CN109704310A - A kind of manufacture craft of graphene carbon nano-tube film - Google Patents
A kind of manufacture craft of graphene carbon nano-tube film Download PDFInfo
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- CN109704310A CN109704310A CN201910158584.8A CN201910158584A CN109704310A CN 109704310 A CN109704310 A CN 109704310A CN 201910158584 A CN201910158584 A CN 201910158584A CN 109704310 A CN109704310 A CN 109704310A
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Abstract
The invention discloses a kind of manufacture crafts of graphene carbon nano-tube film, the following steps are included: by configured ethyl alcohol, thiophene, CVD tube furnace is conveyed by syringe pump after ferrocene raw material liq ultrasound and carries out heating operation, and it is passed through hydrogen and argon gas, obtain cotton-shaped graphene carbon nano tube line, cotton-shaped graphene carbon nano tube line is under the promotion of mixed gas, it is wound on cabinet collection cylinder after CVD tube furnace ceramic tube, until the winding thickness of cotton-shaped graphene carbon nano tube line reaches 3 centimetres or more, flat bench is then moved to be compacted, the cotton-shaped graphene carbon nano tube line wound on cabinet collection cylinder successively carries out sprinkling ethyl alcohol, cutting, rotary flat pressure compacting is finally carried out on flat bench, obtain graphene carbon nano-tube film.The manufacture craft of graphene carbon nano-tube film of the invention, rationally, the production time has obtained great shortening, improves production efficiency, meets the use of people for design.
Description
Technical field
The present invention relates to graphene carbon nano-tube film preparation field more particularly to a kind of graphene carbon nano-tube films
Manufacture craft.
Background technique
Graphene is a kind of honeycomb flat film formed by carbon atom with sp2 hybrid form, be it is a kind of only one
The quasi- two-dimensional material of atomic layer level thickness does monoatomic layer graphite so being called, due to its very good intensity, it is flexible, conductive,
Thermally conductive, optical characteristics has all obtained considerable hair in fields such as physics, materialogy, electronic information, computer, aerospaces
Exhibition, as presently found most thin, maximum intensity, a kind of strongest novel nano-material of electrical and thermal conductivity performance, wherein graphene
Carbon nano-tube film is graphene and one of the derived product that carbon nanotube combines, existing graphene carbon nano-tube film
Manufacture craft is cumbersome, therefore we have proposed a kind of manufacture crafts of graphene carbon nano-tube film for solving the above problems.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of production works of graphene carbon nano-tube film
Skill.
A kind of manufacture craft of graphene carbon nano-tube film proposed by the present invention, comprising the following steps:
S1: after configured ethyl alcohol, thiophene, ferrocene raw material liq are ultrasonically treated using ultrasonic equipment, ethyl alcohol, thiophene
Pheno, ferrocene raw material liq are conveyed in CVD tube furnace by syringe pump again, and then the inside of CVD tube furnace is passed through hydrogen and argon
Gas, the inside of CVD tube furnace build the atmosphere of hydrogen and argon gas, and the internal temperature of CVD tube furnace is set as 1200-
1300 DEG C, CVD tube furnace 1200-1300 DEG C at a temperature of the mixture of its inside is heated, CVD tube furnace go out
Cotton-shaped graphene carbon nano tube line is obtained at material；
Cotton-shaped graphene carbon nano tube line described in S2:S1 is under the promotion of the mixed gas of hydrogen and argon gas, cotton-shaped graphene
Carbon nano tube line is wound on cabinet collection cylinder after the ceramic tube of CVD tube furnace, until cotton-shaped graphene carbon is received
The winding thickness of mitron line reaches 3 centimetres or more；
S3: the cabinet collection cylinder that flocculence graphene carbon nano tube line is wound with described in S2 is moved to flat bench
On, and the flocculence graphene carbon nano tube line wound on the outside of cabinet collection cylinder is compacted on flat bench,
Then sprinkling tool carries out uniformly spraying ethyl alcohol on flocculence graphene carbon nano tube line, recycles cutting tool by graphene
Carbon nano tube line carries out cutting on the outside of cabinet collection cylinder and removes, and is placed on flat bench and carries out rotary flat pressure pressure
It is real, finally obtain graphene carbon nano-tube film.
Preferably, in the S3, cutting equipment is cutter or laser.
Preferably, in the S3, spray appliance is nozzle or watering can etc..
The manufacture craft of graphene carbon nano-tube film of the invention, rationally, the production time has obtained great contracting for design
It is short, production efficiency is improved, the use of people is met.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
The present embodiment proposes a kind of manufacture craft of graphene carbon nano-tube film, comprising the following steps:
S1: after configured ethyl alcohol, thiophene, ferrocene raw material liq are ultrasonically treated using ultrasonic equipment, ethyl alcohol, thiophene
Pheno, ferrocene raw material liq are conveyed in CVD tube furnace by syringe pump again, and then the inside of CVD tube furnace is passed through hydrogen and argon
Gas, the inside of CVD tube furnace build the atmosphere of hydrogen and argon gas, and the internal temperature of CVD tube furnace is set as 1200 DEG C,
CVD tube furnace 1200 DEG C at a temperature of the mixture of its inside is heated, obtained at the discharging of CVD tube furnace cotton-shaped
Graphene carbon nano tube line；
Cotton-shaped graphene carbon nano tube line described in S2:S1 is under the promotion of the mixed gas of hydrogen and argon gas, cotton-shaped graphene
Carbon nano tube line is wound on cabinet collection cylinder after the ceramic tube of CVD tube furnace, until cotton-shaped graphene carbon is received
The winding thickness of mitron line reaches 3 centimetres or more；
S3: the cabinet collection cylinder that flocculence graphene carbon nano tube line is wound with described in S2 is moved to flat bench
On, and the flocculence graphene carbon nano tube line wound on the outside of cabinet collection cylinder is compacted on flat bench,
Then watering can carries out uniformly spraying ethyl alcohol on flocculence graphene carbon nano tube line, recycles cutter by graphene carbon nanotube
Line carries out cutting on the outside of cabinet collection cylinder and removes, and is placed on flat bench and carries out rotary flat pressure compacting, finally
Obtain graphene carbon nano-tube film.
Embodiment two
The present embodiment proposes a kind of manufacture craft of graphene carbon nano-tube film, comprising the following steps:
S1: after configured ethyl alcohol, thiophene, ferrocene raw material liq are ultrasonically treated using ultrasonic equipment, ethyl alcohol, thiophene
Pheno, ferrocene raw material liq are conveyed in CVD tube furnace by syringe pump again, and then the inside of CVD tube furnace is passed through hydrogen and argon
Gas, the inside of CVD tube furnace build the atmosphere of hydrogen and argon gas, and the internal temperature of CVD tube furnace is set as 1250 DEG C,
CVD tube furnace 1250 DEG C at a temperature of the mixture of its inside is heated, obtained at the discharging of CVD tube furnace cotton-shaped
Graphene carbon nano tube line；
Cotton-shaped graphene carbon nano tube line described in S2:S1 is under the promotion of the mixed gas of hydrogen and argon gas, cotton-shaped graphene
Carbon nano tube line is wound on cabinet collection cylinder after the ceramic tube of CVD tube furnace, until cotton-shaped graphene carbon is received
The winding thickness of mitron line reaches 3 centimetres or more；
S3: the cabinet collection cylinder that flocculence graphene carbon nano tube line is wound with described in S2 is moved to flat bench
On, and the flocculence graphene carbon nano tube line wound on the outside of cabinet collection cylinder is compacted on flat bench,
Then watering can carries out uniformly spraying ethyl alcohol on flocculence graphene carbon nano tube line, recycles cutter by graphene carbon nanotube
Line carries out cutting on the outside of cabinet collection cylinder and removes, and is placed on flat bench and carries out rotary flat pressure compacting, finally
Obtain graphene carbon nano-tube film.
Embodiment three
The present embodiment proposes a kind of manufacture craft of graphene carbon nano-tube film, comprising the following steps:
S1: after configured ethyl alcohol, thiophene, ferrocene raw material liq are ultrasonically treated using ultrasonic equipment, ethyl alcohol, thiophene
Pheno, ferrocene raw material liq are conveyed in CVD tube furnace by syringe pump again, and then the inside of CVD tube furnace is passed through hydrogen and argon
Gas, the inside of CVD tube furnace build the atmosphere of hydrogen and argon gas, and the internal temperature of CVD tube furnace is set as 1300 DEG C,
CVD tube furnace 1300 DEG C at a temperature of the mixture of its inside is heated, obtained at the discharging of CVD tube furnace cotton-shaped
Graphene carbon nano tube line；
Cotton-shaped graphene carbon nano tube line described in S2:S1 is under the promotion of the mixed gas of hydrogen and argon gas, cotton-shaped graphene
Carbon nano tube line is wound on cabinet collection cylinder after the ceramic tube of CVD tube furnace, until cotton-shaped graphene carbon is received
The winding thickness of mitron line reaches 3 centimetres or more；
S3: the cabinet collection cylinder that flocculence graphene carbon nano tube line is wound with described in S2 is moved to flat bench
On, and the flocculence graphene carbon nano tube line wound on the outside of cabinet collection cylinder is compacted on flat bench,
Then watering can carries out uniformly spraying ethyl alcohol on flocculence graphene carbon nano tube line, recycles cutter by graphene carbon nanotube
Line carries out cutting on the outside of cabinet collection cylinder and removes, and is placed on flat bench and carries out rotary flat pressure compacting, finally
Obtain graphene carbon nano-tube film.
To the manufacture craft of graphene carbon nano-tube film made from embodiment one to three, it is shown that the experimental data are shown in the following table:
By above table it is found that a kind of production efficiency of the manufacture craft of graphene carbon nano-tube film proposed by the present invention obtains
The raising increased, and the production time obtained great shortening, wherein implementing two is most preferred embodiment.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (3)
1. a kind of manufacture craft of graphene carbon nano-tube film, which comprises the following steps:
S1: after configured ethyl alcohol, thiophene, ferrocene raw material liq are ultrasonically treated using ultrasonic equipment, ethyl alcohol, thiophene
Pheno, ferrocene raw material liq are conveyed in CVD tube furnace by syringe pump again, and then the inside of CVD tube furnace is passed through hydrogen and argon
Gas, the inside of CVD tube furnace build the atmosphere of hydrogen and argon gas, and the internal temperature of CVD tube furnace is set as 1200-
1300 DEG C, CVD tube furnace 1200-1300 DEG C at a temperature of the mixture of its inside is heated, CVD tube furnace go out
Cotton-shaped graphene carbon nano tube line is obtained at material；
Cotton-shaped graphene carbon nano tube line described in S2:S1 is under the promotion of the mixed gas of hydrogen and argon gas, cotton-shaped graphene
Carbon nano tube line is wound on cabinet collection cylinder after the ceramic tube of CVD tube furnace, until cotton-shaped graphene carbon is received
The winding thickness of mitron line reaches 3 centimetres or more；
S3: the cabinet collection cylinder that flocculence graphene carbon nano tube line is wound with described in S2 is moved to flat bench
On, and the flocculence graphene carbon nano tube line wound on the outside of cabinet collection cylinder is compacted on flat bench,
Then spray appliance carries out uniformly spraying ethyl alcohol on flocculence graphene carbon nano tube line, recycles cutting equipment by graphene
Carbon nano tube line carries out cutting on the outside of cabinet collection cylinder and removes, and is placed on flat bench and carries out rotary flat pressure pressure
It is real, finally obtain graphene carbon nano-tube film.
2. a kind of manufacture craft of graphene carbon nano-tube film according to claim 1, which is characterized in that the S3
In, cutting equipment is cutter or laser cutting.
3. a kind of manufacture craft of graphene carbon nano-tube film according to claim 1, which is characterized in that the S3
In, spray appliance is watering can, nozzle etc..
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101830455A (en) * | 2010-04-30 | 2010-09-15 | 北京航空航天大学 | Method for synthesizing continuous carbon nanometer tube film |
| RU2012151993A (en) * | 2012-12-05 | 2014-06-10 | Федеральное государственное бюджетное научное учреждение "Технологический институт сверхтвердых и новых углеродных материалов" (ФГБНУ ТИСНУМ) | METHOD FOR PRODUCING MATERIAL BASED ON CARBON NANOTUBES |
| CN105000542A (en) * | 2015-04-27 | 2015-10-28 | 中国科学院重庆绿色智能技术研究院 | Preparation method for graphene-carbon nano tube three-dimensional structure composite material |
| CN105439119A (en) * | 2015-12-02 | 2016-03-30 | 苏州捷迪纳米科技有限公司 | Vertical continuous preparing device for carbon nano tube fibers and preparing method |
| CN106783217A (en) * | 2017-01-16 | 2017-05-31 | 天津大学 | Method for efficiently preparing nitrogen-doped graphene carbon nanotube film |
| CN108264038A (en) * | 2018-02-26 | 2018-07-10 | 陕西科技大学 | A kind of method that simple and direct batch prepares large scale carbon nano tube/graphene hybrid |
-
2019
- 2019-03-04 CN CN201910158584.8A patent/CN109704310A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101830455A (en) * | 2010-04-30 | 2010-09-15 | 北京航空航天大学 | Method for synthesizing continuous carbon nanometer tube film |
| RU2012151993A (en) * | 2012-12-05 | 2014-06-10 | Федеральное государственное бюджетное научное учреждение "Технологический институт сверхтвердых и новых углеродных материалов" (ФГБНУ ТИСНУМ) | METHOD FOR PRODUCING MATERIAL BASED ON CARBON NANOTUBES |
| CN105000542A (en) * | 2015-04-27 | 2015-10-28 | 中国科学院重庆绿色智能技术研究院 | Preparation method for graphene-carbon nano tube three-dimensional structure composite material |
| CN105439119A (en) * | 2015-12-02 | 2016-03-30 | 苏州捷迪纳米科技有限公司 | Vertical continuous preparing device for carbon nano tube fibers and preparing method |
| CN106783217A (en) * | 2017-01-16 | 2017-05-31 | 天津大学 | Method for efficiently preparing nitrogen-doped graphene carbon nanotube film |
| CN108264038A (en) * | 2018-02-26 | 2018-07-10 | 陕西科技大学 | A kind of method that simple and direct batch prepares large scale carbon nano tube/graphene hybrid |
Non-Patent Citations (1)
| Title |
|---|
| 李清文等: "《碳纳米管纤维》", 31 July 2018, 国防工业出版社 * |
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