CN109775833A - The processing unit and method of the bright water of tar in a kind of carbon black generating process - Google Patents
The processing unit and method of the bright water of tar in a kind of carbon black generating process Download PDFInfo
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- CN109775833A CN109775833A CN201910152822.4A CN201910152822A CN109775833A CN 109775833 A CN109775833 A CN 109775833A CN 201910152822 A CN201910152822 A CN 201910152822A CN 109775833 A CN109775833 A CN 109775833A
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Abstract
The present invention provides the processing units and method of the bright water of tar in a kind of carbon black generating process.The processing unit includes including reacting furnace, tar tank, the bright water reserve tank of tar, the bright water dilution trap of tar and VOCs processing unit, and the reacting furnace includes sequentially connected burning zone, aditus laryngis section, conversion zone, quench zone and gasification stay segment;The bright water reserve tank of tar tank, tar, the bright water dilution trap of tar are sequentially connected;The bright water reserve tank of tar tank, tar, the bright water dilution trap of tar are connect with VOCs processing unit, the quench zone connection of the bright water dilution trap of tar and reacting furnace.The bright water of tar is diluted in the bright water dilution trap of tar, is subsequently used for the quench zone of reacting furnace as a chilled water (chw);The gas to volatilize from tar tank, the bright water reserve tank of tar, the bright water dilution trap of tar is purified by VOCs processing unit.
Description
Technical field
The present invention relates to production of carbon black water treatment technologies, and in particular to the processing of the bright water of tar in a kind of carbon black generating process
Device and method.
Background technique
The primary raw material of China's production of carbon black is coal tar, and coal tar is the primary raw material of coal chemical industry, and ingredient reaches
Up to ten thousand kinds, mainly contain the aromatic hydrocarbons such as benzene,toluene,xylene, naphthalene, anthracene and aromatic series oxygenatedchemicals (such as phenol phenol generalization
Close object);Coal tar is divided into different boilings by the gas chromatographies such as nitrogenous, sulfur heterocyclic ring compound, the method that fractionation can be used
The fraction of point range.Coal tar moisture average out to 2.5~3.5%, water are inorganic matters, and coal tar is organic matter, and the two specific gravity
It is different.Thus can occur to stand dehydration during tar storage, the specific gravity of water is low, water layer in the top of tar tank, top
Water layer is the bright water of tar;The specific gravity of coal tar is high, and oil reservoir is in the lower section of tar tank.The bright water main component of tar is ammonia
Water, there are also a small amount of light oils, the metal ions such as chloride ion, potassium sodium Ca, Mg and Fe, and wherein chloride ion content is 1000mg/l, chloride ion
Caused by penetrating the oxide layer and protective layer and interior metal generation electrochemical reaction of metal surface;Meanwhile chloride ion contains one
Fixed hydration energy is easily attracted to the hole of metal surface, crack is squeezed and replaces oxygen in chlorination layer, insoluble oxidation
Object becomes soluble chloride, so that passivation state surface is become nonreactive surfaces, causes the adverse reaction extremely bad to product;Carbon black is received
Collection, purification, granulation, dry, conveying are all environment of the chlorine ion concentration >=200mg/l at 250 DEG C in closed metal space
It is doubled and redoubled in the corrosiveness to stainless steel, therefore rationally controls the use of the bright water of tar.
The method that the prior art handles the bright water of tar is that bright water is arranged to the bright water of tar from 10 top discharge outlet of tar tank
It is put into bright water receiving tank 11, the ball valve of a DN15 is installed on bright 11 outlet line of water receiving tank, is guaranteed by regulation ball valve bright
Water continuous uniform is discharged into water process ponding well 12, will be mixed after mixing with other water for flowing into ponding well by immersible pump
Water squeezes into water process primary sedimentation tank 13, and water bright so just have passed through the dilution of continuous uniform;Using other hydrolysis acidifications, connect
The water treatment procedures such as touching oxidation enter water process secondary settling tank 14;Subsequently into 600 water pots 15 of production of carbon black, then pass through water pump 16
By treated, water is used for production of carbon black, is mainly used for a chilling, secondary chilling, granulation water.
The prior art mainly using increase receiving tank by the bright water of tar be diluted it is up to standard after use, in the bright water of tar
Gas escape, and chloride ion poor processing effect are had at water process containing ammonium hydroxide, light oil, it is unfriendly to environment;Environmental requirement
Promotion, this processing method certainly will be denied.
Summary of the invention
The problem of being proposed according to background technique, the present invention provide a kind of processing unit of the bright water of tar in carbon black generating process
It is solved with method, next the present invention is done and is further illustrated.
The technical solution adopted by the invention is as follows:
The processing unit of the bright water of tar in a kind of carbon black generating process, including the bright water storage of reacting furnace, tar tank, tar
The bright water dilution trap of slot, tar and VOCs processing unit, the reacting furnace include sequentially connected burning zone, aditus laryngis section, conversion zone,
Quench zone and gasification stay segment;The bright water reserve tank of tar tank, tar, the bright water dilution trap of tar are sequentially connected;Tar tank, coke
The bright water reserve tank of oil, the bright water dilution trap of tar are connect with VOCs processing unit, the chilling of tar bright water dilution trap and reacting furnace
Section connection.The bright water of tar that stratification is formed in tar tank first flows into the bright water reserve tank of tar, then to be delivered to tar bright
Water dilution trap is diluted, and the bright water of the tar after dilution is transported to the quench zone of reacting furnace as a chilled water (chw).Tar tank,
The gas evaporated in the bright water reserve tank of tar, the bright water dilution trap of tar enters VOCs processing unit, by VOCs processing unit
It is discharged after purification.
Further, the top discharge outlet of tar tank connects the bright water reserve tank of tar, the bright water of tar by first pipe
Reserve tank connects the bright water dilution trap of tar by second pipe, and the bright water dilution trap of tar connects the urgency of reacting furnace by third pipeline
Cold section;Second pipe is equipped with the first water pump, and third pipeline is equipped with the second water pump.First water pump is used to store in the bright water of tar
The bright water of the tar of slot is transported to the bright water dilution trap of tar, and the bright water of tar is diluted in the bright water dilution trap of tar;Second water pump is used
In the quench zone that the bright water of tar after dilution is transported to reacting furnace, the bright water of tar after dilution is as a chilled water (chw).
Further, the bright water reserve tank of tar tank, tar, the bright water dilution trap of tar top pass through the 4th pipeline connect
VOCs processing unit.
According to a kind of processing unit of the bright water of tar in carbon black generating process, propose that tar is bright in a kind of carbon black generating process
The processing method of water, includes the following steps:
(1) the bright water of tar is introduced into the bright water reserve tank of tar from the discharge outlet on tar tank top;
(2) the bright water of tar of the bright water reserve tank of tar is pumped into the bright water dilution trap of tar by the first water pump, tar is bright
The bright water of tar in water dilution trap is to 200mg/L or less;
(3) the bright water of the tar after dilution is made by the quench zone that the second water pump is pumped into reacting furnace as a chilled water (chw)
With the usage amount of the bright water of tar after control dilution is in the 20% of chilling water inventory;
(4) gas evaporated in tar tank, the bright water reserve tank of tar, the bright water dilution trap of tar is introduced at VOCs
Device is managed, the VOCs processing unit purification gas is passed through.
In the above-mentioned methods, in the bright water dilution trap of tar, by the way that sewage or the bright water of industry water cut back tar is added extremely
200mg/L or less.
Beneficial effects of the present invention: compared with prior art, apparatus of the present invention structure is simple, and method flow is short;It does not need
By water process process, chloride ion in a quench zone with regard to processed, secondary chilling compared with prior art, the chlorine being granulated in water
Ion is remarkably decreased, and further reduced the corrosiveness of chloride ion, is increased the service life of equipment, is alleviated production of carbon black
The load of middle deironing apparatus improves the quality of carbon black products;Pernicious gas, volatility light oil in the bright water of tar is by VOCs
Processing unit processing, has reached the requirement of environmental protection.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the processing unit of the bright water of tar in the prior art.
Fig. 2 is the structural schematic diagram of the processing unit of the bright water of tar in the present invention.
Fig. 3 is the flow chart of the processing method of the bright water of tar in this method.
In figure: the bright water receiving tank of 10- tar tank, 11- tar, 12- water process ponding well, 13- water process primary sedimentation tank,
14- water process secondary settling tank, 600 water pots of 15- production of carbon black, 16- water pump, 20- burning zone, 21- aditus laryngis section, 22- conversion zone,
23- quench zone, 24- gasification stay segment, 25- tar tank, the bright water reserve tank of 26- tar, the bright water dilution trap of 27- tar, 28- the
One water pump, the second water pump of 29-, 30-VOCs processing unit, 31- first pipe, 32- second pipe, 33- third pipeline, 34-
Four pipelines.
Specific embodiment
Next a specific embodiment of the invention is set forth in conjunction with attached drawing.
Audit For Process carbon black imperfect combustion and is cracked to form by hydrocarbon compound, and the reaction unit of production of carbon black is
Reacting furnace, the reacting furnace are divided into sequentially connected burning zone, aditus laryngis section, conversion zone, quench zone, gasification stay segment;Fuel exists
Burning zone burning be carbon black cracking reaction improve energy, aditus laryngis section be raw material Injection Section, conversion zone be carbon black imperfect combustion and
The region of cracking, quench zone terminate production of carbon black by water and react, and gasification stay segment is that carbon black smoke forms area.
Feedstock oil is formed the elementary particle gelinite of carbon black by carbon black conversion zone, surface have carbon-oxygen surface group,
Carbon-hydrogen surface group, other chemical functional groups, these group parts are more active, can with metal and nonmetal ions binding,
So that carbon black contains metal and nonmetalloid, the performance of carbon black can be made to change the functional group transformation of carbon black in this way
Become, has spreaded the application field of carbon black.
The present embodiment provides a kind of processing units of the bright water of tar in carbon black generating process, and device processing is burnt through this process
The bright water of oil, is used for a chilled water (chw) for the bright water of tar after dilution on a small quantity, make to have the metals such as stainless steel the chlorine of corrosiveness from
Son declines chlorine ion concentration in conjunction with carbon black functional group, prevents the corrosion of equipment box etc., guarantees carbon black products matter
Amount.
The processing unit of the bright water of tar in a kind of carbon black generating process, including the bright water storage of reacting furnace, tar tank 25, tar
Deposit the bright water dilution trap 27 of slot 26, tar, VOCs processing unit 30, wherein reacting furnace includes sequentially connected burning zone 20, aditus laryngis
Section 21, conversion zone 22, quench zone 23 and gasification stay segment 24.The discharge outlet of 25 top of tar tank passes through first pipe 31 and coke
The bright water reserve tank 26 of oil connects, and the bright water reserve tank 26 of tar is connect by second pipe 32 with the bright water dilution trap 27 of tar, tar
Bright water dilution trap 27 is connected to the quench zone 23 of reacting furnace by third pipeline 33;Wherein, first is equipped on second pipe 32
Water pump 28 is equipped with the second water pump 29 on third pipeline 33.The bright water reserve tank 26 of tar oil storage tank 25, tar, the bright water of tar are dilute
The top for releasing slot 27 passes through the 4th pipeline 34 and is connected with VOCs processing unit 30.
Method and step using the processing unit processing bright water of tar is as follows:
(1) the bright water of tar is discharged into the bright water reserve tank 26 of tar from the discharge outlet on 25 top of tar oil storage tank;
(2) the bright water of tar of the bright water reserve tank 26 of tar is pumped into the bright water dilution trap 27 of tar by the first water pump 28,
Sewage or industry water are added in the bright water dilution trap 27 of tar, the bright water of tar is made to be diluted to 200mg/l or less;
(3) quench zone 23 that the bright water of tar after diluting in the bright water dilution trap 27 of tar is sent into reacting furnace uses, and dilutes
The bright water of tar afterwards is as a chilled water (chw), and the usage amount of the bright water of tar after control dilution is in the 20% of chilling water inventory;
(4) gas evaporated in tar tank 25, the bright water reserve tank 26 of tar, the bright water dilution trap 27 of tar is introduced
VOCs processing unit 30 purifies the gas by VOCs processing unit 30.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (5)
1. the processing unit of the bright water of tar in a kind of carbon black generating process, including the bright water storage of reacting furnace, tar tank, tar
The bright water dilution trap of slot, tar and VOCs processing unit, the reacting furnace include sequentially connected burning zone, aditus laryngis section, conversion zone,
Quench zone and gasification stay segment;The bright water reserve tank of tar tank, tar, the bright water dilution trap of tar are sequentially connected;Tar tank, coke
The bright water reserve tank of oil, the bright water dilution trap of tar are connect with VOCs processing unit, the chilling of tar bright water dilution trap and reacting furnace
Section connection.
2. the processing unit of the bright water of tar in carbon black generating process according to claim 1, it is characterised in that: tar tank
Top discharge outlet the bright water reserve tank of tar is connected by first pipe, the bright water reserve tank of tar connects tar by second pipe
Bright water dilution trap, the bright water dilution trap of tar connect the quench zone of reacting furnace by third pipeline;Second pipe is equipped with the first water
Pump, third pipeline are equipped with the second water pump.
3. the processing unit of the bright water of tar in carbon black generating process according to claim 1, it is characterised in that: tar storage
The bright water reserve tank of slot, tar, the bright water dilution trap of tar top by the 4th pipeline connect VOCs processing unit.
4. the processing method of the bright water of tar, includes the following steps: in a kind of carbon black generating process
(1) the bright water of tar is introduced into the bright water reserve tank of tar from the discharge outlet on tar tank top;
(2) the bright water of tar of the bright water reserve tank of tar is pumped into the bright water dilution trap of tar by the first water pump, the bright water of tar is dilute
The bright water of tar in slot is released to 200mg/L or less;
(3) the bright water of the tar after dilution is used by the quench zone that the second water pump is pumped into reacting furnace as a chilled water (chw), is controlled
The usage amount of the bright water of tar after system dilution is in the 20% of chilling water inventory;
(4) gas evaporated in tar tank, the bright water reserve tank of tar, the bright water dilution trap of tar is introduced into VOCs processing dress
It sets, passes through the VOCs processing unit purification gas.
5. according to the method described in claim 4, it is characterized by: passing through addition sewage or work in the bright water dilution trap of tar
The bright water of industry water cut back tar is to 200mg/L or less.
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CN201855643U (en) * | 2010-11-09 | 2011-06-08 | 萍乡市飞虎炭黑有限公司 | Apparatus and device for waste gas treatment |
CN201971774U (en) * | 2011-01-06 | 2011-09-14 | 萍乡市飞虎炭黑有限公司 | Waste water processing device |
CN202131271U (en) * | 2011-05-31 | 2012-02-01 | 中橡集团炭黑工业研究设计院 | Carbon black and oil processing co-production equipment |
CN104672953A (en) * | 2015-02-10 | 2015-06-03 | 安徽黑钰颜料新材料有限公司 | Pigment carbon black reacting furnace with super-long remaining section and pigment carbon black produced by the pigment carbon black reacting furnace |
CN204757726U (en) * | 2015-05-26 | 2015-11-11 | 邯郸黑猫炭黑有限责任公司 | Carbon black production steam recycle's device |
CN205412334U (en) * | 2016-02-02 | 2016-08-03 | 朝阳黑猫伍兴岐炭黑有限责任公司 | Be applied to carbon black production's raw oil oil -water separator |
CN208449017U (en) * | 2018-06-15 | 2019-02-01 | 朝阳黑猫伍兴岐炭黑有限责任公司 | A kind of VOC recycling reprocessing device |
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2019
- 2019-02-28 CN CN201910152822.4A patent/CN109775833A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201855643U (en) * | 2010-11-09 | 2011-06-08 | 萍乡市飞虎炭黑有限公司 | Apparatus and device for waste gas treatment |
CN201971774U (en) * | 2011-01-06 | 2011-09-14 | 萍乡市飞虎炭黑有限公司 | Waste water processing device |
CN202131271U (en) * | 2011-05-31 | 2012-02-01 | 中橡集团炭黑工业研究设计院 | Carbon black and oil processing co-production equipment |
CN104672953A (en) * | 2015-02-10 | 2015-06-03 | 安徽黑钰颜料新材料有限公司 | Pigment carbon black reacting furnace with super-long remaining section and pigment carbon black produced by the pigment carbon black reacting furnace |
CN204757726U (en) * | 2015-05-26 | 2015-11-11 | 邯郸黑猫炭黑有限责任公司 | Carbon black production steam recycle's device |
CN205412334U (en) * | 2016-02-02 | 2016-08-03 | 朝阳黑猫伍兴岐炭黑有限责任公司 | Be applied to carbon black production's raw oil oil -water separator |
CN208449017U (en) * | 2018-06-15 | 2019-02-01 | 朝阳黑猫伍兴岐炭黑有限责任公司 | A kind of VOC recycling reprocessing device |
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