CN109746028B - Propane dehydrogenation catalyst, preparation method thereof and method for preparing propylene by propane dehydrogenation - Google Patents
Propane dehydrogenation catalyst, preparation method thereof and method for preparing propylene by propane dehydrogenation Download PDFInfo
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Abstract
The invention relates to the field of catalysts, and discloses a propane dehydrogenation catalyst, a preparation method thereof and a method for preparing propylene by propane dehydrogenation. The propane dehydrogenation catalyst comprises a carrier, and a Pt component, a Sn component and a Na component which are loaded on the carrier, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum component, a mesoporous molecular sieve material with a three-dimensional cubic pore structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 mu m, and the specific surface area is 100-180 m-2The pore volume is 0.5-2mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 30-40nm respectively. The propane dehydrogenation catalyst shows good catalytic performance when used for preparing propylene by propane dehydrogenation, and has the advantages of high propane conversion rate, high propylene selectivity, good catalyst stability and strong poisoning resistance.
Description
Technical Field
The invention relates to the field of catalysts, in particular to a propane dehydrogenation catalyst, a preparation method thereof and a method for preparing propylene by propane dehydrogenation.
Background
Propylene is a basic raw material of petrochemical industry and is mainly used for producing polypropylene, acrylonitrile, acetone, propylene oxide, acrylic acid, butanol and octanol and the like. Half of the propylene supply comes from refinery by-products and about 45% from steam cracking, a few other alternative technologies. In recent years, the demand of propylene is increasing year by year, and the traditional propylene production can not meet the demand of the chemical industry for propylene, so that the propylene yield increase becomes a great hot point for research. The dehydrogenation of propane to propylene is one of the main technologies for increasing the yield of propylene. For more than 10 years, the dehydrogenation of propane to prepare propylene has become an important process for the industrial production of propylene. The main catalysts for propane dehydrogenation are the chromium oxide/alumina catalyst in the CYLofin process from ABB Lummus and the platinum tin/alumina catalyst in the Oleflex process from UOP. The chromium catalyst has lower requirements on raw material impurities and lower price compared with noble metals; however, the catalyst is easy to deposit carbon and deactivate, and is regenerated every 15 to 30 minutes, and the chromium in the catalyst is heavy metal, so that the environmental pollution is serious. The platinum-tin catalyst has high activity and good selectivity, the reaction period can reach several days, and the catalyst can bear harsh process conditions and is more environment-friendly; however, the noble metal platinum is expensive, so that the cost of the catalyst is high. The industrial production of the process for preparing propylene by propane dehydrogenation is over twenty years, and the research on dehydrogenation catalysts is more, but the current catalysts still have the defects of low propane conversion rate, easy inactivation and the like, and further improvement and perfection are needed. Therefore, it is of practical significance to develop a propane dehydrogenation catalyst having excellent performance. Much work has been done by researchers to improve the reaction performance of propane dehydrogenation catalysts. Such as: the molecular sieve carrier is adopted to replace the traditional gamma-Al 2O3 carrier, and the carrier has good effect and comprises MFI type microporous molecular sieves (CN104307555A, CN101066532A, CN101380587A and CN101513613A), mesoporous MCM-41 molecular sieves (CN102389831A), mesoporous SBA-15 molecular sieves (CN101972664A and CN101972664B) and the like. However, the pore diameter of the commonly used mesoporous material is small (average pore diameter is 6-9 nm), and if macromolecule catalytic reaction is carried out, the macromolecule is difficult to enter the pore channel, so that the catalytic effect is influenced. Therefore, the selection of a good carrier is an urgent problem to be solved in the field of propane dehydrogenation.
Disclosure of Invention
The propane dehydrogenation catalysts of the prior art are usually based on PtThe metal active component is gamma-Al2O3As a carrier, the catalyst has the defects of poor dispersion of active components and poor catalytic activity and stability. The invention aims to overcome the defects that in the prior art, the mesoporous structure is unstable, the conversion rate of propane and the selectivity of propylene are not high, the catalyst is easy to inactivate and the like, and provides a propane dehydrogenation catalyst, a preparation method thereof and a method for preparing propylene by propane dehydrogenation.
In order to achieve the above object, the present invention provides a propane dehydrogenation catalyst, which comprises a carrier and a Pt component, a Sn component and a Na component supported on the carrier, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum component, a mesoporous molecular sieve material having a three-dimensional cubic pore structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 μm, and the specific surface area is 100-180 m-2The pore volume is 0.5-2mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 30-40nm respectively.
The second aspect of the present invention provides a method for preparing the above propane dehydrogenation catalyst, comprising: carrying out heat activation on a carrier, then carrying out dipping treatment in a mixed solution containing a Pt component precursor, a Sn component precursor and a Na component precursor, and then sequentially carrying out solvent removal treatment, drying and roasting, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum component, a mesoporous molecular sieve material with a three-dimensional cubic pore channel structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 mu m, and the specific surface area is 100-180 m-2The pore volume is 0.5-2mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 30-40nm respectively.
In a third aspect, the present invention provides a propane dehydrogenation catalyst prepared by the above process.
In a fourth aspect of the present invention, there is provided a method for producing propylene by dehydrogenation of propane, the method comprising: and carrying out dehydrogenation reaction on propane in the presence of a catalyst and hydrogen, wherein the catalyst is the propane dehydrogenation catalyst provided by the invention or the propane dehydrogenation catalyst prepared by the method provided by the invention.
The carrier of the propane dehydrogenation catalyst is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, combines the mesoporous molecular sieve with a three-dimensional cubic pore channel distribution structure, the regular ordered mesoporous space characteristic of silica gel and the spherical morphology advantage, not only retains the characteristics of high specific surface area and large pore volume of the ordered mesoporous material, but also increases the advantages of large pore diameter and narrow distribution, the pore diameter distribution of the ordered mesoporous molecular sieve presents unique bimodal distribution, and the advantages of the ordered mesoporous material with bimodal distribution in pore diameter and the microsphere structure are skillfully combined, so that the loading of active components is facilitated. In addition, the introduction of the aluminum component in the ball milling process increases the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material, can effectively prevent the sphere from being broken when the active component is loaded, improves the stability of the carrier and prolongs the service life of the catalyst. Therefore, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is suitable for being used as a carrier of a supported catalyst, and is particularly suitable for being used as a carrier of a supported catalyst used in the reaction of preparing propylene by propane dehydrogenation.
In the propane dehydrogenation catalyst, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is used as a carrier, and a Pt component, a Sn component and a Na component are loaded, so that the supported catalyst has the advantages of the supported catalyst, such as high catalytic activity, less side reaction, simple post-treatment and the like, and has stronger catalytic activity, the supported catalyst has better dehydrogenation activity and selectivity when being used in the propane dehydrogenation reaction, and the conversion rate of reaction raw materials is remarkably improved, specifically, in the reaction of preparing propylene by using the supported catalyst for propane dehydrogenation, the conversion rate of propane can reach 30%, and the selectivity of propylene can reach 82.4%.
In addition, the co-impregnation method is adopted to replace the conventional step-by-step impregnation method, the preparation process is simple, the conditions are easy to control, and the product repeatability is good.
And, when the propane dehydrogenation catalyst is prepared by a spray-drying method, the propane dehydrogenation catalyst can be recycled, and a high conversion rate of reaction raw materials can be still obtained during recycling.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention. In the drawings:
FIG. 1 is an X-ray diffraction (XRD) spectrum of a spherical aluminum-containing mesoporous molecular sieve silica composite of example 1;
FIG. 2 is an SEM scanning electron micrograph of the microstructure of the spherical aluminum-containing mesoporous molecular sieve silica composite of example 1.
Detailed Description
The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual points, and between the individual points may be combined with each other to give one or more new ranges of values, and these ranges of values should be considered as specifically disclosed herein.
The invention provides a propane dehydrogenation catalyst which comprises a carrier, and a Pt component, an Sn component and a Na component which are loaded on the carrier, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum component, a mesoporous molecular sieve material with a three-dimensional cubic pore structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 mu m, and the specific surface area is 100-180m2Per g, pore volume of 0.5-2mL/gThe pore diameters are distributed in a bimodal mode, and the most probable pore diameters corresponding to the bimodal mode are 4-8nm and 30-40nm respectively.
According to the invention, the carrier has a special three-dimensional cubic pore channel distribution structure, the limitation of a one-dimensional pore channel on molecular transmission is broken through, and the carrier is combined with the special three-dimensional cubic ordered mesoporous pore channel distribution structure and the pore channel structure of silica gel, so that the metal components can be well dispersed in the pore channel of the carrier. In addition, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is remarkably increased due to the aluminum component contained in the spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the sphere can be effectively prevented from being broken when an active component is loaded, and the stability of the carrier is improved. The supported catalyst obtained by using the spherical aluminum-containing mesoporous molecular sieve silica gel composite material as a carrier and loading the Pt component, the Sn component and the Na component has the advantages of the supported catalyst such as high catalytic activity, less side reactions, simple post-treatment and the like, and also has stronger catalytic activity and higher stability, so that the supported catalyst has better dehydrogenation activity and selectivity when being used for propane dehydrogenation reaction, and the conversion rate of reaction raw materials is obviously improved.
According to the invention, the average particle diameter of the particles of the support is determined using a laser particle size distribution instrument, and the specific surface area, pore volume and most probable pore diameter are determined according to a nitrogen adsorption method.
According to the invention, the structural parameters of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material are controlled within the range, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is ensured not to be easily agglomerated, and the supported catalyst prepared by using the spherical aluminum-containing mesoporous molecular sieve silica gel composite material as a carrier can improve the conversion rate of reaction raw materials in the reaction process of preparing propylene by propane dehydrogenation. When the specific surface area of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is less than 100m2When the volume/g and/or pore volume is less than 0.5mL/g, the catalytic activity of the supported catalyst prepared by using the supported catalyst is remarkably reduced; when the specific surface area of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is more than 180m2When the volume of the catalyst is more than 2mL/g, the catalyst is used as a carrier to prepare a supported catalyst for propane dehydrogenationAgglomeration is easy to occur in the reaction process of preparing the propylene, thereby influencing the conversion rate of reaction raw materials in the reaction process of preparing the propylene by propane dehydrogenation.
Preferably, the compressive strength of the carrier is 14-16MPa, the average particle diameter is 30-60 μm, and the specific surface area is 100-170m2Pore volume of 0.8-1.8mL/g, and bimodal distribution with comparable maximum pore diameters of 4-8nm and 32-39nm, respectively.
According to the present invention, the propane dehydrogenation catalyst comprises a carrier, and a Pt component, a Sn component, and a Na component supported on the carrier, wherein the Pt component is an active metal component, and the Sn component and the Na component are metal promoters.
According to the present invention, the carrier has a content of 97.5 to 99.3 wt%, the Pt component has a content of 0.2 to 0.5 wt% in terms of Pt element, the Sn component has a content of 0.2 to 1.2 wt% in terms of Sn element, and the Na component has a content of 0.3 to 0.8 wt% in terms of Na element, with respect to 100 parts by weight of the propane dehydrogenation catalyst.
Preferably, the compressive strength of the propane dehydrogenation catalyst is 14-16MPa, the average particle diameter is 30-60 μm, and the specific surface area is 80-150m2The pore volume is 0.5-1.5mL/g, the pore size distribution is bimodal, and the most probable pore sizes corresponding to the bimodal are 4-8nm and 32-39nm respectively.
According to the invention, the increase of the content of the aluminum component is beneficial to improving the compressive strength of the carrier, the content of the mesoporous molecular sieve material and the content of the silica gel can adjust the channel structure of the carrier, and in order to ensure that the carrier has higher compressive strength and better channel structure parameters, in the spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the content of the aluminum component is 1-20 parts by weight, preferably 5-19 parts by weight, and the content of the silica gel is 1-90 parts by weight, preferably 2-85 parts by weight, relative to 100 parts by weight of the mesoporous molecular sieve material with a three-dimensional cubic channel structure.
The present invention also provides a method for preparing a propane dehydrogenation catalyst, the method comprising: carrying out thermal activation on the carrier in a mixed solution containing a Pt component precursor, a Sn component precursor and a Na component precursorDipping, then sequentially removing a solvent, drying and roasting, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum-containing component, a mesoporous molecular sieve material with a three-dimensional cubic pore channel structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 mu m, and the specific surface area is 100-180 m-2The pore volume is 0.5-2mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 30-40nm respectively.
According to the present invention, in order to remove hydroxyl and residual moisture of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material, before the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is loaded with metal components, a thermal activation treatment is first performed, and the conditions of the thermal activation treatment may include: in the presence of nitrogen, the carrier is calcined at the temperature of 300-900 ℃ for 7-10 h.
According to the invention, the metal component loaded on the spherical aluminum-containing mesoporous molecular sieve silica gel composite material can adopt an impregnation mode, the metal component enters the pore channel of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material by virtue of the capillary pressure of the pore channel structure of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material, and meanwhile, the metal component can be adsorbed on the surface of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material until the metal component reaches adsorption balance on the surface of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material. Preferably, the impregnation treatment is performed after the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is subjected to thermal activation treatment, and the impregnation treatment can be co-impregnation treatment or step-by-step impregnation treatment. In order to save the preparation cost and simplify the experimental process, the dipping treatment is preferably co-dipping treatment; further preferably, the conditions of the co-impregnation treatment include: the spherical aluminum-containing mesoporous molecular sieve silica gel composite material after thermal activation is mixed and contacted with a solution containing a Pt component precursor, a Sn component precursor and a Na component precursor, the dipping temperature can be 25-50 ℃, and the dipping time can be 2-6 h.
According to the present invention, the solutions of the Pt component precursor, the Sn component precursor, and the Na component precursor are not particularly limited as long as they are water-soluble, and may be conventionally selected in the art. For example, the Pt component precursor can be H2PtCl6The Sn component precursor may be SnCl4The Na component precursor can be NaNO3。
The concentration of the solution containing the Pt component precursor, the Sn component precursor, and the Na component precursor is not particularly limited in the present invention and may be conventionally selected in the art, for example, the concentration of the Pt component precursor may be 0.1 to 0.3mol/L, the concentration of the Sn component precursor may be 0.15 to 1mol/L, and the concentration of the Na component precursor may be 1 to 3.5 mol/L.
According to the present invention, the carrier, the Pt component precursor, the Sn component precursor, and the Na component precursor may be used in amounts such that the carrier has a content of 97.5 to 99.3 wt%, the Pt component has a content of 0.2 to 0.5 wt% in terms of Pt element, the Sn component has a content of 0.2 to 1.2 wt% in terms of Sn element, and the Na component has a content of 0.3 to 0.8 wt% in terms of Na element in the prepared propane dehydrogenation catalyst, based on the total weight of the propane dehydrogenation catalyst.
According to the present invention, the solvent removal treatment can be carried out by a method conventional in the art, for example, a rotary evaporator can be used to remove the solvent in the system.
According to the invention, the drying can be carried out in a drying oven and the baking can be carried out in a muffle furnace. The conditions for the drying and firing are also not particularly limited in the present invention, and may be conventionally selected in the art, for example, the conditions for the drying may include: the temperature is 110-150 ℃ and the time is 3-6 h; the conditions for the firing may include: the temperature is 600 ℃ and 650 ℃, and the time is 5-8 h.
According to the present invention, the method of forming the carrier includes the steps of:
(a) in the presence of a template agent and butanol, a silicon source is contacted with an acid agent, and the mixture obtained after the contact is crystallized and filtered in sequence to obtain a filter cake of the mesoporous molecular sieve;
(b) contacting water glass with inorganic acid and n-butyl alcohol, and filtering a mixture obtained after the contact to obtain a silica gel filter cake;
(c) mixing the spherical double mesoporous molecular sieve filter cake and the silica gel filter cake, performing ball milling in a high-alumina ceramic tank, pulping solid powder obtained after ball milling by using water, performing spray drying on the obtained slurry, and removing the template agent from the obtained product.
In the forming process of the carrier, the filter cake of the mesoporous molecular sieve is the filter cake of the mesoporous molecular sieve with a three-dimensional cubic pore channel distribution structure.
In the forming process of the carrier, the pore size distribution of the carrier is controlled to be bimodal distribution mainly by controlling the composition of a mesoporous molecular sieve filter cake and a silica gel filter cake, so that the spherical aluminum-containing mesoporous molecular sieve silica gel composite material has a diplopore distribution structure, the mesoporous molecular sieve filter cake and the silica gel filter cake are firstly mixed and ball-milled in a high-aluminum ceramic tank by controlling a forming method, then the obtained solid powder is slurried with water and then spray-dried, the microscopic morphology of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is controlled to be spherical, and the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is introduced with an aluminum component.
According to the present invention, in the step (a), the process for preparing the mesoporous molecular sieve filter cake may comprise: mixing and contacting the template agent, butanol, the acid agent and the silicon source, and crystallizing and filtering the obtained mixture. The order of the mixing and contacting is not particularly limited, and the template agent, butanol, the acid agent and the silicon source may be mixed at the same time, or any two or three of them may be mixed, and then the other components may be added and mixed uniformly. According to a preferred embodiment, the template agent, butanol and the acid agent are mixed uniformly, and then the silicon source is added and mixed uniformly. The contact mode is that the template agent, butanol and acidic aqueous solution are mixed evenly, the obtained mixture is placed in a water bath with the temperature of 30-45 ℃, then the temperature is kept unchanged, a silicon source is slowly added into the mixture in a dropwise manner, and the mixture is stirred and reacts for 20-40 hours. The silicon source may be added dropwise at a rate of 0.1 to 1g/min, based on 1g of template.
According to the present invention, the amount of each substance used in the preparation of the mesoporous molecular sieve filter cake can be selected and adjusted within a wide range. For example, the molar ratio of the templating agent, butanol, and silicon source may be 1:10 to 100:10 to 90, preferably 1: 60-90: 50-75, more preferably 1: 75-85: 50-70.
According to the invention, in order to make the obtained mesoporous sieve filter cake have the three-dimensional cubic pore channel distribution structure, the template agent is preferably triblock copolymer polyoxyethylene-polyoxypropylene-polyoxyethylene. The template may be prepared by methods known to those skilled in the art or may be obtained commercially, for example, from Aldrich under the trade designation P123, formula EO20PO70EO20The average molecular weight Mn was 5800. Wherein the number of moles of polyoxyethylene-polyoxypropylene-polyoxyethylene is calculated from the average molecular weight of polyoxyethylene-polyoxypropylene-polyoxyethylene.
In the present invention, the silicon source may be various silicon sources conventionally used in the art, and preferably the silicon source is at least one of tetraethoxysilane, methyl orthosilicate, propyl orthosilicate, sodium orthosilicate and silica sol, and more preferably tetraethoxysilane.
In the present invention, the acid agent may be various acidic aqueous solutions conventionally used in the art, and for example, may be at least one aqueous solution of hydrochloric acid, sulfuric acid, nitric acid and hydrobromic acid, preferably an aqueous hydrochloric acid solution.
The amount of the acid agent is not particularly limited, and may be varied within a wide range, and it is preferable that the pH value of the mixing contact is 1 to 6.
The conditions of the mixing and contacting are not particularly limited in the present invention, and for example, the conditions of the mixing and contacting may include: the temperature is 25-60 deg.C, the time is 10-72h, and the pH value is 1-6. In order to further facilitate uniform mixing between the substances, according to a preferred embodiment of the invention, the mixing contact is carried out under stirring conditions.
In a preferred embodiment, the contacting mode is that the template agent, butanol and acidic aqueous solution are mixed uniformly, the obtained mixture is placed in a water bath at the temperature of 30-45 ℃, then the temperature is kept unchanged, tetraethoxysilane is slowly and dropwise added into the mixture, and the mixture is stirred and reacts for 20-40 hours. The dropping rate of the tetraethoxysilane can be 0.1-1g/min based on 1g of the template agent.
In the present invention, the crystallization conditions are not particularly limited, and for example, the crystallization conditions may include: the temperature is 30-150 ℃, preferably 90-150 ℃; the time is 10-72h, preferably 10-40 h. According to a preferred embodiment, the crystallization is carried out by hydrothermal crystallization.
The conditions for contacting the water glass, the inorganic acid and the n-butanol are not particularly limited in the present invention, and for example, in the step (b), the conditions for contacting the water glass, the inorganic acid and the n-butanol generally include: the temperature can be 10-60 ℃, preferably 20-40 ℃; the time may be 1 to 5 hours, preferably 1.5 to 3 hours, and the pH value is 2 to 4. In order to increase the pore size of the prepared silica gel, preferably, the weight ratio of the amounts of water glass, inorganic acid and n-butanol may be 3-6:1: 1. In order to further facilitate uniform mixing between the substances, the contact of the water glass, the inorganic acid and the n-butanol is preferably carried out under stirring.
According to the invention, the water glass is an aqueous solution of sodium silicate conventional in the art, and its concentration may be 10 to 50% by weight, preferably 12 to 30% by weight.
According to the present invention, the kind of the inorganic acid may be conventionally selected in the art, and for example, may be one or more of sulfuric acid, nitric acid and hydrochloric acid. The inorganic acid may be used in a pure form or in the form of an aqueous solution thereof. The inorganic acid is preferably used in such an amount that the reaction system has a pH of 2 to 4 under the contact conditions of the water glass and the inorganic acid.
Further, in the above-described process for preparing the mesoporous molecular sieve cake and the silica gel cake, the process for obtaining the cake by filtration may include: after filtration, washing with distilled water was repeated (the number of washing may be 2 to 10), followed by suction filtration. Preferably, the washing during the preparation of the mesoporous molecular sieve filter cake results in a filter cake pH of 7 and the washing during the preparation of the silica gel filter cake results in a sodium ion content of less than 0.02 wt.%.
According to the present invention, in the step (c), the amount of the mesoporous molecular sieve filter cake and the silica gel filter cake can be selected according to the components of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material expected to be obtained, and preferably, the weight ratio of the amount of the mesoporous molecular sieve filter cake to the silica gel filter cake is 1: 1-3.
According to the invention, in order to enable the finally prepared spherical aluminum-containing mesoporous molecular sieve silica gel composite material to contain the aluminum component with the content, so as to improve the mechanical strength of the composite material, prevent powder segregation after ball milling on the basis of not damaging or basically not damaging a carrier structure and enabling silica gel to enter a carrier pore channel, in the step (c), the specific operation method and conditions of the ball milling are preferably carried out in a high-aluminum ceramic ball milling tank, wherein the diameter of a milling ball in the high-aluminum ceramic ball milling tank can be 2-3 mm; the number of the grinding balls can be reasonably selected according to the size of the high-alumina ceramic ball-milling tank, and 1 grinding ball can be generally used for the high-alumina ceramic ball-milling tank with the size of 50-150 mL; the grinding balls are made of high-alumina ceramic balls. The high-alumina ceramic ball milling conditions comprise: the rotation speed of the grinding ball can be 300-.
In the present invention, the process of slurrying the solid powder obtained after ball milling with water may be performed at 25 to 60 ℃. The weight ratio of solid powder to water used in the pulping process may be 1:0.5-5, preferably 1: 1-2.
In the present invention, the specific operation method and conditions of the spray drying are conventional in the art. Specifically, a slurry prepared from the solid powder and water is added into an atomizer and rotated at a high speed to realize spray drying. Wherein the spray drying conditions comprise: the temperature can be 100-300 ℃, and the rotating speed can be 10000-15000 r/min; preferably, the spray drying conditions include: the temperature is 150-250 ℃, and the rotating speed is 11000-13000 r/min; most preferably, the spray drying conditions include: the temperature is 200 ℃, and the rotating speed is 12000 r/min.
According to the invention, the method for removing the template agent is generally a calcination method. The conditions for removing the template agent may be selected conventionally in the art, and for example, the conditions for removing the template agent include: the temperature can be 300-600 ℃, preferably 350-550 ℃, and most preferably 500 ℃; the time may be 10 to 80 hours, preferably 20 to 30 hours, most preferably 24 hours.
The invention also provides a propane dehydrogenation catalyst prepared by the method.
The invention also provides a method for preparing propylene by propane dehydrogenation, which comprises the following steps: carrying out dehydrogenation reaction on propane in the presence of a catalyst and hydrogen, wherein the catalyst is the propane dehydrogenation catalyst.
According to the present invention, in order to improve the propane conversion and prevent the catalyst from coking, it is preferable that the molar ratio of the amount of propane to the amount of hydrogen is from 0.5 to 1.5: 1.
the conditions for the dehydrogenation reaction in the present invention are not particularly limited and may be conventionally selected in the art, and for example, the conditions for the dehydrogenation reaction may include: the reaction temperature is 600-650 ℃, the reaction pressure is 0.05-0.2MPa, the reaction time is 40-60h, and the propane mass space velocity is 2-5h-1。
The present invention will be described in detail below by way of examples.
In the following examples and comparative examples, polyoxyethylene-polyoxypropylene-polyoxyethylene, available from Aldrich, abbreviated as P123, and having the formula EO20PO70EO20The substance having a registration number of 9003-11-6 in the American chemical Abstract had an average molecular weight Mn of 5800.
In the following examples and comparative examples, X-ray diffraction analysis was carried out on an X-ray diffractometer, model D8Advance, available from Bruker AXS, Germany; scanning electron microscopy analysis was performed on a scanning electron microscope, model XL-30, available from FEI, USA; pore structure parameter analysis was performed on an ASAP2020-M + C adsorption apparatus manufactured by Micromeritics, USA; the specific surface area and the pore volume of the sample are calculated by adopting a BET method; the result of the aluminum content is measured by a photoelectron spectrum analyzer; the particle size distribution of the sample is carried out on a Malvern laser particle sizer; the rotary evaporator is produced by German IKA company, and the model is RV10 digital; the active component loading of the propane dehydrogenation catalyst was measured on a wavelength dispersive X-ray fluorescence spectrometer, model Axios-Advanced, available from parnacco, netherlands; analysis of the reaction product composition was performed on a gas chromatograph available from Agilent under model 7890A.
In the following experimental examples and experimental comparative examples, the conversion (%) of propane is ═ amount of propane-content of propane in the reaction product ÷ amount of propane used × 100%;
selectivity (%) of propylene ÷ actual yield of propylene ÷ theoretical yield of propylene × 100%.
Example 1
This example illustrates a propane dehydrogenation catalyst and a method for its preparation.
(1) Preparation of the support
Dissolving 6g (0.001mol) of triblock copolymer template agent P123 in 10mL of concentrated hydrochloric acid and 220mL of deionized water solution, stirring for 4h at 15 ℃ to dissolve the P123 to form a transparent solution, adding 6g (0.08mol) of n-butanol into the solution, stirring for 1h, then placing the solution in a water bath at 30 ℃, slowly dropwise adding 12.9g (0.062mol) of ethyl orthosilicate at the speed of 1g/min, stirring for 24h under the conditions that the temperature is kept at 30 ℃ and the pH value is 4.5, then performing hydrothermal treatment for 24h at 100 ℃, finally repeatedly washing with deionized water after filtration, and performing suction filtration to obtain a filter cake A1 of the mesoporous molecular sieve material with the three-dimensional cubic pore structure.
Mixing 15 wt% of water glass, 12 wt% of sulfuric acid solution and n-butyl alcohol according to the weight ratio of water glass, sulfuric acid and n-butyl alcohol of 5: 1:1, stirring and reacting for 1.5h at 15 ℃, adjusting the pH value of the obtained reaction product to 3 by using sulfuric acid with the concentration of 98 weight percent, and then carrying out suction filtration and washing with distilled water until the content of sodium ions is 0.02 weight percent to obtain a silica gel filter cake B1.
And (2) putting 20g of the prepared filter cake A1 and 20g of the prepared filter cake B1 into a 100mL high-alumina ceramic ball milling tank (wherein the high-alumina ceramic ball milling tank is made of high-alumina ceramic, the diameter of the grinding balls is 3mm, the number of the grinding balls is 1, and the rotating speed is 400r/min), sealing the high-alumina ceramic ball milling tank, and carrying out high-alumina ceramic ball milling for 1h at the temperature of 60 ℃ in the high-alumina ceramic ball milling tank to obtain 40g of solid powder. Dissolving the solid powder in 30g of deionized water, carrying out spray drying at the temperature of 200 ℃ and the rotating speed of 12000r/min, and then calcining a product obtained after spray drying in a muffle furnace at the temperature of 500 ℃ for 24h to remove a template agent to obtain a target product of 30g of template agent-removed spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 with a high-strength large-hole three-dimensional cubic pore channel. According to the result of photoelectron spectroscopy, the content of aluminum in C1 was 6% by weight.
(2) Preparation of propane dehydrogenation catalyst
Calcining 30g of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 obtained in the step (1) at 400 ℃ for 10h under the protection of nitrogen for thermal activation treatment, and removing hydroxyl and residual moisture of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1;
0.08g H2PtCl6·6H2O、0.207g SnCl4·5H2O and 0.185g NaNO3Dissolving the spherical aluminum-containing mesoporous molecular sieve silica gel composite material subjected to thermal activation treatment in 100ml of deionized water to obtain a mixture solution, soaking the mixture solution at 25 ℃ for 5 hours, evaporating solvent water in a system by using a rotary evaporator to obtain a solid product, placing the solid product in a drying box at the temperature of 120 ℃, drying the solid product for 3 hours, then placing the dried solid product in a muffle furnace at the temperature of 600 ℃, and roasting the dried solid product for 6 hours to obtain the propane dehydrogenation catalyst Cat-1 (based on the total weight of the propane dehydrogenation catalyst Cat-1, the content of the Pt component in terms of the Pt element is 0.3 wt%, the content of the Sn component in terms of the Sn element is 0.7 wt%, the content of the Na component in terms of the Na element is 0.5 wt%, and the balance is a carrier).
The spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 and the propane dehydrogenation catalyst Cat-1 are characterized by an XRD, a scanning electron microscope and an ASAP2020-M + C type adsorption instrument;
fig. 1 is an X-ray diffraction (XRD) spectrum of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1, wherein the abscissa is 2 θ and the ordinate is intensity, and the XRD spectrum of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 has a three-dimensional cubic pore structure specific to a mesoporous material, as can be seen from a small-angle spectrum peak appearing in the XRD spectrum;
fig. 2 is an SEM scanning electron microscope image of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1, and it can be seen from the image that the microscopic morphology of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 is microspheres with a particle size of 10-80 μm, and the monodispersity thereof is good.
Table 1 shows the pore structure parameters of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 and the propane dehydrogenation catalyst Cat-1.
TABLE 1
*: the first most probable aperture and the second most probable aperture are separated by a comma: the first most probable aperture and the second most probable aperture are arranged in the order from left to right.
As can be seen from the data of table 1, the specific surface area and pore volume of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 as a support were reduced after supporting the main active Pt component, the auxiliary Sn component and the auxiliary Na component, which indicates that the main active Pt component, the auxiliary Sn component and the auxiliary Na component entered the interior of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C1 during the supporting reaction.
Comparative example 1
This comparative example serves to illustrate a reference propane dehydrogenation catalyst and a method of making the same.
The carrier and the propane dehydrogenation catalyst were prepared according to the method of example 1, except that a mesoporous molecular sieve having a three-dimensional cubic pore distribution structure was not added in the process of preparing the carrier, thereby preparing the carrier D1 and the propane dehydrogenation catalyst Cat-D-1, respectively.
Comparative example 2
This comparative example serves to illustrate a reference propane dehydrogenation catalyst and a method of making the same.
A carrier and a propane dehydrogenation catalyst were prepared according to the method of example 1, except that no silica gel was added during the preparation of the carrier, thereby preparing a carrier D2 and a propane dehydrogenation catalyst Cat-D-2, respectively.
Comparative example 3
This comparative example serves to illustrate a reference propane dehydrogenation catalyst and a method of making the same.
The carrier and the propane dehydrogenation catalyst were prepared according to the method of example 1, except that no aluminum component was introduced during the preparation of the carrier, the material of the ball mill pot used during the ball milling was polytetrafluoroethylene, and the material of the milling balls was agate, thereby obtaining the carrier D3 and the propane dehydrogenation catalyst Cat-D-3, respectively.
Comparative example 4
This comparative example serves to illustrate a reference propane dehydrogenation catalyst and a method of making the same.
A carrier and a propane dehydrogenation catalyst were prepared according to the method of example 1, except that during the impregnation process for preparing the propane dehydrogenation catalyst, NaNO was not added3Addition of only 0.133g H2PtCl6·6H2O and 0.295g SnCl4·5H2And O, loading an active component Pt and a metal auxiliary agent Sn on the spherical aluminum-containing mesoporous molecular sieve silica gel composite material serving as the carrier after thermal activation by a co-impregnation method to prepare the propane dehydrogenation catalyst Cat-D-4, wherein the content of the Pt component in terms of Pt element is 0.5 wt%, the content of the Sn component in terms of Sn element is 1 wt% and the balance is the carrier, based on the total weight of the propane dehydrogenation catalyst Cat-D-4).
Comparative example 5
A carrier and a propane dehydrogenation catalyst were prepared according to the method of example 1, except that there was no spray-drying step in the preparation of the carrier, and a Pt component, a Sn component, and a Na component were supported on a spherical aluminum-containing mesoporous molecular sieve silica gel composite as a carrier only by the impregnation method, thereby preparing a propane dehydrogenation catalyst Cat-D-5.
Example 2
This example illustrates a propane dehydrogenation catalyst and a method for its preparation.
(1) Preparation of the support
Dissolving 6g (0.001mol) of triblock copolymer template agent P123 in 10mL of concentrated hydrochloric acid and 220mL of deionized water solution, stirring for 4h at 15 ℃ to dissolve the P123 to form a transparent solution, adding 4.5g (0.06mol) of n-butyl alcohol into the solution, stirring for 1h, then placing the solution in a water bath at 30 ℃, slowly dropwise adding 10.4g (0.05mol) of tetraethoxysilane at the speed of 1g/min, stirring for 10h under the conditions that the temperature is kept at 60 ℃ and the pH value is 6, then performing hydrothermal treatment for 24h at 150 ℃, finally repeatedly washing with deionized water after filtration, and obtaining a filter cake A2 of the mesoporous molecular sieve material with the three-dimensional cubic pore structure after suction filtration.
Mixing 15 wt% of water glass, 12 wt% of sulfuric acid solution and n-butyl alcohol according to the weight ratio of the water glass to the sulfuric acid to the n-butyl alcohol of 6:1:1, stirring and reacting for 1h at 60 ℃, adjusting the pH value of the obtained reaction product to 2 by using sulfuric acid with the concentration of 98 weight percent, and then carrying out suction filtration and washing with distilled water until the content of sodium ions is 0.02 weight percent to obtain a silica gel filter cake B2.
And (2) putting 20g of the prepared filter cake A2 and 40g of the prepared filter cake B2 into a 100mL high-alumina ceramic ball milling tank (wherein the high-alumina ceramic ball milling tank is made of high-alumina ceramic, the diameter of the grinding balls is 3mm, the number of the grinding balls is 1, and the rotating speed is 300r/min), sealing the high-alumina ceramic ball milling tank, and carrying out high-alumina ceramic ball milling for 0.5h at the temperature of 100 ℃ in the high-alumina ceramic ball milling tank to obtain 40g of solid powder. Dissolving the solid powder in 30g of deionized water, carrying out spray drying at the temperature of 150 ℃ and the rotating speed of 11000r/min, and then calcining a product obtained after spray drying in a muffle furnace at the temperature of 300 ℃ for 72 hours to remove a template agent to obtain a target product of 35g of template agent-removed spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2 with a high-strength large-hole three-dimensional cubic pore channel. According to the result of photoelectron spectroscopy, the content of aluminum in C2 was 9% by weight.
(2) Preparation of propane dehydrogenation catalyst
Calcining 35g of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2 obtained in the step (1) at 400 ℃ for 10h under the protection of nitrogen for thermal activation treatment, and removing hydroxyl and residual moisture of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2;
0.08g H2PtCl6·6H2O、0.207g SnCl4·5H2O and 0.185g NaNO3Dissolving the spherical aluminum-containing mesoporous molecular sieve silica gel composite material subjected to thermal activation treatment in 100ml of deionized water to obtain a mixture solution, soaking the mixture solution at 25 ℃ for 5 hours, evaporating solvent water in a system by using a rotary evaporator to obtain a solid product, placing the solid product in a drying box at the temperature of 120 ℃, drying the solid product for 3 hours, then placing the dried solid product in a muffle furnace at the temperature of 600 ℃, and roasting the dried solid product for 6 hours to obtain the propane dehydrogenation catalyst Cat-2 (based on the total weight of the propane dehydrogenation catalyst Cat-2, the content of the Pt component in terms of the Pt element is 0.3 wt%, the content of the Sn component in terms of the Sn element is 0.7 wt%, the content of the Na component in terms of the Na element is 0.5 wt%, and the balance is a carrier).
The spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2 and the propane dehydrogenation catalyst Cat-2 are characterized by an XRD, a scanning electron microscope and an ASAP2020-M + C type adsorption instrument;
table 2 shows the pore structure parameters of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2 and the propane dehydrogenation catalyst Cat-2.
TABLE 2
*: the first most probable aperture and the second most probable aperture are separated by a comma: the first most probable aperture and the second most probable aperture are arranged in the order from left to right.
As can be seen from the data of table 2, the specific surface area and pore volume of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2 as a carrier were reduced after supporting the main active Pt component, the auxiliary Sn component and the auxiliary Na component, which indicates that the main active Pt component, the auxiliary Sn component and the auxiliary Na component entered the interior of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C2 during the supporting reaction.
Example 3
This example illustrates a propane dehydrogenation catalyst and a method for its preparation.
(1) Preparation of the support
Dissolving 6g (0.001mol) of triblock copolymer template agent P123 in 10mL of concentrated hydrochloric acid and 220mL of deionized water solution, stirring for 4h at 15 ℃ to dissolve the P123 to form a transparent solution, adding 6.75g (0.09mol) of n-butyl alcohol into the solution, stirring for 1h, placing the solution in a water bath at 30 ℃, slowly dropwise adding 15.6g (0.075mol) of ethyl orthosilicate at the rate of 1g/min, stirring for 72h under the condition that the temperature is kept at 10 ℃ and the pH value is 1, then performing hydrothermal treatment for 72h at 30 ℃, repeatedly washing with deionized water after filtration, and performing suction filtration to obtain a filter cake A3 of the mesoporous molecular sieve material with the three-dimensional cubic pore structure.
Mixing 15 wt% of water glass, 12 wt% of sulfuric acid solution and n-butyl alcohol according to the weight ratio of water glass, sulfuric acid and n-butyl alcohol of 3: 1:1, stirring and reacting for 5 hours at 10 ℃, adjusting the pH value of the obtained reaction product to 4 by using sulfuric acid with the concentration of 98 weight percent, and then carrying out suction filtration and washing with distilled water until the content of sodium ions is 0.02 weight percent to obtain a silica gel filter cake B3.
And (2) putting 20g of the prepared filter cake A3 and 60g of the prepared filter cake B3 into a 100mL high-alumina ceramic ball milling tank (wherein the high-alumina ceramic ball milling tank is made of high-alumina ceramic, the diameter of the grinding balls is 3mm, the number of the grinding balls is 1, and the rotating speed is 500r/min), sealing the high-alumina ceramic ball milling tank, and carrying out high-alumina ceramic ball milling for 10 hours at the temperature of 25 ℃ in the high-alumina ceramic ball milling tank to obtain 40g of solid powder. Dissolving the solid powder in 30g of deionized water, carrying out spray drying at 300 ℃ and 13000r/min of rotation speed, and then calcining the product obtained after spray drying in a 600 ℃ muffle furnace for 12h to remove the template agent to obtain 30g of a target product of the template agent-removed spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3 with high-strength large-hole three-dimensional cubic pore channels. According to the results of photoelectron spectroscopy, the content of aluminum in C3 was 15% by weight.
(2) Preparation of propane dehydrogenation catalyst
Calcining 30g of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3 obtained in the step (1) at 400 ℃ for 10h under the protection of nitrogen for thermal activation treatment, and removing hydroxyl and residual moisture of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3;
0.08g H2PtCl6·6H2O、0.207g SnCl4·5H2O and 0.185g NaNO3Dissolving the spherical aluminum-containing mesoporous molecular sieve silica gel composite material subjected to thermal activation treatment in 100ml of deionized water to obtain a mixture solution, soaking the mixture solution at 25 ℃ for 5 hours, evaporating solvent water in a system by using a rotary evaporator to obtain a solid product, placing the solid product in a drying box at the temperature of 120 ℃, drying the solid product for 3 hours, then placing the dried solid product in a muffle furnace at the temperature of 600 ℃, and roasting the dried solid product for 6 hours to obtain the propane dehydrogenation catalyst Cat-3 (based on the total weight of the propane dehydrogenation catalyst Cat-3, the content of the Pt component in terms of the Pt element is 0.3 wt%, the content of the Sn component in terms of the Sn element is 0.7 wt%, the content of the Na component in terms of the Na element is 0.5 wt%, and the balance is a carrier).
The spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3 and the propane dehydrogenation catalyst Cat-3 are characterized by an XRD, a scanning electron microscope and an ASAP2020-M + C type adsorption instrument;
table 3 shows the pore structure parameters of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3 and the propane dehydrogenation catalyst Cat-3.
TABLE 3
*: the first most probable aperture and the second most probable aperture are separated by a comma: the first most probable aperture and the second most probable aperture are arranged in the order from left to right.
As can be seen from the data of table 3, the specific surface area and pore volume of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3 as a support were reduced after supporting the main active Pt component, the auxiliary Sn component and the auxiliary Na component, which indicates that the main active Pt component, the auxiliary Sn component and the auxiliary Na component entered the interior of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material C3 during the supporting reaction.
Experimental example 1
This example is intended to illustrate the preparation of propylene using the propane dehydrogenation catalyst of the present invention
0.5g of propane dehydrogenation catalyst Cat-1 was charged into a fixed bed quartz reactor, the reaction temperature was controlled at 610 ℃, the reaction pressure was 0.1MPa, and the molar ratio of propane: the molar ratio of hydrogen is 1:1, the reaction time is 50h, and the mass space velocity of propane is 3h-1. Propane conversion and propylene selectivity are shown in table 4.
Experimental examples 2 to 3
Propane dehydrogenation was carried out to produce propylene in accordance with the procedure of experimental example 1, except that the propane dehydrogenation catalyst Cat-1 was replaced with the propane dehydrogenation catalyst Cat-2 and the propane dehydrogenation catalyst Cat-3, respectively. Propane conversion and propylene selectivity are shown in table 4.
Experimental comparative examples 1 to 5
Propane dehydrogenation was carried out to produce propylene in the same manner as in Experimental example 1, except that propane dehydrogenation catalysts Cat-D-1 to Cat-D-5 were used in place of propane dehydrogenation catalyst Cat-1. Propane conversion and propylene selectivity are shown in table 4.
TABLE 4
As can be seen from Table 4, the propane dehydrogenation catalyst prepared by using the spherical aluminum-containing mesoporous molecular sieve silica gel composite material of the present invention has high compressive strength, and when the catalyst is used in a reaction for preparing propylene by propane dehydrogenation, a high propane conversion rate and propylene selectivity can be obtained after 50 hours of reaction, which indicates that the propane dehydrogenation catalyst of the present invention not only has good catalytic performance, but also has excellent stability.
The preferred embodiments of the present invention have been described above in detail, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, many simple modifications can be made to the technical solution of the invention, including combinations of various technical features in any other suitable way, and these simple modifications and combinations should also be regarded as the disclosure of the invention, and all fall within the scope of the invention.
Claims (12)
1. The propane dehydrogenation catalyst is characterized by comprising a carrier, and a Pt component, a Sn component and a Na component which are loaded on the carrier, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum component, a mesoporous molecular sieve material with a three-dimensional cubic pore structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 mu m, and the specific surface area is 100-180m2The pore volume is 0.5-2mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 30-40nm respectively;
wherein the forming method of the carrier comprises the following steps:
(a) in the presence of a template agent and butanol, a silicon source is contacted with an acid agent, and the mixture obtained after the contact is crystallized and filtered in sequence to obtain a filter cake of the mesoporous molecular sieve;
(b) contacting water glass with inorganic acid and n-butyl alcohol, and filtering a mixture obtained after the contact to obtain a silica gel filter cake;
(c) mixing the mesoporous molecular sieve filter cake and the silica gel filter cake, carrying out ball milling in a high-alumina ceramic tank, pulping solid powder obtained after ball milling by using water, carrying out spray drying on the obtained slurry, and removing the template agent from the obtained product.
2. The propane dehydrogenation catalyst of claim 1, wherein the support is present in an amount of 97.5 to 99.3 wt.%, the Pt component is present in an amount of 0.2 to 0.5 wt.% as Pt element, the Sn component is present in an amount of 0.2 to 1.2 wt.% as Sn element, and the Na component is present in an amount of 0.3 to 0.8 wt.% as Na element, based on the total weight of the propane dehydrogenation catalyst;
and/or the compressive strength of the carrier is 14-16MPa, the average particle size is 30-60 mu m, and the specific surface area is 100-170m2Pore volume of 0.8-1.8mL/g, and bimodal distribution with comparable maximum pore diameters of 4-8nm and 32-39nm, respectively.
3. The propane dehydrogenation catalyst according to claim 1, wherein the content of the aluminum component is 1 to 20 parts by weight and the content of the silica gel is 1 to 90 parts by weight with respect to 100 parts by weight of the mesoporous molecular sieve material having a three-dimensional cubic pore channel structure.
4. The propane dehydrogenation catalyst according to claim 3, wherein the content of the aluminum component is 5 to 19 parts by weight and the content of the silica gel is 2 to 85 parts by weight with respect to 100 parts by weight of the mesoporous molecular sieve material having a three-dimensional cubic pore channel structure.
5. A process for preparing a propane dehydrogenation catalyst, the process comprising: carrying out heat activation on a carrier, then carrying out immersion treatment in a mixed solution containing a Pt component precursor, a Sn component precursor and a Na component precursor, and then sequentially carrying out solvent removal treatment, drying and roasting, wherein the carrier is a spherical aluminum-containing mesoporous molecular sieve silica gel composite material, the spherical aluminum-containing mesoporous molecular sieve silica gel composite material contains an aluminum component, a mesoporous molecular sieve material with a three-dimensional cubic pore structure and silica gel, the compressive strength of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 12-16MPa, the average particle size is 10-80 mu m, and the specific surface area is 100-180 m-2The pore volume is 0.5-2mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 30-40nm respectively;
wherein the forming method of the carrier comprises the following steps:
(a) in the presence of a template agent and butanol, a silicon source is contacted with an acid agent, and the mixture obtained after the contact is crystallized and filtered in sequence to obtain a filter cake of the mesoporous molecular sieve;
(b) contacting water glass with inorganic acid and n-butyl alcohol, and filtering a mixture obtained after the contact to obtain a silica gel filter cake;
(c) mixing the mesoporous molecular sieve filter cake and the silica gel filter cake, carrying out ball milling in a high-alumina ceramic tank, pulping solid powder obtained after ball milling by using water, carrying out spray drying on the obtained slurry, and removing the template agent from the obtained product.
6. The method according to claim 5, wherein the support, the Pt component precursor, the Sn component precursor and the Na component precursor are used in amounts such that the propane dehydrogenation catalyst is prepared in which the support is contained in an amount of 97.5 to 99.3% by weight, the Pt component is contained in an amount of 0.2 to 0.5% by weight in terms of Pt element, the Sn component is contained in an amount of 0.2 to 1.2% by weight in terms of Sn element, and the Na component is contained in an amount of 0.3 to 0.8% by weight in terms of Na element, based on the total weight of the propane dehydrogenation catalyst;
and/or the compressive strength of the carrier is 14-16MPa, the average particle size of the spherical aluminum-containing mesoporous molecular sieve silica gel composite material is 30-60 mu m, and the specific surface area is 100-170m2The pore volume is 0.8-1.8mL/g, the pore diameter is in bimodal distribution, and the most probable pore diameters corresponding to the bimodal distribution are 4-8nm and 32-39nm respectively;
and/or, the conditions of thermal activation include: the temperature is 300-900 ℃ and the time is 7-10 h; the conditions of the impregnation treatment include: the temperature is 25-50 ℃ and the time is 2-6 h.
7. The method of claim 5, wherein, in the step (a), the templating agent, butanol and silicon source are used in a molar ratio of 1:10-100: 10-90;
and/or the template agent is triblock copolymer polyoxyethylene-polyoxypropylene-polyoxyethylene, the acid agent is hydrochloric acid, and the silicon source is at least one of ethyl orthosilicate, methyl orthosilicate, propyl orthosilicate, sodium orthosilicate and silica sol;
and/or, the contacting conditions include: the temperature is 25-60 ℃, the time is 10-72h, the pH value is 1-6, and the crystallization conditions comprise: the temperature is 30-150 ℃ and the time is 10-72 h.
8. The method of claim 7, wherein in step (a), the templating agent, butanol, and silicon source are used in a molar ratio of 1: 60-90: 50-75.
9. The preparation method according to claim 5 or 7, wherein, in the step (b), the conditions under which the water glass, the inorganic acid and the n-butanol are contacted include: the weight ratio of the water glass to the inorganic acid to the n-butyl alcohol is 3-6:1:1, the temperature is 10-60 ℃, the time is 1-5 hours, and the pH value is 2-4; the inorganic acid is one or more of sulfuric acid, nitric acid and hydrochloric acid;
and/or, in the step (c), the weight ratio of the dosage of the spherical mesoporous molecular sieve filter cake to the dosage of the silica gel filter cake is 1: 1-3;
and/or the conditions for ball milling in the high-alumina ceramic pot comprise: the rotation speed of the grinding ball is 300-; the conditions of the spray drying include: the temperature is 100-300 ℃, and the rotating speed is 10000-15000 r/min;
and/or the template agent removing process comprises the following steps: calcining at 600 ℃ for 10-80 h.
10. A propane dehydrogenation catalyst prepared by the process of any of claims 5-9.
11. A method for producing propylene by propane dehydrogenation, comprising: the dehydrogenation of propane in the presence of a catalyst and hydrogen, characterized in that the catalyst is a propane dehydrogenation catalyst according to any one of claims 1 to 4 and 10.
12. The process according to claim 11, wherein the molar ratio of the amount of propane to the amount of hydrogen is between 0.5 and 1.5: 1;
and/or, the dehydrogenation reaction conditions include: the reaction temperature is 600-650 ℃, the reaction pressure is 0.05-0.2MPa, the reaction time is 40-60h, and the propane mass space velocity is 2-5h-1。
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