CN109778422A - A kind of antibacterial textile cloth and preparation method thereof - Google Patents
A kind of antibacterial textile cloth and preparation method thereof Download PDFInfo
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- CN109778422A CN109778422A CN201811523365.7A CN201811523365A CN109778422A CN 109778422 A CN109778422 A CN 109778422A CN 201811523365 A CN201811523365 A CN 201811523365A CN 109778422 A CN109778422 A CN 109778422A
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- ion
- textile cloth
- antibacterial textile
- antibacterial
- zinc
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Abstract
The present invention provides a kind of antibacterial textile cloth, and the blended acquisition of composite metal ion is added by matrix resin in the textile cloth.The antibacterial textile cloth is broad-spectrum antiseptic, antibacterial textile cloth, has the characteristics such as efficient, quick, safety, is with a wide range of applications.
Description
Technical field
The present invention relates to textile cloth technical fields, in particular it relates to a kind of antibacterial textile cloth and preparation method thereof.
Background technique
Fabric is the important raw material for manufacturing ready-made clothes, and existing fabric variety is numerous, but with people's living standard
Raising, it is desirable to provide be able to satisfy different crowd needs new varieties.Requirement of the people to clothes not only to clothes fashion, do
The requirement of work is more the requirement to clothes quality, this requires to get caught up in the development of clothing form on garment material,
The feature of the fabrics such as its functional, comfortable, environmental protection, health becomes the topic that people increasingly pay close attention to.Especially guaranteeing safety
On the basis of, people increasingly focus on fabric deodorization, it is antibacterial, in terms of function.
Summary of the invention
The present invention provides a kind of antibacterial textile cloth to meet the market demand.The antibacterial textile cloth is broad-spectrum antiseptic, suppression
Bacterium textile cloth has the characteristics such as efficient, quick, safety.
In order to achieve the object of the present invention, the present invention adopts the following technical scheme:
One aspect of the present invention provides a kind of antibacterial textile cloth, and composite metal ion is added by matrix resin in the textile cloth
Blended acquisition.
In the specific embodiment of the present invention, by weight percentage, the total amount of the composite metal ion is
The 2%-5% of matrix resin weight.
In the specific embodiment of the present invention, the composite metal ion include silver ion, copper ion, zinc from
Son.
The silver ion can be provided by silver nitrate, silver sulfate, silver chlorate, silver hydroxide, silver iodide etc..
The copper ion can be provided by copper nitrate, copper sulphate, Kocide SD, copper chloride etc..
The zinc ion can be provided by zinc nitrate, zinc sulfate, zinc chloride, zinc hydroxide etc..
In the specific embodiment of the present invention, according to molar ratio computing, the silver ion, copper ion, zinc ion
The ratio of content is 1:(10~100): (10~100).Preferably, the ratio of the content of the silver ion, copper ion, zinc ion
For 1:(20~80): (20~80).It is highly preferred that the ratio of the content of the silver ion, copper ion, zinc ion be 1:(40~:
60): (40~60).For example, silver ion: copper ion: the content ratio of zinc ion is 1:40:40 or silver ion: copper ion: zinc
The content ratio of ion is 1:40:50 or silver ion: copper ion: the content ratio of zinc ion is 1:50:50 or silver ion: copper
Ion: the content ratio of zinc ion is 1:50:60 or silver ion: copper ion: the content ratio of zinc ion is 1:60:50.
In the specific embodiment of the present invention, the composite metal ion further includes tin ion.The tin ion
It is provided by stannous chloride, stannous sulfate etc..
In the specific embodiment of the present invention, according to molar ratio computing, the content of the tin ion be the silver from
The 2%~30% of the content of son, copper ion, zinc ion.For example, the content of the tin ion is the silver ion, copper ion, zinc
2%, 5%, 10%, 15%, 20%, 25% or the 30% of the content of ion.
In the specific embodiment of the present invention, described matrix resin is polypropylene, polyethylene, polystyrene, Buddhist nun
One of dragon is a variety of.
In the specific embodiment of the present invention, the antibacterial textile cloth further includes emulsifier, and the emulsifier is
Dodecyl sodium sulfate, neopelex or hexadecyltrimethylammonium chloride.By weight percentage, the emulsification
Agent is the 3%~10% of described matrix resin.
In the specific embodiment of the present invention, the antibacterial textile cloth includes or is prepared from the following components:
In every 100g polypropylene, 4.1 × 10-4mol silver ion, 1.1 × 10-2mol copper ion, 9.9 × 10-3 zinc ion, 6.3 is added
× 10-3 tin ion and 5g hexadecyltrimethylammonium chloride.
Another aspect of the present invention also provides the preparation method of above-mentioned antibacterial textile cloth, comprising the following steps:
(1) silver ion, copper ion, zinc ion (or and tin ion) are dissolved in deionized water, are stirred evenly, ammonia is added
Water adjusts pH value to 8-12, is again stirring for 5-10 minutes, forms suspension；
(2) suspension in step (1) is added in matrix resin and textile cloth is formed by melt-blown.
Illustratively, the present invention one of at least has the advantage that:
The antibacterial textile cloth containing composite metal ion that the present invention provides a kind of, the antibacterial textile cloth production technology letter
It is single, can the characteristics such as high-efficiency antimicrobial, quick antibacterial, broad-spectrum antibacterial, safety is antibacterial, have broad application prospects.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states.Obviously, the described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts,
It shall fall within the protection scope of the present invention.
The antibacterial textile cloth of embodiment 1
Antibacterial textile cloth in the present embodiment includes composite metal ion and matrix resin.Composite metal ion be silver from
Son, copper ion, zinc ion and tin ion, silver ion can be mentioned by silver nitrate, silver sulfate, silver chlorate, silver hydroxide, silver iodide etc.
For；Copper ion can be provided by copper nitrate, copper sulphate, Kocide SD, copper chloride etc.；Zinc ion can be by zinc nitrate, zinc sulfate, chlorination
Zinc, zinc hydroxide etc. provide；Tin ion can be provided by stannous chloride, stannous sulfate etc..According to molar ratio computing, silver ion, copper from
The ratio of the content of son, zinc ion is 1:(10~100): (10~100).According to molar ratio computing, the content of tin ion be silver from
The 2%~30% of the content of son, copper ion, zinc ion.
Wherein, matrix resin is polypropylene, polyethylene or polystyrene.By weight percentage, composite metal ion
Total amount is the 2%-5% of matrix resin weight.Specific ingredient and content are as shown in table 1 below.
The each ingredient and content of antibacterial textile cloth in 1 embodiment 1 of table
In above-mentioned table 1, in 1-A, 1-D, 1-G example antibacterial textile cloth the preparation method comprises the following steps:
(1) composite metal ion is dissolved in deionized water, is configured to the metal ion solution of respective concentration, stirring is equal
It is even, ammonium hydroxide is added, adjusts pH value to 8-12, is again stirring for 5-10 minutes, forms suspension；
(2) suspension in step (1) is added in matrix resin and textile cloth is formed by melt-blown.
In above-mentioned table 1, the preparation method of antibacterial textile cloth in 1-B, 1-C, 1-E, 1-F, 1-H, 1-I, 1-J, 1-K example
Are as follows:
(1) composite metal ion is dissolved in deionized water, is configured to the metal ion solution of respective concentration, stirring is equal
It is even.
(2) emulsifier is dissolved in deionized water, then the composite metal ion solution in step 1 is added to emulsifier
In, it stirs evenly, ammonium hydroxide is added, adjust pH value to 8-12, be again stirring for 5-10 minutes, form suspension；
(3) suspension in step (2) is added in matrix resin and textile cloth is formed by melt-blown.
The antibacterial textile cloth anti-microbial property test of embodiment 2
Each example in above-described embodiment 1 is subjected to anti-microbial property test, anti-microbial property test presses QB/T2591-2003
Test.The results are shown in Table 2 for its experiment.
The anti-microbial property test of antibacterial textile cloth in 2 embodiment 1 of table
Anti-microbial property test is carried out to the antibacterial textile cloth of each example in embodiment 1, the test strain selected is big
Enterobacteria ATCC25922, staphylococcus aureus ATCC6538, Candida albicans CMCC (F) 98001, enterococcus faecalis
ATCC29212, Friedlander's bacillus CMCC46117, aspergillus niger AS3.4463, Aureobasidium pullulans AS3.3984, test result
As shown in table 2.From Table 2, it can be seen that the antibacterial textile cloth of each example in embodiment 1 is broad-spectrum antibacterial textile cloth,
To the bacteriums such as Escherichia coli, staphylococcus aureus, Candida albicans, enterococcus faecalis, Friedlander's bacillus and aspergillus niger, go out
Mould equal moulds of the short stalk of bud all have antibacterial effect, and can high-efficiency antimicrobial, antibacterial effect reaches 99% or more, mould proof etc.
Grade is 0-1 grades.Especially to enterococcus faecalis, Candida albicans, antimicrobial efficiency has nearly reached 100%.
Anti-microbial property test of the antibacterial textile cloth of embodiment 3 in different times of contact
By taking Escherichia coli ATCC25922 as an example, the antibacterial textile cloth in each example in EXPERIMENTAL EXAMPLE 1 connects in difference
Touch the anti-microbial property when time.
Antibacterial textile cloth in each example in embodiment 1 is put into containing in certain density inoculum, is led to
Crossing oscillation comes into full contact with textile cloth with bacterium solution, its bacterium solution is then put into constant temperature incubation in agar medium, before oscillation
Clump count difference is evaluated afterwards, and antibacterial effect is indicated with bacteriostasis rate, formula are as follows:
Bacteriostasis rate (%)=(X-Y)/X × 100%
In formula, X is the clump count before vibrating in bottle；Y is the clump count after vibrating in bottle.It is multiple to be not added every time when experiment
The textile cloth of metal ion is as blank control.Its experimental result is as shown in table 3 below.
The antibacterial textile cloth of table 3 and Escherichia coli contact different time
| Example | 5min | 8min | 10min | 12min |
| 1-A | 70.1% | 89.5% | 99.9% | 100% |
| 1-B | 70.4% | 85.6% | 99.1% | 100% |
| 1-C | 70.2% | 83.2% | 99.6% | 100% |
| 1-D | 69.5% | 82.7% | 99.1% | 100% |
| 1-E | 73.2% | 84.3% | 99.4% | 100% |
| 1-F | 64.8% | 81.5% | 99.9% | 100% |
| 1-G | 69.2% | 84.5% | 98.9% | 100% |
| 1-H | 59.9% | 84.8% | 99.2% | 100% |
| 1-I | 57.8% | 83.9% | 99.7% | 100% |
| 1-J | 68.7% | 86.1% | 100% | 100% |
| 1-K | 71.6% | 88.2% | 100% | 100% |
Antibiotic rate of each antibacterial textile cloth provided in embodiment 1 it can be seen from above-mentioned table 3 in 10min
Reaching 99% or more, 12min can reach 100%, it is seen then that each antibacterial textile cloth that embodiment 1 provides can be rapidly and efficiently
Antibacterial.And due to the antibacterial textile cloth provided in the embodiment of the present application be in matrix resin be added composite metal ion into
Property it is modified and be meltblown the antibacterial textile cloth formed, not only there is antibacterial and mouldproof performance, but also antimicrobial component will not ooze out, antibacterial
Substance effective content can remain unchanged for a long time, and therefore, antibacterial effect remains unchanged with being also able to maintain.In addition, this
The concentration for the composite metal ion being added in the antibacterial textile cloth provided in application embodiment will not produce within safe range
Raw any toxicity or irritation effect.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, made any modification, equivalent replacement etc. be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of antibacterial textile cloth, which is characterized in that the textile cloth is added that composite metal ion is blended obtains by matrix resin
?.
2. antibacterial textile cloth as described in claim 1, which is characterized in that by weight percentage, the composite metal ion
Total amount be matrix resin weight 2%-5%.
3. antibacterial textile cloth as claimed in claim 1 or 2, which is characterized in that the composite metal ion includes silver ion, copper
Ion, zinc ion.
4. antibacterial textile cloth as claimed in claim 3, which is characterized in that according to molar ratio computing, the silver ion, copper ion,
The ratio of the content of zinc ion is 1:(10~100): (10~100).
5. such as antibacterial textile cloth of any of claims 1-4, which is characterized in that the composite metal ion further includes
Tin ion.
6. antibacterial textile cloth as claimed in claim 5, which is characterized in that according to molar ratio computing, the content of the tin ion is
The silver ion, copper ion, zinc ion content summation 2~30%.
7. such as antibacterial textile cloth of any of claims 1-6, which is characterized in that described matrix resin be polypropylene,
One of polyethylene, polystyrene, nylon are a variety of.
8. such as antibacterial textile cloth of any of claims 1-7, which is characterized in that it further include emulsifier, the emulsification
Agent is dodecyl sodium sulfate, neopelex or hexadecyltrimethylammonium chloride.
9. antibacterial textile cloth as claimed in claim 8, which is characterized in that the antibacterial textile cloth includes or by following components system
It is standby to form: in every 100g polypropylene, to be added 4.1 × 10-4Mol silver ion, 1.1 × 10-2Mol copper ion, 9.9 × 10-3Zinc from
Son, 6.3 × 10-3Tin ion and 5g hexadecyltrimethylammonium chloride.
10. the preparation method of antibacterial textile cloth of any of claims 1-9, comprising the following steps:
(1) silver ion, copper ion, zinc ion (or and tin ion) are dissolved in deionized water, are stirred evenly, ammonium hydroxide is added, adjusted
PH value is saved to 8-12, is again stirring for 5-10 minutes, forms suspension；
(2) suspension in step (1) is added in matrix resin and textile cloth is formed by melt-blown.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811523365.7A CN109778422A (en) | 2018-12-13 | 2018-12-13 | A kind of antibacterial textile cloth and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811523365.7A CN109778422A (en) | 2018-12-13 | 2018-12-13 | A kind of antibacterial textile cloth and preparation method thereof |
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| CN109778422A true CN109778422A (en) | 2019-05-21 |
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| CN201811523365.7A Pending CN109778422A (en) | 2018-12-13 | 2018-12-13 | A kind of antibacterial textile cloth and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114892345A (en) * | 2022-05-09 | 2022-08-12 | 西南大学 | Antibacterial polypropylene non-woven fabric and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007107144A (en) * | 2005-10-14 | 2007-04-26 | Chisso Corp | Hydrophilic antimicrobial/deodorant fiber, fiber formed product and textile product |
| CN102121174A (en) * | 2010-12-24 | 2011-07-13 | 北京美格赛斯无纺科技有限公司 | Nonwovens containing antibacterial and antiviral master batches and method and device for producing same |
| KR20120028115A (en) * | 2010-09-14 | 2012-03-22 | 대한민국(관리부서 : 산림청 국립산림과학원장) | A non-woven fabric containing white charcoal and manufacturing method thereof |
| CN104047114A (en) * | 2014-06-17 | 2014-09-17 | 李文博 | Nano-silver antibacterial melt-blown non-woven fabric and production method thereof |
| CN104389038A (en) * | 2014-11-04 | 2015-03-04 | 佛山市优特医疗科技有限公司 | Antibacterial fiber as well as product and preparation method thereof |
| CN106637683A (en) * | 2016-11-17 | 2017-05-10 | 浙江水马环保科技有限公司 | Multi-ion antibacterial filter cloth and making method thereof |
-
2018
- 2018-12-13 CN CN201811523365.7A patent/CN109778422A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007107144A (en) * | 2005-10-14 | 2007-04-26 | Chisso Corp | Hydrophilic antimicrobial/deodorant fiber, fiber formed product and textile product |
| KR20120028115A (en) * | 2010-09-14 | 2012-03-22 | 대한민국(관리부서 : 산림청 국립산림과학원장) | A non-woven fabric containing white charcoal and manufacturing method thereof |
| CN102121174A (en) * | 2010-12-24 | 2011-07-13 | 北京美格赛斯无纺科技有限公司 | Nonwovens containing antibacterial and antiviral master batches and method and device for producing same |
| CN104047114A (en) * | 2014-06-17 | 2014-09-17 | 李文博 | Nano-silver antibacterial melt-blown non-woven fabric and production method thereof |
| CN104389038A (en) * | 2014-11-04 | 2015-03-04 | 佛山市优特医疗科技有限公司 | Antibacterial fiber as well as product and preparation method thereof |
| CN106637683A (en) * | 2016-11-17 | 2017-05-10 | 浙江水马环保科技有限公司 | Multi-ion antibacterial filter cloth and making method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114892345A (en) * | 2022-05-09 | 2022-08-12 | 西南大学 | Antibacterial polypropylene non-woven fabric and preparation method and application thereof |
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