CN109721777A - A kind of ageing-resistant cable and preparation method thereof - Google Patents

A kind of ageing-resistant cable and preparation method thereof Download PDF

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Publication number
CN109721777A
CN109721777A CN201811651844.7A CN201811651844A CN109721777A CN 109721777 A CN109721777 A CN 109721777A CN 201811651844 A CN201811651844 A CN 201811651844A CN 109721777 A CN109721777 A CN 109721777A
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CN
China
Prior art keywords
parts
ageing
rubber
resistant cable
agent
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Pending
Application number
CN201811651844.7A
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Chinese (zh)
Inventor
夏喜明
梁钰
梁福秋
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Anhui Tiankang Group Co Ltd
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Anhui Tiankang Group Co Ltd
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Priority to CN201811651844.7A priority Critical patent/CN109721777A/en
Publication of CN109721777A publication Critical patent/CN109721777A/en
Pending legal-status Critical Current

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Abstract

The present invention provides a kind of ageing-resistant cable and preparation method thereof, it is related to field of cable technology, ageing-resistant cable includes the raw material of following parts by weight: 23-41 parts of butadiene-styrene rubber, 18-24 parts of butadiene rubber, 17-31 parts of isoprene rubber, 12-17 parts of polyethylene, 9-13 parts of gas-phase silica, 6-12 parts of nano-titanium dioxide, 4-6 parts of polycarbonate, 7-11 parts of hollow glass micropearl, 8-16 parts of attapulgite, 4-8 parts of calcium acetylacetonate, 13-17 parts of activated Calcium carbonate, 0.3-0.5 parts of antioxidant, 0.7-0.9 parts of anti-aging agent, 0.4-0.8 parts of plasticizer, 0.2-0.4 parts and release agent 0.6-1.2 parts of coupling agent;Preparation method includes weighing raw material, crushing, stirring and extrusion molding.High-temperature resistant coating produced by the present invention has the advantages that durability.

Description

A kind of ageing-resistant cable and preparation method thereof
Technical field
The invention belongs to field of cable technology, and in particular to a kind of ageing-resistant cable and preparation method thereof.
Background technique
Cable is the important materials in power engineering, and cable is exposed for a long time to be exposed to the sun and rain in outdoor, or even is imbedded in Underground, by the corrosion of underground water, these lead to cable quick aging, damage the construction of cable, shorten its service life, because This, needs to develop a kind of ageing-resistant cable.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of ageing-resistant cables and preparation method thereof.
The present invention provides the following technical solutions:
A kind of ageing-resistant cable, the raw material including following parts by weight: 23-41 parts of butadiene-styrene rubber, butadiene rubber 18-24 Part, 17-31 parts of isoprene rubber, 12-17 parts of polyethylene, 9-13 parts of gas-phase silica, 6-12 parts of nano-titanium dioxide, polycarbonate 4-6 parts, it is 7-11 parts of hollow glass micropearl, 8-16 parts of attapulgite, 4-8 parts of calcium acetylacetonate, 13-17 parts of activated Calcium carbonate, anti- 0.3-0.5 parts of oxidant, 0.7-0.9 parts of anti-aging agent, 0.4-0.8 parts of plasticizer, 0.2-0.4 parts of coupling agent and release agent 0.6- 1.2 part.
Further, the raw material including following parts by weight: 25 parts of butadiene-styrene rubber, 21 parts of butadiene rubber, isoprene rubber 30 Part, 15 parts of polyethylene, 12 parts of gas-phase silica, 8 parts of nano-titanium dioxide, 4 parts of polycarbonate, 8 parts of hollow glass micropearl, bumps 9 parts of stick soil, 5 parts of calcium acetylacetonate, 15 parts of activated Calcium carbonate, 0.4 part of antioxidant, 0.7 part of anti-aging agent, 0.7 part of plasticizer, idol Join 0.4 part and 0.8 part of release agent of agent.
Further, the raw material including following parts by weight: 28 parts of butadiene-styrene rubber, 19 parts of butadiene rubber, isoprene rubber 18 It is part, 16 parts of polyethylene, 11 parts of gas-phase silica, 10 parts of nano-titanium dioxide, 5 parts of polycarbonate, 9 parts of hollow glass micropearl, recessed Convex stick native 13 parts, 6 parts of calcium acetylacetonate, 16 parts of activated Calcium carbonate, 0.4 part of antioxidant, 0.9 part of anti-aging agent, plasticizer 0.5 Part, 0.3 part of coupling agent and 0.9 part of release agent.
Further, the raw material including following parts by weight: 32 parts of butadiene-styrene rubber, 21 parts of butadiene rubber, isoprene rubber 24 It is part, 14.5 parts of polyethylene, 11 parts of gas-phase silica, 9 parts of nano-titanium dioxide, 5 parts of polycarbonate, 9 parts of hollow glass micropearl, recessed Convex stick native 12 parts, 6 parts of calcium acetylacetonate, 15 parts of activated Calcium carbonate, 0.4 part of antioxidant, 0.8 part of anti-aging agent, plasticizer 0.6 Part, 0.3 part of coupling agent and 0.9 part of release agent.
Further, the antioxidant is to diphenylamines.
Further, the anti-aging agent is anti-aging agent RD.
Further, the plasticizer is repefral.
A kind of preparation method of ageing-resistant cable, comprising the following steps:
(1) raw material is weighed according to the parts by weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, acetylacetone,2,4-pentanedione Calcium and activated Calcium carbonate are mixed, and stir 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent It is mixed with release agent, stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, in 100- 120 DEG C of mixing 20-25min are finally granulated with double screw extruder to get ageing-resistant cable.
Compared with prior art, the beneficial effects of the present invention are: ageing-resistant cable produced by the present invention has durability Good advantage.
Specific embodiment
Embodiment 1
A kind of ageing-resistant cable, the raw material including following weight: butadiene-styrene rubber 23kg, butadiene rubber 18kg, isoamyl rubber Glue 17kg, polyethylene 12kg, gas-phase silica 9kg, nano-titanium dioxide 6kg, polycarbonate 4kg, hollow glass micropearl 7kg, Attapulgite 8kg, calcium acetylacetonate 4kg, activated Calcium carbonate 13kg, antioxidant 0.3kg, anti-aging agent 0.7kg, plasticizer 0.4kg, coupling agent 0.2kg and release agent 0.6kg.
Antioxidant is to diphenylamines.
Anti-aging agent is anti-aging agent RD.
Plasticizer is repefral.
A kind of preparation method of ageing-resistant cable, comprising the following steps:
(1) raw material is weighed according to the weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, acetylacetone,2,4-pentanedione Calcium and activated Calcium carbonate are mixed, and stir 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent It is mixed with release agent, stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, in 100- 120 DEG C of mixing 20-25min are finally granulated with double screw extruder to get ageing-resistant cable.
Compared with prior art, the beneficial effects of the present invention are: ageing-resistant cable produced by the present invention has durability Good advantage.
Embodiment 2
A kind of ageing-resistant cable, the raw material including following weight: butadiene-styrene rubber 41kg, butadiene rubber 24kg, isoamyl rubber Glue 31kg, polyethylene 17kg, gas-phase silica 13kg, nano-titanium dioxide 12kg, polycarbonate 6kg, hollow glass micropearl 11kg, attapulgite 16kg, calcium acetylacetonate 8kg, activated Calcium carbonate 17kg, antioxidant 0.5kg, anti-aging agent 0.9kg, plasticising Agent 0.8kg, coupling agent 0.4kg and release agent 1.2kg.
Antioxidant is to diphenylamines.
Anti-aging agent is anti-aging agent RD.
Plasticizer is repefral.
A kind of preparation method of ageing-resistant cable, comprising the following steps:
(1) raw material is weighed according to the weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, acetylacetone,2,4-pentanedione Calcium and activated Calcium carbonate are mixed, and stir 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent It is mixed with release agent, stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, in 100- 120 DEG C of mixing 20-25min are finally granulated with double screw extruder to get ageing-resistant cable.
Compared with prior art, the beneficial effects of the present invention are: ageing-resistant cable produced by the present invention has durability Good advantage.
Embodiment 3
A kind of ageing-resistant cable, the raw material including following weight: butadiene-styrene rubber 25kg, butadiene rubber 21kg, isoamyl rubber Glue 30kg, polyethylene 15kg, gas-phase silica 12kg, nano-titanium dioxide 8kg, polycarbonate 4kg, hollow glass micropearl 8kg, Attapulgite 9kg, calcium acetylacetonate 5kg, activated Calcium carbonate 15kg, antioxidant 0.4kg, anti-aging agent 0.7kg, plasticizer 0.7kg, coupling agent 0.4kg and release agent 0.8kg.
Antioxidant is to diphenylamines.
Anti-aging agent is anti-aging agent RD.
Plasticizer is repefral.
A kind of preparation method of ageing-resistant cable, comprising the following steps:
(1) raw material is weighed according to the weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, acetylacetone,2,4-pentanedione Calcium and activated Calcium carbonate are mixed, and stir 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent It is mixed with release agent, stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, in 100- 120 DEG C of mixing 20-25min are finally granulated with double screw extruder to get ageing-resistant cable.
Compared with prior art, the beneficial effects of the present invention are: ageing-resistant cable produced by the present invention has durability Good advantage.
Embodiment 4
A kind of ageing-resistant cable, the raw material including following weight: butadiene-styrene rubber 28kg, butadiene rubber 19kg, isoamyl rubber Glue 18kg, polyethylene 16kg, gas-phase silica 11kg, nano-titanium dioxide 10kg, polycarbonate 5kg, hollow glass micropearl 9kg, attapulgite 13kg, calcium acetylacetonate 6kg, activated Calcium carbonate 16kg, antioxidant 0.4kg, anti-aging agent 0.9kg, plasticising Agent 0.5kg, coupling agent 0.3kg and release agent 0.9kg.
Antioxidant is to diphenylamines.
Anti-aging agent is anti-aging agent RD.
Plasticizer is repefral.
A kind of preparation method of ageing-resistant cable, comprising the following steps:
(1) raw material is weighed according to the weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, acetylacetone,2,4-pentanedione Calcium and activated Calcium carbonate are mixed, and stir 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent It is mixed with release agent, stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, in 100- 120 DEG C of mixing 20-25min are finally granulated with double screw extruder to get ageing-resistant cable.
Compared with prior art, the beneficial effects of the present invention are: ageing-resistant cable produced by the present invention has durability Good advantage.
Embodiment 5
A kind of ageing-resistant cable, the raw material including following weight: butadiene-styrene rubber 32kg, butadiene rubber 21kg, isoamyl rubber Glue 24kg, polyethylene 14.5kg, gas-phase silica 11kg, nano-titanium dioxide 9kg, polycarbonate 5kg, hollow glass micropearl 9kg, attapulgite 12kg, calcium acetylacetonate 6kg, activated Calcium carbonate 15kg, antioxidant 0.4kg, anti-aging agent 0.8kg, plasticising Agent 0.6kg, coupling agent 0.3kg and release agent 0.9kg.
Antioxidant is to diphenylamines.
Anti-aging agent is anti-aging agent RD.
Plasticizer is repefral.
A kind of preparation method of ageing-resistant cable, comprising the following steps:
(1) raw material is weighed according to the weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, acetylacetone,2,4-pentanedione Calcium and activated Calcium carbonate are mixed, and stir 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent It is mixed with release agent, stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, in 100- 120 DEG C of mixing 20-25min are finally granulated with double screw extruder to get ageing-resistant cable.
Compared with prior art, the beneficial effects of the present invention are: ageing-resistant cable produced by the present invention has durability Good advantage.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of ageing-resistant cable, which is characterized in that the raw material including following parts by weight: 23-41 parts of butadiene-styrene rubber, suitable fourth 18-24 parts of rubber, 17-31 parts of isoprene rubber, 12-17 parts of polyethylene, 9-13 parts of gas-phase silica, nano-titanium dioxide 6-12 Part, 4-6 parts of polycarbonate, 7-11 parts of hollow glass micropearl, 8-16 parts of attapulgite, 4-8 parts of calcium acetylacetonate, activated Calcium carbonate 13-17 parts, 0.3-0.5 parts of antioxidant, 0.7-0.9 parts of anti-aging agent, 0.4-0.8 parts of plasticizer, 0.2-0.4 parts of coupling agent and de- 0.6-1.2 parts of mould agent.
2. ageing-resistant cable according to claim 1, which is characterized in that the raw material including following parts by weight: butylbenzene 25 parts of rubber, 21 parts of butadiene rubber, 30 parts of isoprene rubber, 15 parts of polyethylene, 12 parts of gas-phase silica, 8 parts of nano-titanium dioxide, 4 parts of polycarbonate, 8 parts of hollow glass micropearl, 9 parts of attapulgite, 5 parts of calcium acetylacetonate, 15 parts of activated Calcium carbonate, antioxidant 0.4 part, 0.7 part of anti-aging agent, 0.7 part of plasticizer, 0.4 part of coupling agent and 0.8 part of release agent.
3. ageing-resistant cable according to claim 1, which is characterized in that the raw material including following parts by weight: butylbenzene 28 parts of rubber, 19 parts of butadiene rubber, 18 parts of isoprene rubber, 16 parts of polyethylene, 11 parts of gas-phase silica, nano-titanium dioxide 10 Part, 5 parts of polycarbonate, 9 parts of hollow glass micropearl, 13 parts of attapulgite, 6 parts of calcium acetylacetonate, 16 parts of activated Calcium carbonate, antioxygen 0.4 part of agent, 0.9 part of anti-aging agent, 0.5 part of plasticizer, 0.3 part of coupling agent and 0.9 part of release agent.
4. ageing-resistant cable according to claim 1, which is characterized in that the raw material including following parts by weight: butylbenzene 32 parts of rubber, 21 parts of butadiene rubber, 24 parts of isoprene rubber, 14.5 parts of polyethylene, 11 parts of gas-phase silica, nano-titanium dioxide 9 Part, 5 parts of polycarbonate, 9 parts of hollow glass micropearl, 12 parts of attapulgite, 6 parts of calcium acetylacetonate, 15 parts of activated Calcium carbonate, antioxygen 0.4 part of agent, 0.8 part of anti-aging agent, 0.6 part of plasticizer, 0.3 part of coupling agent and 0.9 part of release agent.
5. ageing-resistant cable according to claim 1, it is characterised in that: the antioxidant is to diphenylamines.
6. ageing-resistant cable according to claim 1, it is characterised in that: the anti-aging agent is anti-aging agent RD.
7. ageing-resistant cable according to claim 1, it is characterised in that: the plasticizer is phthalic acid diformazan Ester.
8. a kind of preparation method of the ageing-resistant cable as described in claim 1-7 any one, which is characterized in that including Following steps:
(1) raw material is weighed according to the parts by weight of ageing-resistant cable raw material;
(2) by gas-phase silica, nano-titanium dioxide, polycarbonate, hollow glass micropearl, attapulgite, calcium acetylacetonate and Activated Calcium carbonate is mixed, and stirs 25-40min to get mixture A;
(3) by butadiene-styrene rubber, butadiene rubber, isoprene rubber, polyethylene, antioxidant, anti-aging agent, plasticizer, coupling agent and de- Mould agent is mixed, and stirs 2-3h to get mixture B;
(4) the mixture B in the mixture A and step (3) in step (2) is mixed and added into reaction kettle, at 100-120 DEG C 20-25min is mixed, is finally granulated with double screw extruder to get ageing-resistant cable.
CN201811651844.7A 2018-12-31 2018-12-31 A kind of ageing-resistant cable and preparation method thereof Pending CN109721777A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110491594A (en) * 2019-08-30 2019-11-22 安徽电缆股份有限公司 A kind of cross-linking polyethylene insulated fire resistant water-proof ultraviolet-preventing power cable

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110491594A (en) * 2019-08-30 2019-11-22 安徽电缆股份有限公司 A kind of cross-linking polyethylene insulated fire resistant water-proof ultraviolet-preventing power cable

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