CN109722891B - A kind of anti-xanthochromia softening compositions of hyperconcetration - Google Patents
A kind of anti-xanthochromia softening compositions of hyperconcetration Download PDFInfo
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- CN109722891B CN109722891B CN201811632204.1A CN201811632204A CN109722891B CN 109722891 B CN109722891 B CN 109722891B CN 201811632204 A CN201811632204 A CN 201811632204A CN 109722891 B CN109722891 B CN 109722891B
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- hyperconcetration
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Abstract
The present invention relates to a kind of fabric-conditioning compositions, provide a kind of anti-xanthochromia softening compositions of hyperconcetration, and the composition is made of following components and parts by weight: 40-70 parts of cation softener of (A) poplar bundles；(B) it modified siloxane mixture 60-90 parts, is made of modified siloxane A and modified siloxane B；(C) film 10-30 parts；(D) solubilizer 5-10 parts；(E) yellowing-resistant component 3-7 parts.Product of the present invention is different from traditional softener, has hyperconcetration feature, can directly be watered as softener, use in proportion in any leviathan, and the dosage of product of the present invention corresponding to every 100 kilograms of dry cloth grass is only 0.3-0.5 kilograms, and dosage is few；By softener treated hotel towel class cloth grass, have the characteristics that submissive effect is good, whiteness is high, good hydrophilic property, antistatic and quick 130 DEG C of drying non yellowing.
Description
Technical field
The present invention relates to a kind of fabric-conditioning compositions, specially a kind of anti-xanthochromia softening compositions of hyperconcetration.
Background technique
Cloth grass is the common name of towel, the tablecloth and sheet, pillowcase etc. that guest room is placed in hotel guest room portion, is referred in hotel
Almost all with " cloth " related thing, include bedding such as bedding quilt cover, bat core, sheet bedcover, pillowcase pillow
Core, fitted sheet bed skirt, tailstock pad, neonychium and towel based article such as face-cloth, shawl, bath towel, bath mats, bathrobe etc., are also wrapped
Napkin containing the tablecloth, chair cover platform skirt, shower curtain etc. are usually all white.
Since cloth grass belongs to public use, spot above is varied, is cleaned with general detergent to it
It is extremely difficult to clean thoroughly, and cloth grass, in washing process, fiber fines often wind, intertwine, or even occurs
Fracture, after clothing is washed repeatedly, slickness that the alkalinity effect of detergent more makes fiber intrinsic, extensibility and it is elastic by
It influences, what is shown is that cloth grass seems to wear, deform and feel is stiff, and cloth grass washing times are more, and this feeling is just
It is more obvious, especially hard water washing more exacerbation xanthochromia and the phenomenon that hardening.It commonly needs that different function is added step by step
Detergent, operating procedure are complicated, and master washes step and usually requires temperature to be turned up to 60-80 DEG C in washing, such ability
So that cloth grass is washed clean, in this way, the addition of either complicated washing step or a variety of detergent all makes cloth careless
Wash increased costs.
Therefore, it in view of above-mentioned main problem, needs to develop a kind of anti-xanthochromia softening compositions of hyperconcetration, passes through cloth grass
The conditioning of softening compositions and cationic antistatic processing, fiber restore original form, do not play electrostatic, the fold on fabric
Also it significantly reduces, xanthochromia does not occur for fabric, shows comfortable feel and beautiful color, and make originally complicated pressers
Work becomes simple, easy, time saving and energy saving.
Summary of the invention
(deficiency) in order to overcome at least one of the drawbacks of the prior art described above, the present invention provide a kind of anti-Huang of hyperconcetration
Become softening compositions, product of the invention has hyperconcetration feature, can directly be watered in proportion as softener, any big
Type washing machine uses, the hotel towel class cloth grass by submissive processing, have submissive effect is good, whiteness is high, good hydrophilic property,
The features such as antistatic and quick 130 DEG C of drying non yellowing.
To achieve the above object, The technical solution adopted by the invention is as follows:
A kind of anti-xanthochromia softening compositions of hyperconcetration, by weight, consisting of:
(A) 40-70 parts of poplar bundles cation softener；
(B) it modified siloxane mixture 60-90 parts, is made of modified siloxane A and modified siloxane B；
(C) film: 10-30 parts；
(D) solubilizer: 5-10 parts；
(E) yellowing-resistant component: 3-7 parts.
Further, poplar bundles cation softener, the poplar bundles cation softener are following nitrogenous compounds,
Its molecular formula are as follows:
Wherein, R isThe softener has a core and four branches, compared to more general
Logical cationic softener, submissive effect is more prominent, and since its end is ester group, hydrophilic effect is more prominent.
Further, the modified siloxane mixture is made of modified siloxane A and modified siloxane B, modified silicon oxygen
The molecular structure of alkane A and modified siloxane B are as follows, but the R in modified siloxane A and modified siloxane B molecular formula3
It is different:
Wherein, in modified siloxane A molecule, R1For methyl, R2For hydroxyl, R3For
M is 5000-50000, n 50-500, and m/n >=100；In modified siloxane B molecule, R1For methyl, R2For hydroxyl, R3
ForM is 5000-50000, n 50-500, and m/n > 100；The modified siloxane A and
Modified siloxane B optimum weight ratio is 2:1, can play synergy, plays and improves antistatic property and raising fabric softening
Effect.
Further, in modified siloxane A molecule, R1For methyl, R2For hydroxyl, R3ForM is 5000-50000, n 50-500, and m/n >=100；In modified siloxane B molecule
In, R1For methyl, R2For hydroxyl, R3ForM be 5000-50000, n 50-500, and m/n >
100；The modified siloxane A and modified siloxane B weight ratio are 3:2.
Further, the film is film FC, the main component of the film are as follows: C17H35COOH。
Further, the solubilizer is sodium xylene sulfonate, xylene monosulfonic acid potassium, xylene monosulfonic acid amine, toluenesulfonic acid
Sodium, potassium toluene sulfonate, toluenesulfonic acid amine, cumene sodium sulfonate, isopropyl sulfonic acid potassium, isopropylbenzene sulfanilamide (SN) it is one or more, it is excellent
Select sodium xylene sulfonate.
Further, the yellowing-resistant group is divided into one of sodium dithionite, zinc dithionite, hydrogen peroxide, excellent
Select sodium dithionite.
Compared with prior art, the beneficial effect of technical solution of the present invention is:
1. product of the invention is different from traditional softener, there is hyperconcetration feature, can directly be watered in proportion becomes
Softener is used in any leviathan；The dosage of product of the present invention corresponding to every 100 kilograms of dry cloth grass is only 0.3-
0.5 kilogram, dosage is few；
2. having submissive by the anti-xanthochromia softening compositions of hyperconcetration of the invention treated hotel towel class cloth grass
The features such as effect is good, whiteness is high, good hydrophilic property, antistatic and quick 130 DEG C of drying non yellowing.
Specific embodiment
Further illustrate that the present invention, following embodiment are that the present invention is preferably implemented below by specific embodiment
Mode, but embodiments of the present invention are not limited by following embodiments, therefore the scope of protection of present invention not office
It is limited to described.
Embodiment 1-11 and comparative example 1 be carry out being mixed to get the anti-xanthochromia of hyperconcetration according to content in following table it is soft
Along composition, wherein film is film FC, and solubilizer is sodium xylene sulfonate, and yellowing-resistant group is divided into sodium dithionite.
The poplar bundles cation softener in the application is substituted using polyquaternium -7 in comparative example 2.
1 embodiment 1-7 dosage of each component of table
2 embodiment 8-11 dosage of each component of table
Submissive test condition uses: machine washing (fully automatic roll type washing machine), and laundry object is practical common cloth grass.
Wash conditions: 20 grams of the anti-xanthochromia softening compositions of the hyperconcetration of the embodiment of the present invention add water 24L, common cloth grass 4
Kilogram.Washing machine working procedure: washing 20mi n rinses 2 times, is dehydrated 3mi n, naturally dry.
Submissive test method are as follows: 10 people's Blind Test, according to 1 point for compliance it is minimum, 10 points be compliance highest, respectively into
Row marking, and provide average mark.
Antistatic property test content: according to the test request of " GB/T 12703.1-2008 textile antistatic property ",
The measurement of electrostatic potential and half-life period is carried out to above-mentioned test object treated fabric.
The antistatic property of softening compositions is mainly reflected by static of the fabric voltage and electrostatic pressure half-life period.Electrostatic
Voltage mainly judges the size of static of the fabric；It is required when half that electrostatic pressure half-life period is that fabric surface electrostatic potential decays to
Time, the main speed degree for reflecting static of the fabric decaying.The two comprehensive analysis could judge the anti-of softener more comprehensively
Antistatic property, after softener is handled, if static of the fabric voltage is low, and can decay rapidly, resisting for this softener is quiet
Electrical property is that comparison is outstanding；If electrostatic potential is higher, but rapid or electrostatic potential of decaying is lower, but the rate of decay is slow
Slowly, the antistatic property of this softener is more general；If electrostatic potential is high, the rate of decay is again slow, this softener
Antistatic property is with regard to undesirable.
Test obtains data as listed in table 3:
The test data of table 3 embodiment and comparative example
It can be seen that according to the comparison of embodiment 1-5 and comparative example 1-2, in the case where other components are fixed, tree
Cladodification cation softener plays the submissive scoring of raising and antistatic effect, dosage to be advisable at 40-60 parts, and 60 parts
When dosage it is best；In addition, in the case that fixed poplar bundles cation softener is 50 parts, according to the measurement of embodiment 6-11, when
For modified siloxane amount of the mixture at 60-90 parts, the flexibility and antistatic property for the cloth grass being washed are relatively good, and
And modified siloxane A: optimum efficiency can be obtained when modified siloxane B=2:1.
Meanwhile using the anti-xanthochromia softening compositions of hyperconcetration of the invention treated cloth grass, whiteness is high, washup
Xanthochromia does not occur after reason.
The above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be to this hair
The restriction of bright embodiment.For those of ordinary skill in the art, it can also make on the basis of the above description
Other various forms of variations or variation, there is no need and unable to be exhaustive to all embodiments.It is all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should be included in the protection of the claims in the present invention within mind and principle
Within the scope of.
Claims (6)
1. a kind of anti-xanthochromia softening compositions of hyperconcetration, which is characterized in that by weight, described submissive group of the anti-xanthochromia of hyperconcetration
Close the composition of object are as follows:
(A) 40-70 parts of poplar bundles cation softener；
(B) it modified siloxane mixture 60-90 parts, is made of modified siloxane A and modified siloxane B；
(C) film 10-30 parts；
(D) solubilizer 5-10 parts；
(E) yellowing-resistant component 3-7 parts；
The poplar bundles cation softener is nitrogenous compound, molecular formula are as follows:
Wherein, the R in above-mentioned molecular formula is
The molecular structure of the modified siloxane A and modified siloxane B is as follows:
Wherein, in modified siloxane A molecule, R1For methyl, R2For hydroxyl, R3ForM is
5000-50000, n 50-500, and m/n >=100；In modified siloxane B molecule, R1For methyl, R2For hydroxyl, R3ForM is 5000-50000, n 50-500, and m/n > 100.
2. the anti-xanthochromia softening compositions of hyperconcetration according to claim 1, the modified siloxane A and modified siloxane B
Weight ratio be 2:1.
3. -2 described in any item anti-xanthochromia softening compositions of hyperconcetration according to claim 1, which is characterized in that the film is
Film FC, the main component of the film are as follows: C17H35COOH。
4. -2 described in any item anti-xanthochromia softening compositions of hyperconcetration according to claim 1, which is characterized in that the solubilizer
For sodium xylene sulfonate, xylene monosulfonic acid potassium, xylene monosulfonic acid amine, toluenesulfonic acid sodium salt, potassium toluene sulfonate, toluenesulfonic acid amine, different
One of propyl benzene sodium sulfonate, isopropyl sulfonic acid potassium, isopropylbenzene sulfanilamide (SN) are a variety of.
5. -2 described in any item anti-xanthochromia softening compositions of hyperconcetration according to claim 1, which is characterized in that the yellowing-resistant
Group is divided into one of sodium dithionite, zinc dithionite, hydrogen peroxide.
6. a kind of washing methods, including use the anti-xanthochromia softening compositions of hyperconcetration as described in any one in claim 1-5 into
The method of row washing.
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| CN111518634A (en) * | 2020-05-13 | 2020-08-11 | 杭州炫墨生物科技有限公司 | Laundry detergent capable of increasing clothes flexibility |
| CN114703669B (en) * | 2022-03-31 | 2023-11-10 | 浙江传化功能新材料有限公司 | High-stability anti-phenolic yellowing silicone oil softener and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736580A (en) * | 2009-12-21 | 2010-06-16 | 北京绿泽宇和科技有限公司 | Fabric maintenance softener |
| CN102643435A (en) * | 2012-05-04 | 2012-08-22 | 浙江润禾有机硅新材料有限公司 | Supersoft hydrophilic block silicone oil compound and preparation method thereof |
| CN105463857A (en) * | 2015-11-16 | 2016-04-06 | 上海华峰超纤材料股份有限公司 | Environmentally friendly anti-siphon afterfinishing method for suede microfiber synthetic leather |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090163402A1 (en) * | 2007-12-19 | 2009-06-25 | Eastman Chemical Company | Fabric softener |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736580A (en) * | 2009-12-21 | 2010-06-16 | 北京绿泽宇和科技有限公司 | Fabric maintenance softener |
| CN102643435A (en) * | 2012-05-04 | 2012-08-22 | 浙江润禾有机硅新材料有限公司 | Supersoft hydrophilic block silicone oil compound and preparation method thereof |
| CN105463857A (en) * | 2015-11-16 | 2016-04-06 | 上海华峰超纤材料股份有限公司 | Environmentally friendly anti-siphon afterfinishing method for suede microfiber synthetic leather |
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Address after: 510000 No. 8 Huaxiu Road, Renren and Donghua Industrial Zone, Baiyun District, Guangzhou City, Guangdong Province Applicant after: Guangzhou Bailishi Clean Technology Co.,Ltd. Address before: 510000 No. 8 Huaxiu Road, Renren and Donghua Industrial Zone, Baiyun District, Guangzhou City, Guangdong Province Applicant before: GUANGZHOU BAILISHI HOTEL SUPPLIES CO.,LTD. |
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Address after: 510000 No.2 Huaxiu Road, Donghua Industrial Zone, Renhe Town, Baiyun District, Guangzhou City, Guangdong Province (Airport Baiyun) Patentee after: Guangdong BLS Cleaning Technology Co.,Ltd. Address before: 510000 No.2 Huaxiu Road, Donghua Industrial Zone, Renhe Town, Baiyun District, Guangzhou City, Guangdong Province (Airport Baiyun) Patentee before: Guangzhou Bailishi Clean Technology Co.,Ltd. |