CN109698198A - A kind of semiconductor devices and preparation method thereof - Google Patents

A kind of semiconductor devices and preparation method thereof Download PDF

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Publication number
CN109698198A
CN109698198A CN201710995782.0A CN201710995782A CN109698198A CN 109698198 A CN109698198 A CN 109698198A CN 201710995782 A CN201710995782 A CN 201710995782A CN 109698198 A CN109698198 A CN 109698198A
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China
Prior art keywords
fin
ion
ion implanting
semiconductor substrate
side wall
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CN201710995782.0A
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Chinese (zh)
Inventor
赵猛
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Semiconductor Manufacturing International Shanghai Corp
Semiconductor Manufacturing International Beijing Corp
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Semiconductor Manufacturing International Shanghai Corp
Semiconductor Manufacturing International Beijing Corp
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Priority to CN201710995782.0A priority Critical patent/CN109698198A/en
Publication of CN109698198A publication Critical patent/CN109698198A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/823431MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type with a particular manufacturing method of transistors with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
    • H01L27/04Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
    • H01L27/08Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind
    • H01L27/085Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only
    • H01L27/088Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate
    • H01L27/0886Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate including transistors with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66787Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
    • H01L29/66795Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • H01L29/66803Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET with a step of doping the vertical sidewall, e.g. using tilted or multi-angled implants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66787Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
    • H01L29/66795Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • H01L29/66818Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET the channel being thinned after patterning, e.g. sacrificial oxidation on fin

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The present invention provides a kind of semiconductor devices and preparation method thereof, which comprises provides semiconductor substrate, forms multiple fins on the semiconductor substrate;Isolation structure is formed in gap between the fin, the top surface of the isolation structure is lower than the top surface of the fin, to expose a part of the fin;First ion implanting is executed to the side wall of the fin of exposing;The side wall for the fin that etching removal part is exposed, to reduce the width of the exposed portion of the fin;Second ion implanting is executed to the fin of exposing, to form buffering diffusion layer in the fin.The production method of the semiconductor devices provided according to the present invention, etching removes the side wall for the fin that part is exposed to reduce its width after executing the first ion implanting by the side wall to fin, then the second ion implanting is executed to form buffering diffusion layer in the fin to the fin of exposing, to overcome short-channel effect, Exchange Settlement is avoided to reveal, the performance and yield of semiconductor devices are improved.

Description

A kind of semiconductor devices and preparation method thereof
Technical field
The present invention relates to technical field of semiconductors, in particular to a kind of semiconductor devices and preparation method thereof.
Background technique
Main devices metal-with the development of semiconductor technology, in integrated circuit especially super large-scale integration The geometric dimension of Oxide-Semiconductor Field effect transistor (MOSFET) is constantly reducing always, the feature ruler of semiconductor devices It is very little to have narrowed down to Nano grade.Semiconductor devices is under this characteristic size, the method for conventional planar production semiconductor devices It can not be applicable in.Then there has been proposed various novel semiconductor device structures, wherein fin formula field effect transistor It (FinFET) is advanced semiconductor device structure for 22nm and following process node, relative to existing planar transistor, FinFET has more superior performance in terms of channel controls and reduces.
However as fin formula field effect transistor (FinFET) critical dimension reduction to 7nm~14nm process node, it is short Channelling effect (SCE) is increasingly severe, also becomes its increasing challenge to the control of short-channel effect using doping process. In order to overcome this problem, various manufacturing process are attempted in semiconductor fabrication, such as ultra-shallow junctions, abrupt junction, pre-amorphous note Enter (PAI), stress technique etc. for optimizing LDD and halo doping profile to improve device performance, but in performance and short channel Balance is obtained between effect increasingly becomes a big problem, meanwhile, these methods cannot all completely eliminate short-channel effect.This Outside, FinFET is separated between each fin using isolation structure, in order to preferably overcome short-channel effect to mention Being isolated between high fin and between fin and substrate, although this can further overcome short-channel effect, due to fin The doping concentration of piece is higher than substrate, and for the ease of being subsequently formed contact, fin source-drain electrode meeting selective epitaxy technique is to grow The source-drain electrode of biggish contact area is formed, in this way since substrate area doping concentration corresponding below fin is low, is be easy to cause Diffusion from top to bottom results in knot leakage problem.
Therefore, it is necessary to which the production method for proposing a kind of new semiconductor devices, above-mentioned to solve the problems, such as.
Summary of the invention
A series of concept of reduced forms is introduced in Summary, this will in the detailed description section into One step is described in detail.Summary of the invention is not meant to attempt to limit technical solution claimed Key feature and essential features do not mean that the protection scope for attempting to determine technical solution claimed more.
The present invention provides a kind of production method of semiconductor devices, comprising the following steps:
Semiconductor substrate is provided, forms multiple fins on the semiconductor substrate;
Isolation structure is formed in gap between the fin, the top surface of the isolation structure is lower than the top of the fin Face, to expose a part of the fin;
First ion implanting is executed to the side wall of the fin of exposing;
The side wall for the fin that etching removal part is exposed, to reduce the width of the exposed portion of the fin;
Second ion implanting is executed to the fin of exposing, to form buffering diffusion layer in the fin.
Further, the step of forming multiple fins on the semiconductor substrate include:
The hard mask layer with fin pattern is formed on the semiconductor substrate;
The part semiconductor substrate is removed by mask etch of the hard mask layer, to form multiple fins.
Further, the step of forming the isolation structure in the gap between the fin include:
Depositing isolation material layer, with the gap being filled up completely between the fin;
It is etched back to the spacer material layer, to form isolation structure.
It further, further include removing the hard mask layer and execution third ion implanting after executing the second ion implanting The step of with adjusting threshold voltage.
Further, the ion of first ion implanting injection include carbon ion and boron ion or carbon ion and phosphorus from Son.
Further, the implant angle of first ion implanting is 0 °~5 °, the energy of ion implanting be 5keV~ 20keV, the dosage of ion implanting are 5E12atom/cm2~5E13atom/cm2
Further, the ion of the second ion implanting injection includes carbon ion and Nitrogen ion, germanium ion and Nitrogen ion, carbon Ion and germanium ion, carbon ion or germanium ion.
Further, the implant angle of second ion implanting is 10 °~20 °, the energy of ion implanting be 5keV~ 20keV, the dosage of ion implanting are 5E13atom/cm2~5E14atom/cm2
Further, the buffering diffusion layer is formed in the bottom of the fin exposed portion and on the side wall of bottom.
Further, the side wall for the fin that removal part is exposed is etched using wet-etching technology.
The present invention also provides a kind of semiconductor devices, comprising:
Semiconductor substrate is formed with multiple fins in the semiconductor substrate;
Isolation structure is formed in gap between the fin, the top surface of the isolation structure is lower than the top of the fin Face, to expose a part of the fin;
The width of the fin exposed portion is less than the width of non-exposed portion;
Buffering diffusion layer is formed in the fin.
Further, the Doped ions of the buffering diffusion layer include carbon ion and Nitrogen ion, germanium ion and Nitrogen ion, carbon from Son and germanium ion, carbon ion or germanium ion.
Further, the buffering diffusion layer is formed in the bottom of the fin exposed portion and on the side wall of bottom.
The production method of the semiconductor devices provided according to the present invention executes the first ion implanting by the side wall to fin The side wall for the fin that etching removal part is exposed afterwards to reduce its width, then to the fin of exposing execute second from Son injection improves semiconductor to overcome short-channel effect, Exchange Settlement is avoided to reveal to form buffering diffusion layer in the fin The performance and yield of device.
Detailed description of the invention
The embodiment of the present invention is described in more detail in conjunction with the accompanying drawings, the above and other purposes of the present invention, Feature and advantage will be apparent.Attached drawing is used to provide to further understand the embodiment of the present invention, and constitutes explanation A part of book, is used to explain the present invention together with the embodiment of the present invention, is not construed as limiting the invention.In the accompanying drawings, Identical reference label typically represents same parts or step.
In attached drawing:
Fig. 1 is a kind of schematic flow chart of the production method of semiconductor devices according to an exemplary embodiment of the present invention.
Fig. 2A -2E is the device that the step of method according to an exemplary embodiment of the present invention is successively implemented obtains respectively Schematic cross sectional view.
Specific embodiment
In the following description, a large amount of concrete details are given so as to provide a more thorough understanding of the present invention.So And it is obvious to the skilled person that the present invention may not need one or more of these details and be able to Implement.In other examples, in order to avoid confusion with the present invention, for some technical characteristics well known in the art not into Row description.
It should be understood that the present invention can be implemented in different forms, and should not be construed as being limited to propose here Embodiment.On the contrary, provide these embodiments will make it is open thoroughly and completely, and will fully convey the scope of the invention to Those skilled in the art.In the accompanying drawings, for clarity, the size and relative size in the area Ceng He may be exaggerated.From beginning to end Same reference numerals indicate identical element.
It should be understood that when element or layer be referred to " ... on ", " with ... it is adjacent ", " being connected to " or " being coupled to " it is other When element or layer, can directly on other elements or layer, it is adjacent thereto, be connected or coupled to other elements or layer, or There may be elements or layer between two parties by person.On the contrary, when element is referred to as " on directly existing ... ", " with ... direct neighbor ", " directly It is connected to " or " being directly coupled to " other elements or when layer, then there is no elements or layer between two parties.It should be understood that although can make Various component, assembly units, area, floor and/or part are described with term first, second, third, etc., these component, assembly units, area, floor and/ Or part should not be limited by these terms.These terms be used merely to distinguish a component, assembly unit, area, floor or part with it is another One component, assembly unit, area, floor or part.Therefore, do not depart from present invention teach that under, first element discussed below, portion Part, area, floor or part are represented by second element, component, area, floor or part.
Spatial relation term for example " ... under ", " ... below ", " below ", " ... under ", " ... it On ", " above " etc., herein can for convenience description and being used describe an elements or features shown in figure with The relationship of other elements or features.It should be understood that spatial relation term intention further includes making other than orientation shown in figure With the different orientation with the device in operation.For example, then, being described as " under other elements if the device in attached drawing is overturn Face " or " under it " or " under it " elements or features will be oriented in other elements or features "upper".Therefore, exemplary art Language " ... below " and " ... under " it may include upper and lower two orientations.Device can additionally be orientated (be rotated by 90 ° or its It is orientated) and spatial description language as used herein correspondingly explained.
The purpose of term as used herein is only that description specific embodiment and not as limitation of the invention.Make herein Used time, " one " of singular, "one" and " described/should " be also intended to include plural form, unless the context clearly indicates separately Outer mode.It is also to be understood that term " composition " and/or " comprising ", when being used in this specification, determines the feature, whole The presence of number, step, operations, elements, and/or components, but be not excluded for one or more other features, integer, step, operation, The presence or addition of component, assembly unit and/or group.Herein in use, term "and/or" includes any of related listed item and institute There is combination.
In order to thoroughly understand the present invention, detailed step and detailed structure will be proposed in following description, so as to Illustrate technical solution proposed by the present invention.Presently preferred embodiments of the present invention is described in detail as follows, however in addition to these detailed descriptions Outside, the present invention can also have other embodiments.
As the critical dimension reduction of fin formula field effect transistor (FinFET) is to 7nm~14nm process node, short channel Effect (SCE) is increasingly severe, also becomes its increasing challenge to the control of short-channel effect using doping process.In order to Overcome this problem, various manufacturing process are attempted in semiconductor fabrication, such as ultra-shallow junctions, abrupt junction, pre-amorphous injection (PAI), stress technique etc. improves device performance for optimizing LDD and halo doping profile, but imitates in performance and short channel Balance is obtained between answering increasingly becomes a big problem, meanwhile, these methods cannot all completely eliminate short-channel effect.This Outside, FinFET is separated between each fin using isolation structure, in order to preferably overcome short-channel effect to mention Being isolated between high fin and between fin and substrate, although this can further overcome short-channel effect, due to fin The doping concentration of piece is higher than substrate, and for the ease of being subsequently formed contact, fin source-drain electrode meeting selective epitaxy technique is to grow The source-drain electrode of biggish contact area is formed, in this way since substrate area doping concentration corresponding below fin is low, is be easy to cause Diffusion from top to bottom results in knot leakage problem.
Therefore, it is necessary to which the production method for proposing a kind of new semiconductor devices, above-mentioned to solve the problems, such as.
In view of the above deficiencies, the present invention provides a kind of production method of semiconductor devices, comprising:
Semiconductor substrate is provided, forms multiple fins on the semiconductor substrate;
Isolation structure is formed in gap between the fin, the top surface of the isolation structure is lower than the top of the fin Face, to expose a part of the fin;
First ion implanting is executed to the side wall of the fin of exposing;
The side wall for the fin that etching removal part is exposed, to reduce the width of the exposed portion of the fin;
Second ion implanting is executed to the fin of exposing, to form buffering diffusion layer in the fin.
Wherein, the step of forming multiple fins on the semiconductor substrate includes: to be formed on the semiconductor substrate Hard mask layer with fin pattern;The part semiconductor substrate is removed by mask etch of the hard mask layer, to be formed Multiple fins.The step of forming the isolation structure in gap between the fin includes: depositing isolation material layer, with complete Gap between fin described in full packing;It is etched back to the spacer material layer, to form isolation structure.Executing the second ion note Further include the steps that removing the hard mask layer after entering and executes third ion implanting with adjusting threshold voltage.Described first from The ion of son injection injection includes carbon ion and boron ion or carbon ion and phosphonium ion.The injection of first ion implanting Angle is 0 °~5 °, and the energy of ion implanting is 5keV~20keV, and the dosage of ion implanting is 5E12atom/cm2~ 5E13atom/cm2.The ion of second ion implanting injection include carbon ion and Nitrogen ion, germanium ion and Nitrogen ion, carbon from Son and germanium ion, carbon ion or germanium ion.The implant angle of second ion implanting is 10 °~20 °, the energy of ion implanting Amount is 5keV~20keV, and the dosage of ion implanting is 5E13atom/cm2~5E14atom/cm2.The buffering diffusion layer is formed On bottom in the fin exposed portion and the side wall close to bottom.Etch what removal part was exposed using wet-etching technology The side wall of the fin.
The production method of the semiconductor devices provided according to the present invention executes the first ion implanting by the side wall to fin The side wall for the fin that etching removal part is exposed afterwards to reduce its width, then to the fin of exposing execute second from Son injection improves semiconductor to overcome short-channel effect, Exchange Settlement is avoided to reveal to form buffering diffusion layer in the fin The performance and yield of device.
Below with reference to Fig. 1 and Fig. 2A -2E, wherein Fig. 1 is a kind of semiconductor devices according to an exemplary embodiment of the present invention Production method schematic flow chart;Fig. 2A -2E is the step of method according to an exemplary embodiment of the present invention is successively implemented The schematic cross sectional view of the device obtained respectively.
The present invention provides a kind of preparation method of semiconductor devices, as shown in Figure 1, the key step packet of the preparation method It includes:
Step S101: semiconductor substrate is provided, forms multiple fins on the semiconductor substrate;
Step S102: forming isolation structure in the gap between the fin, the top surface of the isolation structure is lower than institute The top surface of fin is stated, to expose a part of the fin;
Step S103: the first ion implanting is executed to the side wall of the fin of exposing;
Step S104: the side wall for the fin that etching removal part is exposed, to reduce the exposed portion of the fin Width;
Step S105: executing the second ion implanting to the fin of exposing, to form buffering diffusion in the fin Layer.
In the following, being described in detail to the specific embodiment of the production method of semiconductor devices of the invention.
Firstly, executing step S101 provides semiconductor substrate 200 as shown in Figure 2 A, in the semiconductor substrate 200 Form multiple fins 202.
Illustratively, in the present invention the semiconductor substrate 200 can be in the following material being previously mentioned at least one Kind: monocrystalline silicon, silicon-on-insulator (SOI), be laminated on insulator silicon (SSOI), be laminated on insulator SiGe (S-SiGeOI), Germanium on insulator SiClx (SiGeOI) and germanium on insulator (GeOI) etc..In the present invention, the composition material of semiconductor substrate 200 Material selects monocrystalline silicon.
Then, the hard mask layer 201 with fin pattern is formed in the semiconductor substrate 200.
Illustratively, forming hard mask layer 201 on semiconductor substrate 200 can be familiar with using those skilled in the art Various suitable techniques, such as chemical vapor deposition process.The hard mask layer 201 can be the oxidation being laminated from bottom to top Nitride layer and silicon nitride layer, the present invention in, hard mask layer 201 be silicon nitride layer.The hard mask layer 201 is patterned, formation is used for Semiconductor substrate 200 is etched to be formed on multiple exposure masks being isolated from each other of fin, in the present invention, using photoetching process Implement the patterning process.
It then, is that mask etch removes the part semiconductor substrate 200 with the hard mask layer 201, it is multiple to be formed Fin 202.
Illustratively, semiconductor substrate 200 can be etched using dry etch process or wet-etching technology.Wherein, Dry method etch technology includes but is not limited to: reactive ion etching (RIE), ion beam milling, plasma etching or laser are cut It cuts.In the present invention, using plasma etching technics, the etching gas used is based on oxygen (O2- based) gas, The range of flow of etching gas can be 50 cc/mins (sccm)~150 cc/min (sccm), in reaction chamber Pressure can be 5 millitorrs (mTorr)~20 millitorr (mTorr).In addition, the etching gas of dry etching can also be bromination hydrogen Body, carbon tetrafluoride gas or gas of nitrogen trifluoride.It should be noted that above-mentioned engraving method is only exemplary, not office Limit and this method, those skilled in the art can also select other common methods.
Next, executing step S102, as shown in Figure 2 B, isolation structure 203, the isolation junction are formed in the gap The top surface of structure 203 is lower than the top surface of the fin 202, to expose a part of the fin 202.Specifically, formed it is described every It include: depositing isolation material layer 203 ' from the step of structure 203, with the gap being filled up completely between the fin 202;It is etched back to The spacer material layer 203 ', to form isolation structure 203.The isolation structure 203 of formation can be shallow trench isolation (STI) knot Structure.
Illustratively, the spacer material layer 203 ' can be any insulating materials with buffer action, such as aoxidize Silicon, silicon oxynitride (SiON) etc., in the present invention, spacer material layer 203 ' are silicon oxide layer.Those skilled in the art can be used Any deposition method known to member forms the spacer material layer 203 ', including but not limited to chemical vapour deposition technique (CVD), physics Vapour deposition process (PVD) or atomic layer deposition method (ALD) etc..In the present invention, the chemical vapor deposition with flowability is selected It is deposited described in product (FCVD) process implementing.Further, it the spacer material layer 203 ' fills up between fin 202 gap simultaneously overflows Out, the top surface of post-depositional spacer material layer 203 ' is caused to be higher than the top surface of hard mask layer 201, therefore to spacer material layer 203 ' Surface planarized, flush the top surface of spacer material layer 203 ' and the top surface of hard mask layer 201, which can To use chemical mechanical grinding (CMP) technique.
Illustratively, it is etched back to the spacer material layer 203 ', to form isolation structure 203, the isolation structure 203 Top surface is lower than the top surface of the fin 202, to expose a part of the fin 202.SiCoNi can be used by being etched back to technique Etching or dry etching etc..Wherein, when carrying out SiCoNi etching, SiCoNi etching in situ or ex situ SiCoNi can be selected Common dry etching can be used in dry etching by etching silicon of making a return journey;Also it can control etching intensity, use is low The dry etching (soft dry etch) of bias low-power, to avoid excessive etching is caused to spacer material layer 203 '.It needs What is illustrated is that above-mentioned engraving method is only exemplary, and limitation and this method, those skilled in the art can also not select Other common methods.
Next, executing step S103, referring to Fig. 2 C, the first ion note is executed to the side wall of the fin 202 of exposing Enter.
Illustratively, the ion that first ion implanting is injected into the side wall of 202 exposed portion of fin includes Carbon ion and p-type doping ion (such as boron ion, gallium ion) or carbon ion and n-type doping ion (such as phosphonium ion, arsenic ion). Specifically, in PMOS area, the injection ion of first ion implanting is carbon ion and boron ion, described in NMOS area The injection ion of first ion implanting is carbon ion and phosphonium ion.Wherein, the implant angle of first ion implanting be 0 °~ 5 °, the energy of ion implanting is 5keV~20keV, and the dosage of ion implanting is 5E12atom/cm2~5E13atom/cm2.Pass through On the one hand the first ion implanting step improves the homogeneity and controllability of subsequent fin etch process, on the other hand, carbon The injection of ion can inhibit the transient enhanced diffusion (TED) of silicon substrate intermediate ion, to overcome short-channel effect.
Next, step S104 is executed, the side wall for the fin 202 that etching removal part is exposed, to reduce the fin The width of the exposed portion of piece 202.
Illustratively, the side wall of the exposed portion of the fin 202 is etched using wet-etching technology.It specifically, can be with The silicon fin is etched using the mixed solvent of nitric acid and hydrofluoric acid, so as to reach target wide for the width of the fin 202 after etching Degree.The width that fin 202 after etching is higher than the part (i.e. exposed portion) of 203 ' top surface of spacer material layer is less than lower than isolation The width of the part (i.e. non-exposed portion) of 203 ' top surface of material layer, the fin 202 form " convex " font structure.
Next, executing step S105, as shown in Figure 2 D, the second ion implanting is executed to the fin 202 of exposing, with Buffering diffusion layer 204 is formed in the fin 202.
Illustratively, be that exposure mask executes the second ion implanting to the fin 202 of exposing with hard mask layer 201, with The bottom of 202 exposed portion of fin and the formation buffering diffusion layer 204 on the side wall of bottom.The second ion implanting injection Ion include carbon ion and Nitrogen ion, germanium ion and Nitrogen ion, carbon ion and germanium ion, carbon ion or germanium ion.Specifically Ground, being infused in FinFET for ion form buffering diffusion layer 204, to inhibit to be formed semiconductor substrate after source electrode and drain electrode The horizontal proliferation of interior Doped ions (such as boron ion or phosphonium ion), to reduce short-channel effect.Wherein, second ion The implant angle of injection is 10 °~20 °, and the energy of ion implanting is 5keV~20keV, and the dosage of ion implanting is 5E13atom/cm2~5E14atom/cm2.The injection depth of second ion implanting is 1nm~20nm, and concentration is 1E19atom/cm3~5E20atom/cm3
Next, further including removing the hard mask layer 201, third ion implanting is executed with the step of adjusting threshold voltage Suddenly.
Illustratively, hard mask layer 201 can be removed using dry etch process or wet-etching technology.Wherein, it does Method etch process includes but is not limited to: reactive ion etching (RIE), ion beam milling, plasma etching or laser cutting. It should be noted that above-mentioned engraving method is only exemplary, limitation and this method, those skilled in the art can be with Select other common methods.
Illustratively, third ion implanting is executed, with adjusting threshold voltage.The ion packet of the third ion implanting injection Include n-type doping ion or p-type doping ion.Specifically, in PMOS area, the injection ion of the third ion implanting be boron from Son, in NMOS area, the injection ion of the third ion implanting is phosphonium ion.Wherein, the third ion implanting can root According to needing to select vertical ion injection, angle-tilt ion injection or multi-angle ion implanting, in the present invention, using multi-angle from Son injection.
So far, the processing step implemented according to the method for the embodiment of the present invention is completed, it is to be understood that the present embodiment Manufacturing method of semiconductor device not only includes above-mentioned steps, before above-mentioned steps, among or may also include other needs later The step of.
Illustratively, further include the steps that forming source-drain electrode (S/D) and metal gates (MG) after the above step, it can be with The threshold voltage of formed device is further adjusted by work-function layer during forming metal gates.Wherein, gold is formed Belong to gate structure method can use after after high k dielectric layer metal gates formation process and also using first high k dielectric layer after Metal gate process, these process routes are without prejudice to connotation of the invention.
The structure of semiconductor devices provided by the invention is described in 2E with reference to the accompanying drawing.The semiconductor devices packet Include the buffering diffusion layer 204 in semiconductor substrate 200, fin 202, isolation structure 203 and the fin.Wherein:
In the present invention, the semiconductor substrate 200 can be following at least one of the material being previously mentioned: monocrystalline Silicon (SSOI) is laminated on insulator, SiGe (S-SiGeOI) is laminated on insulator, on insulator for silicon, silicon-on-insulator (SOI) SiGe (SiGeOI) and germanium on insulator (GeOI) etc..In the present invention, the constituent material of semiconductor substrate 200 is selected single Crystal silicon.
Multiple fins 202 are formed in the semiconductor substrate 200, the fin 202 includes being higher than the isolation junction The exposed portion of 203 top surface of structure and non-exposed portion lower than 203 top surface of isolation structure.Wherein, the dew of the fin The width of part is less than the width of the non-exposed portion of the fin out.Buffering diffusion layer is formed in the fin 202, it is described The Doped ions buffered in diffusion layer 204 include carbon ion and Nitrogen ion, germanium ion and Nitrogen ion, carbon ion and germanium ion, carbon Ion or germanium ion are formed in the bottom of 202 exposed portion of fin and on the side wall of bottom, to be formed with inhibiting After source electrode and drain electrode in semiconductor substrate Doped ions (such as boron ion or phosphonium ion) horizontal proliferation, to reduce short channel Effect.
For the isolation structure 203 in the gap between the fin, the isolation structure 203 can select any tool There are insulating materials of buffer action, such as silica, silicon oxynitride (SiON) etc., in the present invention, the isolation structure 203 Material is silica.
The production method of the semiconductor devices provided according to the present invention executes the first ion implanting by the side wall to fin The side wall for the fin that etching removal part is exposed afterwards to reduce its width, then to the fin of exposing execute second from Son injection improves semiconductor to overcome short-channel effect, Exchange Settlement is avoided to reveal to form buffering diffusion layer in the fin The performance and yield of device.
The present invention has been explained by the above embodiments, but it is to be understood that, above-described embodiment is only intended to The purpose of citing and explanation, is not intended to limit the invention to the scope of the described embodiments.Furthermore those skilled in the art It is understood that the present invention is not limited to the above embodiments, introduction according to the present invention can also be made more kinds of member Variants and modifications, all fall within the scope of the claimed invention for these variants and modifications.Protection scope of the present invention by The appended claims and its equivalent scope are defined.

Claims (13)

1. a kind of production method of semiconductor devices, which comprises the following steps:
Semiconductor substrate is provided, forms multiple fins on the semiconductor substrate;
Isolation structure is formed in gap between the fin, the top surface of the isolation structure is lower than the top surface of the fin, To expose a part of the fin;
First ion implanting is executed to the side wall of the fin of exposing;
The side wall for the fin that etching removal part is exposed, to reduce the width of the exposed portion of the fin;
Second ion implanting is executed to the fin of exposing, to form buffering diffusion layer in the fin.
2. the method according to claim 1, wherein the step of forming multiple fins on the semiconductor substrate Include:
The hard mask layer with fin pattern is formed on the semiconductor substrate;
The part semiconductor substrate is removed by mask etch of the hard mask layer, to form multiple fins.
3. the method according to claim 1, wherein forming the isolation junction in gap between the fin The step of structure includes:
Depositing isolation material layer, with the gap being filled up completely between the fin;
It is etched back to the spacer material layer, to form isolation structure.
4. according to the method described in claim 2, it is characterized in that, further including that removal is described hard after executing the second ion implanting The step of mask layer and execution third ion implanting are with adjusting threshold voltage.
5. the method according to claim 1, wherein the ion of first ion implanting injection includes carbon ion With boron ion or carbon ion and phosphonium ion.
6. the method according to claim 1, wherein the implant angle of first ion implanting be 0 °~5 °, The energy of ion implanting is 5keV~20keV, and the dosage of ion implanting is 5E12atom/cm2~5E13atom/cm2
7. the method according to claim 1, wherein the ion of second ion implanting injection includes carbon ion With Nitrogen ion, germanium ion and Nitrogen ion, carbon ion and germanium ion, carbon ion or germanium ion.
8. the method according to claim 1, wherein the implant angle of second ion implanting be 10 °~ 20 °, the energy of ion implanting is 5keV~20keV, and the dosage of ion implanting is 5E13atom/cm2~5E14atom/cm2
9. the method according to claim 1, wherein the buffering diffusion layer is formed in the fin exposed portion Bottom and close to bottom side wall on.
10. the method according to claim 1, wherein etching what removal part was exposed using wet-etching technology The side wall of the fin.
11. a kind of semiconductor devices characterized by comprising
Semiconductor substrate is formed with multiple fins in the semiconductor substrate;
Isolation structure is formed in gap between the fin, the top surface of the isolation structure is lower than the top surface of the fin, To expose a part of the fin;
The width of the fin exposed portion is less than the width of non-exposed portion;
Buffering diffusion layer is formed in the fin.
12. semiconductor devices according to claim 11, which is characterized in that it is described buffering diffusion layer Doped ions include Carbon ion and Nitrogen ion, germanium ion and Nitrogen ion, carbon ion and germanium ion, carbon ion or germanium ion.
13. semiconductor devices according to claim 11, which is characterized in that the buffering diffusion layer is formed in the fin On the side wall of the bottom of exposed portion and close bottom.
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