CN109762955A - A kind of dedicated nodulizer of wind power plant casting - Google Patents

A kind of dedicated nodulizer of wind power plant casting Download PDF

Info

Publication number
CN109762955A
CN109762955A CN201910141354.0A CN201910141354A CN109762955A CN 109762955 A CN109762955 A CN 109762955A CN 201910141354 A CN201910141354 A CN 201910141354A CN 109762955 A CN109762955 A CN 109762955A
Authority
CN
China
Prior art keywords
parts
nodulizer
power plant
wind power
lanthanum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910141354.0A
Other languages
Chinese (zh)
Inventor
陈明
何赛洲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU YAFENG ALLOY MATERIAL CO Ltd
Original Assignee
JIANGSU YAFENG ALLOY MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU YAFENG ALLOY MATERIAL CO Ltd filed Critical JIANGSU YAFENG ALLOY MATERIAL CO Ltd
Priority to CN201910141354.0A priority Critical patent/CN109762955A/en
Publication of CN109762955A publication Critical patent/CN109762955A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses a kind of dedicated nodulizers of wind power plant casting, belong to cast casting preparation field, and for nodulizer according to mass parts meter, specific ingredient the following is 42-50 parts of silicon;5.2-6.8 parts of magnesium;0.4-1.2 parts of aluminium;0.8-3 parts of calcium;15-30 parts of iron;0.3-2.0 parts of norium;The norium includes yttrium, cerium, lanthanum, neodymium;The yttrium, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: lanthanum: neodymium 1:1:1:0.1;Rare earth element in the present invention is used cooperatively the element of silicon, magnesium, aluminium, calcium, iron etc., the phosphorous sulfur content of wind power plant casting of preparation is lower, yttrium, cerium, lanthanum, the cooperation of neodymium rare earth element are higher with the affinity of sulphur, therefore phosphorous sulfur content is to 0.01% or less, it can guarantee the decline ability of anti-nodularization, since silicone content is lower, and it can guarantee high impact at low temperature.

Description

A kind of dedicated nodulizer of wind power plant casting
Technical field
The invention belongs to cast casting preparation field, in particular to a kind of dedicated nodulizers of wind power plant casting.
Background technique
With the development of new energy, wind-power electricity generation enters the visual field of industry masses, wind power plant therein already The requirement of casting is even more very high, and the preparation of the casting is typically required the spheroidal graphite cast-iron of high gauge, because of wind-power electricity generation casting Itself need extremely high Anti-pull-press, elongation and extremely high rigidity.In addition, wind-power electricity generation casting is due in production application Series of factors, therefore the requirement for nodulizer used in wind-power electricity generation casting is also relatively high, generally requires such Nodulizer must satisfy certain anti-decaying spheroidisation ability, and Oxygen potential is high, and above-mentioned is all the nodulizer that wind power plant uses The general main idea to be met
But even if China has the technique of many wind power plant casting, the nodulizer used also has to a certain extent Standby certain anti-decaying spheroidisation ability, Oxygen potential, but with the development of casting manufacturing process, siliceous phosphorous sulfur-bearing in nodulizer While amount is adjusted to minimumization, the dedicated nodulizer of wind power plant casting still keeps the decline ability of anti-nodularization, low The certain those skilled in the art's strategic point of high impact technical problem to be solved under temperature.
Summary of the invention
Aiming at the problems existing in the prior art, the invention discloses a kind of dedicated nodulizer of wind power plant casting, By the application of norium, the phosphorous sulfur content in nodulizer is enabled to be adjusted to for the content of heavy rare earth element High impact that is minimum, being also equipped under low temperature, solves the problems, such as of the existing technology.
The present invention is implemented as follows:
A kind of dedicated nodulizer of wind power plant casting, which is characterized in that the nodulizer according to mass parts meter, specifically at Divide as follows:
42-50 parts of silicon;5.2-6.8 parts of magnesium;0.4-1.2 parts of aluminium;0.8-3 parts of calcium;15-30 parts of iron;Norium 0.3-2.0 Part;
The norium includes yttrium, cerium, lanthanum, neodymium;The yttrium, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: Lanthanum: neodymium=1:1:1:0.1.
Further, the inovulant of baric is also mixed in the nodulizer.
Further, the mass parts accounting of the inovulant is 0.2 ~ 0.3% of iron in nodulizer, the inovulant Granularity be 0.5 ± 0.1mm.
Further, sulfur-bearing, phosphorus content when the nodulizer handles magnesium iron are respectively less than 0.01%, lower sulfur-bearing, phosphorous Amount can guarantee the high impact of casting at low temperature.
Further, the nodulizer further includes 0.07-0.2 parts of manganese according to mass parts meter.
Further, the silicon components are nanometer silicon carbide and micrometer silicon carbide silicon;The nanometer silicon carbide and micron The mass parts ratio of silicon carbide is 2:1, and nanometer silicon carbide and micrometer silicon carbide silicon are due to large specific surface area, with spheroidal graphite cast-iron Lattice Matching rate is high, can significantly improve the mechanical performance of wind power plant casting.
The beneficial effect of the present invention and the prior art with:
1) norium in the present invention includes yttrium, cerium, lanthanum, neodymium, and the use of the rare earth element of yttrium base therein can drop The amount of magnesium needed for low ball agent can avoid decaying spheroidisation to the full extent;
2) due to can more or less there is the phenomenon that reversion during the preparation of wind power plant casting, element sulphur can be led The decline ability of nodularization is caused, but the mass parts accounting of yttrium in the present invention, cerium, lanthanum, neodymium is yttrium: cerium: lanthanum: neodymium 1:1:1:0.1 Be used in mixed way, it is ensured that the phenomenon that the reversion of minimum flow, to ensure that nodulizer of the invention still keeps anti-nodularization Decline ability;
3) element of the yttrium in the present invention, cerium, lanthanum, neodymium rare earth element with the use of silicon, magnesium, aluminium, calcium, iron etc., the wind-force of preparation The phosphorous sulfur content of generating equipment casting is lower, and yttrium, cerium, lanthanum, the cooperation of neodymium rare earth element are higher with the affinity of sulphur, therefore phosphorous contain Sulfur content since silicone content is lower, and can guarantee in low temperature to 0.01% hereinafter, therefore can guarantee the decline ability of anti-nodularization Under high impact.
Specific embodiment
It is clear to keep the purpose of the present invention, technical solution and effect clearer, example is exemplified below to the present invention into one Step is described in detail.It should be understood that specific implementation described herein is not intended to limit the present invention only to explain the present invention.
Embodiment 1
Step 1: setting smelting temperature in 0.5T middle frequency furnace as 1260-1400 DEG C, being added 42 parts of silicon;5.2 parts of magnesium;Aluminium 0.4 part;0.8 part of calcium;15 parts of iron;0.3 part of norium;Yttrium therein, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: Lanthanum: neodymium=1:1:1:0.1 obtains the molten alloy of form of spherical particles.
Step 2: being added the inovulant of baric in the molten alloy of form of spherical particles, and melting to above-mentioned raw materials is uniformly melted Melt in the graininess alloy spherical in shape prepared to step 1, the mass parts accounting of the inovulant is iron in nodulizer 0.2 ~ 0.3%, the granularity of the inovulant is 0.5 ± 0.1mm;
Step 3: being added 0.07 part of mass parts of manganese in the molten homogeneous liquid of step 2 preparation, and 1260-1400 DEG C of heating is molten Refining, is smelted into uniform alloy raw material;
Step 4: alloy raw material uniform in step 3 is cooling in liquid nitrogen, it is cooling after i.e. preparation complete, after according to technique system Standby wind power plant casting.
Embodiment 2
Step 1: setting smelting temperature in 0.5T middle frequency furnace as 1260-1400 DEG C, being added 50 parts of silicon;6.8 parts of magnesium;Aluminium 1.2 part;3 parts of calcium;30 parts of iron;2.0 parts of norium;Yttrium therein, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: lanthanum: Neodymium=1:1:1:0.1 obtains the molten alloy of form of spherical particles.
Step 2: being added the inovulant of baric in the molten alloy of form of spherical particles, and melting to above-mentioned raw materials is uniformly melted Melt in the graininess alloy spherical in shape prepared to step 1, the mass parts accounting of the inovulant is iron in nodulizer 0.2 ~ 0.3%, the granularity of the inovulant is 0.5 ± 0.1mm;
Step 3: the manganese of 0.2 part of mass parts of addition in the molten homogeneous liquid of step 2 preparation, 1260-1400 DEG C of heating melting, It is smelted into uniform alloy raw material;
Step 4: alloy raw material uniform in step 3 is cooling in liquid nitrogen, it is cooling after i.e. preparation complete, after according to technique system Standby wind power plant casting.
Embodiment 3
Step 1: setting smelting temperature in 0.5T middle frequency furnace as 1260-1400 DEG C, being added 47 parts of silicon;5.8 parts of magnesium;Aluminium 0.9 part;0.8 part of calcium;20 parts of iron;0.3 part of norium;Yttrium therein, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: Lanthanum: neodymium=1:1:1:0.1 obtains the molten alloy of form of spherical particles.
Step 2: being added the inovulant of baric in the molten alloy of form of spherical particles, and melting to above-mentioned raw materials is uniformly melted Melt in the graininess alloy spherical in shape prepared to step 1, the mass parts accounting of the inovulant is iron in nodulizer 0.2 ~ 0.3%, the granularity of the inovulant is 0.5 ± 0.1mm;
Step 3: being added the manganese that mass parts are 0.1 part in the molten homogeneous liquid of step 2 preparation, and 1260-1400 DEG C of heating is molten Refining, is smelted into uniform alloy raw material;
Step 4: alloy raw material uniform in step 3 is cooling in liquid nitrogen, it is cooling after i.e. preparation complete, after according to technique system Standby wind power plant casting.
Embodiment 4
Step 1: setting smelting temperature in 0.5T middle frequency furnace as 1260-1400 DEG C, being added 45 parts of silicon;6.0 parts of magnesium;Aluminium 1.2 part;3 parts of calcium;19 parts of iron;1.0 parts of norium;Yttrium therein, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: lanthanum: Neodymium=1:1:1:0.1 obtains the molten alloy of form of spherical particles.
Step 2: being added the inovulant of baric in the molten alloy of form of spherical particles, and melting to above-mentioned raw materials is uniformly melted Melt in the graininess alloy spherical in shape prepared to step 1, the mass parts accounting of the inovulant is iron in nodulizer 0.2 ~ 0.3%, the granularity of the inovulant is 0.5 ± 0.1mm;
Step 3: being added 0.12 part of mass parts of manganese in the molten homogeneous liquid of step 2 preparation, and 1260-1400 DEG C of heating is molten Refining, is smelted into uniform alloy raw material;
Step 4: alloy raw material uniform in step 3 is cooling in liquid nitrogen, it is cooling after i.e. preparation complete, after according to technique system Standby wind power plant casting.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as of the invention Protection scope.

Claims (6)

1. a kind of dedicated nodulizer of wind power plant casting, which is characterized in that the nodulizer is according to mass parts meter, specifically Ingredient is as follows:
42-50 parts of silicon;5.2-6.8 parts of magnesium;0.4-1.2 parts of aluminium;0.8-3 parts of calcium;15-30 parts of iron;Norium 0.3-2.0 Part;
The norium includes yttrium, cerium, lanthanum, neodymium;The yttrium, cerium, lanthanum, neodymium mass parts accounting be yttrium: cerium: Lanthanum: neodymium=1:1:1:0.1.
2. a kind of dedicated nodulizer of wind power plant casting according to claim 1, which is characterized in that the nodularization The inovulant of baric is also mixed in agent.
3. a kind of dedicated nodulizer of wind power plant casting according to claim 2, which is characterized in that described breeds The mass parts accounting of agent is 0.2 ~ 0.3% of iron in nodulizer, and the granularity of the inovulant is 0.5 ± 0.1mm.
4. a kind of dedicated nodulizer of wind power plant casting according to claim 1, which is characterized in that the nodularization Sulfur-bearing, phosphorus content when agent handles magnesium iron are respectively less than 0.01%.
5. a kind of dedicated nodulizer of wind power plant casting according to claim 1, which is characterized in that the nodularization Agent further includes 0.07-0.2 parts of manganese according to mass parts meter.
6. a kind of dedicated nodulizer of wind power plant casting according to claim 1, which is characterized in that the silicon group It is divided into nanometer silicon carbide and micrometer silicon carbide silicon;The mass parts ratio of the nanometer silicon carbide and micrometer silicon carbide silicon is 2:1.
CN201910141354.0A 2019-02-26 2019-02-26 A kind of dedicated nodulizer of wind power plant casting Pending CN109762955A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910141354.0A CN109762955A (en) 2019-02-26 2019-02-26 A kind of dedicated nodulizer of wind power plant casting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910141354.0A CN109762955A (en) 2019-02-26 2019-02-26 A kind of dedicated nodulizer of wind power plant casting

Publications (1)

Publication Number Publication Date
CN109762955A true CN109762955A (en) 2019-05-17

Family

ID=66457164

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910141354.0A Pending CN109762955A (en) 2019-02-26 2019-02-26 A kind of dedicated nodulizer of wind power plant casting

Country Status (1)

Country Link
CN (1) CN109762955A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484675A (en) * 2019-08-20 2019-11-22 新沂永新机械配件有限公司 A kind of rare earth Mg-Si nodularizer and preparation method thereof for heavy section ductile iron
CN113136473A (en) * 2021-04-01 2021-07-20 江苏亚峰合金材料有限公司 Preparation method of novel low-silicon low-magnesium nodulizer
CN116287527A (en) * 2023-03-27 2023-06-23 江苏亚峰合金材料有限公司 Barium-containing high-magnesium composite nodulizer and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070134149A1 (en) * 2005-12-07 2007-06-14 Asahi Tec Corporation Spheroidizing agent of graphite
CN101787403A (en) * 2010-01-29 2010-07-28 河北工业大学 Short process production technique for preparing casting of wind power generation equipment
CN101906566A (en) * 2010-08-11 2010-12-08 江苏吉鑫风能科技股份有限公司 Preparation method of low temperature spherical iron casting for 3 MW wind power wheel hub as well as additive, nodulizing agent, inoculant and instantaneous inoculant for founding
CN102102136A (en) * 2011-03-07 2011-06-22 衡阳中钢衡重铸锻有限公司 As-cast high-toughness ferrite nodular iron and production method thereof
CN102615255A (en) * 2012-03-26 2012-08-01 江苏亚峰合金材料有限公司 Special nodulizer for low-temperature impact resistant and high-ductility nodular cast iron and method for preparing special nodulizer
CN105401049A (en) * 2015-10-29 2016-03-16 宁波康发铸造有限公司 Spheroidizing agent and preparation method and application thereof in spheroidal graphite cast iron smelting
EP3238854A1 (en) * 2016-04-29 2017-11-01 General Electric Company A ductile iron and process of forming a ductile iron component
CN108251589A (en) * 2018-01-31 2018-07-06 重庆卡森科技有限公司 A kind of novel nothing breeds nodulizer

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070134149A1 (en) * 2005-12-07 2007-06-14 Asahi Tec Corporation Spheroidizing agent of graphite
CN101787403A (en) * 2010-01-29 2010-07-28 河北工业大学 Short process production technique for preparing casting of wind power generation equipment
CN101906566A (en) * 2010-08-11 2010-12-08 江苏吉鑫风能科技股份有限公司 Preparation method of low temperature spherical iron casting for 3 MW wind power wheel hub as well as additive, nodulizing agent, inoculant and instantaneous inoculant for founding
CN102102136A (en) * 2011-03-07 2011-06-22 衡阳中钢衡重铸锻有限公司 As-cast high-toughness ferrite nodular iron and production method thereof
CN102615255A (en) * 2012-03-26 2012-08-01 江苏亚峰合金材料有限公司 Special nodulizer for low-temperature impact resistant and high-ductility nodular cast iron and method for preparing special nodulizer
CN105401049A (en) * 2015-10-29 2016-03-16 宁波康发铸造有限公司 Spheroidizing agent and preparation method and application thereof in spheroidal graphite cast iron smelting
EP3238854A1 (en) * 2016-04-29 2017-11-01 General Electric Company A ductile iron and process of forming a ductile iron component
CN108251589A (en) * 2018-01-31 2018-07-06 重庆卡森科技有限公司 A kind of novel nothing breeds nodulizer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李隆盛主编: "《铸造合金及熔炼》", 30 November 1989, 机械工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484675A (en) * 2019-08-20 2019-11-22 新沂永新机械配件有限公司 A kind of rare earth Mg-Si nodularizer and preparation method thereof for heavy section ductile iron
CN113136473A (en) * 2021-04-01 2021-07-20 江苏亚峰合金材料有限公司 Preparation method of novel low-silicon low-magnesium nodulizer
CN116287527A (en) * 2023-03-27 2023-06-23 江苏亚峰合金材料有限公司 Barium-containing high-magnesium composite nodulizer and preparation method thereof

Similar Documents

Publication Publication Date Title
CN109762955A (en) A kind of dedicated nodulizer of wind power plant casting
CN102094147B (en) Control method for producing low temperature spheroidal graphite cast iron
CN101787403B (en) Short process production technique for preparing casting of wind power generation equipment
CN107903047B (en) Iron runner castable containing more than 70% of high-alumina aggregate
CN101906566B (en) Preparation method of low temperature spherical iron casting for 3 MW wind power wheel hub as well as additive, nodulizing agent, inoculant and instantaneous inoculant for founding
CN107058861A (en) A kind of preparation method of ductile cast iron material, the composition comprising it and wind power casting and wind power casting
CN105886883B (en) Inovulant and preparation method thereof and the application in spheroidal graphite cast-iron
CN112408957B (en) Iron runner castable and preparation method thereof
CN109252087A (en) The alloying technology that Ce inhibits TiN complex inclusion to be formed is added in bearing steel
WO2018166248A1 (en) Nodulizing and inoculation process for nodular cast iron
CN102703802A (en) High-strength high-toughness low-temperature-resistant ferritic nodular cast iron
CN106011572B (en) A kind of high roll forming ability magnesium-rare earth alloy and preparation method thereof
WO2018166247A1 (en) Development method for high-strength and high-toughness nodular cast iron for wind electricity
CN102560231A (en) Ferrite nodular cast iron liquid for wind-power castings and preparation method thereof
CN106098279A (en) A kind of robot Nd-Fe-B permanent magnet material and preparation method thereof
CN102373364A (en) Wind-power equipment casting and manufacturing method thereof
CN104862448A (en) Preparation method applying nano molten iron modificator to high-chrome cast ball
CN106319129A (en) Short-process manufacturing method for producing casting for wind power generation equipment
CN103350184A (en) Metal mold casting chromium white cast iron grinding ball used inoculation coating and preparation method thereof
CN101602611A (en) The composition of raw materials of ladle heat insulation cover and the preparation method of ladle heat insulation cover
CN105296856B (en) Extra-high voltage Special electric tower high-strength steel
CN207418779U (en) A kind of pre-melted slag casting device
CN111139364A (en) Manufacturing method of over 40 tons of 9Ni large steel ingots
CN113878124B (en) Water-gas combined atomization preparation method of iron-silicon-chromium-gallium-indium-nitrogen alloy soft magnetic powder
CN1831164A (en) Method for producing high titanium iron contg. low oxygen and low nitrogen

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190517