CN109734916A - A kind of backbone chain type silicon Acrylote-zinc condensation polymer, hydrolyzable antifouling paint and preparation method thereof - Google Patents
A kind of backbone chain type silicon Acrylote-zinc condensation polymer, hydrolyzable antifouling paint and preparation method thereof Download PDFInfo
- Publication number
- CN109734916A CN109734916A CN201910042379.5A CN201910042379A CN109734916A CN 109734916 A CN109734916 A CN 109734916A CN 201910042379 A CN201910042379 A CN 201910042379A CN 109734916 A CN109734916 A CN 109734916A
- Authority
- CN
- China
- Prior art keywords
- chain type
- zinc
- backbone chain
- type silicon
- condensation polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to marine antifouling coating technical fields, and in particular to a kind of backbone chain type silicon Acrylote-zinc condensation polymer, hydrolyzable antifouling paint and preparation method thereof.Backbone chain type silicon Acrylote-zinc condensation polymer provided by the invention, first synthesizing organo-silicon oxygen alkanes acrylic acid, pass through organosiloxane class acrylic acid preparation synthesis backbone chain type silicon Acrylote-zinc condensation polymer of synthesis again, obtained backbone chain type silicon Acrylote-zinc condensation polymer can keep surface long term to stablize hydrolysis in the seawater, and has the advantages that low antifouling agent content/lower resistance using this polymer as coating prepared by film forming matter, it is low by seawater abrasion rear surface roughness, it is more smooth, seawater is advantageously reduced to its resistance, there is important application value.
Description
Technical field
The invention belongs to marine antifouling coating technical fields, and in particular to a kind of backbone chain type silicon Acrylote-zinc condensation polymer,
Hydrolyzable antifouling paint and preparation method thereof.
Background technique
Antifouling paint can save fuel oil to ship and reduce carbon emission, add anti-fouling agent antifouling paint be it is economical, can
Capable and effective method.But common film forming matter of the hydrolysis-type copolymer as coating usually contains a large amount of anti-fouling agents in formula,
This aspect increases the cost of coating and the burden of marine environment, on the other hand increases the roughness of coating surface in turn
Increase the oil consumption of ship.Therefore it is significant to seek a kind of low antifouling agent content/lower resistance antifouling paint, and as antifouling
Key technique-functional polymer of coating is the most effective means for realizing this target.
US5795374, publication date: 19980818, it discloses and is prevented by the ship of the polymer containing three Organosilyls
Dirt paint, but prepared thin polymer film hydrolysis rate is very low, is unable to satisfy the low antifouling painting of anti-fouling agent/lower resistance at all
The film forming matter requirement of material.
EP0802243B1, publication date: 20010627, in disclose a kind of anti-fouling paint, the anti-fouling paint has one
Plant Organosilyl acrylate based polymer adhesive and a kind of for improving the rosin compound of the hydrolysis rate of paint.
But surface is painted after one section of long period can occur to rupture and remove, this is mainly due to the variations on paint surface.
EP1208167B1, publication date: on 07 30th, 2003 and EP1476509A2, publication date: November 17 in 2004
Day, in addition fiber and methacrylate polymers are respectively adopted then to improve the mechanical performance of anti-fouling paint.However, it was found that throwing
Light and anti-pollution are difficult to keep for a long time, and the addition of side-chain hydrolysis characteristic and fiber causes surface coating roughness opposite
It is larger.
CN103131289B, publication date: on 06 05th, 2013, in Organosilyl acrylate and fluorine-containing (first
Base) acrylic ester copolymer carrys out the matrix resin obtained from polishing performance and low surface property, hydrophobic and oil repellent, but with this resin
The antifouling paint heavy dependence ship's speed of matrix preparation, the antifouling period is short, and static anti-fouling effect is undesirable.
US7045560B2, publication date: on May 16th, 2006, using containing metal-resin, as film forming matter, static state is antifouling
Effect is good, but anti-fouling agent additive amount is big, and coating surface is coarse to be unable to satisfy low anti-fouling agent/lower resistance antifouling paint film forming
Object requirement.
Hydrating polymer in the above patent is difficult to keep the hydrolysis property of stable uniform, and seawater for a long time
It is also relatively rough with the coating surface that the resin does film forming matter after washing away a period of time, it is unfavorable for preparing energy saving anti-drag type antifouling
Coating.
Summary of the invention
To solve the problems in above-mentioned background technique, the present invention provides a kind of backbone chain type silicon Acrylote-zinc condensation polymer, knot
Structure formula is as follows:
Wherein, R1For alkyl, hydroxyalkyl, carboxyalkyl or Asia at most 8 carbon atoms with 1-10 carbon atom
Oxyalkyl；
R2For alkyl, aryl or alkenyl, the R of different location2It may be the same or different；
R3、R4For alkyl, aryl, sealing end or uncapped polyoxyalkylene alkane, aryl, arylmethylene alkyl and alkenyl；
R5For the alkylidene with 1-14 carbon atom；
A is the integer of 0-100, and b is the integer of 0-50,0≤a+b≤100.
Further, backbone chain type silicon Acrylote-zinc condensation polymer molecular weight is 10000~60000, solid content 45%
~55%, viscosity is 500~5000mPas.
The present invention also provides a kind of preparation methods of backbone chain type silicon Acrylote-zinc condensation polymer, comprising the following steps:
Step a, synthesizing organo-silicon oxygen alkanes acrylic acid
Binary acid is dissolved in solvent B, the polysiloxanes of bisamination is added after mixing, acquired solution is heated to 50
DEG C~110 DEG C, and flow back 4~8 hours, supernatant is removed, subnatant is the organosiloxane class acrylic acid；
Step b, backbone chain type silicon Acrylote-zinc condensation polymer is synthesized
Solvent C and zinc oxide are packed into container, are heated to 70 DEG C~150 DEG C, the organic of step a preparation is added later
Type siloxane acrylic acid solution, and keep temperature conditioned response 6~12 hours, obtain pale yellow transparent substance, as backbone chain type
Silicon Acrylote-zinc condensation polymer；
Wherein, the solvent B and solvent C are polar solvent.
Further, in step a, the raw material including following parts by weight:
10~42 parts of binary acid
40~80 parts of solvent B
20~50 parts of the polysiloxanes of bisamination.
Further, in step a, the binary acid is that carbochain is no more than 16 binary acid, including malonic acid, succinic acid
With one of sebacic acid or a variety of mixing.
Further, in step b, the raw material including following parts by weight:
20~50 parts of organosiloxane class acrylic acid
10~42 parts of zinc oxide
30~60 parts of solvent C.
Further, the solvent B and solvent C include tetrahydrofuran, methanol, ethyl alcohol, butanone, N, N dimethyl formyl
Amine, the mixing of one or more of dimethyl sulfoxide.
The present invention also provides a kind of hydrolyzable antifouling paints, using any backbone chain type silicon Acrylote-zinc polycondensation as above
Object.
The preparation method of above-mentioned hydrolyzable antifouling paint, including following preparation step: by the backbone chain type silicon Acrylote-
Zinc condensation polymer, pigments and fillers, organic solvent, main anti-fouling agent, auxiliary anti-fouling agent, auxiliary agent are added in dispersion tank together, 1500~
It obtains primary coating material within high speed dispersion 20 minutes under the revolving speed of 3000r/min, the primary coating material is ground later, works as institute
To get hydrolyzable antifouling paint when stating granularity≤80um of coating；
The anti-fouling agent is inorganic anti-fouling agent or organic anti-fouling agent；
The auxiliary anti-fouling agent is copper pyrithione, zinc pyrithione, zineb, pyridinium triphenylboron salt, sea-
At least one of Nine211 and bromo pyrrole carbonitrile.
Further, the inorganic anti-fouling agent includes copper powder, cuprous oxide, copper naphthenate, cuprous sulfocyanide, alkali formula carbon
At least one of sour copper and Kocide SD；
The auxiliary agent includes aluminium, calcium, zinc salt, polyethylene wax, amide waxe plus the hydrogen of stearic acid, lecithin and alkyl sulfonic acid
Castor oil wax and polyamide wax, synthesis at least one of fumed silica and bentonite.
Backbone chain type silicon Acrylote-zinc condensation polymer provided by the invention can keep surface long term to stablize hydrolysis in the seawater,
And it is low by seawater abrasion rear surface roughness using this polymer as the coating of film forming matter, it is more smooth, it advantageously reduces
Seawater has important application value to its resistance.
Detailed description of the invention
Fig. 1 is that the weight-loss ratio of embodiment 1-4 provided by the invention and comparative example 1-2 changes over time schematic diagram.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention
In technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, without
It is whole embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not before making creative work
Every other embodiment obtained is put, shall fall within the protection scope of the present invention.
The present invention provides a kind of backbone chain type silicon Acrylote-zinc condensation polymer, and structural formula is as follows:
Wherein, R1For alkyl, hydroxyalkyl, carboxyalkyl or Asia at most 8 carbon atoms with 1-10 carbon atom
Oxyalkyl；
R2For alkyl, aryl or alkenyl, the R of different location2It may be the same or different；
R3、R4For alkyl, aryl, sealing end or uncapped polyoxyalkylene alkane, aryl, arylmethylene alkyl and alkenyl；
R5For the alkylidene with 1-14 carbon atom；
A is the integer of 0-100, and b is the integer of 0-50,0≤a+b≤100.
Further, backbone chain type silicon Acrylote-zinc condensation polymer molecular weight is 10000~60000, solid content 45%
~55%, viscosity is 500~5000mPas.
The present invention also provides a kind of preparation methods of backbone chain type silicon Acrylote-zinc condensation polymer, comprising the following steps:
Step a, synthesizing organo-silicon oxygen alkanes acrylic acid
Binary acid is dissolved in solvent B, the polysiloxanes (referred to as: DN-PDS) of bisamination is added after mixing, by gained
Solution is heated to 50 DEG C~110 DEG C, and flows back 4~8 hours, removes supernatant, subnatant is the organosiloxane class third
Olefin(e) acid；The binary acid is that carbochain is no more than 16 binary acid, including malonic acid, one of succinic acid and sebacic acid or more
Kind mixing.
Wherein, the structural formula of DN-PDS is as follows:
In above formula, R1Selected from 1-10 carbon atom alkyl, hydroxyalkyl, carboxyalkyl and have at most 8 carbon atoms
Oxyalkylene；
R2It may be the same or different and selected from alkyl, aryl and alkenyl；R3And R4It may be the same or different, be selected from alkyl, virtue
Base, sealing end or uncapped polyoxyalkylene alkane, aryl, arylmethylene alkyl and alkenyl；A is the integer of 0-100, and b is 0-50's
Integer 0≤a+b≤100.
Step b, backbone chain type silicon Acrylote-zinc condensation polymer is synthesized；
Solvent C and zinc oxide are packed into container, are heated to 70 DEG C~150 DEG C, the organic of step a preparation is added later
Type siloxane acrylic acid solution, and keep temperature conditioned response 6~12 hours, obtain pale yellow transparent substance, as backbone chain type
Silicon Acrylote-zinc condensation polymer；
Wherein, the solvent B and solvent C are polar solvent, including tetrahydrofuran, methanol, ethyl alcohol, butanone, N, N bis-
Methylformamide, the mixing of one or more of dimethyl sulfoxide；
According to above-mentioned preparation method, the present invention also provides embodiments as shown in the table:
Table 1
Backbone chain type silicon Acrylote-zinc condensation polymer provided by the above embodiment and corresponding comparative example are subjected to surface contact angle
Test, wherein comparative example 1 is silicon Acrylote polymer, and comparative example 2 is zinc acrylate polymer；Test method are as follows: using complete
Automatic surface/interfacial tensimeter is tested, and it is shown that test result is as follows:
Table 2
Backbone chain type zinc acrylate resin-silica polycondensate object initial contact angle provided by the invention is obvious it can be seen from the comparison of upper table
Greater than the prior art, roughness can be significantly reduced and be conducive to reach lower resistance.
Rate test is hydrolyzed in backbone chain type silicon Acrylote-zinc condensation polymer provided by the above embodiment and comparative example, is had
Rate evaluation is hydrolyzed using weight-loss ratio in body, and test results are shown in figure 1, as figure shows, using main chain provided by the invention
The slope of type zinc acrylate resin-silica polycondensate object weight-loss ratio image is obviously more steady than comparative example, illustrates that its hydrolysis is more equal
One, stablize.
The present invention also provides a kind of hydrolyzable antifouling paints, using any backbone chain type silicon Acrylote-zinc polycondensation as above
Object.
The preparation method of above-mentioned hydrolyzable antifouling paint, including following preparation step: by the backbone chain type silicon Acrylote-
Zinc condensation polymer, pigments and fillers, organic solvent, main anti-fouling agent, auxiliary anti-fouling agent, auxiliary agent are added in dispersion tank together, 1500~
It obtains primary coating material within high speed dispersion 20 minutes under the revolving speed of 3000r/min, the primary coating material is ground later, works as institute
To get hydrolyzable antifouling paint when stating granularity≤80um of coating；
The anti-fouling agent is inorganic anti-fouling agent or organic anti-fouling agent；The auxiliary anti-fouling agent is copper pyrithione, pyridine sulphur
At least one of ketone zinc, zineb, pyridinium triphenylboron salt, sea-Nine211 and bromo pyrrole carbonitrile.In above-mentioned anti-fouling agent,
It may be used alone, can also be used in combination, the various anti-fouling agents in addition to cuprous oxide, preferably combining with cuprous oxide makes
With.
Preferably, the inorganic anti-fouling agent includes copper powder, cuprous oxide, copper naphthenate, cuprous sulfocyanide, basic carbonate
At least one of copper and Kocide SD, preferably cuprous oxide.
The auxiliary agent includes aluminium, calcium, zinc salt, polyethylene wax, amide waxe plus the hydrogen of stearic acid, lecithin and alkyl sulfonic acid
Castor oil wax and polyamide wax, synthesis at least one of fumed silica and bentonite, preferably polyamide wax and swelling
Soil.
It is prepared according to the method described above accordingly according to backbone chain type zinc acrylate resin-silica polycondensate object prepared by embodiment 1-4
Coating after corresponding coating is denuded 5 months in the seawater, carries out roughness test using copolymerization coke 3d contourgraph；Test result
As follows, wherein comparative example 1 is silicon Acrylote anti-fouling paint, and comparative example 2 is zinc acrylate resin anti-fouling paint；
Table 3
It can be seen that by upper table using antifouling prepared by backbone chain type zinc acrylate resin-silica polycondensate object provided by the invention
Coating, it is compared with prior art, low by seawater abrasion rear surface roughness, it is more smooth, advantageously reduce resistance of the seawater to it
Power.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；
Although present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its
It is still possible to modify the technical solutions described in the foregoing embodiments, or special to some or all of technologies
Sign is equivalently replaced；And these are modified or replaceed, various embodiments of the present invention that it does not separate the essence of the corresponding technical solution
The range of technical solution.
Claims (10)
1. a kind of backbone chain type silicon Acrylote-zinc condensation polymer, which is characterized in that structural formula is as follows:
Wherein, R1For alkyl, hydroxyalkyl, carboxyalkyl or sub- oxygen alkane at most 8 carbon atoms with 1-10 carbon atom
Base；
R2For alkyl, aryl or alkenyl, the R of different location2It may be the same or different；
R3、R4For alkyl, aryl, sealing end or uncapped polyoxyalkylene alkane, aryl, arylmethylene alkyl and alkenyl；
R5For the alkylidene with 1-14 carbon atom；
A is the integer of 0-100, and b is the integer of 0-50,0≤a+b≤100.
2. backbone chain type silicon Acrylote-zinc condensation polymer according to claim 1, it is characterised in that: backbone chain type silicon Acrylote-zinc
The molecular weight of condensation polymer is 10000~60000, and solid content is 45%~55%, and viscosity is 500~5000mPas.
3. a kind of preparation method of backbone chain type silicon Acrylote-zinc condensation polymer, which comprises the following steps:
Step a, synthesizing organo-silicon oxygen alkanes acrylic acid
Binary acid is dissolved in solvent B, after mixing be added bisamination polysiloxanes, by acquired solution be heated to 50 DEG C~
110 DEG C, and flow back 4~8 hours, supernatant is removed, subnatant is the organosiloxane class acrylic acid；
Step b, backbone chain type silicon Acrylote-zinc condensation polymer is synthesized
Solvent C and zinc oxide are packed into container, are heated to 70 DEG C~150 DEG C, the organosiloxane of step a preparation is added later
Class acrylic acid solution, and keep temperature conditioned response 6~12 hours, obtain pale yellow transparent substance, as backbone chain type acrylic acid
Silicon-zinc condensation polymer；
Wherein, the solvent B and solvent C are polar solvent.
4. the preparation method of backbone chain type silicon Acrylote-zinc condensation polymer according to claim 3, which is characterized in that step a
In, the raw material including following parts by weight:
10~42 parts of binary acid
40~80 parts of solvent B
20~50 parts of the polysiloxanes of bisamination.
5. the preparation method of backbone chain type silicon Acrylote-zinc condensation polymer according to claim 3, it is characterised in that: step a
In, the binary acid is that carbochain is no more than 16 binary acid, including malonic acid, one of succinic acid and sebacic acid or a variety of mixed
It closes.
6. the preparation method of backbone chain type silicon Acrylote-zinc condensation polymer according to claim 3, which is characterized in that step b
In, the raw material including following parts by weight:
20~50 parts of organosiloxane class acrylic acid
10~42 parts of zinc oxide
30~60 parts of solvent C.
7. the preparation method of backbone chain type silicon Acrylote-zinc condensation polymer according to claim 3, it is characterised in that: described molten
Agent B and solvent C include tetrahydrofuran, methanol, ethyl alcohol, butanone, n,N dimethylformamide, one of dimethyl sulfoxide or
A variety of mixing.
8. a kind of hydrolyzable antifouling paint, it is characterised in that: use backbone chain type silicon Acrylote-zinc polycondensation as described in any one of 1-7
Object.
9. a kind of preparation method of hydrolyzable antifouling paint according to claim 8, which is characterized in that including following preparation
Step: by the backbone chain type silicon Acrylote-zinc condensation polymer, pigments and fillers, organic solvent, main anti-fouling agent, auxiliary anti-fouling agent, auxiliary agent one
With being added in dispersion tank, primary coating material is obtained within high speed dispersion 20 minutes under the revolving speed of 1500~3000r/min, later to institute
It states primary coating material to be ground, as granularity≤80um of the coating to get hydrolyzable antifouling paint；
The anti-fouling agent is inorganic anti-fouling agent or organic anti-fouling agent；
The auxiliary anti-fouling agent be copper pyrithione, zinc pyrithione, zineb, pyridinium triphenylboron salt, sea-Nine211 and
At least one of bromo pyrrole carbonitrile.
10. the preparation method of hydrolyzable antifouling paint according to claim 9, it is characterised in that:
The inorganic anti-fouling agent includes copper powder, cuprous oxide, copper naphthenate, cuprous sulfocyanide, basic copper carbonate and Kocide SD
At least one of；
The auxiliary agent includes aluminium, calcium, zinc salt, polyethylene wax, amide waxe plus the hydrogen castor-oil plant of stearic acid, lecithin and alkyl sulfonic acid
Oily wax and polyamide wax, synthesis at least one of fumed silica and bentonite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910042379.5A CN109734916B (en) | 2019-01-17 | 2019-01-17 | Main-chain silicon-zinc polycondensate, hydrolysable antifouling paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910042379.5A CN109734916B (en) | 2019-01-17 | 2019-01-17 | Main-chain silicon-zinc polycondensate, hydrolysable antifouling paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109734916A true CN109734916A (en) | 2019-05-10 |
| CN109734916B CN109734916B (en) | 2021-05-14 |
Family
ID=66365141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910042379.5A Active CN109734916B (en) | 2019-01-17 | 2019-01-17 | Main-chain silicon-zinc polycondensate, hydrolysable antifouling paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109734916B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115298274A (en) * | 2020-03-13 | 2022-11-04 | 中国涂料株式会社 | Antifouling coating composition |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0376410A2 (en) * | 1988-12-29 | 1990-07-04 | Nippon Paint Co., Ltd. | Novel hydrolyzable silicone resin composition, preparation method and coating composition containing the same |
| JP2006077095A (en) * | 2004-09-08 | 2006-03-23 | Chugoku Marine Paints Ltd | Antifouling coating composition, its coated film, ship or underwater construction coated with the same and method of antifouling |
| JP2011032489A (en) * | 2010-11-01 | 2011-02-17 | Chugoku Marine Paints Ltd | Antifouling coating composition, antifouling coating film, ship or underwater structure covered with the antifouling coating film and antifouling method of ship outer panel or underwater structure |
| CN102702913A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Anti-fouling coating composition |
| CN104974631A (en) * | 2015-07-06 | 2015-10-14 | 海洋化工研究院有限公司 | Matrix resin having self-polishing performance and self-polishing antifouling coating prepared by same |
| CN106497414A (en) * | 2016-11-07 | 2017-03-15 | 上海华谊精细化工有限公司 | A kind of low-surface-energy is from polishing type antifouling paint and its application on the cuprous anti-fouling paint of non-oxidation |
| CN107001845A (en) * | 2014-11-26 | 2017-08-01 | 中国涂料株式会社 | Antifouling paint compositions, antifouling coat, the base material with antifouling coat, soil resistance base material, the manufacture method of base material with antifouling coat and the anti-fouling method of base material |
| CN108047865A (en) * | 2017-12-29 | 2018-05-18 | 厦门双瑞船舶涂料有限公司 | It is a kind of（Methyl）Zinc acrylate resin-siliceous copolymer and antifouling paint |
-
2019
- 2019-01-17 CN CN201910042379.5A patent/CN109734916B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0376410A2 (en) * | 1988-12-29 | 1990-07-04 | Nippon Paint Co., Ltd. | Novel hydrolyzable silicone resin composition, preparation method and coating composition containing the same |
| JP2006077095A (en) * | 2004-09-08 | 2006-03-23 | Chugoku Marine Paints Ltd | Antifouling coating composition, its coated film, ship or underwater construction coated with the same and method of antifouling |
| JP2011032489A (en) * | 2010-11-01 | 2011-02-17 | Chugoku Marine Paints Ltd | Antifouling coating composition, antifouling coating film, ship or underwater structure covered with the antifouling coating film and antifouling method of ship outer panel or underwater structure |
| CN102702913A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Anti-fouling coating composition |
| CN107001845A (en) * | 2014-11-26 | 2017-08-01 | 中国涂料株式会社 | Antifouling paint compositions, antifouling coat, the base material with antifouling coat, soil resistance base material, the manufacture method of base material with antifouling coat and the anti-fouling method of base material |
| CN104974631A (en) * | 2015-07-06 | 2015-10-14 | 海洋化工研究院有限公司 | Matrix resin having self-polishing performance and self-polishing antifouling coating prepared by same |
| CN106497414A (en) * | 2016-11-07 | 2017-03-15 | 上海华谊精细化工有限公司 | A kind of low-surface-energy is from polishing type antifouling paint and its application on the cuprous anti-fouling paint of non-oxidation |
| CN108047865A (en) * | 2017-12-29 | 2018-05-18 | 厦门双瑞船舶涂料有限公司 | It is a kind of（Methyl）Zinc acrylate resin-siliceous copolymer and antifouling paint |
Non-Patent Citations (3)
| Title |
|---|
| VALLEE-REHEL,K，等: "A new approach in the development and testing of antifouling paints without organotin derivatives", 《JOURNAL OF COATING TECHNOLOGY》 * |
| ZHOU XIN，等: "Inhibition of Marine Biofouling by Use of Degradable and Hydrolyzable Silyl Acrylate Copolymer", 《INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH》 * |
| 王娴娴: "一种低氧化亚铜自抛光型防污漆的制备及其性能", 《上海涂料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115298274A (en) * | 2020-03-13 | 2022-11-04 | 中国涂料株式会社 | Antifouling coating composition |
| CN115298274B (en) * | 2020-03-13 | 2023-08-25 | 中国涂料株式会社 | Antifouling coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109734916B (en) | 2021-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102993853B (en) | A kind of nontoxic material release type anti-fouling paint and preparation method thereof | |
| US6476095B2 (en) | Antifouling coating composition | |
| ES2262490T3 (en) | A CURABLE COMPOSITION, A COATING COMPOSITION, A PAINT, AN ANTI-CORROSIVE PAINT, CURED PRODUCTS AND METHOD FOR GIVING ANTI-CORROSIVE PROPERTIES TO A SURFACE. | |
| US7709552B2 (en) | Organic/inorganic composite | |
| KR102159871B1 (en) | Coating composition for forming a coating film with reduced frictional resistance, coating film, and substrate with coating film | |
| CN102558989A (en) | Anti-fouling coating material with excellent compatibility and use thereof | |
| JPH03255169A (en) | Nontoxic antifouling coating composition | |
| EP1115799A1 (en) | Curable silicone foul release coatings and articles | |
| CN107189617B (en) | A kind of biodegradable low-surface-energy graphene marine anti-pollution anticorrosion coating material and preparation method thereof | |
| JP2001139816A (en) | Curable composition, composition for coating, coating material, stainproofing coating material, its cured product, and method of rendering substrate antifoulancy | |
| EP1360253A2 (en) | Silicone resin composition for water repellent coating | |
| CN105461930A (en) | Anti-pollution coating composition and preparation thereof and application to low surface energy antifouling paint | |
| CN106280969A (en) | Preparation method based on modified polyether fluorosilicon oil low surface energy antifouling coating for seas | |
| EP2661648A1 (en) | Polyheterosiloxanes for high refractive index materials | |
| US6313193B1 (en) | Antifouling coating composition | |
| WO2023039917A1 (en) | Polyaspartic polyurea resin system having marine antifouling function and coating composition | |
| CN109971281A (en) | A kind of rapid-curing cutback building water-proof paint | |
| CN102382555B (en) | Solvent-free low-temperature solidified phenolic epoxy anticorrosive paint and preparation method thereof | |
| CN109734916A (en) | A kind of backbone chain type silicon Acrylote-zinc condensation polymer, hydrolyzable antifouling paint and preparation method thereof | |
| JP2012214588A (en) | Water- and oil-repellent resin composition and coated product | |
| JP2013523905A (en) | Thermosetting composition for colorable transparent wear-resistant hard coatings | |
| CN108690414A (en) | A kind of automobile-used water paint and preparation method thereof | |
| CN104513340B (en) | A kind of fluorine silica acrylic acid is from polishing antifouling resin and preparation method thereof | |
| KR20110089762A (en) | One-component type, room-temperature curing and water-soluble top coating composition | |
| CN104449172B (en) | A kind of antifouling paint containing bioantifouling agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |