CN109730540A - Metallic object and heat-generating disc suitable for food container - Google Patents
Metallic object and heat-generating disc suitable for food container Download PDFInfo
- Publication number
- CN109730540A CN109730540A CN201910097392.0A CN201910097392A CN109730540A CN 109730540 A CN109730540 A CN 109730540A CN 201910097392 A CN201910097392 A CN 201910097392A CN 109730540 A CN109730540 A CN 109730540A
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- Prior art keywords
- glass powder
- glass
- coating
- metallic object
- food container
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Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
- A47J36/025—Vessels with non-stick features, e.g. coatings
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
- A47J36/04—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay the materials being non-metallic
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/24—Warming devices
- A47J36/26—Devices for warming vessels containing drinks or food, especially by means of burners Warming devices with a burner, e.g. using gasoline; Travelling cookers, e.g. using petroleum or gasoline with one burner
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
Abstract
The invention discloses a kind of metallic object suitable for food container, glass powder coating is coated on the metallic object, the glass powder coating can form glass function coating in metal surface;Wherein, the glass powder coating includes 50~90wt% glass powder and 10~50wt% organic component.Using the present invention, when it being made to be applied to make full glass water pot, can solve simultaneously cost is relatively low, the service life is long, safety, can volume production, cleaning the problems such as being easy.
Description
Technical field
The present invention relates to heating kettle technical field, in particular to a kind of metallic object and heat-generating disc suitable for food container.
Background technique
Kettle is the necessity of life, from coal gas kettle to intelligent plastic electric heating kettle, arrives stainless steel insulating pot, then to partly
Glass water pot, full glass water pot, product are being kept updating.It is glass physical stability of characteristics, safety, clean, it will not be with heating
Food generate chemical reaction, do not have the secret worry of heavy metal, the transparent body of glass can penetrate far infrared, promoted water quality,
Optimize water source.
Current full glass water pot substantially has technologies several in this way: transparent nano film, carbon film and thick film.The first two kind power declines
Subtract fastly, abandoned by various manufacturers, the latter's power stability is good, but technique requires height, wants to the processing index of glass body
Ask stringent, such as: smoothness, the uniformity of thickness, compactness cannot have bubble, hollow etc..In These parameters, any one
Standard is not achieved, Electric radiant Heating Film is also easy to produce hot knot and micro- sudden strain of a muscle electric discharge, and instantaneous temperature is high, and it is broken to eventually lead to vitreum.Moreover, hair
Hotting mask needs temperature characterisitic, the matched coefficients of thermal expansion with glass, while good can also adhere to, infiltrate with glass.And
It also to fire and test after the slurry modulation of heating film, test period is long, and uncertain factor is big, once the physical property variation of glass is again
The long period is spent to re-modulate.
With current glass industry level of processing both domestic and external, it is unable to satisfy above-mentioned processing index.Then at high cost
High quartz glass comes into being to substitute the solution of the Pyrex of good economy performance.However, the cost of quartz glass is
Tens times of Pyrex, although the thickness of quartz, flatness, bubble hollow are superior to borosilicate, quartzy fusing point is high, kettle body at
Type difficult processing, cost is huge, is unable to volume production.
In order to solve the inherent shortcoming of glass material, occur other some solutions these years, such as: cut bottom glass
Glass kettle body uses ceramic heating plate/crystallite heating plate and silica gel sealing ring, is embedded in and cuts in the glass pot body of bottom, form one kind
Pseudo- full glass health-promotion kettle.It is directly contacted with heating liquid due to metal heating tray, although heat transfer efficiency can be improved, it is broken
It is broken all-glass theory, during hot cooking food, food and silica gel are chemically reacted, and cause pollution, discoloration, heavy metal super
Mark.Moreover, the place of sealing ring and heater transition is usually also the dead angle of cleaning, it cannot be guaranteed that safety and sanitation.In addition, above-mentioned
The sealing consistency of structure is bad, can not achieve volume production.
For another example: heating film is attached directly in kettle body, since kettle body material conducts heat is bad, be easy to cause hot-spot,
So that heating film overheats and ablation, it is also possible to cause kettle body to rupture because kettle body material cold-heat shrinks unevenness.
For another example: the scheme of external radiation places quartz heating-pipe in glass pot bottom, to being filled with water, glass container adds
Heat, the disadvantage is that: bottom heat is high, it is seen that polished bard eye, control system inaccuracy etc..
That is, the scheme of current full glass water pot can not meet simultaneously, cost is relatively low, the service life is long, safety, can volume production, cleaning
The problems such as being easy.
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of metallic object suitable for food container, make its application
When making full glass water pot, can solve simultaneously cost is relatively low, the service life is long, safety, can volume production, cleaning the problems such as being easy.
Technical problem to be solved by the present invention lies in provide a kind of heat-generating disc suitable for food container, make its application
When making full glass water pot, can solve simultaneously cost is relatively low, the service life is long, safety, can volume production, cleaning the problems such as being easy.
To reach above-mentioned technical effect, the present invention provides a kind of metallic object suitable for food container, the metallic objects
Upper to be coated with glass powder coating, the glass powder coating can form glass function coating in metal surface;
Wherein, the glass powder coating is mainly made of 50~90wt% glass powder and 10~50wt% organic component;
The glass powder includes glass powder component A and 0~83wt% the glass powder component B of 17~100wt%, the glass
Powder component A includes SiO2、Al2O3、B2O3, one of CaO or a variety of.
As an improvement of the above technical solution, the glass powder component A includes:
SiO25~60%, Al2O35~60%, B2O32~10%, CaO 5~60%.
As an improvement of the above technical solution, the glass powder component B includes:
MgO 0~5%, P2O50~5%, TiO20~5%, ZrO20~5%, ZnO 0~50%, K2O 0~5%,
Na2O 0~5%, Li2O 0~10%.
As an improvement of the above technical solution, the glass powder is made by following methods:
By glass powder component A and glass powder component B 1250~1450 DEG C melting uniformly, water quenching, drying, crush to get
To glass powder.
As an improvement of the above technical solution, the glass powder coating is mainly by 50~80wt% glass powder, 10~
40wt% organic component and 0.5~10wt% functional mixture composition;
The glass powder coating can form the glass function coating with function far infrared radiation function in metal surface.
As an improvement of the above technical solution, the functional mixture includes oxide, carbide, nitride, rare earth oxygen
One of compound is a variety of.
As an improvement of the above technical solution, the functional mixture include iron oxide, nickel oxide, cobalt oxide, copper oxide,
One of zinc oxide, silica, silicon carbide, tungsten carbide, aluminium nitride, aluminum tungstate, rare earth oxide are a variety of.
As an improvement of the above technical solution, the glass function coating 9~50 μm infra red radiation band emissivity >
0.5。
As an improvement of the above technical solution, the glass function coating 9~15 μm infra red radiation band emissivity >
0.8。
As an improvement of the above technical solution, the organic component is resin or alcohols solvent, and the resin includes ethyl
Cellulose, the alcohols solvent include terpinol.
Correspondingly, being coated with glass on the heat-generating disc the present invention also provides a kind of heat-generating disc suitable for food container
Powder coating, the glass powder coating can form glass function coating in fever panel surface;
Wherein, the glass powder coating is mainly made of 50~90wt% glass powder and 10~50wt% organic component;
The glass powder includes glass powder component A and 0~83wt% the glass powder component B of 17~100wt%, the glass
Powder component A includes SiO2、Al2O3、B2O3, one of CaO or a variety of.
Implement the invention has the following beneficial effects:
The present invention provides a kind of metallic object and heat-generating disc suitable for food container, and metal surface is formed with one layer of glass
Functional coating makes it at applied at elevated temperature (heating for food), has safety, health, the function of health care.It is formed with glass function
The metallic object of energy coating, has the advantages that
1, heat-resist: coating is intact after being subjected to 0-500 DEG C of cooling thermal impact, does not crack, and does not fall off;
2, compactness is good: the coating can completely cut off completely metal surface and air, high-temperature heating when, guarantee metal not by
Oxidation;The coating has good insulating properties simultaneously, when being used for electric heating plate, can charge to avoid surface, meet electrical safety
Needs;
3, chemical stability is good: the coating substantially belongs to crystallite-glass mixture, and chemical property is stablized, for adding
When warm-served food product (< 400 DEG C), element-free is precipitated, and acid-proof alkaline is good, can meet the needs of food safety with direct food contact;
The coating is bright and clean, smooth, and it is easy to clean to encounter greasy dirt;
4, specific far infrared radiation feature: in 50~200 DEG C of temperature ranges, infra-red radiation of the coating at 9~15 μm
Wave band emissivity > 0.8, the radiation wave band are also the infra-red radiation fluctuation of water and human body simultaneously, are accordingly used in heating water or food,
There is health-care effect to human body.
5, when the present invention is formed with the metallic object of glass function coating for making full glass heating container, as heating
Pedestal solves the problems, such as that glass thermal coefficient is extremely low from source, to realize high-power, which can
Matched with arbitrarily being set in 800-3000 watts of area.
6, the metallic object that the present invention is formed with glass function coating has excellent thermal conductivity, and the operating temperature of heat-generating disc is only
At 109 degree or so, so that the stability of heat-generating disc, reliability, life cycle be made to greatly improve.
Therefore, the glass function coating is fine and close, bright and clean, smooth, hard, chemical property is stable, it is made to be applied to production
When full glass water pot, can solve simultaneously cost is relatively low, the service life is long, safety, can volume production, cleaning the problems such as being easy.
Detailed description of the invention
Fig. 1 is a kind of cross-sectional view of nonmetallic heating kettle of the present invention.
Fig. 2 is the perspective view of the nonmetallic kettle body of the present invention.
Fig. 3 is the front sectional view of the nonmetallic kettle body of the present invention.
Fig. 4 is the partial enlarged view in the portion A shown in Fig. 3.
Fig. 5 is the bottom view of the nonmetallic kettle body of the present invention.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made into one below in conjunction with attached drawing
The detailed description of step.
The scheme of current full glass water pot can not meet simultaneously cost is relatively low, the service life is long, safety, can volume production, cleaning hold
The problems such as easy.Therefore, the present invention provides a kind of solution of new thought, by increasing on the metal heating tray of heated base
If one layer of glass function coating, full glass water pot is realized with this.The method structure is simple, and cleaning is easy, easy to accomplish, however
Glass and metal belong to two kinds of entirely different materials, and performance gap is very big, and glass is the non-conductor of heat, is sent out with metal
Hot plate connection is difficult.How it to be equipped with glass function coating on metal heating tray, and solves it and be connected firmly, do not crack, do not take off
Fall, service life length, safety, good heat conductivity the problems such as, become key point.
For this purpose, the present invention devises a kind of metallic object suitable for food container, glass powder is coated on the metallic object
Coating, the glass powder coating can form glass function coating in metal surface;The glass powder coating mainly by 50~
90wt% glass powder and 10~50wt% organic component composition.
Wherein, the glass powder includes glass powder component A and 0~83wt% the glass powder component B of 17~100wt%, institute
Stating glass powder component A includes SiO2、Al2O3、B2O3, one of CaO or a variety of.The glass powder component B includes MgO, P2O5,
TiO2, ZrO2, ZnO, K2O, Na2O, Li2One of O or a variety of.
Preferably, the glass powder component A includes: SiO25~60%, Al2O35~60%, B2O32~10%, CaO
5~60%.More preferably, the glass powder component A includes: SiO210~50%, Al2O310~50%, B2O33~8%, CaO
10~50%.
The glass powder component B includes: MgO 0~5%, P2O50~5%, TiO20~5%, ZrO20~5%, ZnO
0~50%, K2O 0~5%, Na2O 0~5%, Li2O 0~10%.
Preferably, the glass powder component B includes: MgO 1~4%, P2O51~4%, TiO21~4%, ZrO21~
4%, ZnO 10~50%, K2O 1~4%, Na2O 1~4%, Li2O 2~8%.
More preferably, the glass powder component B includes: MgO 2~3%, P2O52~3%, TiO22~3%, ZrO22~
3%, ZnO 15~35%, K2O 2~3%, Na2O 2~3%, Li2O 3~5%.
The glass powder component A is necessary component, and glass powder component B is that component may be selected, by adjusting glass powder component
A, in glass powder component B different component content ratio, different metal surfaces can be matched, form fine and close coating.
The glass powder is made by following methods:
By glass powder component A and glass powder component B 1250~1450 DEG C melting uniformly, water quenching, drying, crush to get
To glass powder.Crush obtained powder D50=2.5 μm.
Common glass for sealing powder on the market, can not meet simultaneously matching metal surface, heat-resist, compactness is good,
Chemical stability is good, safety and sanitation, specific far infrared radiation etc. require.That is, common glass for sealing powder on the market
May there is no problem in terms of matching metal base, but heavy metal may be contained, it is also relatively low using temperature, when it is used to burn
When kettle, hot and cold alternation is constantly carried out, is easily broken.
As glass powder coating more preferably embodiment, mainly by 50~80wt% glass powder, 0.5~10wt% function
Mixture and 10~50wt% of organic component composition.Preferably, the glass powder coating is mainly by 55~75wt% glass powder,
2~10wt% functional mixture and 15~35wt% of organic component composition.The glass powder coating can be formed in metal surface
Glass function coating with function far infrared radiation function.
The functional mixture is the mixture of a variety of inorganic compounds, and main purpose is to realize specific Far-infrared spoke
Penetrate function.The functional mixture includes one of oxide, carbide, nitride, rare earth oxide or a variety of.
Specifically, the functional mixture include iron oxide, nickel oxide, cobalt oxide, copper oxide, zinc oxide, silica,
One of silicon carbide, tungsten carbide, aluminium nitride, aluminum tungstate, rare earth oxide are a variety of, are matched by above-mentioned different compounds,
The adjustable glass function coating it is different at use temperature, have optimal infra-red radiation emissivity.
Common glass for sealing powder does not have far infrared characteristic radiation function on the market, for heating water or food, to people
Body does not have health-care effect.
The organic component can select resin or alcohols solvent, and the resin includes ethyl cellulose, and the alcohols is molten
Agent includes terpinol, but not limited to this.The organic component provides certain rheological behavior to coating as auxiliary material, the company of being formed
Continue uniform film layer.
The present invention mixes functional mixture with glass powder, organic component, is sufficiently stirred, and is uniformly dispersed and can be prepared by institute
State glass powder coating.The glass powder coating can form the glass function coating with function far infrared radiation function in metal surface.
The glass function coating with a thickness of 9~50 μm, preferably 9~15 μm or 20~40 μm.
In 50~200 DEG C of temperature ranges, the glass function coating 9~50 μm infra red radiation band emissivity >
0.5。
Preferably, in 50~200 DEG C of temperature ranges, infra red radiation band of the glass function coating at 9~15 μm
Emissivity > 0.8.In 50~200 DEG C of temperature ranges, the glass function coating emits in 20~40 μm of infra red radiation band
Rate > 0.8.The radiation wave band is also the infra-red radiation fluctuation of water and human body simultaneously, is accordingly used in heating water or food, has to human body
Health-care effect.
The metallic object includes aluminium, copper, stainless steel, aluminium alloy or copper alloy, but is not limited to.Coating of the present invention can satisfy
The demand of a variety of different metals, by adjusting the content ratio of different component in glass powder component A, glass powder component B, can with
With different metal surfaces, fine and close coating is formed.Again by matching feature mixture, the adjustable glass function is applied
Layer it is different at use temperature, have optimal infra-red radiation emissivity.
Coating is coated on metallic object, glass function coating is formed, has the advantages that
1, heat-resist: coating is intact after being subjected to 0-500 DEG C of cooling thermal impact, does not crack, and does not fall off;
2, compactness is good: the coating can completely cut off completely metal surface and air, high-temperature heating when, guarantee metal not by
Oxidation;The coating has good insulating properties simultaneously, when being used for electric heating plate, can charge to avoid surface, meet electrical safety
Needs;
3, chemical stability is good: the coating substantially belongs to crystallite-glass mixture, and chemical property is stablized, for adding
When warm-served food product (< 400 DEG C), element-free is precipitated, and acid-proof alkaline is good, can meet the needs of food safety with direct food contact;
The coating is bright and clean, smooth, and it is easy to clean to encounter greasy dirt;
4, specific far infrared radiation feature: in 50~200 DEG C of temperature ranges, infra-red radiation of the coating at 9~15 μm
Wave band emissivity > 0.8, the radiation wave band are also the infra-red radiation fluctuation of water and human body simultaneously, are accordingly used in heating water or food,
There is health-care effect to human body.
Therefore, the glass function coating is fine and close, bright and clean, smooth, hard, chemical property is stable, it is made to be applied to production
When full glass water pot, can solve simultaneously cost is relatively low, the service life is long, safety, can volume production, cleaning the problems such as being easy.Specifically, this hair
When the bright metallic object for being formed with glass function coating is for making full glass heating container, it is used as heated base, from source
Solve the problems, such as that glass thermal coefficient is extremely low, to realize high-power, which can be in 800-3000
Watt area, which is arbitrarily set, matches.Moreover, the metallic object that the present invention is formed with glass function coating has excellent thermal conductivity, heat-generating disc
Operating temperature is only at 109 degree or so, so that the stability of heat-generating disc, reliability, life cycle be made to greatly improve.
Further, the metallic object is made by following methods:
Metal body surface is pre-processed, keeps its bright and clean, smooth;
By the way of spraying or printing, coating is uniformly coated on metal body surface;
The metallic object for being coated with coating is sintered at 600~1000 DEG C, is formed on the surface of metallic object fine and close, bright and clean, flat
The glass function coating whole, hard, chemical property is stable.
Correspondingly, being coated with glass on the heat-generating disc invention additionally discloses a kind of heat-generating disc suitable for food container
Powder coating, the glass powder coating can form glass function coating in fever panel surface;Wherein, the glass powder coating mainly by
50~90wt% glass powder and 10~50wt% organic component composition;The glass powder includes the glass powder of 17~100wt%
Component A and 0~83wt% glass powder component B, the glass powder component A includes SiO2、Al2O3、B2O3, one of CaO or more
Kind.
It should be noted that the technical detail for the glass powder coating being set on heat-generating disc is same as above, details are not described herein.
As shown in Figure 1, nonmetallic heating device includes nonmetallic kettle body 1, heated base 2 and function control pedestal 3, non-gold
Belong to kettle body 1 and heated base 2 is molded as one structure, then be placed on function control pedestal 3, realizes that intelligent control is heated up water.
The heated base 2 includes heat-generating disc 21, and the surface of the heat-generating disc 21 is formed at least one layer of glass function and applies
Layer 22, the heat-generating disc 21 are molded as one structure by glass function coating 22 and nonmetallic kettle body 1, and the glass function applies
Food in nonmetallic kettle body 1 is spaced by layer 22 with heat-generating disc 21.
In conjunction with Fig. 2 and Fig. 3, the nonmetallic kettle body 1 is to cut the kettle body at bottom.
It should be noted that the kettle body for cutting bottom only includes side wall, and it is not provided with bottom, the side wall forms hollow kettle body
Structure.The present invention cuts the bottom of the kettle body 1 at bottom and the glass function coating 22 of heated base connects, and forms a complete kettle body knot
Structure.
The nonmetallic kettle body 1 can be glass pot body, ceramic pot body or quartzy kettle body, but not limited to this.Preferably, institute
Stating nonmetallic kettle body is glass pot body.
As shown in figure 5, the heat-generating disc 21 is located at the bottom of glass function coating 22, it is made of metal, such as aluminium,
Copper, stainless steel, aluminium alloy or copper alloy.The heat-generating disc 21 is preferably heating film, but not limited to this.
Further, as shown in Figure 3 and Figure 4, in order to guarantee between nonmetallic kettle body and glass function coating have more preferably
Connection effect, the nonmetallic kettle body 11 for cutting bottom includes bottle body 11A, the recess portion 11B connecting with bottle body 11A or protrusion, described
Recess portion 11B or protrusion either laterally or medially form an evener 11C, and the evener 11C passes through with glass function coating 22
Glass powder coating is connected and fixed.
Preferably, the width of the evener is 2-5mm.If the width of flatness is less than 2mm, lead to compactness not
It is good, it is easy to happen leak or infiltration.If the width of flatness is greater than 5mm, the heat transfer efficiency of heating device will affect.
Fixed ring can be equipped on the recess portion 11B or protrusion.The fixed ring can according to the face shaping of product come
Matching design is carried out, moreover, be also provided with connector in the fixed ring, for realizing being connected and fixed for kettle body and pedestal.
The nonmetallic heating device can be the kitchen appliances such as kettle, electrical boiler, electric cooker, but not limited to this.Figure
Heating device shown in 1-4 is kettle.
The present invention forms glass function coating on the surface of heat-generating disc using coating, is connected to form one formula with glass pot body
Full glass heating kettle, full glass heating kettle property is stable, safety, clean, will not generate chemical reaction with the food of heating, not have
There are the secret worry of heavy metal, health.Moreover, the full glass heating kettle good heat conductivity of the present invention, the heat that heat-generating disc can be made to issue
Uniformly, it is efficiently transmitted to kettle body and heated liquid, and then improves the service life of kettle body and heater, avoids kettle body broken
It splits, avoids heater ablation, avoid being detached between kettle body and heater.
Therefore, present invention employs the nonmetallic heating kettle of brand new, it can solve that cost is relatively low, the service life is long, peace simultaneously
Entirely, can volume production, cleaning be easy the problems such as.
With specific embodiment, the present invention is further explained below
Embodiment 1
430 stainless steel surfaces form glass function coating
1, the preparation of glass powder: the proportion of glass powder is SiO229%, Al2O314%, B2O37%, CaO 45%, TiO2
3%, ZrO22%, by said components, in 1450 DEG C of meltings, uniform, water quenching, drying, crushing obtain D50=2.5 μm of powder, i.e.,
Obtain glass powder;
2, coating is modulated: said components are sufficiently stirred for organic component 38%, glass powder 62%, and it is equal to cross three-roller dispersion
It is even, obtain the coating that viscosity is 1~2pa.s;
3,430 stainless steel surfaces are cleaned up, by the way of spraying, coating are uniformly coated on stainless steel surface,
It is dried at 150 DEG C, then in 850 DEG C of sintering 10min, obtains about 20~40 μm of thickness of semitransparent coating;
4, the coating can be used for 430 stainless steel surfaces, in 400 DEG C or less steady operations, can be used for heating electrical appliance heat-generating disc
Surface treatment.
Embodiment 2
430 stainless steel surfaces form glass function coating
1, the preparation of glass powder: the proportion of glass powder is SiO232%, Al2O312%, B2O37%, CaO 45%, TiO2
2%, ZrO22%, by said components, in 1450 DEG C of meltings, uniform, water quenching, drying, crushing obtain D50=2.5 μm of powder, i.e.,
Obtain glass powder;
2, the proportion of functional mixture: tungsten carbide 60%, iron oxide 25%, zinc oxide 15%;
3, coating is modulated: said components are sufficiently stirred for organic component 40%, glass powder 50%, functional mixture 10%,
It crosses three-roller to be uniformly dispersed, obtains the coating that viscosity is 1~2pa.s;
4,430 stainless steel surfaces are cleaned up, by the way of spraying, coating are uniformly coated on stainless steel surface,
It is dried at 150 DEG C, then in 850 DEG C of sintering 10min, obtains about 9~15 μm of thickness of semitransparent coating;
5, the coating can be used for 430 stainless steel surfaces, in 400 DEG C or less steady operations, have apparent far infrared radiation
Feature can be used for the surface treatment of heating electrical appliance heat-generating disc.
Embodiment 3
Aluminium base plate surface forms glass function coating
1, the preparation of glass powder: the proportion of glass powder is SiO25%, Al2O330%, B2O38%, CaO 50%, TiO2
3%, ZrO23%, K2O1%, by said components, in 1250 DEG C of meltings, uniform, water quenching, drying, crushing obtain D50=2.5 μm
Powder to get arrive glass powder;
2, coating is modulated: said components are sufficiently stirred for organic component 25%, glass powder 75%, and it is equal to cross three-roller dispersion
It is even, obtain the coating that viscosity is 20~30pa.s;
3, aluminum substrate surface clean is clean, by the way of silk-screen printing, coating is uniformly coated on aluminium base plate surface,
It is dried at 150 DEG C, then in 650 DEG C of sintering 10min, obtains about 20~40 μm of thickness of semitransparent coating;
4, the coating can be used for aluminium base plate surface, in 300 DEG C or less steady operations, can be used for part heating electrical appliance heat-generating disc
Surface treatment.
Embodiment 4
Aluminium base plate surface forms glass function coating
1, the preparation of glass powder: the proportion of glass powder is SiO210%, Al2O325%, B2O310%, CaO 50%,
TiO22%, ZrO22%, K2O 1%, by said components, in 1250 DEG C of meltings, uniform, water quenching, drying, crushing obtain D50=2.5
μm powder to get arrive glass powder;
2, the proportion of functional mixture: silica 70%, iron oxide 20%, copper oxide 10%;
3, coating is modulated: said components are sufficiently stirred for organic component 25%, glass powder 70%, functional mixture 5%,
It crosses three-roller to be uniformly dispersed, obtains the coating that viscosity is 20~30pa.s;
4, aluminum substrate surface clean is clean, by the way of silk-screen printing, coating is uniformly coated on aluminium base plate surface,
It is dried at 150 DEG C, then in 650 DEG C of sintering 10min, obtains about 20~40 μm of thickness of semitransparent coating;
5, the coating can be used for aluminium base plate surface, in 300 DEG C or less steady operations, have apparent far infrared radiation special
Sign, can be used for the surface treatment of part heating electrical appliance heat-generating disc.
Embodiment 5
304 stainless steel surfaces form glass function coating
1, the preparation of glass powder: the proportion of glass powder is SiO256%, P2O53%, Li2O 6%, CaO 0.5%, K2O
2.5%, ZnO 28%, B2O34%, by said components, in 1450 DEG C of meltings, uniform, water quenching, drying, crushing obtain D50=2.5 μ
The powder of m to get arrive glass powder;
2, the proportion of functional mixture: silicon carbide 60%, cobalt oxide 20%, copper oxide 20%;
3, coating is modulated: said components are sufficiently stirred for organic component 35%, glass powder 62%, functional mixture 3%,
It crosses three-roller to be uniformly dispersed, obtains the coating that viscosity is 1~2pa.s;
4,304 stainless steel surfaces are cleaned up, by the way of spraying, coating are uniformly coated on stainless steel surface,
It is dried at 150 DEG C, then in 850 DEG C of sintering 10min, obtains about 20~40 μm of thickness of semitransparent coating;
5, the coating can be used for 304 stainless steel surfaces, in 400 DEG C or less steady operations, have apparent far infrared radiation
Feature can be used for the surface treatment of heating electrical appliance heat-generating disc.
Embodiment 6
304 stainless steel surfaces form glass function coating
1, the preparation of glass powder: the proportion of glass powder is SiO215%, Al2O319%, P2O53%, Li2O 6%, CaO
0.5%, K2O 2.5%, ZnO 50%, B2O34%, by said components, in 1450 DEG C of meltings, uniform, water quenching, drying are crushed
To D50=2.5 μm of powder to get arrive glass powder;
2, the proportion of functional mixture: silicon carbide 60%, iron oxide 20%, copper oxide 20%;
3, coating is modulated: said components are sufficiently stirred for organic component 19%, glass powder 80%, functional mixture 1%,
It crosses three-roller to be uniformly dispersed, obtains the coating that viscosity is 1~2pa.s;
4,304 stainless steel surfaces are cleaned up, by the way of spraying, coating are uniformly coated on stainless steel surface,
It is dried at 150 DEG C, then in 850 DEG C of sintering 10min, obtains about 20~40 μm of thickness of semitransparent coating;
5, the coating can be used for 304 stainless steel surfaces, in 400 DEG C or less steady operations, have apparent far infrared radiation
Feature can be used for the surface treatment of heating electrical appliance heat-generating disc.
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art
For, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (10)
1. a kind of metallic object suitable for food container, which is characterized in that glass powder coating is coated on the metallic object, it is described
Glass powder coating can form glass function coating in metal surface;
Wherein, the glass powder coating is mainly made of 50~90wt% glass powder and 10~50wt% organic component;
The glass powder includes glass powder component A and 0~83wt% glass the powder component B of 17~100wt%, the glass powder group
Dividing A includes SiO2、Al2O3、B2O3, one of CaO or a variety of.
2. being suitable for the metallic object of food container as described in claim 1, which is characterized in that the glass powder component A includes:
SiO25~60%, Al2O35~60%, B2O32~10%, CaO 5~60%.
3. being suitable for the metallic object of food container as described in claim 1, which is characterized in that the glass powder component B includes:
MgO 0~5%, P2O50~5%, TiO20~5%, ZrO20~5%, ZnO 0~50%, K2O 0~5%, Na2O
0~5%, Li2O 0~10%.
4. the metallic object as claimed in claim 1,2 or 3 suitable for food container, which is characterized in that the glass powder is under
Method is stated to be made:
Glass powder component A and glass powder component B uniform, water quenching, drying in 1250~1450 DEG C of meltings is crushed to get glass is arrived
Glass powder.
5. as described in claim 1 be suitable for food container metallic object, which is characterized in that the glass powder coating mainly by
50~80wt% glass powder, 10~40wt% organic component and 0.5~10wt% functional mixture composition;
The glass powder coating can form the glass function coating with function far infrared radiation function in metal surface.
6. being suitable for the metallic object of food container as claimed in claim 5, which is characterized in that the functional mixture includes oxygen
One of compound, carbide, nitride, rare earth oxide are a variety of.
7. being suitable for the metallic object of food container as claimed in claim 6, which is characterized in that the functional mixture includes oxygen
Change iron, nickel oxide, cobalt oxide, copper oxide, zinc oxide, silica, silicon carbide, tungsten carbide, aluminium nitride, aluminum tungstate, rare earth oxygen
One of compound is a variety of.
8. being suitable for the metallic object of food container as claimed in claim 5, which is characterized in that the glass function coating is 9
~50 μm of infra red radiation band emissivity > 0.5.
9. as described in claim 1 be suitable for food container metallic object, which is characterized in that the organic component be resin or
Alcohols solvent, the resin include ethyl cellulose, and the alcohols solvent includes terpinol.
10. a kind of heat-generating disc suitable for food container, which is characterized in that be coated with glass powder coating, institute on the heat-generating disc
Glass function coating can be formed in fever panel surface by stating glass powder coating;
Wherein, the glass powder coating is mainly made of 50~90wt% glass powder and 10~50wt% organic component;
The glass powder includes glass powder component A and 0~83wt% glass the powder component B of 17~100wt%, the glass powder group
Dividing A includes SiO2、Al2O3、B2O3, one of CaO or a variety of.
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CN201910097392.0A CN109730540A (en) | 2019-01-31 | 2019-01-31 | Metallic object and heat-generating disc suitable for food container |
CN202010078221.6A CN111166188B (en) | 2019-01-31 | 2020-01-23 | Metal body and heating plate suitable for food utensil |
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CN202010078221.6A Active CN111166188B (en) | 2019-01-31 | 2020-01-23 | Metal body and heating plate suitable for food utensil |
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CN1130336A (en) * | 1995-03-02 | 1996-09-04 | 刘永芬 | Surface uncharged direct heating infrared radiation heater |
DE102005046570B4 (en) * | 2005-10-01 | 2010-01-21 | Schott Ag | Bottom coated glass ceramic plate |
CN102010126A (en) * | 2009-09-07 | 2011-04-13 | 上海歌灵新材料科技有限公司 | Lead-free frit for glass color ceramic glaze and preparation method thereof |
CN204292968U (en) * | 2014-11-27 | 2015-04-29 | 中山市新纪元电器有限公司 | A kind of kettle courage device with quartz glass plate |
CN104858434B (en) * | 2015-04-21 | 2017-03-08 | 中国人民解放军国防科学技术大学 | The oxide coating high temperature resistant low infrared emissivity coating strengthens oxide-base composite and preparation method thereof |
CN107935567B (en) * | 2017-12-05 | 2020-10-16 | 海南中航特玻科技有限公司 | Composite mirror blank material for ceramic-based space reflector |
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