CN109778216A - A kind of method and device using sun photoinduction water power from hydrogen manufacturing - Google Patents

A kind of method and device using sun photoinduction water power from hydrogen manufacturing Download PDF

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Publication number
CN109778216A
CN109778216A CN201910150707.3A CN201910150707A CN109778216A CN 109778216 A CN109778216 A CN 109778216A CN 201910150707 A CN201910150707 A CN 201910150707A CN 109778216 A CN109778216 A CN 109778216A
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Prior art keywords
discharge
water vapor
vapor bubbles
water
plasma
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CN201910150707.3A
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CN109778216B (en
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黄民双
欧文新
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Beijing Institute of Petrochemical Technology
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Beijing Institute of Petrochemical Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention discloses a kind of method and devices using sun photoinduction water power from hydrogen manufacturing, this method places electrode at the water vapor bubbles both ends of region of discharge first and adds voltage, inhomogeneous field is formed, the individual gas atoms in water vapor bubbles generate fast electronics under electric field action;Make the heavy particle in the water vapor bubbles obtain certain energy under the action of electric field, water vapor bubbles is made to be in the critical state of electric discharge;Then puncture the water vapor bubbles under the induction of sunlight to discharge, form discharge channel and generate plasma, realize that continual and steady electric discharge generates plasma hydrogen preparing.This method and device are easy to operate, low in cost, easy to use and reliable, can effectively improve treatment effeciency, realize that discharge in water persistently generates stable plasma.

Description

A kind of method and device using sun photoinduction water power from hydrogen manufacturing
Technical field
The present invention relates to solar hydrogen making technical field more particularly to a kind of sides using sun photoinduction water power from hydrogen manufacturing Method and device.
Background technique
Currently, solar energy can be converted into Hydrogen Energy, i.e. solar hydrogen making by decomposing water or other approach, it is main at present square Method has: (1) solar energy electrolyzing water hydrogen manufacturing.Water electrolysis hydrogen production is relatively wide and comparative maturity the method for current application, and efficiency is higher (75%-85%), but power consumption is big, only after the cost sharp fall of solar power generation, is just able to achieve extensive electrolysis water Hydrogen manufacturing.(2) solar heat hydrogen production by water decomposition.The method hydrogen production efficiency is high, but needs high power concentrator device that could obtain 3000K or more Temperature, generally not hydrogen manufacturing in this way.(3) solar energy thermochemical cycle for hydrogen production.Thermochemical cycle for hydrogen production method is easily made At environmental pollution.(4) sunlight complex catalysis hydrogen production by water decomposition.Its effect is to absorb luminous energy, generate separation of charge, charge turn It moves and assembles, and by a series of coupling process, finally break water into hydrogen and oxygen.Complex catalysis hydrogen production by water decomposition Shang Bucheng Ripe, research work is continuing.(5) biological photosynthesis hydrogen manufacturing.Due to photosynthesis and the understanding of algae hydrogen release mechanism Not enough, the efficiency of algae hydrogen release is very low, to realize that there are also sizable distances for engineering production hydrogen.(6) solar energy electrochemistry Battery hydrogen production by water decomposition.It realizes hydrogen production by water decomposition, oxygen processed simultaneously under the irradiation of sunlight and obtains electric energy.This experiment knot Fruit causes countries in the world scientist to pay much attention to, but hydrogen production efficiency is very low, and only 0.4%, electrode corrosion-vulnerable, performance is unstable, So real requirement has not yet been reached so far.
In addition, in the prior art further including discharge in water plasma hydrogen preparing, research range includes gas-liquid mixed phase electric discharge Electric discharge hydrogen manufacturing is bubbled in hydrogen manufacturing, liquid and direct discharge in water hydrogen manufacturing, hydrogen feedstock include the liquid such as water, hydro carbons, alcohols, glucose Body substance.Gas-liquid mixed phase electric discharge hydrogen manufacturing is using liquid as ground electrode (also known as water electrode), and plasma causes work in the gas phase Hydrogen is generated for liquid level;Bubbling electric discharge hydrogen manufacturing is at electrode in a liquid in liquid or other positions air-blowing is steeped, plasma Body can be generated relatively easily in bubble, and hydrogen is then generated at bubble;Direct discharge in water is that direct voltage acts in water Electrode.It is lower using gas-liquid mixed phase electric discharge hydrogen manufacturing and the hydrogen output of bubbling electric discharge hydrogen manufacturing in liquid from the point of view of hydrogen manufacturing effect, and energy Consumption is higher, although the percentage concentration for producing hydrogen is higher, from application, there are larger gaps due to hydrogen output is small;Using direct liquid phase Electric discharge has certain advantage on producing Hydrogen Energy consumption in plasma hydrogen preparing, but very high to power requirement.
It can be seen that all can only no matter using typical discharges mode or using differential responses device progress discharge in water To producing, Hydrogen Energy consumes and hydrogen output slightly improves in the unit time.For discharge in water especially can not then eliminate in water due to Liquid phase transmission rate is relatively low, and causes the change dramatically of temperature and concentration between heating region and solution, to lead It causes active group compound in region of discharge and is quenched, this is also the problem of direct discharge in water exists jointly.
Summary of the invention
The object of the present invention is to provide a kind of method and device using sun photoinduction water power from hydrogen manufacturing, this method and dress It sets easy to operate, low in cost, easy to use and reliable, can effectively improve treatment effeciency, realize that discharge in water persistently generates stabilization Plasma.
The purpose of the present invention is what is be achieved through the following technical solutions:
A method of using sun photoinduction water power from hydrogen manufacturing, which comprises
Step 1 places electrode at the water vapor bubbles both ends of region of discharge first and adds voltage, forms inhomogeneous field, water Individual gas atoms in bubble generate fast electronics under electric field action;
Step 2 makes the heavy particle in the water vapor bubbles obtain certain energy under the action of electric field, makes at water vapor bubbles In the critical state of electric discharge;
Then step 3 punctures the water vapor bubbles under the induction of sunlight and discharges, formed discharge channel generate etc. from Daughter realizes that continual and steady electric discharge generates plasma hydrogen preparing.
The water vapor bubbles of the region of discharge are persistently generated by air pump;Or pass through local fast heating in water and gasification shape At.
A kind of device using sun photoinduction water power from hydrogen manufacturing, described device include cathode electrode, plasma discharge Area, air pump, anode electrode and condenser lens, in which:
The plasma discharge region is set between the cathode electrode and anode electrode, and lower part is connected with air pump;
The condenser lens is located at the top of the plasma discharge region;
Water vapor bubbles are constantly constantly generated in the plasma discharge region by the air pump, region of discharge is made to become gas State;Then voltage is recorded on the cathode electrode and anode electrode, forms inhomogeneous field, individual gas in the water vapor bubbles Body atom generates fast electronics under electric field action;Obtain the heavy particle in the water vapor bubbles centainly Energy makes water vapor bubbles be in the critical state of electric discharge;Sunlight is introduced by the condenser lens again, makes the water vapor bubbles too Disruptive discharge under the induction of sunlight forms discharge channel and generates plasma, realizes that continual and steady electric discharge generates plasma Hydrogen manufacturing.
As seen from the above technical solution provided by the invention, the above method and device it is easy to operate, it is low in cost, make It with convenient and reliable, treatment effeciency can be effectively improved, realizes that discharge in water persistently generates stable plasma, be particularly suitable for The changeable hydrogen preparation field of small-scale especially scattered distribution, working condition.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this For the those of ordinary skill in field, without creative efforts, it can also be obtained according to these attached drawings other Attached drawing.
Fig. 1 is the method flow schematic diagram provided in an embodiment of the present invention using sun photoinduction water power from hydrogen manufacturing;
Fig. 2 is the apparatus structure schematic diagram provided in an embodiment of the present invention using sun photoinduction water power from hydrogen manufacturing.
Specific embodiment
With reference to the attached drawing in the embodiment of the present invention, technical solution in the embodiment of the present invention carries out clear, complete Ground description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on this The embodiment of invention, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, belongs to protection scope of the present invention.
The embodiment of the present invention is described in further detail below in conjunction with attached drawing, is implemented as shown in Figure 1 for the present invention The method flow schematic diagram using sun photoinduction water power from hydrogen manufacturing that example provides, which comprises
Step 1 places electrode at the water vapor bubbles both ends of region of discharge first and adds voltage, forms inhomogeneous field, water Individual gas atoms in bubble generate fast electronics (high energy electron) under electric field action;
Step 2 makes the heavy particle in the water vapor bubbles obtain certain energy under the action of electric field, makes at water vapor bubbles In the critical state of electric discharge;
Here, the heavy particle in water vapor bubbles includes molecule, neutral particle.
Then step 3 punctures the water vapor bubbles under the induction of sunlight and discharges, formed discharge channel generate etc. from Daughter realizes that continual and steady electric discharge generates plasma hydrogen preparing.
Specifically, under the continuous action of sunlight, it on the one hand can prevent or delay the compound and suction of electronics and ion Attached, the time-to-live of extending channel, is on the other hand the consumption and electron diffusion losses for supplementing electronics in channel, and realization is held Continue stable electric discharge and generates plasma hydrogen preparing, specifically:
On the one hand, the contradiction that sunlight is directly punctured that liquid water ionization is difficult to realize by the present embodiment is transferred to sun photo-induction In water guide breakdown.When sunlight and aqueous medium, which directly act on, generates plasma, initiating electron is usually by multiphoton ionization It provides, or is provided by the thermal excitation of impurity.Since pure aqueous medium is only possible to provide initiating electron by multiphoton ionization, Energy needed for thus sunlight acts on generation plasma with pure aqueous medium is very high.It, can be abundant under electric field preionization There is provided energy using the sunlight of wide spectrum makes water attack wear ionization, is conducive to make the particle of high level excitation state in water further to inhale Solar energy is received, with the collision between accelerated particle, punctures water and forms plasma channel.
On the other hand, the present embodiment additionally provides a kind of effective ways of electric field preionization water, theoretical according to bubble breakdown, It, can when using gas as region of discharge since gas breakdown electric field ratio liquid is much lower when there is bubble in a liquid Electric field strength needed for preionization is effectively reduced, to make full use of solar energy induction water vapor bubbles breakdown.And the gas in water Bubble mechanism greatly reduces applied voltage duration very long situation.And the method that bubble is generated in liquid, substantially have three Kind: (1) liquid itself gassiness, including the method by additional bubble;(2) electrode emission electric current heats liquid nearby and is allowed to gas Change;(3) the high energy electron impinging fluid molecule in liquid is allowed to ionization and generates gas.When there is bubble in a liquid, due to gas The breakdown field strength of body is more much lower than liquid, and electric field strength is again higher than liquid in bubble, so electricity will occur first for bubble From the high energy electron for ionizing generation ionizes fluid molecule, and generating more gases expands bubble.On this basis, gas The presence of bubble makes the electric field in electric field and bubble in water change, and can change interelectrode field distribution, bubble it Between mutually merge, can greatly reduce breakdown delay time.
Secondly, the bubble channel in liquid water will generate a large amount of initiating electron, and have a large amount of grain under electric field action Son is from ground state transition to upper state, and the particle in water vapor bubbles is easy the amount of absorbing solar energy to obtain more high level excitation state at this time Energy, when this energy is sufficiently large, collision between accelerated particle can be such that atom excitation is ionized.The light of highly excited level atom Ionization and the direct collision of electronics and atom, can further ejected electron.Solar energy can prevent or delay electronics With the compound of ion and absorption, under the lasting focusing illumination of sunlight, so that the electronics being adsorbed on neutral molecule is by again Releasing becomes free electron, with the electron density for maintaining channel to reach certain, so that the time-to-live of extending channel, realizes Continuous discharge generates plasma.
In addition, the water vapor bubbles of above-mentioned region of discharge are persistently generated by air pump;Or it is gentle by local fast heating in water Change and is formed.
Based on above-mentioned method, the embodiment of the invention also provides a kind of dresses using sun photoinduction water power from hydrogen manufacturing It sets, is illustrated in figure 2 the apparatus structure schematic diagram provided in an embodiment of the present invention using sun photoinduction water power from hydrogen manufacturing, it is described Device mainly includes cathode electrode 1, plasma discharge region 2 (also as solar radiation area and Bubble Region), air pump 3, anode Electrode 5 and condenser lens 6, in which:
The plasma discharge region 2 is set between the cathode electrode 1 and anode electrode 5, and lower part is connected with gas Pump 3;
The condenser lens 6 is located at the top of the plasma discharge region 2;
Water vapor bubbles 4 are constantly constantly generated in the plasma discharge region 2 by the air pump 3, become region of discharge For gaseous state, condition is provided for realization continuous discharge;
Then it records voltage on the cathode electrode 1 and anode electrode 5, forms inhomogeneous field, in the water vapor bubbles 4 Individual gas atoms free electron and ion will be formed under electric field action;Make the water vapor bubbles 4 under the action of electric field Interior heavy particle obtains certain energy, and preionization occurs;Sunlight 7 is introduced by the condenser lens 6 again, makes the aqueous vapor 4 disruptive discharges under the induction of sunlight are steeped, discharge channel is formed and generates plasma, realize that continual and steady electric discharge generates Gas ions hydrogen manufacturing.
In the specific implementation, after lighting electric discharge under sun photoinduction on the one hand sunlight is used to supplement plasma channel On the other hand the consumption and electron diffusion losses of middle electronics are used to prevent or delay the compound and desorption of electronics and ion attached, Under the lasting focusing illumination of sunlight, so that the electronics being adsorbed on neutral molecule is released again as free electron, With the electron density for maintaining channel to reach certain, so that the time-to-live of extending channel, realizes that continuous discharge generates plasma Hydrogen manufacturing.
It is worth noting that, the content being not described in detail in the embodiment of the present invention belongs to professional and technical personnel in the field's public affairs The prior art known.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Within the technical scope of the present disclosure, any changes or substitutions that can be easily thought of by anyone skilled in the art, It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims Subject to enclosing.

Claims (3)

1. a kind of method using sun photoinduction water power from hydrogen manufacturing, which is characterized in that the described method includes:
Step 1 places electrode at the water vapor bubbles both ends of region of discharge first and adds voltage, forms inhomogeneous field, water vapor bubbles In individual gas atoms fast electronics is generated under electric field action;
Step 2 makes the heavy particle in the water vapor bubbles obtain certain energy under the action of electric field, is in water vapor bubbles and puts The critical state of electricity;
Then step 3 punctures the water vapor bubbles under the induction of sunlight and discharges, form discharge channel and generate plasma Body realizes that continual and steady electric discharge generates plasma hydrogen preparing.
2. utilizing method of the sun photoinduction water power from hydrogen manufacturing according to claim 1, which is characterized in that the region of discharge Water vapor bubbles persistently generated by air pump;Or it is formed by local fast heating in water and gasification.
3. a kind of device using sun photoinduction water power from hydrogen manufacturing, which is characterized in that described device include cathode electrode, etc. from Daughter region of discharge, air pump, anode electrode and condenser lens, in which:
The plasma discharge region is set between the cathode electrode and anode electrode, and lower part is connected with air pump;
The condenser lens is located at the top of the plasma discharge region;
Water vapor bubbles are constantly constantly generated in the plasma discharge region by the air pump, region of discharge is made to become gaseous state; Then voltage is recorded on the cathode electrode and anode electrode, forms inhomogeneous field, the respective gases in the water vapor bubbles Atom generates fast electronics under electric field action;The heavy particle in the water vapor bubbles is made to obtain certain energy under the action of electric field Amount makes water vapor bubbles be in the critical state of electric discharge;Sunlight is introduced by the condenser lens again, makes the water vapor bubbles in the sun Disruptive discharge under the induction of light forms discharge channel and generates plasma, realizes that continual and steady electric discharge generates plasma system Hydrogen.
CN201910150707.3A 2019-02-28 2019-02-28 Method and device for producing hydrogen by utilizing sunlight induced water ionization Expired - Fee Related CN109778216B (en)

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Cited By (1)

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CN113514741A (en) * 2021-07-21 2021-10-19 北京石油化工学院 Experimental device for liquid electrode partial discharge simulation under direct current excitation

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Publication number Priority date Publication date Assignee Title
CN113514741A (en) * 2021-07-21 2021-10-19 北京石油化工学院 Experimental device for liquid electrode partial discharge simulation under direct current excitation
CN113514741B (en) * 2021-07-21 2023-09-15 北京石油化工学院 Experimental device for liquid electrode partial discharge simulation under direct current excitation

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