CN109732910A - Holographic 3D printing device and holographic 3D printing method - Google Patents

Holographic 3D printing device and holographic 3D printing method Download PDF

Info

Publication number
CN109732910A
CN109732910A CN201910103987.2A CN201910103987A CN109732910A CN 109732910 A CN109732910 A CN 109732910A CN 201910103987 A CN201910103987 A CN 201910103987A CN 109732910 A CN109732910 A CN 109732910A
Authority
CN
China
Prior art keywords
light
slot
light beam
cured resin
light source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910103987.2A
Other languages
Chinese (zh)
Other versions
CN109732910B (en
Inventor
吴磊
宋延林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Chemistry CAS
Original Assignee
Institute of Chemistry CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Chemistry CAS filed Critical Institute of Chemistry CAS
Priority to CN201910103987.2A priority Critical patent/CN109732910B/en
Publication of CN109732910A publication Critical patent/CN109732910A/en
Application granted granted Critical
Publication of CN109732910B publication Critical patent/CN109732910B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The present invention relates to 3D field shaping techniques, disclose holographic 3D printing device and holographic 3D printing method.The device includes low adherency slot and holographic light-source system, wherein, the low adherency slot is used to issue hologram image and projects and irradiate the light-cured resin progress photocuring in the low adherency slot for loading light-cured resin, the holography light-source system, forms 3D printing structure.It is fast with print speed by that printed material can be made to be integrally formed using face array holographic light source using holographic 3D printing device provided by the invention and holographic 3D printing method, good forming effect, the high advantage of printing precision.

Description

Holographic 3D printing device and holographic 3D printing method
Technical field
The present invention relates to 3D field shaping techniques, and in particular to holographic 3D printing device and holographic 3D printing method.
Background technique
3D printing is also known as increases material manufacturing technology, is one kind of rapid shaping technique, it based on digital model file, It is point-by-point or successively print by way of construct three-dimension object.It up to the present, can be by 3D according to three-dimensionally shaped principle Printing technique is divided into melting extrusion rapid shaping, stereolithograghy, digital light processing, foil laminated forming, ink-jet 3D are beaten Print, selective laser sintering and electron-beam melting molding etc..They are compared with traditional manufacture without mold manufacture or machinery Processing avoids the waste that tradition subtracts the material and the energy of manufacture process.
But 3D printing technique existing at present is to be all made of layer-by-layer or point-by-point printing type, is not reached really with body The manufacture of three-dimensional structure is carried out for unit, therefore print speed is greatly limited.Meanwhile by it is point-by-point and by face at When type mode prints hanging structure, due to print point or face sequencing, it is necessary to support construction be added, printing When at rear removal support construction, the techniques such as physics flushing and polishing are generally required, printing precision is caused to reduce, especially printing is high The structure of precision.The holographic 3D printing technique proposed at present can only print simple structure, and molding effect and precision are poor, For realizing really holographic 3D printing, there are also very remote distances, so that its application receives great limitation with popularization.
Summary of the invention
The purpose of the invention is to overcome print speed of the existing technology is slow, prints hanging structure to need that branch is added The low problem of support structure, printing precision provides holographic 3D printing device and holographic 3D printing method, using provided by the invention complete 3D printing device and holographic 3D printing method are ceased, by utilizing face array holographic light source, printed material can be made to be integrally formed, have and beat Print-out rate is fast, good forming effect, the high advantage of printing precision.
To achieve the goals above, first aspect present invention provides a kind of holographic 3D printing device, which includes low Adhere to slot and holographic light-source system, wherein the low adherency slot is used for for loading light-cured resin, the holography light-source system It issues hologram image and projects and irradiate the light-cured resin progress photocuring in the low adherency slot, form 3D printing structure.
Preferably, the holographic light-source system includes area array light source, beam splitter, the first beam expander, reflecting mirror and the second expansion Beam device, wherein
The area array light source is for emitting light beam;
The beam splitter is used to receive the light beam that the area array light source issues, and the light beam is divided into the first light beam and the Two light beams;
First beam expander converts parallel cylinder light wave for first light beam for receiving first light beam And expose to the light-cured resin in the low adherency slot;
The reflecting mirror is for reflecting second light beam to the second beam expander;
Second beam expander is for converting parallel cylinder light wave for second light beam and exposing to the low adherency Light-cured resin in slot;
Wherein, the first light beam turns to interfere with each other and formed hologram image projection in the low adherency slot with the second light beam.
Preferably, the light transmittance of the low adherency slot is not less than 90%.
Preferably, the low adherency slot includes low adhesion layer, and the material of the low adhesion layer includes silicon rubber and surface Activating agent.
Second aspect of the present invention provides a kind of above-mentioned holographic 3D printing method of device progress, and this method includes following step It is rapid:
(a) light-cured resin is loaded into low adherency slot, wherein the adhesion strength of light-cured resin and low adherency slot is less than 10kPa;
(b) the identifiable map data mining platform of area array light source is converted by target three-dimensional, and exported to light source control software, It controls area array light source and emits light beam;
(c) light beam is divided into the first light beam and the second light beam by beam splitter, the first light beam passes through the first beam expander It is converted into parallel cylinder light wave and irradiates the light-cured resin in the low adherency slot, the second light beam reflexes to the by reflecting mirror Two beam expanders, and the light-cured resin being converted into low adherency slot described in parallel cylinder light-wave irradiation, wherein first light beam It is interfered with each other in the low adherency slot with the second light beam and forms hologram image projection;
(d) light-cured resin described in the hologram image projection illumination carries out photocuring, forms the 3D of target three-dimensional Print structure.
Preferably, the photosensitive wavelength of the light-cured resin is 200nm-900nm, preferably 300-450nm, it is preferable that The light-cured resin is selected from polymethyl methacrylate, polyacrylic resin, epoxy acrylic resin, polyurethane acroleic acid tree Rouge, polyester acrylate resin, polyoxyalkylene acrylate resin, phenolic resin, acrylonitrile-butadiene-styrene copolymer performed polymer, One of allyl resin and vinylite are a variety of.
Preferably, the acceptable light beam light intensity of the light-cured resin is 0-100mW/cm2, preferably 3-20mW/cm2
The present invention passes through holographic light-source system formation hologram image and projects and expose to the light-cured resin in low adherency slot Photocuring is carried out, and the adhesion strength of light-cured resin and low adherency slot is less than 10kPa, adjusts the light intensity and light of hologram image projection Solidified resin cause solidify required light intensity it is consistent when can be solidified, to realize holographic 3D printing, printed material one It is body formed.Holographic 3D printing method of the invention has print speed fast, may be implemented the print speed of second-time, and due to Without using support construction when printing hanging structure, to improve printing precision, and good forming effect.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of 3D printing device of the invention.
Description of symbols
It 1, can three-dimensional mobile micro-displacement platform 2, area array light source
3, beam splitter 4, reflecting mirror
5, the first beam expander 6, the second beam expander
7, low adherency slot 8, light-cured resin
9, hologram image projects
Specific embodiment
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more New numberical range, these numberical ranges should be considered as specific open herein.
First aspect present invention provides a kind of holographic 3D printing device, which includes low adherency slot and holographic light source system System, wherein the low adherency slot is for loading light-cured resin, and the holography light-source system is for issuing hologram image projection simultaneously The light-cured resin irradiated in the low adherency slot carries out photocuring, forms 3D printing structure.
In the present invention, term " area array light source " refer at least one side projection light source or by point light source groups at array, Also referred to as holographic light source.
In the present invention, as shown in Figure 1, the holography light-source system may include area array light source 2, the expansion of beam splitter 3, first Beam device 5, reflecting mirror 4 and the second beam expander 6, wherein the area array light source 2 is for emitting light beam;The beam splitter 3 is for receiving The light beam that the area array light source issues, and the light beam is divided into the first light beam and the second light beam;First beam expander 5 is used for First light beam is received, and converts parallel cylinder light wave for first light beam and exposes to the light in the low adherency slot Solidified resin;The reflecting mirror 4 is for reflecting second light beam to the second beam expander;Second beam expander 6 is used for institute The second light beam is stated to be converted into parallel cylinder light wave and expose to the light-cured resin in the low adherency slot;Wherein, the first light beam Turn to interfere with each other and formed hologram image projection 9 in the low adherency slot with the second light beam.
In the present invention, as shown in Figure 1, the holography light-source system can also include can three-dimensional mobile micro-displacement platform 1, it is described can three-dimensional mobile micro-displacement platform 1 connect with area array light source 2, for adjusting the position of area array light source 2.
In the present invention, the holographic light-source system can also include being electrically connected with the area array light source 2 and micro-displacement platform 1 The computer connect for converting the identifiable map data mining platform of the area array light source for target three-dimensional, and is exported to light source Software is controlled, the area array light source transmitting light beam is controlled.
In the present invention, the light beam wavelength of the area array light source transmitting can be 200nm-900nm, preferably 300- 450nm;Light beam light intensity can be 0-100mW/cm2, preferably 3-20mW/cm2.Preferably, the area array light source is sent out selected from laser One of optical diode, light emitting diode with quantum dots, inorganic light-emitting diode and Organic Light Emitting Diode are a variety of.
Light emitting diode be can a kind of electric energy be converted to the device of luminous energy.
Wherein, term " laser luminescence diode " refers to using the hair that the luminous laser active material of stimulated radiation can be achieved Optical diode.
Term " light emitting diode with quantum dots " refers to that addition quantum dot is the light emitting diode of active material.
Term " inorganic light-emitting diode " refers to the light emitting diode using inorganic material for active material.
Term " Organic Light Emitting Diode " refers to the light emitting diode using organic material for active material.
In the present invention, the area array light source can be plane projection light source, curved surface projection light source, monochromatic light source, more One of coloured light light source and dot matrix area source are a variety of.
Wherein, term " plane projection light source " refers to that perspective plane is the projection light source of plane.
Term " curved surface projection light source " refers to that perspective plane is the projection light source of curved surface.
Term " monochromatic light source " refers to the light source that can only emit the light of fixed single wavelength.
Term " polychrome radiant " refers to the light source that can emit the light of multiple wavelength.
Term " dot matrix area source " refers to the area source being made of the array of point light source.
In the present invention, the beam splitter can be adjustable selected from fiber optic splitter, fixed splitting ratio beam splitter and splitting ratio One of beam splitter is a variety of.In the art, splitting ratio refers to that the optical power of the one of output end output of optical splitter accounts for The ratio of total Output optical power.Term " fixed splitting ratio beam splitter " refers to that splitting ratio is the beam splitter of fixed value.Term " light splitting Than adjustable beam splitter " refer to the adjustable beam splitter of the numerical value of splitting ratio.
In the present invention, the low adherency slot can be open, be also possible to closed.The low adherency slot can wrap Include slot bottom, side wall and optional top cover, it is preferable that the light transmittance of the low adherency slot is not less than 90%, such as light transmittance can be with It is any in 90%, 91%, 92%, 93%, 94%, 95%, 96%, 97%, 98%, 99%, 100% and these numerical value Arbitrary value in two ranges constituted.
In a preferred embodiment, the low adherency slot includes low adhesion layer, and the material of the low adhesion layer includes Silicon rubber and surfactant.Wherein, the silicon rubber is limited without special.The surfactant can be floride-free or fluorine-containing Surfactant.Specifically, the fluorine-containing surfactant can be for using carbon fluorine as the compound of main chain or side-chain structure, fluorine-containing One of liquid and fluorine-containing solid are a variety of, such as can be the long chain alkane etc. that side chain is replaced by fluorine atoms, more specifically, The fluorine-containing surfactant can be 17 fluorine ruthenium trimethoxysilanes, (trifluoromethyl) trimethyl silane, triethyl group fluorine Silane and 1,1,1,2,2,4,5,5,5- nine fluoro- 4- (trifluoromethyl)-propione etc..The non-fluorinated surfactant can for Carbochain is the one or more of the compound of main chain or side-chain structure, organic liquid or solid, for example, can for long chain alkane, just Hexadecane or n-eicosane etc..The proportionate relationship of silicon rubber and surfactant is limited without special, such as can be 1:1, and 10: 1,100:1 etc..
In a particular embodiment, the low adherency slot can for quartz, glass, polymethyl formicester, polyethylene, Acrylic, polypropylene etc. are used as skeleton structure, and modify low adhesion layer in the slot bottom of low adherency slot and/or side wall.
In a preferred embodiment, slot bottom, side wall and the optional top cover of the low adherency slot can be the knot of plane Structure.Since curved-surface structure is possible to cause the deformation of light beam, to increase the hologram projection to form required 3D threedimensional model Difficulty, in the case where not considering to be formed the difficulty of hologram projection, slot bottom, side wall and the optional top cover of low adherency slot It may be curved surface.
Second aspect of the present invention provides a kind of above-mentioned holographic 3D printing method of device progress, and this method includes following step It is rapid:
(a) light-cured resin is loaded into low adherency slot, wherein the adhesion strength of light-cured resin and low adherency slot is less than 10kPa;
(b) the identifiable map data mining platform of area array light source is converted by target three-dimensional, and exported to light source control software, It controls area array light source and emits light beam;
(c) light beam is divided into the first light beam and the second light beam by beam splitter, the first light beam passes through the first beam expander It is converted into parallel cylinder light wave and irradiates the light-cured resin in the low adherency slot, the second light beam reflexes to the by reflecting mirror Two beam expanders, and the light-cured resin being converted into low adherency slot described in parallel cylinder light-wave irradiation, wherein first light beam It is interfered with each other in the low adherency slot with the second light beam and forms hologram image projection;
(d) light-cured resin described in the hologram image projection illumination carries out photocuring, forms the 3D of target three-dimensional Print structure.
According to the method for the present invention, the photosensitive wavelength of the light-cured resin can be 200nm-900nm, preferably 300- 450nm.Preferably, the light-cured resin be selected from polymethyl methacrylate, polyacrylic resin, epoxy acrylic resin, Polyurethane acrylic resin, polyester acrylate resin, polyoxyalkylene acrylate resin, phenolic resin, acrylonitrile-butadiene-styrene (ABS) One of performed polymer, allyl resin and vinylite of copolymer are a variety of.
According to the method for the present invention, the acceptable light beam light intensity of the light-cured resin can be 0-100mW/cm2, preferably For 3-20mW/cm2.The light intensity of hologram image projection cause with light-cured resin solidify required light intensity it is consistent when can be into Row solidification.For example, the light intensity of hologram image projection is 3mW/cm2, the light intensity that light-cured resin causes needed for solidifying also is 3mW/ cm2;The light intensity of hologram image projection is 10mW/cm2, the light intensity that light-cured resin causes needed for solidifying also is 10mW/cm2;It is holographic The light intensity of image projection is 20mW/cm2, the light intensity that light-cured resin causes needed for solidifying also is 20mW/cm2
According to the method for the present invention, the volume of the hologram image projection is less than the volume of the light-cured resin, so that Hologram image, which is projected on light-cured resin, forms effectively projection.
The adhesion strength of preferred embodiment according to the present invention, light-cured resin and low adherency slot is 0.01-5kPa, such as It can be any two in 0.01kPa, 0.1kPa, 0.5kPa, 1kPa, 2kPa, 3kPa, 4kPa, 5kPa and these numerical value The arbitrary value in range constituted.Preferably, the adhesion strength of light-cured resin and low viscous slot.
The present invention will be described in detail by way of examples below.
Preparation example 1
By the silastic material liquid of 7.5g (be purchased from Dow Corning company, batch SYLGARD184, initiator with Curing agent ratio is 10:1), (fluorine-containing surfactant is purchased from Sigma- with the 17 fluorine ruthenium trimethoxysilanes of 0.5g Aldrich) mechanical stirring mixing, obtain the raw material for preparing the low adhesion layer of low adherency slot.
Having a size of 8cm × 8cm × 10cm cuboid quartz cell, as skeleton structure, the low adherency of low adherency slot will be prepared The raw material of layer are laid on the bottom of quartz cell, and quartz cell is heated to 80 DEG C later, low adherency slot is obtained after 2h.
Low adherency slot is 92% to the light transmittance of 200nm light.
Preparation example 2
The silastic material of 10g (is purchased from Dow Corning company, batch is SYLGARD 160, initiator and solidification Agent ratio is 6:1), it is stirred with (trifluoromethyl) trimethyl silane (fluorine-containing surfactant is purchased from Acros company) machinery of 0.1g Mixing is mixed, the raw material for preparing the low adhesion layer of low adherency slot are obtained.
Having a size of 12cm × 12cm × 12cm square acrylic slot, as skeleton structure, the low of low adherency slot will be prepared The raw material of adhesion layer are laid on the bottom of acrylic slot, and acrylic slot is heated to 80 DEG C later, and low adherency slot is obtained after 2h.
Low adherency slot is 95% to the light transmittance of 365nm light.
Preparation example 3
The silastic material of 5g (is purchased from Dow Corning company, batch is SYLGARD 170, initiator and curing agent Ratio is 8:1), triethyl group silicon fluoride (fluorine-containing surfactant is purchased from Accela company) mechanical stirring mixing with 1g obtains Prepare the raw material of the low adhesion layer of low adherency slot.
Having a size of 5cm × 5cm × 5cm square glass guide channel, as skeleton structure, the low adherency of low adherency slot will be prepared The raw material of layer are laid on the bottom of glass guide channel, and glass guide channel is heated to 80 DEG C later, low adherency slot is obtained after 2h.
Low adherency slot is 85% to the light transmittance of 900nm light.
Preparation example 4
The silastic material of 15g (is purchased from Dow Corning company, batch is SYLGARD 182, initiator and solidification Agent ratio is 10:1), 1,1,1,2,2,4,5,5,5- nine fluoro- 4- (trifluoromethyl)-propione (fluorine-containing surfactants with 0.5g Agent is purchased from TCI company) mechanical stirring mixing, obtain the raw material for preparing the low adhesion layer of low adherency slot.
Having a size of 15cm × 15cm × 15cm square polyethylene slot, as skeleton structure, the low of low adherency slot will be prepared The raw material of adhesion layer are laid on the bottom of polyethylene slot, and polyethylene slot is heated to 60 DEG C later, and low adherency slot is obtained after 3h.
Low adherency slot is 96% to the light transmittance of 450nm light.
Embodiment 1
It (a) is 512cm by the volume of 481g3Polymethyl methacrylate (light-cured resin, weight average molecular weight are 4000, photosensitive wavelength 200nm, acceptable light beam light intensity are 8mW/cm2) be loaded into low adherency slot (preparation example 1 obtains), Wherein, the adhesion strength of polymethyl methacrylate and low adherency slot is 0.1kPa;
(b) the identifiable map data mining platform of area array light source is converted by the threedimensional model of tooth, and exported soft to light source control Part, control area array light source emit light beam, and micro-displacement platform that can be three-dimensional mobile adjusts the position of area array light source, wherein the face Array light source is the lattice plane light source that laser luminescence diode issues, and light beam wavelength 200nm, light beam light intensity is 8mW/cm2
(c) light beam is divided into the first light beam and the second light beam by fiber optic splitter, the first light beam expands by first Beam device is converted into parallel cylinder light wave and irradiates the light-cured resin in the low adherency slot, and the second light beam is reflected by reflecting mirror To the second beam expander, and the light-cured resin being converted into low adherency slot described in parallel cylinder light-wave irradiation;Wherein, described first Light beam and the second light beam interfere with each other in the low adherency slot and form hologram image projection, projection volume 125cm3
(d) light-cured resin described in the hologram image projection illumination carry out photocuring, hologram image projection light intensity with The light intensity of light-cured resin is consistent, and the 3D printing structure of tooth is formed after 10 seconds.
Embodiment 2
It (a) is 1500cm by the volume of 1425g3Polyurethane acrylic resin (light-cured resin, weight average molecular weight are 2000, photosensitive wavelength 365nm, acceptable light beam light intensity are 7mW/cm2) be loaded into low adherency slot (preparation example 2 obtains), Wherein, the adhesion strength of polyurethane acrylic resin and low adherency slot is 1kPa;
(b) the identifiable map data mining platform of area array light source is converted by the threedimensional model of tooth, and exported soft to light source control Part, control area array light source emit light beam, and micro-displacement platform that can be three-dimensional mobile adjusts the position of area array light source, wherein the face Array light source is the curved surface projection light source that inorganic light-emitting diode and Organic Light Emitting Diode issue, light beam wavelength 365nm, light beam Light intensity is 7mW/cm2
(c) light beam is passed through into fixed splitting ratio beam splitter (beam splitter) and is divided into the first light beam and the second light beam, first Light beam is converted into parallel cylinder light wave by the first beam expander and irradiates the light-cured resin in the low adherency slot, the second light beam The photocuring tree for reflexing to the second beam expander by reflecting mirror, and being converted into low adherency slot described in parallel cylinder light-wave irradiation Rouge;Wherein, first light beam and the second light beam interfere with each other in the low adherency slot and form hologram image projection, projection Volume is 1000cm3
(d) the hologram image projection illumination to the light-cured resin carries out photocuring, the light intensity of hologram image projection It is consistent with the light intensity of light-cured resin, the 3D printing structure of tooth is formed after 20 seconds.
Embodiment 3
It (a) is 75cm by the volume of 68g3Acrylonitrile-butadiene-styrene copolymer performed polymer (light-cured resin, Weight average molecular weight is 5000, photosensitive wavelength 900nm, and acceptable light beam light intensity is 9mW/cm2) it is loaded into low adherency slot (system Standby example 3 obtains) in, wherein the performed polymer of acrylonitrile-butadiene-styrene copolymer and the adhesion strength of low adherency slot are 0.5kPa;
(b) the identifiable map data mining platform of area array light source is converted by the threedimensional model of tooth, and exported soft to light source control Part, control area array light source emit light beam, and micro-displacement platform that can be three-dimensional mobile adjusts the position of area array light source, wherein the face Array light source is the dot matrix area source that light emitting diode with quantum dots issues, and light beam wavelength 900nm, light beam light intensity is 9mW/cm2
(c) light beam is passed through into fixed splitting ratio beam splitter (beam splitter) and is divided into the first light beam and the second light beam, first Light beam is converted into parallel cylinder light wave by the first beam expander and irradiates the light-cured resin in the low adherency slot, the second light beam The photocuring tree for reflexing to the second beam expander by reflecting mirror, and being converted into low adherency slot described in parallel cylinder light-wave irradiation Rouge;Wherein, first light beam and the second light beam interfere with each other in the low adherency slot and form hologram image projection, projection Volume is 9cm3
(d) the hologram image projection illumination to the light-cured resin carries out photocuring, the light intensity of hologram image projection It is consistent with the light intensity of light-cured resin, the 3D printing structure of tooth is formed after 5 seconds.
Embodiment 4
It (a) is 2000cm by the volume of 2300g3Polyacrylic resin (light-cured resin, weight average molecular weight 3000, Photosensitive wavelength is 450nm, and acceptable light beam light intensity is 5mW/cm2) be loaded into low adherency slot (preparation example 4 obtains), wherein The adhesion strength of polyacrylic resin and low adherency slot is 0.01kPa;
(b) the identifiable map data mining platform of area array light source is converted by the threedimensional model of tooth, and exported soft to light source control Part, control area array light source emit light beam, and micro-displacement platform that can be three-dimensional mobile adjusts the position of area array light source, wherein the face Array light source is the dot matrix area source that light emitting diode with quantum dots issues, and light beam wavelength 450nm, light beam light intensity is 5mW/cm2
(c) light beam is divided into the first light beam and the second light beam by fiber optic splitter, the first light beam expands by first Beam device is converted into parallel cylinder light wave and irradiates the light-cured resin in the low adherency slot, and the second light beam is reflected by reflecting mirror To the second beam expander, and the light-cured resin being converted into low adherency slot described in parallel cylinder light-wave irradiation;Wherein, described first Light beam and the second light beam interfere with each other in the low adherency slot and form hologram image projection, projection volume 1000cm3
(d) the hologram image projection illumination to the light-cured resin carries out photocuring, the light intensity of hologram image projection It is consistent with the light intensity of light-cured resin, the 3D printing structure of tooth is formed after 30 seconds.
Comparative example 1
According to the method for embodiment 1, unlike, low adherency slot do not have low adhesion layer, polymethyl methacrylate and The adhesion strength of low adherency slot is 20kPa, the 3D printing structure existing defects of the tooth of printing.
It is can be seen that with comparative example through the foregoing embodiment using 3D printing device provided by the invention, by utilizing face Array holographic light source, light intensity and the light-cured resin for adjusting hologram image projection cause solidify required light intensity it is consistent when consolidated Change, so that printed material is integrally formed.3D printing method of the invention has print speed fast, and the printing of second-time may be implemented Speed, and due to without carrying out the techniques such as physics flushing and polishing, printing essence to improve without using support construction Degree, and good forming effect.
The preferred embodiment of the present invention has been described above in detail, and still, the present invention is not limited thereto.In skill of the invention In art conception range, can with various simple variants of the technical solution of the present invention are made, including each technical characteristic with it is any its Its suitable method is combined, and it should also be regarded as the disclosure of the present invention for these simple variants and combination, is belonged to Protection scope of the present invention.

Claims (10)

1. a kind of holography 3D printing device, which is characterized in that the device includes low adherency slot and holographic light-source system, wherein institute It states low adherency slot and projects and irradiate described low for issuing hologram image for loading light-cured resin, the holography light-source system The light-cured resin adhered in slot carries out photocuring, forms 3D printing structure.
2. holography 3D printing device according to claim 1, wherein the holography light-source system includes area array light source, divides Beam device, the first beam expander, reflecting mirror and the second beam expander, wherein
The area array light source is for emitting light beam;
The beam splitter is used to receive the light beam that the area array light source issues, and the light beam is divided into the first light beam and the second light Beam;
First beam expander converts parallel cylinder light wave for first light beam and shines for receiving first light beam The light-cured resin being incident upon in the low adherency slot;
The reflecting mirror is for reflecting second light beam to the second beam expander;
Second beam expander is for converting parallel cylinder light wave for second light beam and exposing in the low adherency slot Light-cured resin;
Wherein, the first light beam turns to interfere with each other and formed hologram image projection in the low adherency slot with the second light beam.
3. holography 3D printing device according to claim 2, wherein the holography light-source system further includes can be three-dimensional mobile Micro-displacement platform, it is described can three-dimensional mobile micro-displacement platform connect with area array light source, for adjusting the position of area array light source.
4. holography 3D printing device according to claim 2 or 3, wherein the holography light-source system further include with it is described The computer of area array light source and micro-displacement platform electrical connection, can recognize for converting the area array light source for target three-dimensional Map data mining platform, and export to light source control software, control the area array light source transmitting light beam.
5. holography 3D printing device according to claim 2 or 3, wherein the light beam wavelength of the area array light source transmitting is 200nm-900nm, preferably 300-450nm;Light beam light intensity is 0-100mW/cm2, preferably 3-20mW/cm2
Preferably, the area array light source is selected from laser luminescence diode, light emitting diode with quantum dots, inorganic light-emitting diode and has One of machine light emitting diode is a variety of.
6. holography 3D printing device according to claim 2 or 3, wherein the beam splitter is selected from fiber optic splitter, fixation One of splitting ratio beam splitter and the adjustable beam splitter of splitting ratio are a variety of.
7. holographic 3D printing device described in any one of -3 according to claim 1, wherein the light transmittance of the low adherency slot Not less than 90%;
Preferably, the low adherency slot includes low adhesion layer, and the material of the low adhesion layer includes silicon rubber and surface-active Agent.
8. device described in a kind of any one of claim 1-7 carries out holographic 3D printing method, this method includes following step It is rapid:
(a) light-cured resin is loaded into low adherency slot, wherein the adhesion strength of light-cured resin and low adherency slot is less than 10kPa;
(b) the identifiable map data mining platform of area array light source is converted by target three-dimensional, and exported to light source control software, control Area array light source emits light beam;
(c) light beam is divided into the first light beam and the second light beam by beam splitter, the first light beam is converted by the first beam expander For parallel cylinder light wave and the light-cured resin in the low adherency slot is irradiated, the second light beam reflexes to the second expansion by reflecting mirror Beam device, and the light-cured resin being converted into low adherency slot described in parallel cylinder light-wave irradiation, wherein first light beam and the Two light beams interfere with each other in the low adherency slot and form hologram image projection;
(d) light-cured resin described in the hologram image projection illumination carries out photocuring, forms the 3D printing of target three-dimensional Structure.
9. according to the method described in claim 8, wherein, the photosensitive wavelength of the light-cured resin is 200nm-900nm, preferably For 300-450nm, the preferably described light-cured resin is selected from polymethyl methacrylate, polyacrylic resin, epoxy acrylic tree Rouge, polyurethane acrylic resin, polyester acrylate resin, polyoxyalkylene acrylate resin, phenolic resin, acrylonitrile-butadiene-benzene second One of performed polymer, allyl resin and vinylite of alkene copolymer are a variety of.
10. according to the method described in claim 8, wherein, the acceptable light beam light intensity of light-cured resin is 0-100mW/ cm2, preferably 3-20mW/cm2
CN201910103987.2A 2019-02-01 2019-02-01 Holographic 3D printing device and holographic 3D printing method Active CN109732910B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910103987.2A CN109732910B (en) 2019-02-01 2019-02-01 Holographic 3D printing device and holographic 3D printing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910103987.2A CN109732910B (en) 2019-02-01 2019-02-01 Holographic 3D printing device and holographic 3D printing method

Publications (2)

Publication Number Publication Date
CN109732910A true CN109732910A (en) 2019-05-10
CN109732910B CN109732910B (en) 2021-05-07

Family

ID=66367146

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910103987.2A Active CN109732910B (en) 2019-02-01 2019-02-01 Holographic 3D printing device and holographic 3D printing method

Country Status (1)

Country Link
CN (1) CN109732910B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110239087A (en) * 2019-06-04 2019-09-17 浙江大学 A kind of 3D printing equipment based on image-forming principle
CN115052738A (en) * 2019-09-27 2022-09-13 普瑞利思生物制品公司 Three-dimensional printing of organs, devices and substrates

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107972265A (en) * 2017-11-10 2018-05-01 中国科学院化学研究所 A kind of 3D printing system
CN108501363A (en) * 2018-03-21 2018-09-07 深圳大学 A kind of 3D printing method and system based on line holographic projections

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107972265A (en) * 2017-11-10 2018-05-01 中国科学院化学研究所 A kind of 3D printing system
CN108501363A (en) * 2018-03-21 2018-09-07 深圳大学 A kind of 3D printing method and system based on line holographic projections

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110239087A (en) * 2019-06-04 2019-09-17 浙江大学 A kind of 3D printing equipment based on image-forming principle
CN115052738A (en) * 2019-09-27 2022-09-13 普瑞利思生物制品公司 Three-dimensional printing of organs, devices and substrates

Also Published As

Publication number Publication date
CN109732910B (en) 2021-05-07

Similar Documents

Publication Publication Date Title
CN105946237B (en) The method that Three-dimensional Photoelastic model is prepared using ultraviolet face exposure rapid molding device
CN100392444C (en) Method for producing photon crystal and controllable defect therein
CN109732910A (en) Holographic 3D printing device and holographic 3D printing method
US4801477A (en) Method and apparatus for production of three-dimensional objects by photosolidification
CN105216319B (en) 3D stereoprojection formula photocuring 3D printers
US20190351615A1 (en) Exposure systems, printing systems, methods for additive manufacturing, compositions, and the use thereof
CN109532012A (en) 3D printing system and method based on photocuring
CN101563212A (en) Polymer object optical fabrication process
CN108312518A (en) A kind of internal three-dimensional directly Stereolithography 3D printing equipment and its control method
US11872746B2 (en) Photoresponsive materials for volumetric additive manufacturing
EP2199067A1 (en) Additional light source
US11919246B2 (en) 5D part growing machine with volumetric display technology
TW201703988A (en) Three dimensional printing system
CN101537711B (en) Quick molding method for energy following point scanning and photo-curing
Stichel et al. Two-photon Polymerization as Method for the Fabrication of Large Scale Biomedical Scaffold Applications.
CN110524874B (en) Photocuring 3D printing device and printing method thereof
CN101301792B (en) Light-curing quick moulding method based on LCD space light modulator and device
CN114269544A (en) Method and apparatus for volumetric additive manufacturing of cell-loaded resins
CN206011731U (en) A kind of continuous 3D printer of high-precision high-speed
KR20220001437A (en) Method for generating artificial tooth by using 3d printing technique and 3d printer
CN101332649B (en) Light-cured quick forming device and method based on reflection-type liquid crystal light valve
CN207916057U (en) A kind of internal three-dimensional directly Stereolithography 3D printing equipment
CN1236899A (en) Method and apparatus for optical solidifying and shaping by line scan with non-laser light source
CN106696258A (en) Fast 3D printing method
Bongiovanni et al. Vat Photopolymerization

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant