CN109694585A - A kind of high viscosity composite modified asphalt and preparation method thereof - Google Patents
A kind of high viscosity composite modified asphalt and preparation method thereof Download PDFInfo
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- CN109694585A CN109694585A CN201811611194.3A CN201811611194A CN109694585A CN 109694585 A CN109694585 A CN 109694585A CN 201811611194 A CN201811611194 A CN 201811611194A CN 109694585 A CN109694585 A CN 109694585A
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- high viscosity
- modified asphalt
- composite modified
- matrix pitch
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- 239000010426 asphalt Substances 0.000 title claims abstract description 51
- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000011159 matrix material Substances 0.000 claims abstract description 38
- 229920001971 elastomer Polymers 0.000 claims abstract description 31
- 239000005060 rubber Substances 0.000 claims abstract description 31
- 239000002174 Styrene-butadiene Substances 0.000 claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 27
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 25
- 239000003822 epoxy resin Substances 0.000 claims abstract description 24
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 24
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004816 latex Substances 0.000 claims abstract description 21
- 229920000126 latex Polymers 0.000 claims abstract description 21
- 239000011115 styrene butadiene Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 230000035515 penetration Effects 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 15
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 238000010008 shearing Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims 1
- 229940106691 bisphenol a Drugs 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 229920006122 polyamide resin Polymers 0.000 claims 1
- 229920001610 polycaprolactone Polymers 0.000 claims 1
- 239000004632 polycaprolactone Substances 0.000 claims 1
- 239000004566 building material Substances 0.000 abstract description 2
- 239000011295 pitch Substances 0.000 description 47
- 238000001816 cooling Methods 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 230000001932 seasonal effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
The present invention relates to building material technical field, especially a kind of high viscosity composite modified asphalt and preparation method thereof.It includes following raw material component: 500 parts of matrix pitch, 29.1-43.2 parts of rubber powder, 17.0-24.9 parts of carboxylic styrene butadiene latex, 8.7-18.9 parts of polyphosphoric acids, 9.4-17.9 parts of epoxy resin, 9.4-17.9 parts of curing agent.The present invention can be provided simultaneously with outstanding cryogenic property and high-temperature behavior, and have lower needle penetration, and 5 DEG C of ductilities reach 58.7cm, 135 DEG C of kinematic viscosity can be more than 2400mm2/ s, and brittle point is significantly reduced, it can adapt to the performance requirement of summer high temperature and winter frost road surface.
Description
Technical field
The present invention relates to building material technical field, especially a kind of high viscosity composite modified asphalt and preparation method thereof.
Background technique
It is well known that some areas of China's northeastern Inner Mongolia belong to seasonal iced areas, day and night temperature it is larger and
Ultraviolet radiation is serious, and the bituminous pavement in these areas, which exists, to be easy to appear cold cracking and caused because endurance quality is weak
A series of Asphalt Pavement Damages, or even the problem of traffic safety can be seriously affected.In this regard, being proposed in industry to existing pitch
Many improvement projects.
Such as using SBR modified pitch as the scheme of representative, because its cryogenic property is excellent, and there is certain uvioresistant
Aging action and in severe cold, intensive ultraviolet area using more.However, as Chinese invention patent application 201810164122.2 is public
A kind of composite modified asphalt and preparation method thereof suitable for High aititude extremely frigid zones opened, composite modified asphalt component include
SBS modifier 1-3%；Nano-ZnO 1-3%；Sulphur 1-2%；Stabilizer 0.15-0.3%, surplus are SBR modified pitch；Its
By SBS modifier and nano-ZnO being added in SBR modified pitch to improve performance.For another example Chinese invention patent application
A kind of nanoparticle SBR composite modified asphalt disclosed in 201410452130.9, nanoparticle SBR composite modified asphalt is by nanometer
SiO2 particle, butadiene-styrene rubber and matrix pitch composition.According to the record of its specification, with preferable cryogenic property, performance
For its 5 DEG C of ductility about 30.But its high-temperature behavior not on the books.It can be seen from this that the height of these SBR composite modified asphalts
Warm nature can be poor, is not able to satisfy the biggish seasonal freezing region road of day and night temperature and demand is used for a long time.
For another example using rubber modified asphalt as the scheme of representative, resin, the hydrocarbon in pitch are absorbed using waste rubber powder
A variety of organic matters such as class mention wet rubber powder, expansion, viscosity increase, softening point by a series of physical and chemical changes
Height, and the viscosity, toughness, elasticity of rubber and pitch have been taken into account, to improve the pavement performance of rubber asphalt.However, as in
A kind of rubber powder modified asphalt disclosed in state's application for a patent for invention 201810310742.2 and preparation method thereof, raw material are as follows: 30-40
Part rock asphalt, 20-30 parts of polyphosphoric acids, 10-50 parts of rubber powder, 2-3 parts of stabilizer, 1-5 parts of SBS modifier,
1-2 parts of PE modifying agent, 1-10 parts of solubilizer, 1-3 parts of aromatic naphtha, 15 DEG C of ductilities are greater than 160, but are not documented in
Product ductility under lower temperature, does not record its high-temperature behavior yet.For another example Chinese invention patent application 201711415343.4
Disclosed a kind of high-viscosity asphalt, consisting of: Styrene-Butadiene-Styrene Block Copolymer (SBS) 3-8%, butadiene-styrene rubber
(SBR) 1-3%, compatilizer 2-10%, stabilizer 0.08-0.3%, dodecyl sodium sulfate 0.5-2%, polyphosphoric acids (PPA)
0.8-1.5%, other is matrix pitch.However, its 5 DEG C of ductilities only about 30, can not adapt to low temp area.It can be seen from this that
Rubber modified asphalt brings a negative impact cryogenic property, increases through the modified asphalt viscosity of polyphosphoric acids, high-temperature behavior have compared with
It is apparent to improve, while temperature sensitivity reduces, but polyphosphoric acids cannot improve the cryogenic property of pitch.
In conclusion existing modified pitch largely only merely improves the high-temperature behavior or low temperature properties of pitch
Energy；Therefore, existing modified pitch for summer temp is higher and seasonal freezing region adaptability that winter temperature is low is poor.
Summary of the invention
In view of the deficiency of the prior art, the first object of the present invention is to provide a kind of high viscosity composite modified
Pitch；Second object of the present invention is to provide a kind of method for preparing high viscosity composite modified asphalt.
To achieve the goals above, first technical solution that the present invention uses are as follows:
A kind of high viscosity composite modified asphalt, it includes following raw material component:
500 parts of matrix pitch, 29.1-43.2 parts of rubber powder, 17.0-24.9 parts of carboxylic styrene butadiene latex, polyphosphoric acids 8.7-
18.9 parts, 9.4-17.9 parts of epoxy resin, 9.4-17.9 parts of curing agent；Wherein, rubber powder can be according to the actual situation with waste and old wheel
Tire is raw material, is obtained after pulverizing and sieving, and polyphosphoric acids then use industrial raw material standard (phosphorus pentoxide content >=
85wt%, molecular weight 81.99580).
Preferably, it is grouped as by following raw material group: 500 parts of matrix pitch, 41.7-43.2 parts of rubber powder, carboxylic
17.0-24.9 parts of base styrene-butadiene latex, 10.0-10.3 parts of polyphosphoric acids, 9.4-14.1 parts of epoxy resin, curing agent 9.4-14.1
Part.
Preferably, the matrix pitch be No. 90 matrix pitches, 25 DEG C of needle penetration 85dmm, 54.2 DEG C of softening point.
Preferably, the mesh number of the rubber powder is 60 mesh.
Preferably, the solid content of the carboxylic styrene butadiene latex is 48%.
Preferably, the epoxy resin is bisphenol A type epoxy resin, as the source De Lutai epoxy Science and Technology Ltd. produces
E-44 (6101) type epoxy resin, viscosity are 25 DEG C: 6-10Pa.S.
Preferably, the curing agent is and the preferably low molecule pa resin selected from polyamide.Such as moral Shandong, Shandong
650 low molecule pa resins of Tai Yuan epoxy Science and Technology Ltd. production.
Second technical solution that the present invention uses are as follows:
A method of preparing a kind of above-mentioned high viscosity composite modified asphalt, it the following steps are included:
S1 raw material preparation
Matrix pitch, rubber powder, carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and solidification are weighed by weight ratio
Agent；
The pretreatment of S2 matrix pitch
Matrix pitch is placed in high-speed shearing machine, being heated to 140-160 DEG C makes matrix pitch in molten state, shear rate
To shear 10-20min under 2500-3500r/min；
Rubber powder is added into the matrix pitch handled through step S2 and in 170-180 DEG C, shear rate 4500- by S3
30-40min is sheared under 5500r/min；Then carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent are sequentially added
And 39-51min is sheared at 170-180 DEG C, shear rate 4500-5500r/min, asphalt mixture can be obtained；
S4, the asphalt mixture as made from step S3 is kept the temperature into 30-50min at 130-140 DEG C, high viscosity can be obtained
Composite asphalt.
As the above scheme is adopted, composite modified asphalt of the invention can be provided simultaneously with outstanding cryogenic property and high temperature
Performance, and have lower needle penetration, 5 DEG C of ductilities reach 58.7cm, 135 DEG C of kinematic viscosity can be more than 2400mm2/ s, and have
Brittle point is reduced to effect, can adapt to the performance requirement of summer high temperature and winter frost road surface.
Specific embodiment
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover
Multitude of different ways is implemented.
Embodiment 1
S1, weigh raw material: No. 90 500 parts of matrix pitches, 29.8 parts of the rubber powder that mesh number is 60 purposes, solidification amount are
48% 20.8 parts of carboxylic styrene butadiene latex, 18.9 parts of polyphosphoric acids, the bisphenol A type epoxy resin for meeting industrial raw material standard
17.9 parts, 17.9 parts of low molecule pa resin curing agent.
S2, matrix pitch pretreatment: matrix pitch is placed in high-speed shearing machine, being heated to 150 DEG C makes the matrix pitch be in
Molten state, shear rate are to shear 10min under 3000r/min；
S3, rubber powder is added into the matrix pitch handled through step S2 and at 175 DEG C, shear rate 5000r/min
Shear 30min；Then carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent are sequentially added and continues to shear
45min obtains asphalt mixture.
S4, the asphalt mixture as made from step S3 is placed in insulating box, after keeping the temperature 30min at 135 DEG C, then through certainly
Right cooling treatment, can be obtained high viscosity composite asphalt.
Embodiment 2
S1, weigh raw material: No. 90 500 parts of matrix pitches, 29.1 parts of the rubber powder that mesh number is 60 purposes, solidification amount are
48% 20.3 parts of carboxylic styrene butadiene latex, 18.7 parts of polyphosphoric acids, the bisphenol A type epoxy resin for meeting industrial raw material standard
11.6 parts, 11.6 parts of low molecule pa resin curing agent.
S2, matrix pitch is placed in high-speed shearing machine, being heated to 140 DEG C makes matrix pitch in molten state, shear rate
To shear 20min under 2500r/min.
S3, rubber powder is added into the matrix pitch handled through step S2 and at 170 DEG C, shear rate 4800r/min
Shear 35min；Then carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent are sequentially added and continues to shear
45min obtains asphalt mixture.
S4, the drip of the asphalt mixture as made from step S3 is placed in insulating box, after keeping the temperature 35min at 130 DEG C, then is passed through
After natural cooling processing, high viscosity composite asphalt can be obtained.
Embodiment 3
S1, weigh raw material: No. 90 500 parts of matrix pitches, 43.2 parts of the rubber powder that mesh number is 60 purposes, solidification amount are
48% 24.9 parts of carboxylic styrene butadiene latex, 10.3 parts of polyphosphoric acids, the bisphenol A type epoxy resin for meeting industrial raw material standard
14.9 parts, 14.9 parts of low molecule pa resin curing agent.
S2, matrix pitch is placed in high-speed shearing machine, being heated to 140 DEG C makes matrix pitch in molten state, shear rate
To shear 12min under 2500r/min.
S3, rubber powder is added into the matrix pitch handled through step S2 and at 170 DEG C, shear rate 5500r/min
Shear 30min；Then carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent are sequentially added and continues to shear
40min obtains asphalt mixture.
S4, the drip of the asphalt mixture as made from step S3 is placed in insulating box, after keeping the temperature 30min at 140 DEG C, then is passed through
After natural cooling processing, high viscosity composite asphalt can be obtained.
Embodiment 4
Then rubber powder is added, shears 30min at 170 DEG C, shear rate 5000r/min, then sequentially adds carboxylic
Base butadiene-styrene latex, polyphosphoric acids, epoxy resin and curing agent continue to shear 42min, obtain asphalt mixture.
Asphalt mixture is placed in insulating box, 30min is kept the temperature at 135 DEG C, obtains high viscosity composite asphalt after cooling.
S1, weigh raw material: No. 90 500 parts of matrix pitches, 41.7 parts of the rubber powder that mesh number is 60 purposes, solidification amount are
48% 17.0 parts of carboxylic styrene butadiene latex, 10.0 parts of polyphosphoric acids, the bisphenol A type epoxy resin for meeting industrial raw material standard
9.4 parts, 9.4 parts of low molecule pa resin curing agent.
S2, matrix pitch is placed in high-speed shearing machine, being heated to 160 DEG C makes matrix pitch in molten state, shear rate
To shear 12min under 3000r/min.
S3, rubber powder is added into the matrix pitch handled through step S2 and at 180 DEG C, shear rate 5000r/min
Shear 30min；Then carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent are sequentially added and continues to shear
42min obtains asphalt mixture.
S4, the drip of the asphalt mixture as made from step S3 is placed in insulating box, after keeping the temperature 30min at 135 DEG C, then is passed through
After natural cooling processing, high viscosity composite asphalt can be obtained.
Using traditional pitch that any modifying agent is not added as reference examples 1 to be added with modifying rubber powder in the prior art
The pitch of agent is viscous by 25 DEG C of needle penetrations of each example pitch of measurement, softening point, 5 DEG C of ductilities, 135 DEG C of movements as reference examples 2
The indexs such as degree, brittle point embody the performance of each example pitch (each example asphalt performance is shown in Table one)
According to known to table one: composite modified asphalt of the invention is provided simultaneously with outstanding cryogenic property and high-temperature behavior；Especially
It is that the weight of raw material components is 500 parts of matrix pitch, 41.7-43.2 parts of rubber powder, carboxylic styrene butadiene latex 17.0-
When 24.9 parts, 10.0-10.3 parts of polyphosphoric acids, 9.4-14.1 parts of epoxy resin, 9.4-14.1 parts of curing agent, 5 DEG C of pitch prolong
Degree and 135 DEG C of kinematic viscosity phenotypes are prominent, are significantly better than the modified pitch of the prior art.Based on this, the embodiment of the present invention is answered
Closing modified pitch can adapt to the performance requirement of summer high temperature and winter frost road surface.
The above description is only a preferred embodiment of the present invention, is not intended to limit the scope of the invention, all utilizations
Equivalent structure or equivalent flow shift made by present specification is applied directly or indirectly in other relevant technologies
Field is included within the scope of the present invention.
Claims (9)
1. a kind of high viscosity composite modified asphalt, it is characterised in that: it includes following raw material component:
500 parts of matrix pitch, 29.1-43.2 parts of rubber powder, 17.0-24.9 parts of carboxylic styrene butadiene latex, polyphosphoric acids 8.7-18.9
Part, 9.4-17.9 parts of epoxy resin, 9.4-17.9 parts of curing agent.
2. a kind of high viscosity composite modified asphalt as described in claim 1, it is characterised in that: it is by following raw material group
It is grouped as: 500 parts of matrix pitch, 41.7-43.2 parts of rubber powder, 17.0-24.9 parts of carboxylic styrene butadiene latex, polyphosphoric acids 10.0-
10.3 parts, 9.4-14.1 parts of epoxy resin, 9.4-14.1 parts of curing agent.
3. a kind of high viscosity composite modified asphalt as described in claim 1, it is characterised in that: the matrix pitch is No. 90 bases
Matter pitch, 25 DEG C of needle penetration 85dmm, 54.2 DEG C of softening point.
4. a kind of high viscosity composite modified asphalt as described in claim 1, it is characterised in that: the mesh number of the rubber powder is 60
Mesh.
5. a kind of high viscosity composite modified asphalt as described in claim 1, it is characterised in that: the carboxylic styrene butadiene latex is consolidated
Content is 48%.
6. a kind of high viscosity composite modified asphalt as described in claim 1, it is characterised in that: the epoxy resin is bisphenol-A
Type epoxy resin.
7. a kind of high viscosity composite modified asphalt as described in claim 1, it is characterised in that: the curing agent is polyamide resin
Rouge.
8. a kind of high viscosity composite modified asphalt as claimed in claim 7, it is characterised in that: the curing agent is low molecular weight polycaprolactone
Amide resin.
9. a kind of prepare such as a kind of method of high viscosity composite modified asphalt of any of claims 1-8, feature
Be: it the following steps are included:
S1, raw material preparation
Matrix pitch, rubber powder, carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent are weighed by weight ratio；
S2, matrix pitch pretreatment
Matrix pitch is placed in high-speed shearing machine, being heated to 140-160 DEG C makes matrix pitch in molten state, and shear rate is
10-20min is sheared under 2500-3500r/min；
S3, rubber powder is added into the matrix pitch handled through step S2 and in 170-180 DEG C, shear rate 4500-5500r/
30-40min is sheared under min；Then sequentially add carboxylic styrene butadiene latex, polyphosphoric acids, epoxy resin and curing agent and
170-180 DEG C, shear 39-51min under shear rate 4500-5500r/min, asphalt mixture can be obtained；
S4, the asphalt mixture as made from step S3 is kept the temperature into 30-50min at 130-140 DEG C, it is compound that high viscosity can be obtained
Pitch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811611194.3A CN109694585A (en) | 2018-12-27 | 2018-12-27 | A kind of high viscosity composite modified asphalt and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811611194.3A CN109694585A (en) | 2018-12-27 | 2018-12-27 | A kind of high viscosity composite modified asphalt and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015250A (en) * | 2021-11-22 | 2022-02-08 | 河北雄安京德高速公路有限公司 | Rubber modified asphalt for long-life pavement, and preparation method, preparation equipment and application thereof |
| NL2028906A (en) | 2020-09-08 | 2022-05-09 | Univ Fuzhou | A high-tenacity modified asphalt with SBS/SBR and polyphosphoric acid and its preparation method |
| CN115323881A (en) * | 2022-07-21 | 2022-11-11 | 北京通途技术有限公司 | Method for repairing sinking of periphery of pavement well cover by cold-mixed epoxy asphalt mixture |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110196073A1 (en) * | 2010-02-11 | 2011-08-11 | Icl Performance Products Lp | Polymer-modified asphalt with a crosslinking agent and methods of preparing |
| CN103865280A (en) * | 2014-03-12 | 2014-06-18 | 长安大学 | Compound modified asphalt and preparation method thereof |
| CN104559232A (en) * | 2013-10-22 | 2015-04-29 | 中国石油化工股份有限公司 | Chemically-modified hard asphalt and preparation method thereof |
| CN107722414A (en) * | 2017-10-31 | 2018-02-23 | 桂林市漓江机电制造有限公司 | A kind of heat-resisting freeze proof modified asphalt material and preparation method thereof |
| CN108129858A (en) * | 2017-12-22 | 2018-06-08 | 中油佳汇防水科技（深圳）股份有限公司 | A kind of modified pitch sizing material and preparation method thereof, waterproof roll |
| CN108410185A (en) * | 2017-12-25 | 2018-08-17 | 甘肃路桥建设集团养护科技有限责任公司 | A kind of high-viscosity asphalt and preparation method thereof |
| CN108517126A (en) * | 2018-03-30 | 2018-09-11 | 中交公局第三工程有限公司 | A kind of rubber powder modified asphalt and preparation method thereof |
| WO2020035403A1 (en) * | 2018-08-15 | 2020-02-20 | Basf Se | Asphalt composition comprising a mixture of an isocyanate and a polymer as performance additives |
-
2018
- 2018-12-27 CN CN201811611194.3A patent/CN109694585A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110196073A1 (en) * | 2010-02-11 | 2011-08-11 | Icl Performance Products Lp | Polymer-modified asphalt with a crosslinking agent and methods of preparing |
| CN104559232A (en) * | 2013-10-22 | 2015-04-29 | 中国石油化工股份有限公司 | Chemically-modified hard asphalt and preparation method thereof |
| CN103865280A (en) * | 2014-03-12 | 2014-06-18 | 长安大学 | Compound modified asphalt and preparation method thereof |
| CN107722414A (en) * | 2017-10-31 | 2018-02-23 | 桂林市漓江机电制造有限公司 | A kind of heat-resisting freeze proof modified asphalt material and preparation method thereof |
| CN108129858A (en) * | 2017-12-22 | 2018-06-08 | 中油佳汇防水科技（深圳）股份有限公司 | A kind of modified pitch sizing material and preparation method thereof, waterproof roll |
| CN108410185A (en) * | 2017-12-25 | 2018-08-17 | 甘肃路桥建设集团养护科技有限责任公司 | A kind of high-viscosity asphalt and preparation method thereof |
| CN108517126A (en) * | 2018-03-30 | 2018-09-11 | 中交公局第三工程有限公司 | A kind of rubber powder modified asphalt and preparation method thereof |
| WO2020035403A1 (en) * | 2018-08-15 | 2020-02-20 | Basf Se | Asphalt composition comprising a mixture of an isocyanate and a polymer as performance additives |
Non-Patent Citations (5)
| Title |
|---|
| 刘登祥 主编: "《橡胶及橡胶制品》", 31 January 1999, 北京：化学工业出版社 * |
| 张涛 等: "多聚磷酸与SBＲ 复合改性沥青混合料性能及改性机理", 《公路工程》 * |
| 梁松 等主编: "《土木工程材料》", 31 August 2007, 广州：华南理工大学出版社 * |
| 陈桂萍 等主编: "《道路建筑材料》", 31 August 2006, 沈阳：东北大学出版社 * |
| 黄伟典 主编: "《建筑材料》", 31 July 2007, 中国电力出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2028906A (en) | 2020-09-08 | 2022-05-09 | Univ Fuzhou | A high-tenacity modified asphalt with SBS/SBR and polyphosphoric acid and its preparation method |
| CN114015250A (en) * | 2021-11-22 | 2022-02-08 | 河北雄安京德高速公路有限公司 | Rubber modified asphalt for long-life pavement, and preparation method, preparation equipment and application thereof |
| CN115323881A (en) * | 2022-07-21 | 2022-11-11 | 北京通途技术有限公司 | Method for repairing sinking of periphery of pavement well cover by cold-mixed epoxy asphalt mixture |
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