold air after flue gas heat exchange Net;
Step 3: after being located at condenser in desulfurizing tower smokejack, having heaters is installed before chimney, vortex tube separation Heat exchange medium of the natural gas thermal current as heater, is exchanged heat by heater, by condensed flue gas to assigned temperature The lesser flue gas of humidity is formed afterwards flows back into pipe network by the natural gas hot gas after smoke stack emission, with flue gas heat exchange.
Due to the adoption of the above technical scheme, the present invention have it is at least following the utility model has the advantages that
(1) long distance pipeline of China's natural gas uses high pressure gas transmission, and natural gas upstream is sent by high pressure pipe network to each city Or large-scale user, middle pressure is depressurized to by various regions natural gas pressure regulating station or low pressure is sent to user and used, pipe network is in pressure reduction Lose a large amount of pressure energies.The present invention largely loses pressure energy as the gas source of vortex tube using the part, provides in this way for reducing Source waste is significant;
(2) vortex tube structure is simple and convenient to operate, and can be adjusted hot and cold stream ratio according to environment temperature or de- white effect, be obtained To best refrigeration effect or heating effect, different regions are adaptable to, conducive to being widely popularized;
(3) compared to tradition condensation again thermal technology, the present apparatus save water resource and steam resource, be suitable for water resource and The bad enterprise of steam resources supplIes.
Detailed description of the invention
The following drawings are only intended to schematically illustrate and explain the present invention, not delimit the scope of the invention.Wherein:
Fig. 1 is the structural schematic diagram of the embodiment of the present invention;
Fig. 2 is the schematic illustration of the embodiment of the present invention.
Specific embodiment
With reference to the accompanying drawings and examples, the present invention is further explained.In the following detailed description, only pass through explanation Mode describes certain exemplary embodiments of the invention.Undoubtedly, those skilled in the art will recognize, In the case where without departing from the spirit and scope of the present invention, described embodiment can be repaired with a variety of different modes Just.Therefore, attached drawing and description are regarded as illustrative in nature, and are not intended to limit the scope of the claims.
As depicted in figs. 1 and 2, white device is taken off using the flue gas of high-pressure natural gas overbottom pressure, including is installed on the smoke evacuation of desulfurizing tower 1 It condenser 3 in road 2 and is installed in smokejack 2 and the heater 4 between condenser 3 and chimney 5;Desulfurizing tower 1 goes out Mouthful discharge flue gas along smokejack 2 successively through the shell side of condenser 3, heater 4 shell side after from chimney 5 be discharged;
Further include vortex tube 6, can be installed on the outside of smokejack, the vortex tube 6 have inlet end 61 (i.e. nozzle end), The structure at cold air end 62 and out hot gas end 63 out, vortex tube 6 is well-known technique, and details are not described herein;
The inlet end 61 of the vortex tube 6 is connected with natural gas high pressure pipe network (can of course be arranged control on pipeline Valve etc.), the natural gas from natural gas high pressure pipe network is separated into hot and cold two strands of air-flows by vortex tube 6;The vortex tube 6 goes out Cold air end 62 is connected with the tube side import of the condenser 3, flows through through the isolated natural gas cold airflow of vortex tube 6 described cold Gas distributing system is backed into after the heat exchanger tube of condenser;The tube side import phase for going out hot gas end 63 and the heater 4 of the vortex tube 6 Connection, backs into gas distributing system after the isolated natural gas thermal current of vortex tube 6 flows through the heat exchanger tube of the heater.
In the condenser flow direction of flue gas and natural gas cold airflow flow direction on the contrary, in the heater flue gas flow direction Flow direction with natural gas thermal current is on the contrary, the hot and cold air-flow of natural gas and flue gas realize counterflow heat exchange.
Wherein, the shell of the condenser 3 and heat exchanger tube should select anti-corrosion material, and heat exchanger tube material can be ND steel, double Phase stainless steel or titanium alloy etc..Material rate of corrosion is not more than 8mg/cm2.h-1(70 DEG C, 50% sulfuric acid impregnates for 24 hours).
The shell and heat exchanger tube material of the heater 4 are 2205 two phase stainless steels.2205 base tube wall thickness are not less than 3mm, fin (if any) is identical as base tube material, and fin thickness is not less than 1.5mm.The shell plate thickness of heater is not less than 6mm.
With reference to Fig. 2, working principle is as follows: high-pressure natural gas gas is sprayed into via 6 inlet end 61 (nozzle) of vortex tube and is vortexed Behind room, air-flow is rotating with to be up to 1,000,000 turns of speed per minute and flows to vortex tube and go out hot gas end 63 (end tube outlet), and one Fraction is flowed out by control valve, after remaining natural gas gas is blocked, is reversely revolved in former air flow pattern with same revolving speed Turn, and flows to vortex tube and go out cold air end 62 (outlet of cold end pipe).It is ultimately separated into hot and cold two parts air-flow.Wherein cold air circulates Piping enters 3 heat exchanger tube of condenser, and thermal current enters 4 heat exchanger tube of heater by pipeline.
After flue gas is cooled down by 1 spray-absorption of absorption tower, 45 DEG C~60 DEG C saturation wet flue gas of discharge are exported by tower.Flue gas passes through Smokejack 2 enters condenser 3 from left to right, and cryogenic natural gas gas is turned left flowing along condenser coil by the right side, with smoke contacts Realize counterflow heat exchange.Partial moisture is condensed collection after flue gas is cooled down.Flue gas after 3 cool-down dehumidification of condenser shape again At saturation wet flue gas at this temperature, enter heater 4 via flue.It is diverted in the heat exchanger tube of heater 4 for vortex tube 6 High-temperature natural gas gas.Flue gas enters heater 4 by flue from left to right, high-temperature natural gas gas along heater coil by The right side is turned left flowing, realizes counterflow heat exchange with smoke contacts.Flue gas forms the lesser flue gas of humidity after being warmed and is discharged by chimney 5.
Final vortex tube, which takes off white device, reduces the relative humidity of flue gas emission, and the lifting for improving flue gas discharge chimney is high Degree achievees the effect that eliminate " white cigarette ".
The foregoing is merely the schematical specific embodiment of the present invention, the range being not intended to limit the invention.It is any Those skilled in the art, the equivalent changes and modifications made under the premise of not departing from design and the principle of the present invention, It should belong to the scope of protection of the invention.

Claims (7)

1. take off white device using the flue gas of high-pressure natural gas overbottom pressure, including the condenser that is installed in desulfurizing tower smokejack and It is installed in smokejack and the heater between condenser and chimney;Desulfurizing tower outlet discharge flue gas along smokejack successively Through the shell side of condenser, heater shell side after from chimney be discharged;It is characterized by:
It further include vortex tube, the vortex tube has inlet end, out cold air end and out hot gas end;
The inlet end of the vortex tube is connected with natural gas high pressure pipe network, and vortex tube will be from the natural of natural gas high pressure pipe network Gas is separated into hot and cold two strands of air-flows;
The cold air end that goes out of the vortex tube is connected with the tube side import of the condenser, the natural gas cold air separated through vortex tube Stream backs into gas distributing system after flowing through the heat exchanger tube and flue gas heat exchange of the condenser;
The hot gas end that goes out of the vortex tube is connected with the tube side import of the heater, the natural gas hot gas separated through vortex tube Stream backs into gas distributing system after flowing through the heat exchanger tube and flue gas heat exchange of the heater.
2. taking off white device using the flue gas of high-pressure natural gas overbottom pressure as described in claim 1, it is characterised in that: the condenser The flow direction of interior flue gas is opposite with the flow direction of natural gas cold airflow.
3. taking off white device using the flue gas of high-pressure natural gas overbottom pressure as described in claim 1, it is characterised in that: the heater The flow direction of interior flue gas is opposite with the flow direction of natural gas thermal current.
4. taking off white device using the flue gas of high-pressure natural gas overbottom pressure as described in claim 1, it is characterised in that: the natural gas The gas pressure of high pressure pipe network is 2~10Mpa.
5. as the described in any item flue gases using high-pressure natural gas overbottom pressure of Claims 1-4 take off white device, it is characterised in that: The material of the condenser is ND steel, two phase stainless steel or titanium alloy.
6. as the described in any item flue gases using high-pressure natural gas overbottom pressure of Claims 1-4 take off white device, it is characterised in that: The material of the heater is 2205 two phase stainless steels.
7. the flue gas using high-pressure natural gas overbottom pressure takes off whitening method, which comprises the steps of:
Step 1: using vortex tube recycling natural gas high pressure pipe network natural gas overbottom pressure, by high-pressure natural gas gas be separated into it is cold, Hot two strands of air-flows;
Step 2: condenser is installed in desulfurizing tower smokejack, natural gas cold airflow the changing as condenser of vortex tube separation Thermal medium is exchanged heat by condenser, realizes the cool-down dehumidification of flue gas, flows back into pipe network with the natural gas cold air after flue gas heat exchange;
Step 3: after being located at condenser in desulfurizing tower smokejack, installing having heaters before chimney, vortex tube is separated natural Heat exchange medium of the gas thermal current as heater, is exchanged heat by heater, by shape after condensed flue gas to assigned temperature Pipe network is flowed back by the natural gas hot gas after smoke stack emission, with flue gas heat exchange at the lesser flue gas of humidity.
CN201910198179.9A 2019-03-15 2019-03-15 White device is taken off using the flue gas of high-pressure natural gas overbottom pressure and flue gas takes off whitening method Pending CN109794077A (en)

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CN116060574A (en) * 2023-04-07 2023-05-05 山西金瑞高压环件有限公司 Chamber type natural gas energy-saving emission-reducing forging heating furnace

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Publication number Priority date Publication date Assignee Title
CN114719438A (en) * 2022-03-14 2022-07-08 山东保蓝环保工程有限公司 Condensation type boiler flue gas white eliminating device
CN116060574A (en) * 2023-04-07 2023-05-05 山西金瑞高压环件有限公司 Chamber type natural gas energy-saving emission-reducing forging heating furnace
CN116060574B (en) * 2023-04-07 2023-06-13 山西金瑞高压环件有限公司 Chamber type natural gas energy-saving emission-reducing forging heating furnace

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