CN109734991A - A kind of self-extinguishment plastics - Google Patents

A kind of self-extinguishment plastics Download PDF

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Publication number
CN109734991A
CN109734991A CN201910028081.9A CN201910028081A CN109734991A CN 109734991 A CN109734991 A CN 109734991A CN 201910028081 A CN201910028081 A CN 201910028081A CN 109734991 A CN109734991 A CN 109734991A
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CN
China
Prior art keywords
plastics
parts
extinguishment
self
magnesium carbonate
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Pending
Application number
CN201910028081.9A
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Chinese (zh)
Inventor
曹大力
丁涵
刘凯林
范怡宁
李英
牟兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenyang University of Chemical Technology
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Shenyang University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Shenyang University of Chemical Technology filed Critical Shenyang University of Chemical Technology
Priority to CN201910028081.9A priority Critical patent/CN109734991A/en
Publication of CN109734991A publication Critical patent/CN109734991A/en
Pending legal-status Critical Current

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Abstract

A kind of self-extinguishment plastics, are related to a kind of flame-retarded plastic, and the self-extinguishment plastics are formulated in mass ratio are as follows: 100 parts of plastic raw materials;120-175 parts of light magnesium carbonate;And/or 0.2-1 parts of antioxidant;And/or 1-3 parts of lubricant;Plastic raw materials, light magnesium carbonate, and/or antioxidant, and/or lubricant are kneaded according to formula, are granulated or are made product after mixing.Fireproof self-extinguishment plastics will be made after plastics, light magnesium carbonate, and/or antioxidant, and/or lubricant mixing in the present invention, can be used for building materials and cable material.

Description

A kind of self-extinguishment plastics
Technical field
The present invention relates to a kind of flame-retarded plastics, more particularly to a kind of self-extinguishment plastics.
Background technique
With the sharp increase of urban population, skyscraper, hotel, large supermarket, hospital, station, airport are continuous Increase, subway, tunnel and large-scale place of public amusement, public transit facility are also sharply being increased, the importance of security against fire It shows especially out;In particular how in the case of fire, guarantee house security within a certain period of time and ensure electric power and communication It is unimpeded, it tries to gain time precious to one to greatest extent, reduces the injures and deaths of personnel and the loss of lives and properties, be that people constantly explore Project.
The cigarette poison harmfulness generated in fire mainly toxic property, dim light, phobic, smoke damage, environmental pollution.And The harm that drop combustion occurs after combustion for plastics shows further expansion fire dangerous situation, and rescue difficulty is enabled to increase.
Therefore introducing self-extinguishment fireproofing technique in the plastic seems non-to reach the harm such as reduction cigarette poison, drop combustion and Plastics Combustion Often important, self-extinguishment plastics can automatically extinguish the plastics of burning, will be minimized the danger in household.
Summary of the invention
The purpose of the present invention is to provide a kind of self-extinguishment plastics, the present invention by plastics, light magnesium carbonate, and/or antioxidant, And/or fireproof self-extinguishment plastics are made after lubricant mixing, it can be used for building materials and cable material.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of self-extinguishment plastics, the self-extinguishment plastics are formulated in mass ratio are as follows:
100 parts of plastic raw materials;
120-175 parts of light magnesium carbonate;
And/or 0.2-1 parts of antioxidant;
And/or 1-3 parts of lubricant;
Plastic raw materials, light magnesium carbonate, and/or antioxidant, and/or lubricant are kneaded according to formula, is granulated or makes after mixing At product.
A kind of self-extinguishment plastics, the plastics include EVA, polyolefin, ABS, PE, PVC, PS, PMMA.
A kind of self-extinguishment plastics, the molecular formula of the light magnesium carbonate are MgCO3, greater than 90.0%, granularity is purity 200-100 nanometers of mesh.
The advantages and effects of the present invention are:
The present invention has simple production process, and product has excellent self-extinguishment, can meet industrialized mass production requirement;It produces The source of product is wide, cheap, greatly reduces plastics overall cost, improves product competitiveness.The present invention can make burning Plastics self-extinguishment reduces hidden fire-fighting danger.It can be used for building materials and cable material.
Specific embodiment
The following describes the present invention in detail with reference to examples.
Embodiment 1
The principal crystalline phase for selecting XRD test is MgCO3, purity is light magnesium carbonate that 98.5% granularity is 2-200 microns.
By EVA100 parts, 120-175 parts of light magnesium carbonate, 0.2-1 parts of antioxidant, 1-3 parts of lubricant, at 140-150 DEG C Under the conditions of in open mill mix 10-30 min, when be kneaded complete after discharging, by double-cone feeding system to twin-screw extrusion Machine finally enters single screw rod extruding pelletization, then cuts out sample with vulcanizing press with 140-150 DEG C of 15 ~ 20 min of constant temperature tabletting Sample, test performance.
Embodiment 2
The principal crystalline phase for selecting XRD test is MgCO3, purity be light magnesium carbonate that 90.0% granularity is -1000 mesh of 200 mesh.
By ABS100 parts, 120-175 parts of light magnesium carbonate, 0.2-1 parts of antioxidant, 1-3 parts of lubricant, in 170 DEG C of conditions Under 10-30 min is mixed in mixer, then with vulcanizing press with 170 DEG C of 15 ~ 20 min of constant temperature tabletting, cut out all Product, test performance.
Embodiment 3
The principal crystalline phase for selecting XRD test is MgCO3, purity be light magnesium carbonate that 95.0% granularity is 325-1400 mesh.
By PE100 parts, 120-175 parts of light magnesium carbonate, 0.2-1 parts of antioxidant, 1-3 parts of lubricant, under the conditions of 150 DEG C 10-30 min is mixed in open mill, and all product are then cut out with 220 DEG C of 15 ~ 20 min of constant temperature tabletting with vulcanizing press, Test performance.
Embodiment 4
The principal crystalline phase for selecting XRD test is MgCO3, purity be light magnesium carbonate that 98.5% granularity is 30-200 microns.
By 100 parts of polyolefin, 150-175 parts of light magnesium carbonate, 10- is mixed in mixer under the conditions of 140-150 DEG C 30 min discharge after being kneaded, by double-cone feeding system to double screw extruder, finally enter single screw rod extruding pelletization, so All product, test performance are cut out with 140-150 DEG C of 15 ~ 20 min of constant temperature tabletting with vulcanizing press afterwards.
Embodiment 5
The principal crystalline phase for selecting XRD test is MgCO3, purity be light magnesium carbonate that 90.0% granularity is 100 nanometers -2 microns.
By PVC100 parts, 120-175 parts of light magnesium carbonate, 1-3 parts of lubricant, mixed in open mill under the conditions of 120 DEG C 10-30 min is closed, all product, test performance are then cut out with 140 DEG C of 15 ~ 20 min of constant temperature tabletting with vulcanizing press.
Embodiment 6
The principal crystalline phase for selecting XRD test is MgCO3, purity be light magnesium carbonate that 99.0% granularity is 325-1400 mesh.
By 100 parts of PMMA, 120-175 parts of light magnesium carbonate, 1-3 parts of lubricant, under the conditions of 110 DEG C in open mill 10-30 min is mixed, all product, test performance are then cut out with 150 DEG C of 15 ~ 20 min of constant temperature tabletting with vulcanizing press.
Embodiment 7
The principal crystalline phase for selecting XRD test is MgCO3, purity be light magnesium carbonate that 100.0% granularity is 325-1400 mesh.
By 100 parts of PS, 160 parts of light magnesium carbonate, 1 part of lubricant, 10-30 is mixed in mixer under the conditions of 250 DEG C Then min cuts out all product, test performance with vulcanizing press with 250 DEG C of 15 ~ 20 min of constant temperature tabletting.

Claims (3)

1. a kind of self-extinguishment plastics, which is characterized in that the self-extinguishment plastics are formulated in mass ratio are as follows:
100 parts of plastic raw materials;
120-175 parts of light magnesium carbonate;
And/or 0.2-1 parts of antioxidant;
And/or 1-3 parts of lubricant;
Plastic raw materials, light magnesium carbonate, and/or antioxidant, and/or lubricant are kneaded according to formula, is granulated or makes after mixing At product.
2. a kind of self-extinguishment plastics according to claim 1, which is characterized in that the plastics include EVA, polyolefin, ABS, PE、PVC、PS、PMMA。
3. a kind of self-extinguishment plastics according to claim 1, which is characterized in that the molecular formula of the light magnesium carbonate is MgCO3, for purity greater than 90.0%, granularity is -100 nanometers of 200 mesh.
CN201910028081.9A 2019-01-11 2019-01-11 A kind of self-extinguishment plastics Pending CN109734991A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910028081.9A CN109734991A (en) 2019-01-11 2019-01-11 A kind of self-extinguishment plastics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910028081.9A CN109734991A (en) 2019-01-11 2019-01-11 A kind of self-extinguishment plastics

Publications (1)

Publication Number Publication Date
CN109734991A true CN109734991A (en) 2019-05-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910028081.9A Pending CN109734991A (en) 2019-01-11 2019-01-11 A kind of self-extinguishment plastics

Country Status (1)

Country Link
CN (1) CN109734991A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543281A (en) * 1982-05-07 1985-09-24 A/S Norsk Kabelfabrik Fire or flame barrier material
CN102070832A (en) * 2010-12-24 2011-05-25 中国地质大学(武汉) Flame-retardant polypropylene material and preparation method thereof
CN108727685A (en) * 2017-04-25 2018-11-02 武汉金发科技有限公司 A kind of halogen-free flame retardant polypropylene composite material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4543281A (en) * 1982-05-07 1985-09-24 A/S Norsk Kabelfabrik Fire or flame barrier material
CN102070832A (en) * 2010-12-24 2011-05-25 中国地质大学(武汉) Flame-retardant polypropylene material and preparation method thereof
CN108727685A (en) * 2017-04-25 2018-11-02 武汉金发科技有限公司 A kind of halogen-free flame retardant polypropylene composite material and preparation method thereof

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Application publication date: 20190510