CN109761193A - A kind of preparing hydrogen by reforming methanol reactor - Google Patents
A kind of preparing hydrogen by reforming methanol reactor Download PDFInfo
- Publication number
- CN109761193A CN109761193A CN201910212857.2A CN201910212857A CN109761193A CN 109761193 A CN109761193 A CN 109761193A CN 201910212857 A CN201910212857 A CN 201910212857A CN 109761193 A CN109761193 A CN 109761193A
- Authority
- CN
- China
- Prior art keywords
- plate
- cavity
- reformer
- layer
- evaporator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 178
- 239000001257 hydrogen Substances 0.000 title claims abstract description 80
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 80
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 238000002407 reforming Methods 0.000 title claims abstract description 44
- 239000012530 fluid Substances 0.000 claims abstract description 129
- 239000007789 gas Substances 0.000 claims abstract description 47
- 239000003054 catalyst Substances 0.000 claims abstract description 32
- 239000007788 liquid Substances 0.000 claims abstract description 21
- 238000000746 purification Methods 0.000 claims abstract description 21
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000008246 gaseous mixture Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000001833 catalytic reforming Methods 0.000 claims abstract description 6
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 3
- 238000004080 punching Methods 0.000 claims description 24
- 229910003460 diamond Inorganic materials 0.000 claims description 20
- 239000010432 diamond Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 16
- 238000001704 evaporation Methods 0.000 claims description 13
- 230000008020 evaporation Effects 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 238000007789 sealing Methods 0.000 claims description 8
- 238000003860 storage Methods 0.000 claims description 5
- 238000010025 steaming Methods 0.000 claims description 4
- 229910007470 ZnO—Al2O3 Inorganic materials 0.000 claims description 3
- 235000003283 Pachira macrocarpa Nutrition 0.000 claims 1
- 241001083492 Trapa Species 0.000 claims 1
- 235000014364 Trapa natans Nutrition 0.000 claims 1
- 239000012527 feed solution Substances 0.000 claims 1
- 235000009165 saligot Nutrition 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 238000006057 reforming reaction Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Landscapes
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Abstract
The invention discloses a kind of preparing hydrogen by reforming methanol reactors, including evaporator, reformer and purification reservoir, evaporator to be used to heat methanol water mixed liquid raw material and vaporize, and the methanol-water gaseous mixture of formation, which enters, carries out catalytic reforming reaction in reformer；Purification reservoir is used to the hydrogen-rich product obtained by reformer carrying out hydrogen purification and hydrogen stores.Reformer is internally provided with the hot fluid cavity of several layers concatenated cold fluid cavity and several layers parallel connection, reforming catalyst is provided in every layer of cold fluid cavity, methanol-water gaseous mixture enters in the cold fluid cavity of reformer, hot exhaust gas is even into each layer hot fluid cavity of reformer, the cold fluid cavity and hot fluid cavity are the structure of stratiform cavity, and cold fluid cavity and hot fluid cavity are arranged alternately in reformer interior-layer layer.Reformer and evaporator of the invention recycles the heat of hot exhaust gas by the way of exchanging heat layer by layer, greatly improves the utilization rate to hot exhaust gas heat.
Description
Technical field
The present invention relates to a kind of hydrogen-manufacturing reactors, more particularly, to a kind of preparing hydrogen by reforming methanol reactor.
Background technique
Studies have shown that the energy that motor vehicle is discharged in the form of waste heat accounts for the 55%-80% of fuel gross energy, therefore tail gas
Heat recovery is for improving fuel utilization rate and energy saving extremely important.In face of urgent energy crisis, hydrogen fuel electricity
Pond automobile possesses very wide prospect.Existing fuel cell car, the mode for generalling use high-pressure hydrogen storing deliver hydrogen
Onboard, it is not only filled with difficulty, carrying a large amount of hydrogen, there is also the hidden danger exploded in leakage and accident.This method of live hydrogen manufacturing
Solves the above problem very well.The method that Comprehensive Correlation obtains hydrogen, preparing hydrogen by reforming methanol have advantageous advantage.Methanol weight
Whole hydrogen production process is methanol under the conditions of 250 DEG C -300 DEG C, 1-5Mpa, water alcohol ratio 1-5, in catalyst Cu/Al2O3Lower generation
Multi-component complex reaction, specifically includes that
Steam reforming reaction:
Methanol decomposition reaction:
Steam reverse shift reaction:
The mode of preparing hydrogen by reforming methanol generally speaking has following advantage: from the perspective of reactant: first, methanol comes
Source approach is extensive, can not only process and obtain from traditional fossil energy, but also can obtain in the biomass such as animals and plants.Second, with it
He compares hydrogen production process, and the hydrogen generation efficiency of preparing hydrogen by reforming methanol is higher, and impurity is also less.It is talked from hydrogen production process angle: methanol
Reforming hydrogen producing process is mature, easy to operate, reaction safety.From the point of view of equipment angle: preparing hydrogen by reforming methanol reaction temperature is low, required
Pressure is not also high, therefore to the of less demanding of reaction unit, also safer as using on automobile.
The H that reforming reactor generates2With a small amount of CO2The hydrogen of high-purity is obtained through palladium UF membrane.In the mistake of entire reforming reaction
Cheng Zhong, the first alcohol and water as reactant must all keep gaseous state.In addition, Methanol cluster hydrogen manufacturing is strong endothermic reaction,
Outside must provide lasting heat supply.The energy that vehicle exhaust is discharged in the form of waste heat accounts for the 55%-80% of gross energy, while it is flowed
Amount is sufficient, and temperature is up to 500 DEG C -700 DEG C, is that the reaction heat supply fully meets reaction condition using residual heat of tail gas of automobile；Simultaneously
Reaction generates clean hydrogen, can be sent directly into combustion in IC engine, not only improve efficiency of combustion but also reduced pollutant emission.Mesh
Before, preparing hydrogen by reforming methanol reactor largely by the way of external heating, not only makes apparatus structure complicated, also wastes
Mass energy.
Summary of the invention
For above-mentioned technical problem of the existing technology, the purpose of the present invention is to provide a kind of preparing hydrogen by reforming methanol is anti-
Answer device.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that including be arranged from bottom to top evaporator, reform
Device and purification reservoir, the evaporator, reformer and purification reservoir become an entirety by vertical guide rod series connection
Structure；Be provided with thermal fluid inlet and cold fluid outlet at the top of the reformer, reformer bottom be provided with hot fluid outlet ports and
Cold fluid inlet；The reformer is internally provided with the hot-fluid body cavity of several layers concatenated cold fluid cavity and several layers parallel connection
Road is provided with reforming catalyst in every layer of cold fluid cavity, and the entrance of first layer cold fluid cavity is connected to cold fluid inlet,
The outlet of final layer cold fluid cavity is connected to cold fluid outlet；The entrance of every layer of hot fluid cavity connects with thermal fluid inlet
Logical, hot exhaust gas is entered in each layer hot fluid cavity of reformer by thermal fluid inlet, the outlet of every layer of hot fluid cavity with heat
Fluid outlet connection；The cold fluid cavity and hot fluid cavity are the structure of stratiform cavity, and the cold fluid cavity and
Hot fluid cavity is arranged alternately in reformer interior-layer layer；The evaporator is used to heat methanol water mixed liquid raw material and vaporize, shape
At methanol-water gaseous mixture entered by cold fluid inlet and carry out catalytic reforming reaction in the cold fluid cavity of reformer, generate hydrogen-rich
Product；The purification reservoir is used to the hydrogen-rich product obtained by reformer carrying out hydrogen purification and hydrogen stores.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that the reformer is by the first plate, the second plate
And be set to the rubber sheet gasket being sealed between the first plate and the second plate and be successively formed by stacking, first plate,
The stratiform cavity of sealing is enclosed between rubber sheet gasket and the second plate；First plate front, rubber sheet gasket and second
The stratiform cavity formed between the plate back side is the cold fluid cavity, the first plate back side, rubber sheet gasket and the second plate
The stratiform cavity formed between front is the hot fluid cavity；It further include for making each layer cold fluid cavity on the reformer
The reformation runner being sequentially communicated, the entrance for being connected to each layer hot fluid cavity first reform sprue and for being connected to
The second of the outlet of each layer hot fluid cavity reforms sprue.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that the pair of horns of the first plate is symmetrically arranged with a pair
First cold punching hole and another diagonally it is respectively arranged with that the first heat rushes in hole and the first heat goes out hole, second plate corresponding one
It is diagonally symmetrically arranged with a pair of second cold punching hole and corresponding another second heat that is diagonally respectively arranged with rushes in hole and the second heat punching
Portal；When first plate and the second plate successively overlap arrangement, first cold punching hole and the alignment of the second cold punching hole are simultaneously
It is enclosed the reformation runner for the methanol-water gaseous mixture that circulates by rubber sheet gasket, first heat rushes in hole and the second heat
It rushes in hole and is aligned and passes through rubber sheet gasket is enclosed for flowing into hot exhaust gas first and reform sprue, first heat goes out
Hole and the second heat go out hole be aligned and pass through rubber sheet gasket be enclosed for flowing out hot exhaust gas second reform sprue.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that further include catalyst support plate, the reformation is urged
Agent is CuO-ZnO-Al2O3Compound, the reforming catalyst are cylinder block structure and are in a row uniformly fixed on catalyst
In support plate；First plate front is provided with the board slot to match with catalyst support plate shape, catalyst support plate cooperation
It is placed in board slot.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that the two sides of the first plate is provided with the first diamond shape
Slot, the first cold punching of a pair hole of the first plate is symmetrically disposed on the first diamond shape slot compared in the pair of horns of long-diagonal, and institute
The center that board slot is located at the first diamond shape slot is stated, the two sides of the second plate is provided with the second diamond shape compatible with the first diamond shape slot
Slot；When first plate and the second plate successively overlap arrangement, the first plate front, rubber sheet gasket and the second plate back
The Manzo formed between the stratiform cavity formed between face and the first plate back side, rubber sheet gasket and the second plate front
Chamber is diamond structure.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that be provided with evaporator tail gas at the top of the evaporator
Entrance and the outlet of evaporator methanol steam, base of evaporator is provided with evaporator offgas outlet and evaporator methanol aqueous solution enters
Mouthful；Air inlet pipe on the evaporator gas inlet is divided into two-way, all the way with the hot fluid outlet ports piping connection of reformer bottom,
Another way is connect with hot exhaust gas entrance pipe, and is provided with the first Electromagnetic Flow in the air inlet pipe on the evaporator gas inlet
Meter；The evaporator methanol steam outlet is connected by the second electromagnetic flowmeter and the cold fluid inlet pipeline of reformer bottom
It connects.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that the evaporator is internally provided with alternate layer by layer
Hot steam flows cavity and material liquid flows cavity, and the hot steam flowing cavity and material liquid flowing cavity are stratiform cavity
Structure；The entrance of every layer of hot steam flowing cavity is connected to evaporator gas inlet, and every layer of hot steam flows going out for cavity
Mouth is connected to evaporator offgas outlet；The entrance of every layer of material liquid flowing cavity connects with evaporator methanol aqueous solution entrance
It is logical, the outlet of every layer of material liquid flowing cavity with evaporator methanol steam outlet.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that the evaporator is by evaporation plate, gasket
It plate and is set to the rubber sheet gasket that is sealed between evaporation plate and sealed bolster plate and is successively formed by stacking, the evaporation plate
The stratiform cavity of sealing is enclosed between piece, rubber sheet gasket and sealed bolster plate；Evaporate plate front, rubber sheet gasket and sealing
The stratiform cavity formed between the backing plate back side is the material liquid flowing cavity, and it is convex that the evaporation plate front is provided with ripple
Block, to increase the turbulence intensity that methanol aqueous solution is flowed out of material liquid flowing cavity；Evaporate the plate back side, rubber sheet gasket and
The stratiform cavity formed between sealed bolster plate front is the hot steam flowing cavity.
A kind of preparing hydrogen by reforming methanol reactor, it is characterised in that purify and be respectively set at the top and bottom of reservoir
There are hydrogen outlet and hydrogen-rich product inlet, the cold fluid outlet piping connection at the top of the hydrogen-rich product inlet and reformer.
Compared with the existing technology, the beneficial effect that the present invention obtains is:
1, the device of the invention is broadly divided into evaporator, reformer, purifies three parts of reservoir, between three both mutually solely
It stands, be closely connected again.And three parts are all made of plank frame, different function is determined by internal different plates, this
So that device compact overall structure is reasonable and maintenance easy to disassemble.Evaporator and reformer of the invention passes through cold and hot fluid layer
The mode of layer heat exchange, air-film thickness when greatly reducing heat exchange and improves heat exchange area, significantly improves to hot exhaust gas heat
The utilization rate of amount, and heat exchange efficiency is high.
2, the present apparatus uses raw material of the first alcohol and water as reformation hydrogen production, and methanol has energy density high, is easy production, storage
The advantages such as deposit and transport.
3, present apparatus reformer and evaporator can be recycled the heat of automobile hot exhaust gas, and energy is greatly saved
Source.Catalyst arrangement is conducive to the progress of reforming reaction in present apparatus reformer, and modular catalyst (sets catalyst
Be set to cylinder bulk, and be in a row uniformly fixed on catalyst support plate) arrangement be conducive to carry out maintenance with more
Newly.
Detailed description of the invention
Fig. 1 is the overall structure diagram of preparing hydrogen by reforming methanol reactor of the present invention；
Fig. 2 is the positive structure schematic of the first plate；
Fig. 3 is the structure schematic diagram of the first plate；
Fig. 4 is that the structural schematic diagram on catalyst support plate is arranged in reforming catalyst；
Fig. 5 is the positive structure schematic of the second plate；
Fig. 6 is the positive structure schematic for evaporating plate；
Fig. 7 is the glide path schematic diagram of cold and hot fluid in reformer；
In figure: 1- evaporator, 11- evaporator gas inlet, the outlet of 12- evaporator methanol steam, 13- evaporator tail gas go out
Mouthful, 14- evaporator methanol aqueous solution entrance, 15- evaporates plate, 15a- ripple convex block, 16- sealed bolster plate, 2- reformer, 21-
Thermal fluid inlet, 22- hot fluid outlet ports, 23- cold fluid inlet, 24- cold fluid outlet, the first plate of 25-, the first cold punching of 25a-
Hole, the first heat of 25b- rush in hole, and the first heat of 25c- goes out hole, 25d- board slot, 25e- the first diamond shape slot, the second plate of 26-, 26a-
Second cold punching hole, the second heat of 26b- rush in hole, and the second heat of 26c- goes out hole, 26e- the second diamond shape slot, and 3- purifies reservoir, 31-
Hydrogen outlet, 32- hydrogen-rich product inlet, 4- catalyst support plate, 5- hot exhaust gas entrance, the first electromagnetic flowmeter of 6-, 7- second
Electromagnetic flowmeter, 8- pressure plate.
Specific embodiment
The present invention is further explained in the light of specific embodiments, but the scope of protection of the present invention is not limited thereto.
Embodiment: comparative diagram 1 ~ 7
A kind of preparing hydrogen by reforming methanol reactor, including the evaporator 1, reformer 2 and purification reservoir 3 being arranged from bottom to top, position
Evaporator 1, reformer 2 and the purification series connection of reservoir 3 are become an entirety by the guide rod in structure of the invention two sides.Evaporator 1
It is vaporized for heating methanol water mixed liquid raw material, it is anti-that the methanol-water gaseous mixture of formation enters progress catalytic reforming in reformer 2
It answers, generates hydrogen-rich product；The purification reservoir 3 is used to the hydrogen-rich product obtained by reformer 2 carrying out hydrogen purification and hydrogen
(the purification reservoir 3 is plank frame using the purified hydrogen of prior art routine and the device of storage hydrogen for gas storage
And inside is divided into 4 regions, the region of bottom is palladium membrane separation zone, and only hydrogen can extend there through, and plays hydrogen purification ground
Effect；It is disposed with porous hydrogen storage material inside remaining 3 pieces of regions, for hydrogen storage and release).
Thermal fluid inlet 21 and cold fluid outlet 24 are provided at the top of reformer 2,2 bottom of reformer is provided with hot fluid and goes out
Mouth 22 and cold fluid inlet 23.
Evaporator gas inlet 11 and evaporator methanol steam outlet 12,1 bottom of evaporator are provided at the top of evaporator 1
It is provided with evaporator offgas outlet 13 and evaporator methanol aqueous solution entrance 14；Air inlet pipe on the evaporator gas inlet 11
Be divided into two-way, all the way with 22 piping connection of hot fluid outlet ports of 2 bottom of reformer, another way and 5 piping connection of hot exhaust gas entrance,
And the first electromagnetic flowmeter 6 is provided in the air inlet pipe on the evaporator gas inlet 11；The evaporator methanol steam
23 piping connection of cold fluid inlet that outlet 12 passes through the second electromagnetic flowmeter 7 and 2 bottom of reformer.
The top and bottom of purification reservoir 3 are respectively arranged with hydrogen outlet 31 and hydrogen-rich product inlet 32, the hydrogen-rich
24 piping connection of cold fluid outlet at 2 top of product inlet 32 and reformer.
Reformer 2 and evaporator 1 are plank frame, using automobile hot exhaust gas as heat source, respectively to reformer 2 and evaporator
1 is heated.
Reformer 2 is internally provided with the hot fluid cavity of several layers concatenated cold fluid cavity and several layers parallel connection, and every layer
Reforming catalyst is provided in cold fluid cavity, the entrance of first layer cold fluid cavity is connected to cold fluid inlet 23, finally
The outlet of layer cold fluid cavity is connected to cold fluid outlet 24, and thus methanol-water gaseous mixture is flowed into reformation through cold fluid inlet 23
In the cold fluid cavity of device 2, catalytic reforming reaction is carried out under the action of reforming catalyst, the hydrogen-rich product for reacting generation is final
It is flowed out by cold fluid outlet 24, is stored subsequently into hydrogen purification and hydrogen is carried out in purification reservoir 3.Every layer of hot fluid cavity
Entrance be connected to thermal fluid inlet 21, the outlet of every layer of hot fluid cavity is connected to hot fluid outlet ports 22, i.e., by hot-fluid
Body entrance 21 is passed through automobile hot exhaust gas as heat source, and automobile hot exhaust gas uniformly enters in each layer hot fluid cavity of reformer 2,
Reformer 2 is heated.The cold fluid cavity and hot fluid cavity are the structure of stratiform cavity, and the cold flow body cavity
Road and hot fluid cavity are arranged alternately in 2 interior-layer layer of reformer, and thus methanol-water gaseous mixture and automobile hot exhaust gas are in reformer 2
It is exchanged heat layer by layer, substantially increases the capacity usage ratio of automobile hot exhaust gas, secondly automobile hot exhaust gas is uniformly divided into several branch
It flowing into the hot fluid cavity of several layers parallel connection of reformer 2, the temperature thus heated in each hot fluid cavity is uniform,
Hot exhaust gas temperature after longer heat exchange distance is avoided successively to reduce, thus the problem of causing reforming reaction non-uniform temperature
If (hot fluid cavity is to connect layer by layer, then hot exhaust gas is from first layer hot fluid cavity, layer hot fluid cavity is flowed over to the end
The temperature of Cheng Zhong, hot exhaust gas successively reduce).Methanol-water gaseous mixture passes sequentially through the concatenated cold flow of several layers of reformer 2
Body cavity road, it is ensured that reforming reaction raw material has the sufficient residence time in reformer 2, keeps reforming reaction more abundant.Pass through this
The structure of invention flows in the concatenated cold fluid cavity of several layers of the methanol-water in a manner of intimate plug flow in reformer 2.It is right
According in Fig. 7, c → b route is glide path of the methanol-water gaseous mixture in the cold fluid cavity in reformer 2, and a → d route is
Glide path of the automobile hot exhaust gas in the hot fluid cavity in reformer 2.
Reformer 2 is internally provided with the structure of alternate cold fluid cavity and hot fluid cavity layer by layer, and reformer 2 can be adopted
It is by the first plate 25, the second plate 26 and to be set to the first plate 25 and the second plate with structure formed below: reformer 2
The rubber sheet gasket being sealed between piece 26 is successively formed by stacking, first plate 25, rubber sheet gasket and the second plate 26
Between be enclosed the stratiform cavity of sealing, rubber sheet gasket constitutes the side wall of layered cavity, so the thickness of stratiform cavity
The thickness of as rubber sheet gasket (can be respectively provided with adhesive glue on rubber sheet gasket two sides, make the first plate 25 and rubber by adhesive glue
It carries out between glue gasket and pasting sealing between second plate 26 and rubber sheet gasket).First plate, 25 front, rubber sheet gasket
And the stratiform cavity formed between 26 back side of the second plate is the cold fluid cavity, 25 back side of the first plate, rubber sheet gasket
And the stratiform cavity formed between 26 front of the second plate is the hot fluid cavity；It further include being used on the reformer 2
First reformation master of the reformation runner for being sequentially communicated each layer cold fluid cavity, the entrance for being connected to each layer hot fluid cavity
Runner and the second reformation sprue of the outlet for being connected to each layer hot fluid cavity.
The mode that runner, the first reformation sprue and the second reformation sprue are reformed in setting on reformer 2 may is that
Several pipelines are worn in the overall structure that the first plate 25, rubber sheet gasket and the second plate 26 are successively formed by stacking, are being worn
If pipeline on appropriate aperture, make that the several layers cold fluid cavity in reformer 2 is sequentially connected in series and hot fluid cavity is successively in parallel.
Such as: a pipeline passes perpendicularly through the overall structure of reformer 2, and the pipeline upper end opening and thermal fluid inlet 21 carry out pair
Connect, lower end of duct opening is blocked, the part that the pipeline is located in every layer of hot fluid cavity carries out appropriate aperture,
This pipeline is consequently formed above-mentioned first and reforms sprue.
On reformer 2 setting reform runner, first reform sprue and second reform sprue mode can also be with
Be: the quadrangle of the first plate 25 and the second plate 26 offers punching, and the pair of horns of the first plate 25 is symmetrical arranged a pair of the
One cold punching hole 25a and another diagonally it is respectively arranged with that the first heat rushes in hole 25b and the first heat goes out hole 25c, second plate
26 corresponding pair of horns are symmetrical arranged second cold punching hole 26a of a pair and corresponding another diagonal be respectively arranged with the second heat and rush in hole
26b and the second heat go out hole 26c；When first plate 25 and the second plate 26 successively overlap arrangement, first cold punching
Hole 25a and the second cold punching hole 26a be aligned and pass through rubber sheet gasket be enclosed for the methanol-water gaseous mixture that circulates reformation shunting
(reform the specific generation type of runner are as follows: the first cold punching hole 25a and the second cold punching hole 26a encloses shape by rubber sheet gasket in road
At tubular conduit, the side wall of tubular conduit be rubber sheet gasket and tubular conduit both ends open be respectively the first cold punching hole 25a and
Second cold punching hole 26a.In hot fluid luminal portion, the side of the tubular conduit is without aperture；In cold fluid cavity
When part, the appropriate aperture in the side of the tubular conduit, and when the entrance of the side openings of tubular conduit and cold fluid cavity connects
When logical, the upper end opening of tubular conduit is blocked；When the outlet of the side openings of tubular conduit and cold fluid cavity,
The lower ending opening of tubular conduit is blocked.Thus comparative diagram 1 and Fig. 7, methanol-water gaseous mixture are walked in reformer 2 in zigzag
To stay flow up).First heat rushes in hole 25b and the second heat rushes in hole 26b and is aligned and enclosed by rubber sheet gasket
It forms first for flowing into hot exhaust gas and reforms sprue, first heat goes out hole 25c and the second heat goes out hole 26c alignment simultaneously
The second reformation sprue for flowing out hot exhaust gas is enclosed by rubber sheet gasket.
Structure of the invention further includes catalyst support plate 4, and comparative diagram 4, the reforming catalyst is CuO-ZnO-Al2O3
Compound, the reforming catalyst are cylinder block structure and are in a row uniformly fixed on catalyst support plate 4；Described first
25 front of plate is provided with the board slot 25d to match with 4 shape of catalyst support plate, and the cooperation of catalyst support plate 4 is placed on board slot
In 25d.The arrangement mode of reforming catalyst also constitutes reactant runner, methanol steam mixture flow through when, with cylindrical piece
Shape catalyst comes into full contact with, and carries out flowing according to set rule and completes catalytic reforming reaction.
In order to enhance circulation effect of the methanol steam mixture in the cold fluid cavity of reformer 2, changed using following
Into mode: the two sides of the first plate 25 is provided with the first diamond shape slot 25e, 25a pairs of the first cold punching of a pair hole of the first plate 25
Title is set to the first diamond shape slot 25e compared in the pair of horns of long-diagonal, and the board slot 25d is located at the first diamond shape slot 25e
Center, the two sides of the second plate 26 is provided with second diamond shape slot 26e compatible with the first diamond shape slot 25e；When described
When one plate 25 and the second plate 26 successively overlap arrangement, the front of the first plate 25, rubber sheet gasket and 26 back side of the second plate it
Between 25 back side of stratiform cavity and the first plate formed, the stratiform cavity that is formed between 26 front of rubber sheet gasket and the second plate
It is diamond structure.When methanol steam mixture flows in cold fluid cavity as a result, can along the first diamond shape slot 25e compared with
The direction of long-diagonal is flowed, and reactant feed is not easy to form dead angle in cold fluid cavity, forms directed flow route.
The evaporator 1 is internally provided with alternate hot steam flowing cavity layer by layer and material liquid flowing cavity, the heat
Steam flowing cavity and material liquid flowing cavity are the structure of stratiform cavity；The entrance of every layer of hot steam flowing cavity with steaming
It sends out device gas inlet 11 to be connected to, the outlet of every layer of hot steam flowing cavity is connected to evaporator offgas outlet 13；Every layer of raw material
The entrance that liquid stream moves cavity be connected to evaporator methanol aqueous solution entrance 14, every layer of material liquid flow the outlet of cavity with steaming
Send out 12 connection of device methanol steam outlet.
The evaporator 1 can be using structure in detail below: evaporator 1 be by evaporation plate 15, sealed bolster plate 16 and
It is set to the rubber sheet gasket being sealed between evaporation plate 15 and sealed bolster plate 16 to be successively formed by stacking, the evaporation plate
15, the stratiform cavity of sealing is enclosed between rubber sheet gasket and sealed bolster plate 16；Evaporate the front of plate 15, rubber sheet gasket and
The stratiform cavity formed between 16 back side of sealed bolster plate is the material liquid flowing cavity, the 15 front setting of evaporation plate
Have ripple convex block 15a, to increase methanol aqueous solution turbulence intensity for flowing out of material liquid flowing cavity, methanol aqueous solution compared with
It is easy mutually to become gaseous state under strong turbulence intensity；Evaporate shape between 15 back side of plate, 16 front of rubber sheet gasket and sealed bolster plate
At stratiform cavity be hot steam flowing cavity.The entrance of every layer of hot steam flowing cavity with evaporator tail gas
The mode that entrance 11 is connected to may is that wears a pipeline on evaporator 1, and the pipeline passes perpendicularly through the entirety of evaporator 1
The upper end opening of structure, pipeline is docked with evaporator gas inlet 11, and the lower ending opening of pipeline is blocked, the pipeline
Part in every layer of hot steam flowing cavity carries out side mouth, and thus hot steam is uniformly entered by the pipeline
Every layer of hot steam flows cavity.
Evaporator 1 and reformer 2 of the invention can be fixed by pressure plate 8, and two pieces of pressure plates 8 are set respectively
It is placed in the upper and lower ends of evaporator 1 or reformer 2, pressure plate 8 is equipped with screw hole, by bolt by evaporator 1 or reformer 2
The pressure plate 8 of upper and lower ends is fixed, so that evaporator 1 or reformer 2 have better overall stability.
Content described in this specification is only to enumerate to inventive concept way of realization, and protection scope of the present invention is not answered
When the concrete form for being seen as limited by embodiment and being stated.
Claims (9)
1. a kind of preparing hydrogen by reforming methanol reactor, it is characterised in that including evaporator (1), the reformer (2) being arranged from bottom to top
With purification reservoir (3), the evaporator (1), reformer (2) and purification reservoir (3) are become by vertical guide rod series connection
The structure of one entirety；Thermal fluid inlet (21) and cold fluid outlet (24), reformer are provided at the top of the reformer (2)
(2) bottom is provided with hot fluid outlet ports (22) and cold fluid inlet (23)；
The reformer (2) is internally provided with the hot fluid cavity of several layers concatenated cold fluid cavity and several layers parallel connection, often
It is provided with reforming catalyst in layer cold fluid cavity, the entrance of first layer cold fluid cavity is connected to cold fluid inlet (23),
The outlet of final layer cold fluid cavity is connected to cold fluid outlet (24)；The entrance of every layer of hot fluid cavity is and thermal fluid inlet
(21) it is connected to, hot exhaust gas is entered by thermal fluid inlet (21) in each layer hot fluid cavity of reformer (2), every layer of hot fluid cavity
Outlet be connected to hot fluid outlet ports (22)；The cold fluid cavity and hot fluid cavity are the structure of stratiform cavity, and
The cold fluid cavity and hot fluid cavity are arranged alternately in reformer (2) interior-layer layer；
The evaporator (1) is used to heat methanol water mixed liquid raw material and vaporize, and the methanol-water gaseous mixture of formation is entered by cold fluid
Mouth (23), which enters, carries out catalytic reforming reaction in the cold fluid cavity of reformer (2), generate hydrogen-rich product；The purification reservoir
(3) for hydrogen purification and hydrogen storage will to be carried out by the hydrogen-rich product that reformer (2) obtain.
2. a kind of preparing hydrogen by reforming methanol reactor according to claim 1, it is characterised in that the reformer (2) is by first
Plate (25), the second plate (26) and it is set to the rubber pad being sealed between the first plate (25) and the second plate (26)
Piece is successively formed by stacking, and the layer of sealing is enclosed between first plate (25), rubber sheet gasket and the second plate (26)
Shape cavity；The stratiform cavity formed between first plate (25) front, rubber sheet gasket and the second plate (26) back side is described
Cold fluid cavity, the stratiform cavity formed between the first plate (25) back side, rubber sheet gasket and the second plate (26) front are
The hot fluid cavity；Further include on the reformer (2) reformation runner for being sequentially communicated each layer cold fluid cavity,
Outlet for being connected to the first reformation sprue of the entrance of each layer hot fluid cavity and for being connected to each layer hot fluid cavity
Second reform sprue.
3. a kind of preparing hydrogen by reforming methanol reactor according to claim 2, it is characterised in that a pair of the first plate (25)
Angle is symmetrically arranged with a pair of first cold punching hole (25a) and another first heat that is diagonally respectively arranged with rushes in hole (25b) and the first heat
It goes out hole (25c), the corresponding pair of horns of second plate (26) is symmetrically arranged with a pair of second cold punching hole (26a) and corresponding
It is another to be diagonally respectively arranged with that the second heat rushes in hole (26b) and the second heat goes out hole (26c)；When first plate (25) and
When two plates (26) successively overlap arrangement, first cold punching hole (25a) and the second cold punching hole (26a) are aligned and pass through rubber pad
Piece is enclosed the reformation runner for the methanol-water gaseous mixture that circulates, and first heat rushes in hole (25b) and the second heat is rushed in
Hole (26b) alignment is simultaneously enclosed the first reformation sprue for flowing into hot exhaust gas, the first heat punching by rubber sheet gasket
Portal (25c) and the second heat goes out hole (26c) and is aligned and is enclosed the second weight for flowing out hot exhaust gas by rubber sheet gasket
Whole sprue.
4. a kind of preparing hydrogen by reforming methanol reactor according to claim 2, it is characterised in that further include catalyst support plate
(4), the reforming catalyst is CuO-ZnO-Al2O3Compound, the reforming catalyst are that cylinder block structure is simultaneously in a row uniform
Be fixed on catalyst support plate (4)；First plate (25) front is provided with to match with catalyst support plate (4) shape
Board slot (25d), catalyst support plate (4) cooperation is placed in board slot (25d).
5. a kind of preparing hydrogen by reforming methanol reactor according to claim 4, it is characterised in that the two sides of the first plate (25)
It is provided with the first diamond shape slot (25e), the first cold punching of a pair hole (25a) of the first plate (25) is symmetrically disposed on first water chestnut
Shape slot (25e) is compared in the pair of horns of long-diagonal, and the board slot (25d) is located at the center of the first diamond shape slot (25e), the second plate
The two sides of piece (26) is provided with the compatible second diamond shape slot (26e) with the first diamond shape slot (25e)；When first plate
(25) when and the second plate (26) successively overlaps arrangement, the first plate (25) front, rubber sheet gasket and the second plate (26) back side
Between the layer that is formed between the stratiform cavity that is formed and the first plate (25) back side, rubber sheet gasket and the second plate (26) front
Shape cavity is diamond structure.
6. a kind of preparing hydrogen by reforming methanol reactor according to claim 1, it is characterised in that set at the top of the evaporator (1)
It is equipped with evaporator gas inlet (11) and evaporator methanol steam outlet (12), evaporator (1) bottom is provided with evaporator tail
Gas exports (13) and evaporator methanol aqueous solution entrance (14)；Air inlet pipe on the evaporator gas inlet (11) is divided into two
Road, all the way with hot fluid outlet ports (22) piping connection of reformer (2) bottom, another way and hot exhaust gas entrance (5) piping connection,
And the first electromagnetic flowmeter (6) are provided in the air inlet pipe on the evaporator gas inlet (11)；The evaporator methanol-water
Vapor outlet port (12) passes through cold fluid inlet (23) piping connection of the second electromagnetic flowmeter (7) and reformer (2) bottom.
7. a kind of preparing hydrogen by reforming methanol reactor according to claim 6, it is characterised in that set inside the evaporator (1)
It is equipped with alternate hot steam flowing cavity layer by layer and material liquid flowing cavity, the hot steam flowing cavity and material liquid flow cavity
Road is the structure of stratiform cavity；The entrance of every layer of hot steam flowing cavity is connected to, every layer with evaporator gas inlet (11)
The outlet of hot steam flowing cavity is connected to evaporator offgas outlet (13)；The entrance of every layer of material liquid flowing cavity with steaming
Device methanol aqueous solution entrance (14) connection is sent out, the outlet of every layer of material liquid flowing cavity is exported with evaporator methanol steam
(12) it is connected to.
8. a kind of preparing hydrogen by reforming methanol reactor according to claim 6, it is characterised in that the evaporator (1) is by steaming
It sends out plate (15), sealed bolster plate (16) and is set to the rubber being sealed between evaporation plate (15) and sealed bolster plate (16)
Gasket is successively formed by stacking, and the layer of sealing is enclosed between evaporation plate (15), rubber sheet gasket and sealed bolster plate (16)
Shape cavity；The stratiform cavity formed between evaporation plate (15) front, rubber sheet gasket and sealed bolster plate (16) back side is institute
Material liquid flowing cavity is stated, evaporation plate (15) front is provided with ripple convex block (15a), to increase methanol aqueous solution from original
The turbulence intensity flowed in feed solution flow cavity；Evaporate plate (15) back side, rubber sheet gasket and sealed bolster plate (16) front
Between the stratiform cavity that is formed be the hot steam flowing cavity.
9. a kind of preparing hydrogen by reforming methanol reactor according to claim 1, it is characterised in that the top of purification reservoir (3)
Hydrogen outlet (31) and hydrogen-rich product inlet (32), the hydrogen-rich product inlet (32) and reformer are respectively arranged with bottom
(2) cold fluid outlet (24) piping connection at the top of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910212857.2A CN109761193B (en) | 2019-03-20 | 2019-03-20 | Methanol reforming hydrogen production reactor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910212857.2A CN109761193B (en) | 2019-03-20 | 2019-03-20 | Methanol reforming hydrogen production reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109761193A true CN109761193A (en) | 2019-05-17 |
| CN109761193B CN109761193B (en) | 2024-04-09 |
Family
ID=66459286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910212857.2A Active CN109761193B (en) | 2019-03-20 | 2019-03-20 | Methanol reforming hydrogen production reactor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109761193B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110420644A (en) * | 2019-08-16 | 2019-11-08 | 广西氢朝能源科技有限公司 | A kind of production method of palladium membrane component and its application in hydrogen from methyl alcohol reactor |
| CN111864240A (en) * | 2020-08-23 | 2020-10-30 | 浙江工业大学 | Small-size methanol reforming hydrogen plant |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4946667A (en) * | 1985-06-10 | 1990-08-07 | Engelhard Corporation | Method of steam reforming methanol to hydrogen |
| US7048897B1 (en) * | 2000-08-28 | 2006-05-23 | Motorola, Inc. | Hydrogen generator utilizing ceramic technology |
| CN102910584A (en) * | 2012-10-24 | 2013-02-06 | 华南理工大学 | Self-heating laminated micro-channel reforming hydrogen production reactor |
| CN103693618A (en) * | 2013-12-19 | 2014-04-02 | 华南理工大学 | Hydrogen production reactor for carrying out autothermal reforming hydrogen production employing car exhaust waste heat |
| CN203639144U (en) * | 2013-12-19 | 2014-06-11 | 华南理工大学 | Hydrogen production reactor for carrying out self-heating reformed hydrogen production by utilizing automobile tail gas exhaust heat |
| CN106629598A (en) * | 2016-11-11 | 2017-05-10 | 浙江大学 | Self-heating type reactor used for hydrogen production by reforming and filled with high-temperature phase-change material |
| CN206666114U (en) * | 2016-11-11 | 2017-11-24 | 浙江大学 | A kind of self-heating type reforming hydrogen-preparation reactor of filled high-temperature phase-change material |
| CN109179322A (en) * | 2018-11-09 | 2019-01-11 | 沈阳航空航天大学 | A kind of online methanol reformer for producing hydrogen-rich gas using engine tail gas heat quantity |
| CN109455668A (en) * | 2018-11-09 | 2019-03-12 | 沈阳航空航天大学 | A kind of online reforming system of airborne methanol and control method using baffling separating mechanism |
| CN209702303U (en) * | 2019-03-20 | 2019-11-29 | 浙江工业大学 | A kind of preparing hydrogen by reforming methanol reactor |
-
2019
- 2019-03-20 CN CN201910212857.2A patent/CN109761193B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4946667A (en) * | 1985-06-10 | 1990-08-07 | Engelhard Corporation | Method of steam reforming methanol to hydrogen |
| US7048897B1 (en) * | 2000-08-28 | 2006-05-23 | Motorola, Inc. | Hydrogen generator utilizing ceramic technology |
| CN102910584A (en) * | 2012-10-24 | 2013-02-06 | 华南理工大学 | Self-heating laminated micro-channel reforming hydrogen production reactor |
| CN103693618A (en) * | 2013-12-19 | 2014-04-02 | 华南理工大学 | Hydrogen production reactor for carrying out autothermal reforming hydrogen production employing car exhaust waste heat |
| CN203639144U (en) * | 2013-12-19 | 2014-06-11 | 华南理工大学 | Hydrogen production reactor for carrying out self-heating reformed hydrogen production by utilizing automobile tail gas exhaust heat |
| CN106629598A (en) * | 2016-11-11 | 2017-05-10 | 浙江大学 | Self-heating type reactor used for hydrogen production by reforming and filled with high-temperature phase-change material |
| CN206666114U (en) * | 2016-11-11 | 2017-11-24 | 浙江大学 | A kind of self-heating type reforming hydrogen-preparation reactor of filled high-temperature phase-change material |
| CN109179322A (en) * | 2018-11-09 | 2019-01-11 | 沈阳航空航天大学 | A kind of online methanol reformer for producing hydrogen-rich gas using engine tail gas heat quantity |
| CN109455668A (en) * | 2018-11-09 | 2019-03-12 | 沈阳航空航天大学 | A kind of online reforming system of airborne methanol and control method using baffling separating mechanism |
| CN209702303U (en) * | 2019-03-20 | 2019-11-29 | 浙江工业大学 | A kind of preparing hydrogen by reforming methanol reactor |
Non-Patent Citations (1)
| Title |
|---|
| 纪常伟;邓福山;STEFAN KORTE;方泽军;汪硕峰;何洪;: "内燃机余热甲醇催化重整制氢装置设计及实验研究", 北京工业大学学报, no. 06, pages 815 - 819 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110420644A (en) * | 2019-08-16 | 2019-11-08 | 广西氢朝能源科技有限公司 | A kind of production method of palladium membrane component and its application in hydrogen from methyl alcohol reactor |
| CN111864240A (en) * | 2020-08-23 | 2020-10-30 | 浙江工业大学 | Small-size methanol reforming hydrogen plant |
| CN111864240B (en) * | 2020-08-23 | 2024-04-02 | 浙江工业大学 | Small-size methyl alcohol reforming hydrogen plant |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109761193B (en) | 2024-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104025356B (en) | Zero emission power plant with co2 waste utilization | |
| CN100500550C (en) | Method of preparing hydrogen by reforming methanol-water steam | |
| CN110155945B (en) | Self-heating methanol reforming hydrogen production reactor integrating CO selective methanation | |
| CN207572466U (en) | vehicle-mounted fuel cell power generation system | |
| CN102910584B (en) | Self-heating laminated micro-channel reforming hydrogen production reactor | |
| CN108557761B (en) | A kind of hydrogen-manufacturing reactor for inhaling heat release coupling | |
| CN101624178B (en) | Hydrogen production system employing reforming technology | |
| CN209702303U (en) | A kind of preparing hydrogen by reforming methanol reactor | |
| CN101580227A (en) | Self-heating type alcohol reforming hydrogen production micro channel reactor with micro-lug boss array structure | |
| CN112892460B (en) | Self-heating methanol reforming hydrogen production reactor | |
| US20210309516A1 (en) | Integrated small and medium-sized natural gas steam reforming reactor and reforming reaction process | |
| CN109761193A (en) | A kind of preparing hydrogen by reforming methanol reactor | |
| CN102502494B (en) | Laminated type reactor for hydrogen production by reforming alcohols | |
| CN112811390A (en) | Methanol-water fuel reforming hydrogen production system | |
| CN106607002B (en) | One kind being used for CO2The multiple-layer stacked microchannel reaction unit of methanation | |
| KR101243767B1 (en) | Hydrogen production system for pemfc | |
| CN203639144U (en) | Hydrogen production reactor for carrying out self-heating reformed hydrogen production by utilizing automobile tail gas exhaust heat | |
| CN112820914A (en) | Fuel cell system directly utilizing methanol reformed gas and working method thereof | |
| CN210366978U (en) | Methanol reforming hydrogen production reactor | |
| CN202346756U (en) | Laminated type alcohol reforming hydrogen production reactor | |
| CN217062194U (en) | Fuel cell tail row system based on solid hydrogen storage | |
| WO2023115622A1 (en) | Catalytic combustion hydrogen storage and release device and method | |
| CN201207411Y (en) | Portable micro hydrogen source device for fuel cell | |
| CN213976968U (en) | Natural gas hydrogen production equipment | |
| CN212283958U (en) | Ammonia decomposition hydrogen production system and hydrogen station system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |